JP2001011666A - Anode electrode body - Google Patents

Anode electrode body

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Publication number
JP2001011666A
JP2001011666A JP11182819A JP18281999A JP2001011666A JP 2001011666 A JP2001011666 A JP 2001011666A JP 11182819 A JP11182819 A JP 11182819A JP 18281999 A JP18281999 A JP 18281999A JP 2001011666 A JP2001011666 A JP 2001011666A
Authority
JP
Japan
Prior art keywords
electrode
strip
corrosion
square bar
electrode body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11182819A
Other languages
Japanese (ja)
Other versions
JP3798189B2 (en
Inventor
Koji Ishii
浩司 石井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PS Corp
Original Assignee
PS Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PS Corp filed Critical PS Corp
Priority to JP18281999A priority Critical patent/JP3798189B2/en
Publication of JP2001011666A publication Critical patent/JP2001011666A/en
Application granted granted Critical
Publication of JP3798189B2 publication Critical patent/JP3798189B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Prevention Of Electric Corrosion (AREA)

Abstract

PROBLEM TO BE SOLVED: To maintain a uniform spacing between an electrode and an object to be protected from corrosion and to prevent a direct contact between the electrode and the object to be protected from corrosion by coating a strip-like-shaped electrode with mortar or concrete to form a square bar and providing each end face of the square bar with a connecting piece formed by allowing the end of the electrode to appear. SOLUTION: A strip-like electrode 2 is coated with mortar or concrete 3 into a shape of square bar to form an anode electrode body 1. Either of the following can be used as the strip-like electrode 2: one prepared by weaving fine metal wire into mesh and forming it into strip-like shape; one composed of metal sheet. The length of the anode electrode body 1 is about 1 m and the cross-sectional area of the strip-like electrode 2 is 0.1 m2. The size of the mortar-coated square bar is 2.5 cm in thickness. The end of the electrode 2 is exposed from the end of the square bar to form a connecting piece 4. When the electrode body is provided to a structure, the electrode body is used in a state where the connecting pieces 4 are mutually connected to each other by means of spot welding, etc., to the desired length. As the metal for the electrode 2, it is preferable to use, e.g. titanium having natural potential higher than that of iron in a reinforcing bar as the body to be protected from corrosion and having superior durability.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、鋼構造物やコンク
リート構造物の鉄筋などの鋼材の防食に用いられる電極
体に関し、更に詳しくは外部電源方式電気防食法に使用
される陽極(アノード)電極の構造に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electrode body used for corrosion protection of a steel material such as a reinforcing steel of a steel structure or a concrete structure, and more particularly, to an anode (anode) electrode used in an external power supply type cathodic protection method. Related to the structure.

【0002】[0002]

【従来の技術】古来人類は、地球上に大量に存在し、比
較的簡単に精錬でき加工性が良く安価で安定性のある金
属として、大量の鉄(Fe)を利用してきた。しかし、
近年、塩や酸性環境下の鋼構造物やコンクリート構造物
中の鉄筋などの腐食が社会的な問題となっている。これ
は鋼構造物や鉄筋として使用される鉄(Fe)の化学的
な性状が、通常の環境下ではその表面に薄い酸化鉄の不
動態膜で覆われ安定しているが、海洋などの塩分環境下
や環境汚染などによる酸性環境下ではその不動態膜が破
壊され酸化が内部にまで進行し、ついには構造物の破壊
にまで至る事態が発生するからである。
2. Description of the Related Art Since ancient times, humans have used a large amount of iron (Fe) as a metal that exists in large quantities on the earth, is relatively easily refined, has good workability, is inexpensive and is stable. But,
In recent years, corrosion of steel structures in a salt or acidic environment or reinforcing steel in concrete structures has become a social problem. This is because the chemical properties of iron (Fe) used for steel structures and rebars are stable under normal circumstances, with the surface covered with a thin passivation film of iron oxide. This is because the passivation film is destroyed in an environment or in an acidic environment due to environmental pollution or the like, and the oxidation proceeds to the inside, and finally, a situation occurs that leads to the destruction of the structure.

