JP2001052715A - Sealed type lead-acid battery - Google Patents
Sealed type lead-acid batteryInfo
- Publication number
- JP2001052715A JP2001052715A JP11225958A JP22595899A JP2001052715A JP 2001052715 A JP2001052715 A JP 2001052715A JP 11225958 A JP11225958 A JP 11225958A JP 22595899 A JP22595899 A JP 22595899A JP 2001052715 A JP2001052715 A JP 2001052715A
- Authority
- JP
- Japan
- Prior art keywords
- acid battery
- positive electrode
- lead
- section
- electrode plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Cell Separators (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、クラッド式正極板
を用いた密閉形鉛蓄電池の改良に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improvement in a sealed lead-acid battery using a clad type positive electrode plate.
【０００２】[0002]
【従来の技術】フォークリフトなどの電動車に用いる鉛
蓄電池用の正極板として、クラッド式正極板が一般的に
用いられている。なお、クラッド式正極板を用いた鉛蓄
電池は、長寿命であるという特徴を有している。最近、
クラッド式正極板を用いた鉛蓄電池のメンテナンス・フ
リー化、低コスト化及び高率放電特性の向上が強く要求
されている。2. Description of the Related Art A clad type positive electrode plate is generally used as a positive electrode plate for a lead storage battery used in an electric vehicle such as a forklift. Note that a lead storage battery using a clad-type positive electrode plate has a feature that it has a long life. Recently,
There is a strong demand for a lead-acid battery using a clad-type positive electrode plate to be maintenance-free, low in cost, and improved in high-rate discharge characteristics.
【０００３】メンテナンス・フリー化をする手法とし
て、クラッド式正極板の芯金に鉛-カルシウム-錫合金製
を用い、リテーナに電解液を染み込ませて密閉形鉛蓄電
池を作製する技術がすでに確立されている。As a technique for maintenance-free operation, a technique has been already established for manufacturing a sealed lead-acid battery by using a lead-calcium-tin alloy for the core metal of a clad-type positive electrode plate and impregnating the retainer with an electrolytic solution. ing.
【０００４】クラッド式正極板を用いた鉛蓄電池の低コ
スト化をするには、従来の断面が円形のチューブに替え
て、断面が楕円形のチューブを用いることにより、使用
するチューブの数を減らす手法が考えられる。後述する
ように楕円形のチューブを用いると、各チューブ間の活
物質が充填されていないスペースを減らすことができる
ため、低率放電特性は向上する。しかしながら、この形
状を用いると芯金の集電性が低下するために、高率放電
特性が低下するという問題点がある。In order to reduce the cost of a lead-acid battery using a clad-type positive electrode plate, the number of tubes used is reduced by using tubes having an elliptical cross section instead of conventional tubes having a circular cross section. A method is conceivable. As will be described later, when an elliptical tube is used, the space between each tube where the active material is not filled can be reduced, so that the low-rate discharge characteristics are improved. However, when this shape is used, there is a problem that the high-rate discharge characteristics are reduced because the current collecting performance of the core metal is reduced.
【０００５】一方、鉛蓄電池の高率放電特性を向上させ
る手段として、 １）芯金の集電性を向上させること、 ２）正極用活物質量を増加させること ３）電極付近に大量の電解液を保持できる構造にするこ
と、 などの手段が考えられる。On the other hand, as means for improving the high-rate discharge characteristics of a lead storage battery, 1) improving the current collecting performance of the cored bar, 2) increasing the amount of the active material for the positive electrode, and 3) a large amount of electrolysis near the electrode. Means such as a structure that can hold the liquid can be considered.
【０００６】上記した、１）の集電性を向上させる手段
として、クラッド式正極板の芯金の部分を太くする方法
が考えられる。しかしながら、この方法を用いると、ク
ラッド式正極板の体積が限られているため、充填できる
活物質量が減少し、その結果、放電容量が低下するとい
う問題点がある。As a means for improving the current collecting property of 1), a method of increasing the thickness of the core metal of the clad type positive electrode plate can be considered. However, when this method is used, since the volume of the clad type positive electrode plate is limited, the amount of the active material that can be filled is reduced, and as a result, there is a problem that the discharge capacity is reduced.
