JP2000506909A - カルボン酸を含むポリマー/レゾール樹脂耐汚染性剤 - Google Patents
カルボン酸を含むポリマー/レゾール樹脂耐汚染性剤Info
- Publication number
- JP2000506909A JP2000506909A JP9530173A JP53017397A JP2000506909A JP 2000506909 A JP2000506909 A JP 2000506909A JP 9530173 A JP9530173 A JP 9530173A JP 53017397 A JP53017397 A JP 53017397A JP 2000506909 A JP2000506909 A JP 2000506909A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- composition
- hydroxyphenyl
- bis
- sulfone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 酸性染料による汚染に対して耐性を有するポリアミド基体を提供する組成 物であって、 (A)以下から選ばれるカルボン酸を含む耐汚染性ポリマー: (i)メタクリル酸ポリマー、または (ii)無水マレイン酸と、エチレン性不飽和芳香族類、α−オレフィン、ア ルキルビニルエーテルまたはアルキルアリルエーテルとのコポリマーの加水 分解物、または (iii)(i)および(ii)からなる混合物 および (B)アルカリ金属水酸化物の存在下、ビス(ヒドロキシフェニル)スルホン レゾール樹脂:カルボン酸を含む耐汚染性ポリマーの重量比が、約1:20から 2.5:1.0の範囲内において、スルホネート基またはカルボキシレート基 を含まないビス(ヒドロキシフェニル)スルホンとホルムアルデヒドとを反応 させることにより合成したレゾール縮合物 とを含むことを特徴とする組成物。 2. 前記レゾール縮合物は、ホルムアルデヒド:ビス(ヒドロキシフェニル) スルホンの0.6:1.0から1.1:1.0の範囲内にあるモル比、およびア ルカリ金属水酸化物:ビス(ヒドロキシフェニル)スルホンの0.1:1.0か ら3.5:1.0の範囲内にあるモル比で合成することを特徴とする請求項1に 記載の組成物。 3. 前記カルボン酸を含むポリマーは、ポリメタクリル酸、メタクリル酸のコ ポリマー、または無水マレイン酸と1種類以上のエチレン性不飽和モノマーとの コポリマーの加水分解物であることを特徴とする請求項1に記載の組成物。 4. 前記カルボン酸を含むポリマーは、前記レゾール縮合物の存在下で合成す ることを特徴とする請求項1に記載の組成物。 5. 1種類以上の前記エチレン性不飽和モノマーは、4から12の炭素原子を 含む1−アルケンであることを特徴とする請求項3に記載の組成物。 6. 前記エチレン性不飽和モノマーは、1−オクテンを含むことを特徴とする 請求項3に記載の組成物。 7. 前記エチレン性不飽和モノマーは、以下の式で表されることを特徴とする 請求項3に記載の組成物: (式中、 R2は、H−,CH3−; R3は、H− または CH3O−; R4は、H−, CH3−または CH3CO−、および R3に加えてR4は、−O−CH2−O− である。) 8. 前記エチレン性不飽和モノマーは、スチレンを含むことを特徴する請求項 3に記載の組成物。 9. 請求項1の組成物のいずれかを塗布したポリアミド基体を含むことを特徴 とする酸性染料による汚染に対して耐性を有するポリアミド基体。 10. ポリアミド基体を請求項1の組成物のいずれかを含む水溶液と接触させ る工程と、 酸性染料による汚染に対して耐性を有するポリアミド基体を回収する工程 とを具えることを特徴とする酸性染料に対する耐汚染性をポリアミド樹脂に付与 する方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US60613496A | 1996-02-23 | 1996-02-23 | |
US08/606,134 | 1996-02-23 | ||
PCT/US1997/001631 WO1997031149A1 (en) | 1996-02-23 | 1997-02-06 | Carboxylic acid-containing polymer/resole resin stain-resists |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2000506909A true JP2000506909A (ja) | 2000-06-06 |
JP3819034B2 JP3819034B2 (ja) | 2006-09-06 |
Family
ID=24426695
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP53017397A Expired - Fee Related JP3819034B2 (ja) | 1996-02-23 | 1997-02-06 | カルボン酸を含むポリマー/レゾール樹脂耐汚染性剤 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5708087A (ja) |
EP (1) | EP0882149B1 (ja) |
JP (1) | JP3819034B2 (ja) |
AU (1) | AU726171B2 (ja) |
CA (1) | CA2244855C (ja) |
DE (1) | DE69724765T2 (ja) |
WO (1) | WO1997031149A1 (ja) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5736468A (en) * | 1994-02-02 | 1998-04-07 | Trichromatic Carpet Inc. | Stain resistant polyamide substrate treated with sulfonated phosphated resol resin |