【0003】このことは古くから認識されており、その
対策として、鉄の表面に異種金属をメッキするなどの腐
食を防止する手段が実施されてきた。この手段には二通
りあって、鉄(Fe)と化学的性質(イオン化傾向)の
異なる亜鉛(Zn)や錫(Sn)をメッキしたもので、
前者はトタン板、後者はブリキ板として知られている。
トタン板は鉄よりイオン化傾向の大きい(腐食し易い)
亜鉛をメッキすることによって、鉄自体よりも先に亜鉛
を腐食させ、亜鉛を犠牲にして鉄を腐食から守ろうとす
るのに対し、後者のブリキ板は鉄よりイオン化傾向の小
さい(腐食し難い)錫をメッキすることによって、鉄自
体を覆い鉄を腐食から守ろうとする違いがある。
[0003] This has been recognized for a long time, and as a countermeasure, means for preventing corrosion, such as plating a different metal on the surface of iron, have been implemented. There are two types of this means, which are plated with zinc (Zn) or tin (Sn) having different chemical properties (ionization tendency) from iron (Fe).
The former is known as a tin plate, and the latter as a tin plate.
The galvanized sheet has a higher ionization tendency than iron (it is easily corroded)
By plating zinc, it erodes zinc before the iron itself and tries to protect iron from corrosion at the expense of zinc, while the latter tin plate has a lower ionization tendency than iron (less corrosive). The difference is that tin plating covers the iron itself and tries to protect the iron from corrosion.

【0004】近年金属の腐食のメカニズムが解明され、
金属の持つ固有の化学的性質(自然電位差)を積極的に
利用して化学的性質の異なる異種金属を組合せて電気的
に腐食を防止する電気防食技術が開発されている。電気
防食技術には流電陽極方式、外部電源方式の二通りの方
法があり、いずれも鉄を陰極(カソード)とし、これに
対する異種金属を陽極(アノード)として利用するもの
である。
In recent years, the mechanism of metal corrosion has been elucidated,
Cathodic protection technology has been developed that actively utilizes the inherent chemical properties (natural potential difference) of metals and combines different metals with different chemical properties to electrically prevent corrosion. There are two methods of cathodic protection, a galvanic anode method and an external power supply method. In each case, iron is used as a cathode and a dissimilar metal is used as an anode.

【0005】流電陽極方式は、鉄よりイオン化傾向の大
きい(低電位の)、亜鉛やアルミニウム合金、マグネシ
ウム合金などの犠牲電極片を陽極として、鉄の被防食体
に添設しておき、自然界の電界質例えば海水中に浸漬し
電気的回路を形成するものである。この電気回路が形成
されると金属のもつ固有の電位差によって電流が流れ、
鉄よりイオン化傾向の大きい亜鉛などの陽極がイオン化
して溶出し、その陽極を犠牲にして被防食体である鉄の
腐食が防止される。この方式は設置が簡単で特別な設備
を必要しないこと等の利点はあるものの、犠牲となる陽
極金属片の定期的な交換の必要性があり、また制御が難
しいという欠点がある。
In the galvanic anode method, a sacrificial electrode piece of zinc, aluminum alloy, magnesium alloy, or the like having a higher ionization tendency (lower potential) than iron is used as an anode and is attached to an iron corrosion-protected body, and is used in nature. Immersed in, for example, seawater to form an electric circuit. When this electric circuit is formed, current flows due to the inherent potential difference of metal,
An anode such as zinc, which has a higher ionization tendency than iron, is ionized and eluted, and at the expense of the anode, corrosion of iron, which is an anticorrosion target, is prevented. Although this method has advantages such as easy installation and no special equipment required, it has the disadvantage that it requires periodic replacement of sacrificial anode metal pieces and is difficult to control.