【０００７】また、上記した、２）正極活物質量を増加
させる方法を用いるには、前記したクラッド式正極板の
体積が限られているため、その芯金の部分を細くする必
要がある。その結果、芯金の部分が腐食して、破損する
などの理由により、鉛蓄電池が短寿命になるという問題
点がある。In addition, in order to use the above-mentioned method 2) to increase the amount of the positive electrode active material, the volume of the clad-type positive electrode plate is limited, so that it is necessary to make the core metal portion thin. As a result, there is a problem that the life of the lead storage battery is shortened because the core metal portion is corroded and damaged.
【０００８】一方、上記した、３）の電極付近に大量の
電解液を保持できる構造にする手段として、クラッド式
正極板とペースト式負極板の間に、シリカ微粉体を充填
する手法が特許2855693号公報で開示されている。しか
しながら、この方法を用いると、使用中にシリカ微粉体
が鉛蓄電池の下部に移動し、長期間使用した場合に、そ
の効果が失われるという問題点がある。[0008] On the other hand, as a means for providing a structure capable of holding a large amount of electrolyte near the electrodes described in the above 3), a method of filling silica fine powder between a clad type positive electrode plate and a paste type negative electrode plate is disclosed in Japanese Patent No. Are disclosed. However, when this method is used, there is a problem that the silica fine powder moves to the lower part of the lead storage battery during use and its effect is lost when used for a long time.
【０００９】[0009]
【発明が解決しようとする課題】本発明の目的は、メン
テナンス・フリーであり、高率放電特性とサイクル寿命
特性に優れた密閉形鉛蓄電池を提供するものである。SUMMARY OF THE INVENTION An object of the present invention is to provide a sealed lead-acid battery which is maintenance-free and has excellent high rate discharge characteristics and cycle life characteristics.
【００１０】[0010]
【課題を解決するための手段】上記した課題を解決する
ために、第一の発明は、断面が略楕円形状のチューブ
と、鉛-カルシウム-錫合金製の芯金とを有するクラッド
式正極板、ペースト式負極板及びリテーナを用いた密閉
形鉛蓄電池において、前記芯金の断面が略楕円形状をし
ていることを特徴としており、第二の発明は、前記芯金
の断面積が、5.0mm2以上であることを特徴としており、
第三の発明は、前記芯金の合金は、0.06〜0.09wt.%のカ
ルシウムと、1.0wt.%以上の錫を含有するものであるこ
とを特徴としている。第四の発明は、前記芯金の短径方
向を、前記チューブの短径方向にすることを特徴として
いる。第五の発明は、前記リテーナは、50kgf/dm2で圧
縮した場合における厚みが、20kgf/dm2で圧縮した場合
における厚みの85%以下のものであることを特徴として
いる。Means for Solving the Problems To solve the above problems, a first invention is to provide a clad type positive electrode plate having a tube having a substantially elliptical cross section and a core metal made of a lead-calcium-tin alloy. In a sealed lead-acid battery using a paste-type negative electrode plate and a retainer, the cross-section of the core metal is characterized by having a substantially elliptical shape, the second invention, the cross-sectional area of the core metal is 5.0 mm 2 or more,
The third invention is characterized in that the alloy of the metal core contains 0.06 to 0.09 wt.% Of calcium and 1.0 wt.% Or more of tin. A fourth invention is characterized in that the minor axis direction of the cored bar is the minor axis direction of the tube. A fifth invention is characterized in that the thickness of the retainer when compressed at 50 kgf / dm 2 is 85% or less of the thickness when compressed at 20 kgf / dm 2 .
