JP2001185768A - Peltier module and its manufacturing method - Google Patents

Peltier module and its manufacturing method

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Publication number
JP2001185768A
JP2001185768A JP36556399A JP36556399A JP2001185768A JP 2001185768 A JP2001185768 A JP 2001185768A JP 36556399 A JP36556399 A JP 36556399A JP 36556399 A JP36556399 A JP 36556399A JP 2001185768 A JP2001185768 A JP 2001185768A
Authority
JP
Japan
Prior art keywords
peltier module
reinforcing member
thermoelectric elements
electrodes
thermoelectric element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP36556399A
Other languages
Japanese (ja)
Inventor
Narimasa Iwamoto
成正 岩本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Electric Works Co Ltd
Original Assignee
Matsushita Electric Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Works Ltd filed Critical Matsushita Electric Works Ltd
Priority to JP36556399A priority Critical patent/JP2001185768A/en
Publication of JP2001185768A publication Critical patent/JP2001185768A/en
Withdrawn legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To improve strength without deteriorating cooling performance. SOLUTION: In this Peltier module, parts between adjacent thermoelectric elements 1 are connected by using electrodes 2, and the plurality of thermoelectric elements 1 are electrically connected in series by using the plurality of electrodes 2 in a plane. Reinforcing members 3 which have insulating property and are thermal bad conductor and in contact with side surfaces of the adjacent thermoelectric elements 1, and with which air layers are interposed in spaces to the electrodes 2, are arranged between the respective thermoelectric elements 1. Improvement of strength due to the reinforcing members 3 can be obtained, and at the same time, deterioration of cooling performance which is caused by heat leakage can be restrained by existance of the air layers.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は熱電素子を電気的に
接続して構成したペルチェモジュールとその製造方法に
関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a Peltier module formed by electrically connecting thermoelectric elements and a method of manufacturing the same.

【0002】[0002]

【従来の技術】ペルチェモジュールにおいては、その構
成要素である熱電素子が強度的に非常に脆弱なものであ
るために、モジュールの取り扱い時に衝撃を加えたり、
あるいはモジュールの使用時に熱応力が加わると、熱電
素子及びその電極との界面において破壊が生じてしまう
ことが多々ある。
2. Description of the Related Art In a Peltier module, a thermoelectric element, which is a component of the Peltier module, is very fragile in terms of strength.
Alternatively, if thermal stress is applied during use of the module, breakage often occurs at the interface between the thermoelectric element and its electrode.

【0003】このために、従来より図7に示すように熱
電素子1、1間や電極2間において硬化性の液体樹脂充
填材などの補強樹脂8を充填することでペルチェモジュ
ールの強度向上が試みられている。
For this reason, as shown in FIG. 7, it has been attempted to improve the strength of a Peltier module by filling a reinforcing resin 8 such as a curable liquid resin filler between thermoelectric elements 1 and 1 and between electrodes 2 as shown in FIG. Have been.

【0004】[0004]

【発明が解決しようとする課題】しかし、液状樹脂の充
填硬化により強度補強はできても、充填樹脂によって電
極間で熱漏れが生じて冷却性能が大幅に低下してしまう
問題があった。
However, even though the strength can be reinforced by filling and curing the liquid resin, heat leakage occurs between the electrodes due to the filled resin, resulting in a problem that the cooling performance is greatly reduced.

【0005】また、薄肉の樹脂コーティングを行う補強
も試みられているが、これは十分な補強効果を得ること
ができなかった。
[0005] Reinforcement by thin resin coating has also been attempted, but this has not been able to obtain a sufficient reinforcing effect.

【0006】本発明はこのような点に鑑みなされたもの
であって、その目的とするところは冷却性能の低下を招
くことなく強度向上を図ることができるペルチェモジュ
ールを提供するにあり、また他の目的とするところは上
記ペルチェモジュールを簡便に製造することができるペ
ルチェモジュールの製造方法を提供するにある。
SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a Peltier module capable of improving strength without lowering cooling performance. It is an object of the present invention to provide a method of manufacturing a Peltier module that can easily manufacture the Peltier module.