【0006】外部電源方式は、被防食体の鉄よりイオン
化傾向の小さい金属、例えば白金などの貴金属を用いる
ことが望ましいが高価であることから、白金メッキチタ
ン線や鉛合金、黒鉛などを陽極片として用いる。そし
て、被防食体及び陽極片からそれぞれリード線を引き出
し、これらを直流電源に接続し、電源から防食電流を流
すことによって被防食体の腐食を防止するものである。
防食の制御は直流電源の出力電圧を制御することによっ
て簡単に行うことができる。電源のメンテナンスなどを
必要とするが、電極体の交換などを必要としない利点が
ある。
In the external power supply system, it is desirable to use a metal having a lower ionization tendency than iron of the corrosion-protected body, for example, a noble metal such as platinum, but it is expensive, so that a platinum-plated titanium wire, a lead alloy, graphite or the like is used as an anode piece. Used as Then, lead wires are respectively drawn from the corrosion-protected body and the anode piece, connected to a DC power supply, and a corrosion protection current is supplied from the power supply to prevent corrosion of the corrosion-protected body.
The control of anticorrosion can be easily performed by controlling the output voltage of the DC power supply. There is an advantage that the maintenance of the power supply is required, but the replacement of the electrode body is not required.

【0007】本発明者は、この外部電源方式の防食技術
を橋桁に適用する技術を特開平6−158365号公報
にて開示した。この技術は陽極として白金メッキチタン
線の不溶性電極線条を被防食材である鋼材と一定間隔を
保持するように電極線条に張力を付与し展張する技術で
ある。このようにしたのは電極間の間隔が変動すると流
れる防食電流が不均一になり防食効果を阻害するためで
ある。従来の電極は細線状、細線をメッシュ状に織った
もの、又は薄いリボン状の形状のものが用いられてい
た。これらの電極は剛性が小さく変形し易く被防食体と
均一な間隔に配設するには問題があった。
The present inventor has disclosed a technique in which the anticorrosion technique of the external power supply system is applied to a bridge girder in Japanese Patent Application Laid-Open No. Hei 6-158365. This technique is a technique in which a tension is applied to the electrode wire so that an insoluble electrode wire of a platinum-plated titanium wire is maintained at a constant distance from a steel material as an anticorrosion material as an anode. The reason for this is that when the distance between the electrodes fluctuates, the flowing anticorrosion current becomes non-uniform and the anticorrosion effect is hindered. Conventional electrodes have been used in the form of fine wires, fine wires woven into a mesh, or thin ribbons. These electrodes have low rigidity and are easily deformed, and there is a problem in arranging them at a uniform distance from the anticorrosion target.

【0008】[0008]

【発明が解決しようとする課題】本発明は簡単に配設す
ることが可能で、被防食体との間隔を均一に保持するこ
とができ、被防食体と電極が直接接触することのないア
ノード電極体の開発を目的とする。
SUMMARY OF THE INVENTION According to the present invention, an anode which can be easily disposed, can maintain a uniform distance between the object to be protected, and an electrode which is not in direct contact with the electrode to be protected. The purpose is to develop an electrode assembly.

【0009】[0009]

【課題を解決するための手段】本発明は、外部電源方式
の陽極電極であって、金属薄板からなる電極、または金
属細線をメッシュ状に織って帯状に形成した電極を、モ
ルタル又はコンクリートで被覆して角棒を形成し、該角
棒の長手方向端面に該電極の端部が露出した接続片を設
けたこと特徴とするアノード電極体である。この場合電
極としてチタンを主成分とすると好適である。
SUMMARY OF THE INVENTION The present invention relates to an anode electrode of an external power supply system, which is an electrode made of a thin metal plate or an electrode formed by weaving a thin metal wire in a mesh shape to form a strip-like electrode with mortar or concrete. An anode electrode body characterized in that a square bar is formed, and a connection piece having an exposed end of the electrode is provided on a longitudinal end surface of the square bar. In this case, it is preferable to use titanium as a main component for the electrode.