【００１１】[0011]
【発明の実施の形態】以下、図２に示すような、クラッ
ド式正極板、ペースト式負極板及びリテーナを用いた密
閉形鉛蓄電池で実施した。 １．クラッド式正極板の作製 鉛-カルシウム-錫合金を用いて後述する各種形状の芯金
4を作製する（図１）。以下において、特に規定するも
のを除いて、組成がPb-0.09wt.%Ca-1.0wt.%Snの鉛合金
を用いた。次に、前記芯金4をガラス繊維を織り込んだ
チューブ6で包み、一酸化鉛を主成分とする粉末を充填
して正極活物質5とし、チューブ6の下部末端を、図２に
示すように樹脂製の下部連座7で塞ぐことにより、l220m
m×w145mm×t7.5mmのクラッド式正極板1を作製した。な
お、芯金4の断面を略楕円形状にしたもの（図１−
（ｃ）、（ｄ））は、前記芯金4の短径方向を、前記チ
ューブ6の短径方向にすると、前記一酸化鉛を主成分と
する粉末の充填が容易であった。その他のクラッド式正
極板1の作製条件は従来のものと全く同様である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, a sealed lead storage battery using a clad type positive electrode plate, a paste type negative electrode plate and a retainer as shown in FIG. 2 was used. 1. Manufacture of clad type positive electrode plate Metal cores of various shapes described later using lead-calcium-tin alloy
4 is produced (FIG. 1). In the following, a lead alloy having a composition of Pb-0.09 wt.% Ca-1.0 wt.% Sn was used, unless otherwise specified. Next, the core metal 4 is wrapped in a tube 6 woven of glass fiber, and filled with a powder mainly composed of lead monoxide to form a positive electrode active material 5, and the lower end of the tube 6, as shown in FIG. By closing with the lower joint 7 made of resin, l 220m
A clad-type positive electrode plate 1 of mx w 145 mm x t 7.5 mm was produced. Here, the cross section of the cored bar 4 is substantially elliptical (see FIG. 1).
In (c) and (d)), when the minor axis direction of the cored bar 4 is set to the minor axis direction of the tube 6, the powder containing lead monoxide as a main component was easily filled. Other manufacturing conditions of the clad type positive electrode plate 1 are exactly the same as those of the conventional one.
【００１２】２．密閉形鉛蓄電池の作製 前記クラッド式正極板1を１枚、ペースト式負極板3を２
枚用い、ガラス繊維からなるリテーナ2を介して積層
し、公称容量が26Ah-２Vの密閉形鉛蓄電池を作製した
（図２）。以下において、特に規定するものを除いて、
50kgf/dm2で圧縮した場合における厚みが、20kgf/dm2で
圧縮した場合における厚みの85％のリテーナ2を用い
た。すなわち、この値（％）が高いリテーナ2ほど圧縮
しやすいことを示している。なお、ペースト式負極板3
の寸法はl220mm×w145mm×t3.0mmであり、その作製条件
や密閉形鉛蓄電池の組み立て条件等は従来のものと全く
同様である。2. Production of sealed lead-acid battery One clad type positive electrode plate 1 and two paste type negative electrode plates 3
A sealed lead-acid battery having a nominal capacity of 26 Ah-2 V was produced by using a plurality of sheets and laminating them through a glass fiber retainer 2 (FIG. 2). In the following, except where otherwise specified,
Thickness when compressed at 50 kgf / dm 2 was used 85% of the retainer 2 in the thickness when compressed at 20 kgf / dm 2. That is, the higher the value (%), the easier the retainer 2 is to compress. The paste type negative electrode plate 3
The dimensions are l 220mm × w 145mm × t 3.0mm , assembly conditions and the like of the manufacturing conditions and sealed lead-acid battery is exactly the same as conventional.
【００１３】３．密閉形鉛蓄電池の試験 作製した密閉形鉛蓄電池を25℃、0.2CAで放電（放電終
止電圧：1.6V）した後に満充電し、1CAで放電（放電終
止電圧：1.6V）して、初期の放電容量を測定した。3. Test of sealed lead-acid battery The prepared lead-acid battery was discharged at 25 ° C and 0.2 CA (discharge end voltage: 1.6 V), then fully charged, and discharged at 1 CA (discharge end voltage: 1.6 V). The discharge capacity was measured.
