JP2000220033A - Polyester conjugate fiber - Google Patents
Polyester conjugate fiberInfo
- Publication number
- JP2000220033A JP2000220033A JP1955099A JP1955099A JP2000220033A JP 2000220033 A JP2000220033 A JP 2000220033A JP 1955099 A JP1955099 A JP 1955099A JP 1955099 A JP1955099 A JP 1955099A JP 2000220033 A JP2000220033 A JP 2000220033A
- Authority
- JP
- Japan
- Prior art keywords
- viscosity
- yarn
- elongation
- viscosity component
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Multicomponent Fibers (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、捲縮発現性能を有
するポリエステル複合繊維に関するもので、更に詳しく
は粘度の異なる2成分からなる複合繊維で、織編物にし
た際にストレッチバック性を有し、大きな膨らみと反発
性を兼ね備えた高級織編物とすることができるポリエス
テル複合繊維に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polyester composite fiber having a crimp developing performance, and more particularly, to a composite fiber comprising two components having different viscosities and having stretch-back properties when formed into a woven or knitted fabric. The present invention relates to a polyester composite fiber which can be used as a high-grade woven or knitted fabric having both large swelling and resilience.
【0002】[0002]
【従来の技術】一般に、ポリエステルやポリアミドなど
の合成繊維はその優れた特徴を備えているため衣料用か
ら産業用と広範囲に用いられている。中でもポリエステ
ル繊維は強度、寸法安定性、イージケアー性等の機能性
に優れているため衣料用から産業用まで広範囲に用いら
れている。2. Description of the Related Art In general, synthetic fibers such as polyesters and polyamides are widely used for clothing to industrial purposes because of their excellent characteristics. Among them, polyester fibers are widely used from apparel to industrial use because of their excellent functions such as strength, dimensional stability, and easy care property.
【0003】とりわけポリエステル繊維は用途の多様化
に伴い捲縮性の付与、伸縮性、制電性、防汚性、清涼
感、蓄熱性、防透性、保温性、軽量性、抗菌性、発色
性、極細化、起毛性、ソフト感、ドレープ性等機能性か
ら感性に富んだ織編物の開発が活発に行われている。例
えば特開平2−307924号公報では仮撚を施して捲
縮を付与した糸条とポリエステル糸条とを空気交絡さ
せ、ループやタルミを形成させた嵩高加工糸が提案され
ている。この加工糸は、表面に存在するループやタルミ
によって嵩高化されているものの、糸条内部、いわゆる
芯部を形成する糸条には膨らみ感がなく、このため加工
糸の状態では嵩高性を有するものの、製編織して得られ
る布帛にはストレッチバック性、膨らみ感を付与するこ
とはできなかった。特開平3−193945号公報に
は、防皺性と嵩高性を有し、かつ超ソフト風合いを呈す
る織物を得ることが可能な複合糸の製造方法が開示され
ているが、該複合糸を構成する繊維は捲縮を発現しない
フラットヤーンであるため、織物のストレッチ性が不足
して着用感が損なわれるという問題を有していた。[0003] In particular, polyester fibers are provided with crimpability, stretchability, antistatic property, antifouling property, cool feeling, heat storage property, permeability prevention, heat retention property, light weight property, antibacterial property, color development with diversification of uses. The development of woven and knitted fabrics that are highly sensitive from functionalities such as fineness, ultrafineness, napping, softness, and drape are being actively performed. For example, JP-A-2-307924 proposes a bulky processed yarn in which false twisted and crimped yarn and polyester yarn are entangled with air to form a loop or a tarmi. Although this processed yarn is bulked by loops and lumps present on the surface, the yarn forming the so-called core inside the yarn does not have a swelling feeling, and therefore has a bulky property in the state of the processed yarn. However, the fabric obtained by knitting and weaving could not be provided with stretchback properties and swelling. Japanese Unexamined Patent Publication (Kokai) No. 3-193945 discloses a method for producing a composite yarn having anti-wrinkling properties and bulkiness and capable of obtaining a woven fabric having an ultra-soft texture. The resulting fiber is a flat yarn that does not exhibit crimping, and thus has a problem that the stretchability of the woven fabric is insufficient and the feeling of wearing is impaired.