【0007】[0007]

【課題を解決するための手段】しかして本発明は、隣接
する熱電素子間を電極によって接続することで複数個の
熱電素子を平面内において複数個の電極で電気的に直列
に接続しているペルチェモジュールであって、絶縁性で
且つ熱不良導体であり且つ隣接する熱電素子の側面に接
するとともに電極との間に空気層を介在させる補強部材
を各熱電素子間に配設していることに特徴を有してい
る。
According to the present invention, a plurality of thermoelectric elements are electrically connected in series on a plane by a plurality of electrodes by connecting adjacent thermoelectric elements with electrodes. A Peltier module, wherein a reinforcing member that is an insulating and thermally defective conductor, is in contact with a side surface of an adjacent thermoelectric element, and has an air layer interposed between the electrode and the thermoelectric element is disposed between the thermoelectric elements. Has features.

【0008】補強部材には中空の筒状成形品を好適に用
いることができる。
[0008] A hollow cylindrical molded product can be suitably used for the reinforcing member.

【0009】補強部材と熱電素子と電極を被覆する樹脂
被覆層を備えたものとするのも好ましい。
[0009] It is also preferable to provide a resin coating layer for covering the reinforcing member, the thermoelectric element and the electrode.

【0010】また、隣接する熱電素子間を電極によって
接続することで複数個の熱電素子を平面内において複数
個の電極で電気的に直列に接続しているペルチェモジュ
ールであって、絶縁性で且つ熱不良導体であり且つ隣接
する熱電素子の側面に接する中空の補強部材を各熱電素
子間に配設しているとともに、補強部材と熱電素子と電
極との間を充填している樹脂を備えているものであって
もよい。
A Peltier module in which a plurality of thermoelectric elements are electrically connected in series in a plane by a plurality of electrodes by connecting adjacent thermoelectric elements by electrodes, and is a Peltier module having an insulating property. A hollow reinforcing member that is a heat-defective conductor and is in contact with a side surface of an adjacent thermoelectric element is disposed between the thermoelectric elements, and a resin filling between the reinforcing member, the thermoelectric element, and the electrode is provided. May be available.

【0011】そして本発明に係るペルチェモジュールの
製造方法は、電極を各片面に備えた2枚のプレート間に
棒状の熱電素子を挟み込んで熱電素子と電極とを電気的
に接続するとともに、棒状の熱電素子間に絶縁性で且つ
熱不良導体である棒状の補強部材を配設し、この後、棒
状の熱電素子及び棒状の補強部材をプレートごと切断し
て、平面内において複数個の電極で電気的に直列に接続
された複数個の熱電素子間に補強部材が位置するペルチ
ェモジュールを得ることに特徴を有している。
In the method of manufacturing a Peltier module according to the present invention, a rod-shaped thermoelectric element is sandwiched between two plates each having an electrode on one side to electrically connect the thermoelectric element and the electrode and to form a rod-shaped thermoelectric element. A rod-shaped reinforcing member that is an insulating and poorly-heated conductor is disposed between the thermoelectric elements, and thereafter, the rod-shaped thermoelectric element and the rod-shaped reinforcing member are cut together with the plate, and the electric power is applied to a plurality of electrodes in a plane. It is characterized in that a Peltier module is provided in which a reinforcing member is located between a plurality of thermoelectric elements connected in series.

【0012】切断に先立って、樹脂コーティングを行っ
たり、樹脂の充填を行ってもよく、さらには棒状の補強
部材として、複数の補強部材が一端で連結されたものを
用いるのも好ましい。
Prior to cutting, resin coating or resin filling may be performed, and it is also preferable to use a rod-shaped reinforcing member in which a plurality of reinforcing members are connected at one end.