【0010】[0010]

【発明の実施の形態】以下図面を参照して本発明の実施
の形態を説明する。図1は本発明の実施例のアノード電
極体1を示す斜視図である。帯状電極2をモルタル3で
角棒状に被覆してある。帯状電極2は金属細線をメッシ
ュ状に織って帯状に形成したものでもよく、金属薄板か
らなるものでもよい。アノード電極体1の長さは製造容
易で取り扱い容易の観点から、約1m程度に成形されて
いる、帯状電極の断面積は、例えば0.1cm2程度で
よく、モルタルの被覆角棒の寸法は、厚さ2.5cm程
度とする。角棒端部から電極の端部を露出して接続片4
としておき、構造物に電極体を配設するときは接続片4
同士をスポット溶接等の手段で接続し、所望の長さとし
て使用すればよい。電極金属として被防食体である鉄筋
の鉄(Fe)より自然電位が高く耐久性に富むチタン
(Ti)細線をメッシュ(グリッド)状に形成した電極
を使用したが、材料はこれに限定するものではない。使
用可能な電極金属としては、鉄より電位の高い材料であ
ればよく、ニッケル、錫、鉛、銅、銀、金、白金など及
びこれらの合金材、メッキ材などをコストを勘案して選
択すればよい。
Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a perspective view showing an anode electrode body 1 according to an embodiment of the present invention. The strip electrode 2 is covered with a mortar 3 in the shape of a square bar. The strip-shaped electrode 2 may be a strip formed by weaving a thin metal wire in a mesh shape, or may be a thin metal plate. From the viewpoint of easy production and easy handling, the length of the anode electrode body 1 is formed to about 1 m. The cross-sectional area of the strip electrode may be, for example, about 0.1 cm 2 , and the dimension of the mortar-coated square rod is And a thickness of about 2.5 cm. The connection piece 4 is exposed by exposing the end of the electrode from the end of the square rod.
When arranging the electrode body on the structure, the connecting piece 4
They may be connected to each other by a means such as spot welding and used as a desired length. As the electrode metal, an electrode was used in which a titanium (Ti) fine wire having a higher natural potential than the iron (Fe) of the corrosion-protected body and having high durability was formed in a mesh (grid) shape, but the material is not limited to this. is not. Any electrode metal that can be used may be any material having a higher potential than iron, and nickel, tin, lead, copper, silver, gold, platinum, etc., and alloys and plating materials thereof may be selected in consideration of cost. I just need.

【0011】図2は橋桁10の断面図で、新規に桁を製
作する場合のアノード電極体の配設図である。橋桁10
の底面近傍のコンクリート中にアノード電極体1を配設
してある。これは、橋桁10の製作時に橋桁10の底版
型枠の上にモルタルで被覆したアノード電極体1を所定
の長さに接続して配置し、アノード電極体1をスペーサ
として利用して桁の必要な鉄筋11及びPC鋼材12を
組み込み、側型枠を建て込み、通常の方法でコンクリー
ト13を打設し成形したものである。このアノード電極
体1をスペーサとするのではなく鉄筋11に結束線で固
定し、別体のスペーサを使用してもよい。
FIG. 2 is a cross-sectional view of the bridge girder 10, showing the arrangement of the anode electrode body when a new girder is manufactured. Bridge girder 10
The anode electrode body 1 is disposed in the concrete near the bottom surface of (1). This is because, when the bridge girder 10 is manufactured, the anode electrode body 1 covered with mortar is connected to a predetermined length on the bottom slab form of the bridge girder 10, and the anode electrode body 1 is used as a spacer. The steel bars 11 and the PC steel material 12 are assembled, a side formwork is erected, and concrete 13 is cast and formed by an ordinary method. Instead of using the anode electrode body 1 as a spacer, the anode electrode body 1 may be fixed to the reinforcing bar 11 with a binding wire, and a separate spacer may be used.