【0004】また、織物に優れた伸縮性を付与するため
には種々の方法が採用されている。例えば、織物を構成
する糸条として、伸縮性に優れたポリウレタン系糸条を
用いるという方法がある。しかし、このポリウレタン系
糸条は、ポリウレタン固有の性質として風合いが硬く、
従って織物の風合いが低下する、あるいは織物のドレー
プ性が低下するという欠点があった。この欠点を回避す
るために、ポリウレタン系糸条とポリエステル系糸条と
を併用して織物を製織することも行われている。しかし
ながら、ポリウレタン系糸条とポリエステル系糸条とで
は、染色性に差があり、織物を染色する際に染色加工が
複雑になったり、あるいは所望の色彩(多くの場合濃
色)に染色することが困難になるという欠点があった。[0004] Various methods have been adopted to impart excellent stretchability to the woven fabric. For example, there is a method in which a polyurethane yarn having excellent elasticity is used as a yarn constituting a woven fabric. However, this polyurethane yarn has a hard texture as a unique property of polyurethane,
Therefore, there is a drawback that the texture of the fabric is reduced or the drape property of the fabric is reduced. To avoid this drawback, weaving a woven fabric using a combination of a polyurethane yarn and a polyester yarn has also been performed. However, there is a difference in the dyeability between the polyurethane yarn and the polyester yarn, so that the dyeing process becomes complicated when dyeing the fabric, or the yarn is dyed in a desired color (often a dark color). However, there is a drawback that it becomes difficult.
【0005】一方、特開平4−240231号公報に
は、乾熱収縮率差を有するポリエステルマルチフィラメ
ントと自発伸長性を有するコンジュゲートフィラメント
からなる混繊糸が開示されている。しかしながら、該混
繊糸はコンジュゲートフィラメントが熱処理により自発
伸長するため、布帛にした場合芯部にフラットなマルチ
フィラメント、鞘部にコンジュゲートフィラメントが配
置され、捲縮によるストレッチ性が不足する上、肌触り
が悪く、着用感が損なわれるという問題を有していた。On the other hand, Japanese Patent Application Laid-Open No. 4-240231 discloses a mixed yarn comprising a polyester multifilament having a difference in dry heat shrinkage and a conjugate filament having spontaneous elongation. However, since the conjugate filaments are spontaneously elongated by heat treatment, the mixed filaments have a flat multifilament in the core and a conjugate filament in the sheath when formed into a fabric, resulting in insufficient stretchability due to crimping. There was a problem that the feel was bad and the wearing feeling was impaired.
【0006】[0006]
【発明が解決しようとする課題】本発明の目的は、上記
従来技術の欠点を解消し、特に高級感のある織編物用に
した際にポリウレタン系糸条を用いることなく快適なス
トレッチバック性を有し、大きな膨らみと反発性を兼ね
備えた高級織編物とすることができるポリエステル複合
繊維に関するものである。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned drawbacks of the prior art, and to provide a comfortable stretch-back property without using a polyurethane yarn, especially when used for a high-quality woven or knitted fabric. The present invention relates to a polyester composite fiber which can be used as a high-grade woven or knitted fabric having both large swelling and resilience.
【0007】[0007]
【課題を解決するための手段】本発明の上記目的は、粘
度の異なる2成分を繊維軸方向に貼り合わせた複合繊維
で、破断伸度と収縮応力が下式の関係にあることを特徴
とするポリエステル複合繊維によって達成することが出
来る。An object of the present invention is to provide a conjugate fiber in which two components having different viscosities are bonded in the direction of the fiber axis, wherein the elongation at break and the shrinkage stress have the following relationship. This can be achieved by a polyester composite fiber.
【0008】Y≧{6.0×(1/X)} ただし、Yは収縮応力(g/d) Xは破断伸度(%)Y ≧ {6.0 × (1 / X)} where Y is shrinkage stress (g / d) X is breaking elongation (%)
【0009】[0009]
【発明の実施の形態】以下、本発明を詳細に説明する。
本発明のポリエステル複合繊維は、粘度の異なる2成分
のポリマを繊維軸方向に貼り合わせたバイメタル複合繊
維である。本発明の複合繊維は破断伸度(X)と収縮応
力(Y)の関係がY≧{6.0×(1/X)}であるこ
とが必要である。両者の関係を例を挙げて詳細に説明す
る。例えば破断伸度が20%時の収縮応力は0.30g/
d以上、破断伸度が30%時の収縮応力は0.20g/d以
上、破断伸度が40%時の収縮応力は0.15g/d以上
であることを示している。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
The polyester composite fiber of the present invention is a bimetal composite fiber in which two-component polymers having different viscosities are bonded in the fiber axis direction. The relationship between the breaking elongation (X) and the shrinkage stress (Y) of the conjugate fiber of the present invention needs to be Y ≧ {6.0 × (1 / X)}. The relationship between the two will be described in detail using an example. For example, when the breaking elongation is 20%, the shrinkage stress is 0.30 g /
This indicates that the shrinkage stress at a break elongation of 30% or more is 0.20 g / d or more, and the shrinkage stress at a break elongation of 40% is 0.15 g / d or more.