【0013】[0013]

【発明の実施の形態】以下本発明を実施の形態の一例に
基づいて詳述すると、n型の熱電素子1とp型の熱電素
子1とを平面内において交互に電極2によって接続する
とともにπ型配置とすることで、これら熱電素子1を直
列接続している。また、電極2で接続されている対の熱
電素子1,1間には中空筒状の成形品である補強部材3
を配設してある。この補強部材3は、対の熱電素子1,
1の側面には接するものの、電極2,2との間には空気
層が介在するように電極2から少し離してある。補強部
材3の材質は絶縁性があれば、特に問わないが、熱伝導
率が低い樹脂成形品を好適に用いることができる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described in detail below with reference to an example of an embodiment. An n-type thermoelectric element 1 and a p-type thermoelectric element 1 are alternately connected in a plane by an electrode 2 and π By adopting a mold arrangement, these thermoelectric elements 1 are connected in series. A reinforcing member 3 which is a hollow cylindrical molded product is provided between the pair of thermoelectric elements 1 and 1 connected by the electrodes 2.
Is arranged. The reinforcing member 3 includes a pair of thermoelectric elements 1 and
Although it is in contact with the side surface of 1, it is slightly separated from the electrode 2 so that an air layer is interposed between the electrodes 2 and 2. The material of the reinforcing member 3 is not particularly limited as long as it has insulating properties, but a resin molded product having a low thermal conductivity can be suitably used.

【0014】図3に示すように、熱電素子1と電極2と
補強部材3との間の空間に樹脂4を充填してしまっても
よい。この場合、補強効果が非常に高いものとなる。樹
脂4には低い熱伝導率や作業性などの点から、エポキシ
樹脂、ウレタン樹脂、シリコン樹脂などの液状の硬化性
樹脂が望ましい。
As shown in FIG. 3, the space between the thermoelectric element 1, the electrode 2, and the reinforcing member 3 may be filled with a resin 4. In this case, the reinforcing effect is very high. The resin 4 is desirably a liquid curable resin such as an epoxy resin, a urethane resin, and a silicone resin in terms of low thermal conductivity and workability.

【0015】樹脂を充填するのではなく、図3に示すよ
うに、熱電素子1と電極2と補強部材3との表面にコー
ティングして樹脂被覆層40を形成するようにしてもよ
い。この場合のコーティング用樹脂は、熱電素子1と電
極2と補強部材3との狭い空間に毛細管現象で導くため
に、低粘度のものを用いる。種類は特に問わないが、エ
ポキシ樹脂、ウレタン樹脂、シリコン樹脂などが望まし
い対をなす熱電素子1,1間に上記補強部材3を配した
ペルチェモジュールは、次のようにして製造するとよ
い。すなわち、図4に示すように、棒状のp型熱電素子
と棒状のn型熱電素子1とを間隔をおいて並べたものを
電極が各片面に設けられた(もしくは電極そのものとな
る)2枚のプレート5,5間に挟み込んで熱電素子1と
電極との電気的接続を行った構造物に対して、棒状の熱
電素子1間に絶縁性で且つ熱不良導体である棒状の補強
部材3を挿入配設し、この後、棒状の熱電素子1及び棒
状の補強部材3をプレート5ごとダイシングソー6で切
断して、平面内において複数個の電極2で電気的に直列
に接続された複数個の熱電素子1間に補強部材3が位置
するペルチェモジュールを得るのである。
Instead of filling the resin, the resin coating layer 40 may be formed by coating the surfaces of the thermoelectric element 1, the electrode 2, and the reinforcing member 3 as shown in FIG. In this case, a low-viscosity resin is used as the coating resin in order to guide the narrow space between the thermoelectric element 1, the electrode 2, and the reinforcing member 3 by the capillary phenomenon. Although the type is not particularly limited, a Peltier module in which the reinforcing member 3 is disposed between the thermoelectric elements 1 and 1 which are preferably formed of an epoxy resin, a urethane resin, a silicon resin, or the like may be manufactured as follows. That is, as shown in FIG. 4, two rod-shaped p-type thermoelectric elements and a rod-shaped n-type thermoelectric element 1 are arranged at an interval, and two electrodes are provided on each side (or become the electrodes themselves). For the structure in which the thermoelectric element 1 and the electrode are electrically connected by being sandwiched between the plates 5 and 5, the rod-shaped reinforcing member 3 which is an insulating and thermally defective conductor is inserted between the rod-shaped thermoelectric elements 1. After that, the rod-shaped thermoelectric element 1 and the rod-shaped reinforcing member 3 are cut together with the plate 5 by a dicing saw 6, and a plurality of electrodes electrically connected in series with a plurality of electrodes 2 in a plane. The Peltier module in which the reinforcing member 3 is located between the thermoelectric elements 1 is obtained.