WO2000000691A1 (en) * | 1998-06-30 | 2000-01-06 | Peach State Labs, Inc. | Stain resistant polymers and compositions |
US6280648B1 (en) | 1998-10-20 | 2001-08-28 | Sybron Chemicals, Inc. | Stain resistant composition for polyamide containing substrates |
US6395655B1 (en) * | 1999-12-17 | 2002-05-28 | Trichromatic Carpet Inc. | Polyamide fiber substrate having strain resistance, composition and method |
JP4552294B2 (ja) * | 2000-08-31 | 2010-09-29 | ソニー株式会社 | コンテンツ配信システム、コンテンツ配信方法、および情報処理装置、並びにプログラム提供媒体 |
DE60201142T2 (de) * | 2001-04-20 | 2005-10-20 | Kuraray Co., Ltd., Kurashiki | Wasserlösliche Folie und Verpackung, welche dieselbe verwendet |
US20040028876A1 (en) * | 2001-08-20 | 2004-02-12 | Yoshifumi Mizuno | Inorganic fiber mat and method for production thereof |
US20050015886A1 (en) * | 2003-07-24 | 2005-01-27 | Shaw Industries Group, Inc. | Methods of treating and cleaning fibers, carpet yarns and carpets |
US7521410B2 (en) * | 2004-03-26 | 2009-04-21 | Arrowstar, Llc | Compositions and methods for imparting odor resistance and articles thereof |
US7785374B2 (en) * | 2005-01-24 | 2010-08-31 | Columbia Insurance Co. | Methods and compositions for imparting stain resistance to nylon materials |
ATE373137T1 (de) * | 2005-07-15 | 2007-09-15 | Invista Technologies Sarl | Fleck- und schmutzschutz-zusammensetzung |
US7550199B2 (en) | 2006-07-31 | 2009-06-23 | E.I. Du Pont De Nemours And Company | Copolymers for stain resistance |
US20080057019A1 (en) * | 2006-09-06 | 2008-03-06 | Collier Robert B | Compositions and methods for imparting odor resistance and articles thereof |
US20080206506A1 (en) * | 2007-02-23 | 2008-08-28 | Invista North America S.Ar.I. | New stain resistant barrier fabric |
US7642333B2 (en) * | 2007-05-21 | 2010-01-05 | Georgia-Pacific Chemicals Llc | Anhydride and resorcinol latent catalyst system for improving cure characteristics of phenolic resins |
US7914890B2 (en) * | 2007-12-19 | 2011-03-29 | E.I. Dupont De Nemours And Company | Cyclic olefin-maleic acid copolymers for stain resists |
US20100130085A1 (en) * | 2008-11-25 | 2010-05-27 | Invista North America S.A R.L. | Moisture-vapor-breathable and liquid-impermissible structures, moisture-vapor-breathable and liquid-impermissible upholstery structures and methods of making moisture-vapor-breathable and liquid-impermissible structures |
US20130101782A1 (en) * | 2011-10-19 | 2013-04-25 | E I Du Pont De Nemours And Company | Nonfluorinated soil and stain resist compositions |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1972754A (en) * | 1932-09-29 | 1934-09-04 | Firm Of J R Geigy S A | Process for the manufacture of tanning substances |
US4146686A (en) * | 1978-01-23 | 1979-03-27 | Monsanto Company | Phenolic resin composition and a battery separator impregnated therewith |