【００１４】初期の放電容量を測定した密閉形鉛蓄電池
は、25℃で、以下の条件でサイクル寿命試験を行った。 充電条件：2.45Vの定電圧で8時間（ただし、制限電流0.
3CA） 放電条件：0.23CAで3時間 50サイクルごとに満充電した後、0.2CAの定電流で、1.6
V（放電終止電圧）まで放電して放電容量を測定し、前
記した初期の放電容量の60％まで低下した時点を寿命と
した。The sealed lead-acid battery whose initial discharge capacity was measured was subjected to a cycle life test at 25 ° C. under the following conditions. Charging conditions: 8 hours at a constant voltage of 2.45 V
3CA) Discharge condition: Full charge every 50 cycles for 3 hours at 0.23CA, then 1.6 at constant current of 0.2CA
The discharge capacity was measured by discharging to V (discharge end voltage), and the point in time when the discharge capacity was reduced to 60% of the initial discharge capacity was defined as the life.
【００１５】[0015]
【実施例】（比較例１）断面が円形をした半径が7mmの
チューブ6と、断面が円形をした断面積が5mm2の芯金4を
用いてクラッド式正極板1を作製した（図１−ａ）。そ
の他、密閉形鉛蓄電池の作製条件や試験条件等は上記し
たものである。EXAMPLE (Comparative Example 1) A clad-type positive electrode plate 1 was manufactured using a tube 6 having a circular cross section and a radius of 7 mm and a metal core 4 having a circular cross section and a cross sectional area of 5 mm 2 (FIG. 1). -A). In addition, the manufacturing conditions and test conditions of the sealed lead-acid battery are as described above.
【００１６】（比較例２）断面が略楕円形をした長径が
15mm、短径が7mmのチューブ6と、断面が円形をした断面
積が5mm2の芯金4を用いてクラッド式正極板1を作製した
（図１−ｂ）。その他、密閉形鉛蓄電池の作製条件や試
験条件等は上記したものである。(Comparative Example 2) The major axis having a substantially elliptical cross section is
A clad-type positive electrode plate 1 was produced using a tube 6 having a length of 15 mm and a short diameter of 7 mm and a core 4 having a circular cross section and a cross section of 5 mm 2 (FIG. 1-b). In addition, the manufacturing conditions and test conditions of the sealed lead-acid battery are as described above.
【００１７】（実施例１）断面が略楕円形をした長径が
15mm、短径が7mmのチューブ6と、断面が略楕円形をした
断面積が5mm2の芯金4を用いてクラッド式正極板1を作製
した（図１−ｃ）。その他、密閉形鉛蓄電池の作製条件
や試験条件等は上記したものである。(Embodiment 1) The major axis having a substantially elliptical cross section is
A clad-type positive electrode plate 1 was produced using a tube 6 having a length of 15 mm and a short diameter of 7 mm and a core 4 having a substantially elliptical cross section and a cross section of 5 mm 2 (FIG. 1-c). In addition, the manufacturing conditions and test conditions of the sealed lead-acid battery are as described above.
【００１８】（実施例２）断面が略楕円形をした長径が
15mm、短径が7mmのチューブ6と、断面が略楕円形をした
合計の断面積が5mm2の芯金4を２本有する、クラッド式
正極板1を作製した（図１−ｄ）。その他、密閉形鉛蓄
電池の作製条件や試験条件等は上記したものである。(Embodiment 2) The major axis having a substantially elliptical cross section is
A clad-type positive electrode plate 1 having a tube 6 having a length of 15 mm and a minor diameter of 7 mm and two core metals 4 each having a substantially elliptical cross section and a total cross-sectional area of 5 mm 2 was produced (FIG. 1-d). In addition, the manufacturing conditions and test conditions of the sealed lead-acid battery are as described above.