【0010】破断伸度20%とは、複合紡糸した未延伸
糸を所定の延伸倍率で伸度20%になるように延伸した
時の破断伸度の値である。破断伸度30%、破断伸度4
0%も同様に所定の延伸倍率でそれぞれの伸度になるよ
うに延伸したときの値であり、この際に関係式Y≧
{6.0×(1/X)}を満足するものである。The elongation at break of 20% is a value of elongation at break when a composite spun undrawn yarn is drawn at a predetermined draw ratio so as to have an elongation of 20%. Elongation at break 30%, Elongation at break 4
Similarly, 0% is a value when the film is stretched at a predetermined stretching ratio so as to have each elongation. In this case, the relational expression Y ≧
It satisfies {6.0 × (1 / X)}.
【0011】例えば、破断伸度が20%時の収縮応力は
0.30g/d以上である。収縮応力が0.30g/d以上あ
ると織編物にしたときにその拘束力に負けることなく捲
縮発現性能を有し、充分なストレッチバック性が得ら
れ、この結果として、大きな嵩高性と張り、腰、反発性
が得られる。この収縮応力は好ましくは0.40g/d以
上、更に好ましくは0.50g/d以上である。同様に、
破断伸度が30%時の収縮応力が0.20g/d以上であ
り、これらについても関係式Y≧{6.0×(1/
X)}を満足するものである。また、伸度の範囲として
は実用的な観点より10〜60%が好ましい範囲であ
る。For example, when the breaking elongation is 20%, the shrinkage stress is 0.30 g / d or more. When the shrinkage stress is 0.30 g / d or more, the woven or knitted fabric has a crimp developing performance without losing its binding force, and a sufficient stretch back property is obtained. As a result, large bulkiness and tension , Waist and resilience are obtained. This shrinkage stress is preferably at least 0.40 g / d, more preferably at least 0.50 g / d. Similarly,
The shrinkage stress when the elongation at break is 30% is 0.20 g / d or more, and the relational expression Y ≧ {6.0 × (1 /
X) Satisfies}. The range of elongation is preferably 10 to 60% from a practical viewpoint.
【0012】本発明の複合繊維は最終用途により種々使
い分けが可能で、破断伸度が20%レベルの高捲縮発現
性の本発明糸は他のポリエステル繊維とも好適に混繊使
用が可能であるがポリエステル繊維以外の他素材例えば
レーヨン、アセテート、天然繊維等とも好適に混繊使用
が可能である。破断伸度が30%レベルの本発明糸は特
にポリエステルとの混繊に好適である。また破断伸度が
40%レベルの本発明糸は残留伸度を多く有している関
係で仮撚加工、仮撚複合混繊に好適に使用できる。The composite fiber of the present invention can be used in various ways depending on the final use. The yarn of the present invention having a high elongation with a breaking elongation of 20% level can be suitably mixed with other polyester fibers. However, other materials other than polyester fibers, such as rayon, acetate, and natural fibers, can be suitably used. The yarn of the present invention having a breaking elongation of the level of 30% is particularly suitable for blending with polyester. In addition, the yarn of the present invention having a breaking elongation of 40% can be suitably used for false twisting and false-twisted mixed fiber because of its high residual elongation.
【0013】本発明の破断伸度とは通常のS−Sカーブ
で測定した伸度である。The elongation at break of the present invention is an elongation measured by an ordinary SS curve.
【0014】本発明の収縮応力とはカネボウエンジニア
リング(株)社製・熱応力測定機「タイプKE−2S」
を用い次の方法で測定した値である。試料長100mm
(ループで200mm)を測定機にセットし、初荷重1/
10g/dで、常温から250℃まで2.5℃/secの昇温
速度で加熱したときの収縮力の変化を歪計で検出し、チ
ャートからMAX応力値(g)を読みとりg/dに換算
した値である。What is the shrinkage stress of the present invention? Thermal stress measuring device "Type KE-2S" manufactured by Kanebo Engineering Co., Ltd.