【0016】切断に先立って、樹脂コーティングを行っ
ておけば、図3に示すものを得ることができ、切断に先
立って、図5に示すように、樹脂4の充填を行っておけ
ば、図2に示すものを得ることができる。
If the resin coating is performed before cutting, the one shown in FIG. 3 can be obtained. If the resin 4 is filled before cutting as shown in FIG. 2 can be obtained.

【0017】さらには棒状の補強部材3として、図6に
示すように、複数の補強部材3が一端で連結されたもの
を用いると、作業性がさらに向上する。
Further, as shown in FIG. 6, the workability is further improved by using a rod-shaped reinforcing member 3 in which a plurality of reinforcing members 3 are connected at one end.

【0018】[0018]

【発明の効果】以上のように本発明においては、隣接す
る熱電素子間を電極によって接続することで複数個の熱
電素子を平面内において複数個の電極で電気的に直列に
接続しているペルチェモジュールにおいて、絶縁性で且
つ熱不良導体であり且つ隣接する熱電素子の側面に接す
るとともに電極との間に空気層を介在させる補強部材を
各熱電素子間に配設しているために、補強部材によると
ころの強度向上を得ることができると同時に、空気層の
存在により熱漏れによる冷却性能の低下を抑えることが
できる。
As described above, in the present invention, a plurality of thermoelectric elements are electrically connected in series in a plane by a plurality of electrodes by connecting adjacent thermoelectric elements by electrodes. In the module, a reinforcing member that is insulative and has poor thermal conductivity, is in contact with the side surface of the adjacent thermoelectric element, and has an air layer interposed between the thermoelectric element and the electrode is disposed between the thermoelectric elements. Therefore, the strength can be improved, and at the same time, the cooling performance can be prevented from being deteriorated due to heat leakage due to the presence of the air layer.

【0019】補強部材には中空の筒状成形品を用いれ
ば、さらに冷却性能の低下を抑えることができる。
If a hollow cylindrical molded product is used as the reinforcing member, a decrease in cooling performance can be further suppressed.

【0020】補強部材と熱電素子と電極を被覆する樹脂
被覆層を備えたものとするならば、強度の向上をさらに
図ることができる。
If a reinforcing member, a thermoelectric element and a resin coating layer for covering the electrodes are provided, the strength can be further improved.

【0021】また、隣接する熱電素子間を電極によって
接続することで複数個の熱電素子を平面内において複数
個の電極で電気的に直列に接続しているペルチェモジュ
ールであって、絶縁性で且つ熱不良導体であり且つ隣接
する熱電素子の側面に接する中空の補強部材を各熱電素
子間に配設しているとともに、補強部材と熱電素子と電
極との間を充填している樹脂を備えたものとしても、強
度の向上と冷却性能の低下抑制とを図ることができる。
A Peltier module in which a plurality of thermoelectric elements are electrically connected in series in a plane by a plurality of electrodes by connecting adjacent thermoelectric elements by electrodes, and is a Peltier module having insulating properties and A hollow reinforcing member that is a heat-defective conductor and is in contact with a side surface of an adjacent thermoelectric element is disposed between the thermoelectric elements, and a resin filling between the reinforcing member, the thermoelectric element, and the electrode is provided. As a result, it is possible to improve the strength and suppress a decrease in the cooling performance.