【００１９】表１に、密閉形鉛蓄電池の初期の放電容量
試験結果及びサイクル寿命試験結果を示す。断面が楕円
形状をした芯金4を用いた（実施例１、２）は、断面が
円形状をした芯金4を用いた（比較例１、２）に比べ
て、初期の１CA放電容量が高く、長寿命であった。Table 1 shows the initial discharge capacity test results and cycle life test results of the sealed lead-acid battery. The core metal 4 having an elliptical cross section (Examples 1 and 2) has a lower initial 1CA discharge capacity than the core metal 4 having a circular cross section (Comparative Examples 1 and 2). High and long life.
【００２０】[0020]
【表１】 [Table 1]
【００２１】（実施例１、３、４）断面が略楕円形をし
た長径が15mm、短径が7mmのチューブ6と、断面が略楕円
形で、断面積が3mm2、5mm2、8mm2の芯金4を用い（図１
−ｃ）、３種類のクラッド式正極板1を作製した。その
他、密閉形鉛蓄電池の作製条件や試験条件等は上記した
ものである。(Examples 1, 3, 4) A tube 6 having a substantially elliptical cross section and a major axis of 15 mm and a minor axis of 7 mm, and a substantially elliptical section and a sectional area of 3 mm 2 , 5 mm 2 , and 8 mm 2 (Fig. 1)
-C) Three types of clad type positive electrode plates 1 were produced. In addition, the manufacturing conditions and test conditions of the sealed lead-acid battery are as described above.
【００２２】表２に密閉形鉛蓄電池の初期の放電容量試
験結果及びサイクル寿命試験結果を示す。芯金4の断面
積を5mm2以上にすると、密閉形鉛蓄電池を更に長寿命化
できる。なお、寿命になった密閉形鉛蓄電池を解体した
ところ、実施例３では、芯金4の腐食が大であった。Table 2 shows the initial discharge capacity test results and cycle life test results of the sealed lead-acid battery. When the sectional area of the cored bar 4 is 5 mm 2 or more, the life of the sealed lead-acid battery can be further extended. When the sealed lead-acid battery having reached the end of its life was disassembled, in Example 3, the core metal 4 was significantly corroded.
【００２３】[0023]
【表２】 [Table 2]
【００２４】（実施例１、５〜９）断面が略楕円形をし
た長径が15mm、短径が7mmのチューブ6と、断面が略楕円
形で断面積が5mm2の芯金4を用いて（図１−ｃ）、クラ
ッド式正極板1を作製した。なお、表３に示すように、
カルシウムと錫の含有量が異なる鉛合金からなる芯金4
を用いた。その他、密閉形鉛蓄電池の作製条件や試験条
件等は上記したものである。(Examples 1, 5 to 9) A tube 6 having a substantially elliptical cross section and a major axis of 15 mm and a minor axis of 7 mm, and a core 4 having a substantially elliptical cross section and a cross section of 5 mm 2 were used. (FIG. 1-c), a clad type positive electrode plate 1 was produced. In addition, as shown in Table 3,
Core 4 composed of lead alloys with different contents of calcium and tin
Was used. In addition, the manufacturing conditions and test conditions of the sealed lead-acid battery are as described above.
【００２５】表３に密閉形鉛蓄電池のサイクル寿命試験
をした結果を示す。カルシウム量が0.06〜0.9wt.%、ま
た錫量が1wt.%以上の鉛合金を芯金4に使用すると、密閉
形鉛蓄電池を更に長寿命化できる。Table 3 shows the results of a cycle life test of the sealed lead-acid battery. When a lead alloy having a calcium content of 0.06 to 0.9 wt.% And a tin content of 1 wt.% Or more is used for the core 4, the life of the sealed lead-acid battery can be further extended.