Is a value measured by the following method. Sample length 100mm
(200mm in loop) is set on the measuring machine and the initial load 1 /
At 10 g / d, a change in shrinkage force when heated at a heating rate of 2.5 ° C./sec from room temperature to 250 ° C. is detected by a strain meter, and a MAX stress value (g) is read from a chart, and converted to g / d. It is a converted value.
【0015】本発明の複合繊維はカセ採りしてフリーの
状態でも捲縮を発現するが、沸騰水処理後に多くの捲縮
数を発現する潜在捲縮性である。この沸騰水処理後の発
現捲縮数は5コ/cm以上が好ましい。5コ/cm以上
あるとストレッチバック性が良好となり嵩高性も得られ
好ましい。また織編物にしたときに良好なストレッチバ
ック性が得られ、そして嵩高性、張り、腰、反発性も得
られ好ましい。更に好ましくは7コ/cm以上、より一
層好ましくは10コ/cm以上である。The conjugate fiber of the present invention develops crimp even in a free state after skewing, but has a latent crimp property in which a large number of crimps are developed after boiling water treatment. The number of developed crimps after the boiling water treatment is preferably 5 / cm or more. When it is at least 5 cores / cm, the stretch back property will be good and the bulkiness will be obtained, which is preferable. Further, when formed into a woven or knitted fabric, favorable stretch-back properties are obtained, and bulkiness, tension, waist, and resilience are also obtained, which is preferable. It is more preferably at least 7 cores / cm, even more preferably at least 10 cores / cm.
【0016】本発明の捲縮数とは次に説明する方法によ
り測定された値である。まず、7cmの長さにカットした
サンプルをフリーの状態で100℃×15分沸水処理を
行う。次に、取り出したらすぐに1分間冷水処理し、し
かる後5時間自然乾燥させる。乾燥後のサンプルを資料
板に貼り、幅1cmのスリット板をかぶせてプロジェクタ
ーでスクリーンに写して捲縮数を読みとる。n=2で1
0サンプル測定する。The number of crimps according to the present invention is a value measured by the method described below. First, a sample cut to a length of 7 cm is subjected to a boiling water treatment at 100 ° C. for 15 minutes in a free state. Next, immediately after being taken out, it is treated with cold water for 1 minute and then naturally dried for 5 hours. The sample after drying is stuck on a sample plate, covered with a slit plate having a width of 1 cm, transferred to a screen with a projector, and the number of crimps is read. 1 for n = 2
Measure 0 samples.
【0017】捲縮数は数が多いほどストレッチバック性
は向上する。しかしながらこの捲縮数は貼り合わせるポ
リマの粘度差が小さいと少ない捲縮数しか得られず、逆
に大きな粘度差を持たせると捲縮数は多く得られるが紡
糸、延伸時に糸切れが多発して生産に適さなくなる。本
発明の複合繊維の極限粘度差△IVは0.12〜0.3
5である。ΔIVが0.12以上あると所定の延伸倍率
で延伸した時に捲縮発現能力が生じ、収縮応力、捲縮発
現数も得られるので好ましい。より好ましくは0.15
以上、更に好ましくは0.20以上である。また、ΔI
Vが0.35以下であると紡糸、延伸時の糸切れも少な
く良好な捲縮発現と収縮応力が得られるので好ましい。
更に好ましくは0.30以下である。The larger the number of crimps, the better the stretch back property. However, when the viscosity difference of the polymer to be bonded is small, only a small number of crimps can be obtained, and when the viscosity difference is large, a large number of crimps can be obtained, but yarn breakage occurs frequently during spinning and stretching. It is not suitable for production. The intrinsic viscosity difference ΔIV of the conjugate fiber of the present invention is 0.12 to 0.3.
5 When ΔIV is 0.12 or more, crimping ability is generated when the film is stretched at a predetermined stretching ratio, and the shrinkage stress and the number of crimps can be obtained. More preferably 0.15
It is more preferably 0.20 or more. Also, ΔI
When V is 0.35 or less, it is preferable because yarn breakage during spinning and stretching is small and good crimping and shrinkage stress can be obtained.
More preferably, it is 0.30 or less.