【0012】図3は鉄筋の腐食によってコンクリートが
剥離したコンクリート桁10の補修にアノード電極体1
を適用した例を示した。剥離部分の桁10のコンクリー
ト13をはつり取り、鉄筋11及びPC鋼材12の除錆
を行い。さらに必要であれば防食塗装を施し、健全部分
のコンクリートにインサート15を埋設して正規のコン
クリート断面に復元するための型枠14をボルト16で
取付け、骨材17及び充填モルタルを充填して補修した
例である。この場合補修後の鉄筋などの腐食が再発しな
いように、防食のためにアノード電極体1を埋装した。
FIG. 3 shows an anode electrode 1 for repairing a concrete girder 10 from which concrete has peeled off due to corrosion of a reinforcing bar.
The example which applied is shown. The concrete 13 of the girder 10 at the peeled portion was peeled off, and the reinforced steel 11 and the PC steel 12 were removed. Further, if necessary, anticorrosion coating is applied, a formwork 14 for embedding an insert 15 in the healthy part of the concrete and restoring to a regular concrete section is attached with a bolt 16, and an aggregate 17 and a filling mortar are filled and repaired. This is an example. In this case, the anode electrode body 1 was embedded for anticorrosion so that the corrosion of the reinforcing bars and the like after the repair did not recur.

【0013】図4は本発明のアノード電極体1を使用す
る外部電源方式の電気防食法の説明図である。コンクリ
ート13中に埋装されたアノード電極から及びコンクリ
ート桁10の構造鉄筋11からそれぞれリード線24、
25を引き出し、外部に設置された直流電源21に接続
する。アノード電極体1の電極のリード線24は、直流
電源21のプラス(+)端子22に、鉄筋11からのリ
ード線25は直流電源21のマイナス(−)端子23に
接続する。このようにすることにより、直流電源21の
プラス側からアノード電極1に防食電流が流れ鉄筋11
の腐食が防止される。この直流電源21は大容量のもの
が必要な場合は、商用交流電源を整流して用いるとよ
い。
FIG. 4 is an explanatory diagram of an external power supply type anticorrosion method using the anode electrode body 1 of the present invention. Lead wires 24 from the anode electrode embedded in the concrete 13 and from the structural reinforcing bar 11 of the concrete girder 10, respectively.
25 is pulled out and connected to a DC power supply 21 installed outside. The lead wire 24 of the electrode of the anode electrode body 1 is connected to the plus (+) terminal 22 of the DC power supply 21, and the lead wire 25 from the reinforcing bar 11 is connected to the minus (−) terminal 23 of the DC power supply 21. By doing so, the anticorrosion current flows from the plus side of the DC power supply 21 to the anode electrode 1 and the reinforcing steel 11
Corrosion is prevented. When a large capacity is required for the DC power supply 21, a commercial AC power supply may be rectified and used.

【0014】以上はコンクリート桁に適用した例で説明
したが、桁に限らず他のコンクリート構造物の鉄筋の防
食が可能である。更にコンクリート構造物に限定されず
鋼構造物の鋼部材にアノード電極を添設配置することに
よって鋼部材そのものの防食を図ることも可能である。
The above description has been given of the example in which the present invention is applied to a concrete girder. However, the present invention is not limited to the girder, and it is possible to prevent corrosion of reinforcing bars of other concrete structures. Furthermore, the steel member itself is not limited to the concrete structure, and it is also possible to prevent corrosion of the steel member by arranging the anode electrode on the steel member of the steel structure.

【0015】[0015]

【発明の効果】本発明のアノード電極体は、鉄筋より自
然電位の高いチタンを使用した外部電源方式の陽極電極
を用い、薄板帯状の金属板、又は金属細線をメッシュ状
に織った帯状の電極を、モルタルまたはコンクリートで
角棒状に被覆し、角棒の長手方向端面から電極の端部を
露出して接続片としたもので、モルタルで被覆すること
により電極自体が鉄筋に直接接触することもなく、正確
な電極間の間隔を確保することができ、均一な防食電流
を流すことが可能となり、鉄筋などの被防食体の確実な
腐食の防止が可能となる。
The anode electrode body of the present invention uses an anode electrode of an external power supply system using titanium having a higher natural potential than a reinforcing bar, and a strip-shaped metal plate or a strip-shaped electrode in which a thin metal wire is woven in a mesh shape. Is covered with mortar or concrete in the shape of a square bar, and the end of the electrode is exposed from the longitudinal end surface of the square bar to form a connection piece.By coating with mortar, the electrode itself can directly contact the reinforcing steel. Therefore, an accurate distance between electrodes can be ensured, a uniform anticorrosion current can be passed, and the anticorrosion target such as a reinforcing bar can be reliably prevented from corroding.