【００２６】[0026]
【表３】 [Table 3]
【００２７】（実施例１、１０〜１１）断面が略楕円形
をした長径が15mm、短径が7mmのチューブ6と、断面が略
楕円形をした、断面積が5mm2の芯金4を用いて（図１−
ｃ）、クラッド式正極板1を作製した。50kgf/dm2で圧縮
した場合における厚みが、20kgf/dm2で圧縮した場合に
おける厚み（以下、厚み比率（％）と呼ぶ）が、それぞ
れ80％、85％、90％の３種類のリテーナ2を用いた。そ
の他、密閉形鉛蓄電池の作製条件や試験条件等は上記し
たものである。(Examples 1, 10 to 11) A tube 6 having a substantially elliptical section and a major axis of 15 mm and a minor axis of 7 mm and a core 4 having a substantially elliptical section and a sectional area of 5 mm 2 were prepared. (Fig. 1-
c), a clad type positive electrode plate 1 was produced. The thickness when compressed at 50 kgf / dm 2 and the thickness when compressed at 20 kgf / dm 2 (hereinafter referred to as the thickness ratio (%)) are 80%, 85%, and 90%, respectively. Was used. In addition, the manufacturing conditions and test conditions of the sealed lead-acid battery are as described above.
【００２８】厚み比率（％）が、80％及び85％の場合に
は、放電持続時間が長く良好である。厚み比率（％）が
高いと、クラッド式正極板1の、チューブ6間の凹部の隙
間とリテーナ2との密着が不十分となり、電解液がクラ
ッド式正極板1に充分に供給できないため、放電時にお
ける正極活物質が利用されにくいためと考えられる。When the thickness ratio (%) is 80% or 85%, the discharge duration is long and good. If the thickness ratio (%) is high, the gap between the concave portion between the tubes 6 of the clad-type positive electrode plate 1 and the retainer 2 become insufficient, and the electrolyte cannot be sufficiently supplied to the clad-type positive electrode plate 1. It is considered that the positive electrode active material at the time is hardly used.
【００２９】[0029]
【表４】 [Table 4]
【００３０】[0030]
【発明の効果】上述したように本発明を用いるとメンテ
ナンス・フリーで、高率放電特性とサイクル寿命特性に
優れた鉛蓄電池を提供することができる。また、クラッ
ド式正極板に用いるチューブの数を減らすことができる
ため、コスト低減ができる点で優れている。As described above, by using the present invention, it is possible to provide a lead-acid battery which is maintenance-free and excellent in high-rate discharge characteristics and cycle life characteristics. Further, the number of tubes used for the clad type positive electrode plate can be reduced, which is advantageous in that cost can be reduced.
【図１】各種のクラッド式正極板の断面模式図である。 （ａ）円形のチューブと円形の芯金を使用。 （ｂ）略楕円形のチューブと円形の芯金を使用。 （ｃ）略楕円形のチューブと略楕円形の芯金を使用。 （ｄ）略楕円形のチューブと略楕円形の芯金２本を使
用。FIG. 1 is a schematic sectional view of various clad type positive plates. (A) A circular tube and a circular core are used. (B) A substantially elliptical tube and a circular core are used. (C) A substantially elliptical tube and a substantially elliptical core metal are used. (D) A substantially elliptical tube and two substantially elliptical cores are used.
【図２】本発明の密閉形鉛蓄電池の極板群構成を示す斜
視図である。FIG. 2 is a perspective view showing a configuration of an electrode group of the sealed lead-acid battery of the present invention.
１：クラッド式正極板、 ２：リテーナ、 ３：ペースト
式負極板、４：芯金、 ５：正極活物質、 ６：チュー
ブ、 ７：下部連座1: Clad type positive electrode plate, 2: Retainer, 3: Paste type negative electrode plate, 4: Core bar, 5: Positive electrode active material, 6: Tube, 7: Lower seat
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 5H016 AA05 CC02 EE01 HH01 HH13 HH15 5H017 AA01 AS01 CC14 CC22 EE03 EE06 HH01 5H021 AA07 HH06 5H028 AA01 CC11 HH01 HH05 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 5H016 AA05 CC02 EE01 HH01 HH13 HH15 5H017 AA01 AS01 CC14 CC22 EE03 EE06 HH01 5H021 AA07 HH06 5H028 AA01 CC11 HH01 HH05
Claims (5)
シウム-錫合金製の芯金とを有するクラッド式正極板、
ペースト式負極板及びリテーナを用いた密閉形鉛蓄電池
において、前記芯金の断面が略楕円形状をしていること
を特徴とする密閉形鉛蓄電池。1. A clad type positive plate comprising a tube having a substantially elliptical cross section and a core metal made of a lead-calcium-tin alloy,
A sealed lead-acid battery using a paste-type negative electrode plate and a retainer, wherein the cross section of the core is substantially elliptical.