【0018】更に詳しく説明する。複合繊維の低粘度成
分の極限粘度は0.45〜0.55である。低粘度成分
の極限粘度が低いほどΔIVが大きく採れ、得られる捲
縮数も多くなる。また極限粘度が0.45以上あれば原
糸強度が低下して実用に適さなくなることもなく好まし
い。更に捲縮発現性、収縮応力、原糸強度、製糸性等を
勘案してより好ましい低粘度成分の極限粘度は0.47
〜0.53である。This will be described in more detail. The intrinsic viscosity of the low-viscosity component of the conjugate fiber is 0.45 to 0.55. The lower the intrinsic viscosity of the low-viscosity component, the larger ΔIV is taken, and the greater the number of crimps obtained. Further, when the intrinsic viscosity is 0.45 or more, it is preferable because the raw yarn strength is not reduced and the yarn is not suitable for practical use. Further, the intrinsic viscosity of the low-viscosity component is more preferably 0.47 in consideration of the crimp development, shrinkage stress, raw yarn strength, yarn-making properties, and the like.
0.50.53.
【0019】次に高粘度成分の極限粘度は0.60〜
0.85である。この高粘度成分が複合繊維の製糸性、
強伸度特性に大きな影響を与えるので低粘度成分と組み
合わせるポリマの選定は重要である。製糸性を重視して
高い粘度同士の組み合わせでは捲縮特性が不良となる。
また捲縮特性を重視し過ぎ、ΔIVを大きく採りすぎる
と安定生産が不可能となる。このような見知より高粘度
成分の極限粘度は下限は0.60以上が実用的な強度が
得られ捲縮特性も得られるので好ましい。また、上限は
製糸性が良好で良好な捲縮特性が得られる0.85以下
が好ましい。更に好ましくは0.65〜0.75であ
る。Next, the intrinsic viscosity of the high viscosity component is 0.60 to
0.85. This high-viscosity component makes the yarn-forming properties of the composite fiber
It is important to select a polymer to be used in combination with a low-viscosity component because it has a significant effect on the elongation properties. A combination of high viscosities with an emphasis on the spinning properties results in poor crimping characteristics.
Further, if the crimping property is considered too important, and ΔIV is taken too large, stable production becomes impossible. From these observations, the lower limit of the intrinsic viscosity of the high-viscosity component is preferably 0.60 or more because practical strength is obtained and crimping properties are also obtained. The upper limit is preferably 0.85 or less, at which good spinnability and good crimping properties can be obtained. More preferably, it is 0.65 to 0.75.
【0020】ここでいう極限粘度(IV)は、温度25
℃においてオルソクロロフェノール(以下OCPと称す
る。)10mlに対し試料料0.8gを溶解し、オスト
ワルド粘度計を用いて相対粘度(ηr)を下式により求
め、更にIVを算出する。 ηr=(η/ηo)−(t・d/to・do) IV=0.0243ηr+0.2634 ここで、 η:ポリマの溶液の粘度 ηo:溶媒の粘度 t :溶液の落下時間(秒) d :溶液の密度(g/cm3 ) to:OCPの落下時間(秒) do:OCPの密度(g/cm3 ) 本発明の複合繊維の強度は2.5g/d以上が好ましく、
更に好ましくは3.0g/d以上である。強度が2.5g/d
以上あると原糸製造工程において毛羽、糸切れが減少で
き、かつ高次加工工程での取り扱いにおいても糸切れ、
毛羽が減少でき好ましい。更に、製編織した織編物をア
ルカリ減量を含めた染色仕上げ加工しても、布帛の引き
裂き強度の低下が少なく好ましい。The intrinsic viscosity (IV) referred to here is the temperature 25
At 0 ° C., 0.8 g of a sample material is dissolved in 10 ml of orthochlorophenol (hereinafter referred to as OCP), and the relative viscosity (ηr) is obtained by the following formula using an Ostwald viscometer, and IV is further calculated. ηr = (η / ηo) − (t · d / to · do) IV = 0.0243 ηr + 0.2634 where η: viscosity of polymer solution ηo: viscosity of solvent t: drop time of solution (seconds) d: Density of solution (g / cm 3 ) to: drop time of OCP (second) do: density of OCP (g / cm 3 ) The strength of the composite fiber of the present invention is preferably 2.5 g / d or more,
More preferably, it is 3.0 g / d or more. 2.5g / d strength
With the above, fluff and yarn breakage can be reduced in the original yarn manufacturing process, and yarn breakage also occurs in handling in the high-order processing process,
It is preferable because fluff can be reduced. Further, even if the woven or knitted fabric is dyed and finished including alkali weight reduction, the tear strength of the fabric is preferably reduced as it is small.