ZA889534B (en) * | 1987-12-21 | 1990-08-29 | Du Pont | Stain-resistant aromatic/meleic anhydride polymers |
KR920006476B1 (ko) * | 1987-12-21 | 1992-08-07 | 이 아이 듀우판 디 네모아 앤드 캄파니 | 방오성 폴리아미드 직물 지지체 및 직물 지지체에 방오성을 제공하는 방법 |
US4937123A (en) * | 1988-03-11 | 1990-06-26 | Minnesota Mining And Manufacturing Company | Process for providing polyamide materials with stain resistance |
US4940757A (en) * | 1989-04-20 | 1990-07-10 | Peach State Labs, Inc. | Stain resistant polymeric composition |
US5135774A (en) * | 1990-03-27 | 1992-08-04 | Allied-Signal Inc. | Method to impart coffee stain resistance to polyamide fibers |
WO1991019849A1 (en) * | 1990-06-12 | 1991-12-26 | E.I. Du Pont De Nemours And Company | Stain-resistant fabrics |
US5328766A (en) * | 1990-06-26 | 1994-07-12 | West Point Pepperell, Inc. | Stain-resistant, lightfast polyamide textile products and woolen goods and compositions and processes therefor |
CA2098120A1 (en) * | 1990-12-13 | 1992-06-14 | Engelbert Pechhold | Maleic anhydride/olefin polymer stain-resists |
WO1992012286A1 (en) * | 1990-12-27 | 1992-07-23 | E.I. Du Pont De Nemours And Company | Maleic anhydride/vinyl or allyl ether polymer stain-resists |
DE4223830A1 (de) * | 1992-07-20 | 1994-01-27 | Sandoz Ag | Schmutzabweisendes Ausrüstungsmittel |
WO1994018378A1 (en) * | 1993-02-02 | 1994-08-18 | E.I. Du Pont De Nemours And Company | Bis(hydroxyphenyl)sulfone resoles as polyamide stain-resists |
US5401554A (en) * | 1993-12-21 | 1995-03-28 | Basf Corporation | Process for the manufacture of a stain resistant melt colored carpet |
US5436049A (en) * | 1993-12-21 | 1995-07-25 | Basf Corporation | Process for the manufacture of a stain resistant carpet |
-
1997
- 1997-02-06 DE DE69724765T patent/DE69724765T2/de not_active Expired - Lifetime
- 1997-02-06 EP EP97905714A patent/EP0882149B1/en not_active Expired - Lifetime
- 1997-02-06 WO PCT/US1997/001631 patent/WO1997031149A1/en active IP Right Grant
- 1997-02-06 AU AU22542/97A patent/AU726171B2/en not_active Ceased
- 1997-02-06 JP JP53017397A patent/JP3819034B2/ja not_active Expired - Fee Related
- 1997-02-06 CA CA002244855A patent/CA2244855C/en not_active Expired - Fee Related
- 1997-05-14 US US08/856,214 patent/US5708087A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0882149B1 (en) | 2003-09-10 |
DE69724765D1 (de) | 2003-10-16 |
AU726171B2 (en) | 2000-11-02 |
US5708087A (en) | 1998-01-13 |
WO1997031149A1 (en) | 1997-08-28 |
EP0882149A1 (en) | 1998-12-09 |
CA2244855C (en) | 2007-03-20 |
JP3819034B2 (ja) | 2006-09-06 |
DE69724765T2 (de) | 2004-07-15 |
CA2244855A1 (en) | 1997-08-28 |
AU2254297A (en) | 1997-09-10 |
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