とを特徴とする請求項１記載の密閉形鉛蓄電池。2. The sealed lead-acid battery according to claim 1, wherein the core metal has a sectional area of 5.0 mm 2 or more.
シウムと、1.0wt.%以上の錫を含有するものであること
を特徴とする請求項１又は２記載の密閉形鉛蓄電池。3. The sealed lead according to claim 1, wherein the alloy of the core metal contains 0.06 to 0.09 wt.% Of calcium and 1.0 wt.% Or more of tin. Storage battery.
径方向にすることを特徴とする請求項１、２又は３記載
の密閉形鉛蓄電池。4. The sealed lead-acid battery according to claim 1, wherein the minor axis direction of the core is the minor axis direction of the tube.
合における厚みが、20kgf/dm2で圧縮した場合における
厚みの85%以下のものであることを特徴とする請求項
１、２、３又は４記載の密閉形鉛蓄電池。5. The retainer according to claim 1, wherein a thickness when compressed at 50 kgf / dm 2 is not more than 85% of a thickness when compressed at 20 kgf / dm 2 . The sealed lead-acid battery according to 3 or 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11225958A JP2001052715A (en) | 1999-08-10 | 1999-08-10 | Sealed type lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11225958A JP2001052715A (en) | 1999-08-10 | 1999-08-10 | Sealed type lead-acid battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001052715A true JP2001052715A (en) | 2001-02-23 |
Family
ID=16837565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11225958A Pending JP2001052715A (en) | 1999-08-10 | 1999-08-10 | Sealed type lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001052715A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2623450A (en) * | 2021-07-12 | 2024-04-17 | Toyo Shinyaku Co Ltd | Granulated product and method for producing same |
-
1999
- 1999-08-10 JP JP11225958A patent/JP2001052715A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2623450A (en) * | 2021-07-12 | 2024-04-17 | Toyo Shinyaku Co Ltd | Granulated product and method for producing same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5061451B2 (en) | Anode current collector for lead acid battery | |
| JP2003526877A (en) | Rechargeable nickel zinc battery | |
| US5498496A (en) | Lead acid battery | |
| JPH11121028A (en) | Sealed lead-acid battery | |
| JP2004158433A (en) | Base plate for lead storage battery, and lead storage battery using the same | |
| JP2006114417A (en) | Lead-acid storage battery | |
| WO2001004976A1 (en) | Positive plate current collector for lead storage battery and lead storage battery comprising the same | |
| JP2001052715A (en) | Sealed type lead-acid battery | |
| US7223499B2 (en) | Lead battery | |
| JP4892827B2 (en) | Lead acid battery | |
| JP5145644B2 (en) | Lead acid battery | |
| JP2001126735A (en) | Lead accumulator | |
| US3075032A (en) | Electrode assembly for electric batteries or accumulators | |
| JP4904686B2 (en) | Lead acid battery | |
| JP5044888B2 (en) | Liquid lead-acid battery | |
| JP2982630B2 (en) | Lead storage battery | |
| JP4678117B2 (en) | Lead acid battery | |
| JPH11354128A (en) | Sealed lead-acid battery | |
| JP2002042857A (en) | Sealed lead-acid battery | |
| JP2001155722A (en) | Sealed lead acid storage battery and method of fabricating it | |
| JPH10199562A (en) | Sealed lead-acid battery | |
| JPH09231964A (en) | Clad positive plate | |
| JP2961770B2 (en) | Clad lead-acid battery | |
| JP2001229958A (en) | Sealed lead-acid storage battery | |
| GB2156145A (en) | Titanium wire reinforced lead composite electrode structure |