【0022】そして本発明に係るペルチェモジュールの
製造方法は、電極を各片面に備えた2枚のプレート間に
棒状の熱電素子を挟み込んで熱電素子と電極とを電気的
に接続するとともに、棒状の熱電素子間に絶縁性で且つ
熱不良導体である棒状の補強部材を配設し、この後、棒
状の熱電素子及び棒状の補強部材をプレートごと切断し
て、平面内において複数個の電極で電気的に直列に接続
された複数個の熱電素子間に補強部材が位置するペルチ
ェモジュールを得ることから、補強部材を全熱電素子間
に個別に配置することなく、補強部材の配設を行うこと
ができるものであり、補強部材を備えることによる強度
向上を図ったペルチェモジュールを簡便に製造すること
ができる。
In the method of manufacturing a Peltier module according to the present invention, a rod-shaped thermoelectric element is sandwiched between two plates each having an electrode on one side to electrically connect the thermoelectric element and the electrode and to form a rod-shaped thermoelectric element. A rod-shaped reinforcing member that is an insulating and poorly-heated conductor is disposed between the thermoelectric elements, and thereafter, the rod-shaped thermoelectric element and the rod-shaped reinforcing member are cut together with the plate, and the electric power is applied to a plurality of electrodes in a plane. Since a Peltier module in which a reinforcing member is located between a plurality of thermoelectric elements connected in series is obtained, the reinforcing members can be arranged without separately arranging the reinforcing members between all the thermoelectric elements. It is possible to easily manufacture a Peltier module in which the strength is improved by providing the reinforcing member.

【0023】切断に先立って、樹脂コーティングを行っ
たり、樹脂の充填を行えば、さらに強度の高いものを簡
便に製造することができ、さらに棒状の補強部材とし
て、複数の補強部材が一端で連結されたものを用いる
と、製造時の作業性がさらに向上する。
If a resin coating or resin filling is performed prior to cutting, a product having higher strength can be easily manufactured, and a plurality of reinforcing members are connected at one end as a rod-like reinforcing member. The use of such a material further improves the workability during manufacturing.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施の形態の一例を示すもので、(a)
は断面図、(b)は平面図、(c)は補強部材の斜視図であ
る。
FIG. 1 shows an example of an embodiment of the present invention, in which (a)
Is a sectional view, (b) is a plan view, and (c) is a perspective view of a reinforcing member.

【図2】他例を示しており、(a)は断面図、(b)は斜視図
である。
2A and 2B show another example, in which FIG. 2A is a sectional view and FIG. 2B is a perspective view.

【図3】さらに他例を示す断面図である。FIG. 3 is a sectional view showing still another example.

【図4】製造方法の一例を示す説明図である。FIG. 4 is an explanatory diagram illustrating an example of a manufacturing method.

【図5】製造方法の他例を示す説明図である。FIG. 5 is an explanatory view showing another example of the manufacturing method.

【図6】製造方法のさらに他例を示す説明図である。FIG. 6 is an explanatory view showing still another example of the manufacturing method.

【図7】従来例の断面図である。FIG. 7 is a sectional view of a conventional example.

【符号の説明】 1 熱電素子 2 電極 3 補強部材[Description of Signs] 1 Thermoelectric element 2 Electrode 3 Reinforcing member