【0021】本発明の複合繊維の見掛け収縮率は40%
以上が好ましい。この値が40%以上あるとストレッチ
バック性が良好となり嵩高性、張り、腰、反発性も得ら
れる。更に好ましくは50%以上である。The apparent shrinkage of the composite fiber of the present invention is 40%.
The above is preferred. When this value is at least 40%, the stretch-back property will be good and bulkiness, tension, waist, and resilience will be obtained. More preferably, it is 50% or more.
【0022】本発明の見掛け収縮率とは次に説明する方
法により測定された値である。まず、張力をかけずに巻
尺機で10回巻きし、これに(0.01g/d×10×
2)gの加重をかけて原長(l0)を測定する。次に、
加重を外してフリーとして100℃×15分間沸水処理
する。取り出した後直ちに1分間冷水処理し、しかる後
5時間自然乾燥させる。前記の加重をかけて30秒間待
ってから処理後長(l1)を測定する。次式より求め
る。 見掛け収縮率=(l0−l1 )/l0×100 本発明の複合繊維の高粘度成分と低粘度成分の複合比率
は40:60〜70:30の範囲が好ましい。捲縮数を
より細かく数を多く発現させるには、低粘度成分の複合
比率を同等かやや多くすると好ましい。一方、発現捲縮
数と糸条のタフネスを得るには高粘度成分の複合比率を
同等かそれ以上にすると好ましい。発現捲縮数と収縮応
力、そして糸条のタフネスもすべて満足させる複合比は
50:50〜60:40が好ましい。The apparent shrinkage of the present invention is a value measured by the method described below. First of all, it is wound ten times with a tape measure machine without applying tension, and (0.01 g / d × 10 ×
2) Measure the original length (l 0 ) with a weight of g. next,
Remove the load, set free and perform boiling water treatment at 100 ° C for 15 minutes. Immediately after taking out, it is treated with cold water for 1 minute and then naturally dried for 5 hours. After applying the above-mentioned weight and waiting for 30 seconds, the post-processing length (l 1 ) is measured. It is calculated from the following equation Apparent shrinkage = (l 0 −l 1 ) / l 0 × 100 The composite ratio of the high-viscosity component and the low-viscosity component of the composite fiber of the present invention is preferably in the range of 40:60 to 70:30. In order to make the number of crimps smaller and more numerous, it is preferable that the composite ratio of the low-viscosity component is equal or slightly larger. On the other hand, in order to obtain the expressed number of crimps and the toughness of the yarn, it is preferable that the composite ratio of the high-viscosity component is equal or higher. The composite ratio that satisfies all the expressed number of crimps, shrinkage stress, and toughness of the yarn is preferably 50:50 to 60:40.
【0023】本発明の複合繊維の高粘度成分、低粘度成
分の両ポリマの貼り合わせ界面は偏芯タイプ、直線タイ
プのどちらも適用できるが、捲縮発現の容易性より境界
面は実質的に直線であることが好ましい。実質的に直線
とは境界面の接触角度をαとするとαは±20度までで
ある。偏芯タイプとはαが20度より大きく三日月状、
または高粘度、低粘度ポリマで覆われているものを示
す。Either the eccentric type or the linear type can be applied to the bonding interface of the high-viscosity component and the low-viscosity component polymer of the conjugate fiber of the present invention. It is preferably a straight line. When the contact angle of the boundary surface with a substantially straight line is α, α is up to ± 20 degrees. With the eccentric type, α is larger than 20 degrees and crescent shape,
Or, those covered with high-viscosity, low-viscosity polymers.
【0024】本発明の複合繊維を構成する高粘度成分、
低粘度成分のポリマは取り扱いの容易性、捲縮発現のし
やすさ、熱処理による収縮差を糸や織物の膨らみへ容易
に交換できる点、織物に対しドレープ性を付与させ易い
点、および寸法安定性の点等からポリエステルポリマが
好ましい。A high-viscosity component constituting the composite fiber of the present invention,
Low-viscosity polymer is easy to handle, easy to develop crimp, easy to change shrinkage difference due to heat treatment to swelling of yarn and fabric, easy to impart drape to fabric, and dimensionally stable From the viewpoint of properties and the like, polyester polymers are preferred.