【図面の簡単な説明】[Brief description of the drawings]

【図1】実施例のアノード電極体の斜視図である。FIG. 1 is a perspective view of an anode electrode body of an embodiment.

【図2】橋桁の断面図である。FIG. 2 is a sectional view of a bridge girder.

【図3】鉄筋の腐食によってコンクリートが剥離したコ
ンクリート桁の補修に適用した例の説明図である。
FIG. 3 is an explanatory view of an example applied to repair of a concrete girder from which concrete has separated due to corrosion of a reinforcing bar.

【図4】アノード電極体を使用する外部電源方式の電気
防食法の説明図である。
FIG. 4 is an explanatory view of an external power supply-type cathodic protection method using an anode electrode body.

【符号の説明】[Explanation of symbols]

1 アノード電極体 2 電極 3 被覆体(モルタル又はコンクリート) 4 接続片 10 コンクリート桁(橋桁) 11 鉄筋 12 PC鋼材 13 コンクリート 14 型枠 15 インサート 16 ボルト 17 骨材 21 直流電源 22 (+)極端子 23 (−)極端子 24、25 リード線 DESCRIPTION OF SYMBOLS 1 Anode electrode body 2 Electrode 3 Coating body (mortar or concrete) 4 Connection piece 10 Concrete girder (bridge girder) 11 Reinforcing steel 12 PC steel 13 Concrete 14 Formwork 15 Insert 16 Bolt 17 Aggregate 21 DC power supply 22 (+) pole terminal 23 (-) Pole terminal 24, 25 Lead wire

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 金属薄板からなる電極、または金属細線
をメッシュ状に織って帯状に形成した電極を、モルタル
又はコンクリートで被覆して角棒を形成し、該角棒の長
手方向端面に該電極の端部が露出した接続片を設けたこ
と特徴とするアノード電極体。
An electrode made of a thin metal plate or an electrode formed by weaving a thin metal wire into a mesh to form a strip is covered with mortar or concrete to form a square bar, and the electrode is formed on the longitudinal end surface of the square bar. An anode electrode body provided with a connection piece whose end is exposed.
【請求項2】 前記電極はチタン(Ti)を主成分とし
たことを特徴とする請求項1記載のアノード電極体。
2. The anode electrode body according to claim 1, wherein said electrode is mainly composed of titanium (Ti).
JP18281999A 1999-06-29 1999-06-29 Repair method for concrete structures Expired - Lifetime JP3798189B2 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009179876A (en) * 2008-02-01 2009-08-13 Ps Mitsubishi Construction Co Ltd Method for cathodically protecting end of existing pc girder
JP2009185508A (en) * 2008-02-06 2009-08-20 Denki Kagaku Kogyo Kk Desalination method for reinforced concrete floor slab
JP2011252186A (en) * 2010-05-31 2011-12-15 Ihi Corp Electrode for electrolytic protection and method for constructing concrete structure

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101396457B1 (en) * 2007-11-01 2014-05-20 한라비스테온공조 주식회사 A Heat Exchanger

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009179876A (en) * 2008-02-01 2009-08-13 Ps Mitsubishi Construction Co Ltd Method for cathodically protecting end of existing pc girder
JP2009185508A (en) * 2008-02-06 2009-08-20 Denki Kagaku Kogyo Kk Desalination method for reinforced concrete floor slab
JP2011252186A (en) * 2010-05-31 2011-12-15 Ihi Corp Electrode for electrolytic protection and method for constructing concrete structure

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