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 隣接する熱電素子間を電極によって接続
することで複数個の熱電素子を平面内において複数個の
電極で電気的に直列に接続しているペルチェモジュール
であって、絶縁性で且つ熱不良導体であり且つ隣接する
熱電素子の側面に接するとともに電極との間に空気層を
介在させる補強部材を各熱電素子間に配設していること
を特徴とするペルチェモジュール。
1. A Peltier module in which a plurality of thermoelectric elements are electrically connected in series in a plane by a plurality of electrodes by connecting adjacent thermoelectric elements with electrodes, and are insulative and A Peltier module, wherein a reinforcing member that is a thermally defective conductor and is in contact with a side surface of an adjacent thermoelectric element and has an air layer interposed between the thermoelectric element and the electrode is provided between the thermoelectric elements.
【請求項2】 補強部材は中空の筒状成形品であること
を特徴とする請求項1記載のペルチェモジュール。
2. The Peltier module according to claim 1, wherein the reinforcing member is a hollow cylindrical molded product.
【請求項3】 補強部材と熱電素子と電極を被覆する樹
脂被覆層を備えていることを特徴とする請求項1または
2記載のペルチェモジュール。
3. The Peltier module according to claim 1, further comprising a resin coating layer covering the reinforcing member, the thermoelectric element, and the electrode.
【請求項4】 隣接する熱電素子間を電極によって接続
することで複数個の熱電素子を平面内において複数個の
電極で電気的に直列に接続しているペルチェモジュール
であって、絶縁性で且つ熱不良導体であり且つ隣接する
熱電素子の側面に接する中空の補強部材を各熱電素子間
に配設しているとともに、補強部材と熱電素子と電極と
の間を充填している樹脂を備えていることを特徴とする
ペルチェモジュール。
4. A Peltier module in which a plurality of thermoelectric elements are electrically connected in series in a plane by a plurality of electrodes by connecting adjacent thermoelectric elements with electrodes, and wherein the thermoelectric elements are insulative and A hollow reinforcing member that is a heat-defective conductor and is in contact with a side surface of an adjacent thermoelectric element is disposed between the thermoelectric elements, and a resin filling between the reinforcing member, the thermoelectric element, and the electrode is provided. Peltier module
【請求項5】 電極を各片面に備えた2枚のプレート間
に棒状の熱電素子を挟み込んで熱電素子と電極とを電気
的に接続するとともに、棒状の熱電素子間に絶縁性で且
つ熱不良導体である棒状の補強部材を配設し、この後、
棒状の熱電素子及び棒状の補強部材をプレートごと切断
して、平面内において複数個の電極で電気的に直列に接
続された複数個の熱電素子間に補強部材が位置するペル
チェモジュールを得ることを特徴とするペルチェモジュ
ールの製造方法。
5. A rod-shaped thermoelectric element is sandwiched between two plates provided with electrodes on one side to electrically connect the thermoelectric element and the electrode, and the insulation and thermal failure between the rod-shaped thermoelectric elements. A bar-shaped reinforcing member, which is a conductor, is arranged.
Cutting the rod-shaped thermoelectric element and the rod-shaped reinforcing member together with the plate to obtain a Peltier module in which the reinforcing member is located between a plurality of thermoelectric elements electrically connected in series with a plurality of electrodes in a plane. A method for manufacturing a Peltier module.
【請求項6】 切断に先立って、樹脂コーティングを行
うことを特徴とする請求項5記載のペルチェモジュール
の製造方法。
6. The method according to claim 5, wherein a resin coating is performed prior to the cutting.
【請求項7】 切断に先立って、樹脂の充填を行うこと
を特徴とする請求項5記載のペルチェモジュールの製造
方法。
7. The method for manufacturing a Peltier module according to claim 5, wherein a resin is filled before cutting.
【請求項8】 棒状の補強部材として、複数の補強部材
が一端で連結されたものを用いることを特徴とする請求
項5〜7のいずれかの項に記載のペルチェモジュールの
製造方法。
8. The method for manufacturing a Peltier module according to claim 5, wherein a plurality of reinforcing members connected at one end are used as the bar-shaped reinforcing members.
JP36556399A 1999-12-22 1999-12-22 Peltier module and its manufacturing method Withdrawn JP2001185768A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP36556399A JP2001185768A (en) 1999-12-22 1999-12-22 Peltier module and its manufacturing method

Publications (1)

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JP2001185768A true JP2001185768A (en) 2001-07-06

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JP36556399A Withdrawn JP2001185768A (en) 1999-12-22 1999-12-22 Peltier module and its manufacturing method

Country Status (1)

Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005069391A1 (en) * 2004-01-19 2005-07-28 Matsushita Electric Industrial Co., Ltd. Thermoelectric conversion element and its producing method, and thermoelectric conversion apparatus using the element
JP2009239031A (en) * 2008-03-27 2009-10-15 Toshiba Corp Thermoelectric element device and thermoelectric module
RU2545317C2 (en) * 2012-05-02 2015-03-27 Андрей Анатольевич Зыкин Thermoelectric module

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005069391A1 (en) * 2004-01-19 2005-07-28 Matsushita Electric Industrial Co., Ltd. Thermoelectric conversion element and its producing method, and thermoelectric conversion apparatus using the element
US7317159B2 (en) 2004-01-19 2008-01-08 Matsushita Electric Industrial Co., Ltd. Thermoelectric conversion element and method of manufacturing the same, and thermoelectric conversion device using the element
JP2009239031A (en) * 2008-03-27 2009-10-15 Toshiba Corp Thermoelectric element device and thermoelectric module
RU2545317C2 (en) * 2012-05-02 2015-03-27 Андрей Анатольевич Зыкин Thermoelectric module

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