【0025】複合繊維を構成する高粘度成分、低粘度成
分がポリエステルとはテレフタル酸またはその低級アル
キル誘導体(炭素数1〜4のアルカノールジエステル)
とエチレングリコールとから、あるいはテレフタル酸ま
たはその低級アルキル誘導体とエチレングリコールおよ
び少なくとも1種の他成分とから、またはビス−2−ヒ
ドロキシエチレンテレフタレートまたはその低重合体、
あるいはビス−2−ヒドロキシエチレンテレフタレート
および少なくとも1種の他の成分とから得られるポリエ
ステル単位の少なくとも70%がポリエチレンテレフタ
レートであるポリエステルである。The high-viscosity component and the low-viscosity component constituting the composite fiber are polyesters. Terephthalic acid or its lower alkyl derivative (alkanol diester having 1 to 4 carbon atoms)
And ethylene glycol, or from terephthalic acid or a lower alkyl derivative thereof and ethylene glycol and at least one other component, or bis-2-hydroxyethylene terephthalate or a lower polymer thereof,
Alternatively, a polyester in which at least 70% of the polyester units obtained from bis-2-hydroxyethylene terephthalate and at least one other component is polyethylene terephthalate.
【0026】この場合第3成分としては例えばシュウ
酸、アジピン酸、アゼライン酸、セバシン酸などの脂肪
族ジカルボン酸、イソフタル酸、フタル酸、2−6ナフ
タリンジカルボン酸、ジフェン酸などの芳香族ジカルボ
ン酸、1−2−シクロブタンジカルボン酸などの脂環を
もつジカルボン酸などがあげられるがいずれもこれらに
限定されるものではない。In this case, examples of the third component include aliphatic dicarboxylic acids such as oxalic acid, adipic acid, azelaic acid and sebacic acid, and aromatic dicarboxylic acids such as isophthalic acid, phthalic acid, 2-6 naphthalene dicarboxylic acid and diphenic acid. And dicarboxylic acids having an alicyclic ring, such as, for example, 1-2-cyclobutanedicarboxylic acid. However, none of these are limited thereto.
【0027】次に本発明のポリエステル複合繊維の製造
方法について説明する。本発明の複合繊維の製造方法
は、高粘度成分と低粘度成分からなる複合繊維で、高粘
度成分と、低粘度成分を複合紡糸機を用い、所定の複合
パック、複合口金でサイドバイサイド型に貼り合わせ複
合紡糸して未延伸糸を得る。この時に高粘度成分と、低
粘度成分の複合比率は吐出量を調整することで得られ
る。また、両ポリマの極限粘度差は用いるポリマにより
自由に選択できる。しかしながら前記した如く、粘度差
が大き過ぎると捲縮特性は良好となるが、口金吐出孔直
下で両成分の流速差のために吐出線曲がりが大きくなり
紡糸時の糸切れが多発するので本発明の範囲内が好まし
い。逆に粘度差が少なすぎると製糸性は良好となるも捲
縮発現性が低下するので本発明の範囲内の粘度差を選ぶ
ことが好ましい。貼り合わせ境界面を直線にするには、
高粘度成分を縦方向から、低粘度成分を横方向から導入
させ吐出部からの距離を調整した口金により得られる。
貼り合わせ面を偏芯させるには、前記口金の合流位置の
調整で可能であるが、極限粘度差が比較的小さいポリマ
どうしの場合は、両ポリマを縦方向から並列に導入し複
合させることで容易に得ることができる。このようにし
て複合繊維の未延伸糸を得ることができる。Next, a method for producing the polyester composite fiber of the present invention will be described. The method for producing a conjugate fiber of the present invention is a conjugate fiber comprising a high-viscosity component and a low-viscosity component, and a high-viscosity component and a low-viscosity component are pasted into a side-by-side type with a predetermined composite pack and a composite die using a composite spinning machine. An undrawn yarn is obtained by composite spinning. At this time, the composite ratio of the high viscosity component and the low viscosity component can be obtained by adjusting the ejection amount. The difference in intrinsic viscosity between the two polymers can be freely selected depending on the polymer used. However, as described above, if the viscosity difference is too large, the crimping characteristics are good, but the discharge line bend becomes large due to the flow velocity difference between both components immediately below the die discharge hole, and yarn breakage during spinning frequently occurs. Is preferably within the range. Conversely, if the difference in viscosity is too small, the spinning properties will be good, but the crimping property will be reduced. Therefore, it is preferable to select a viscosity difference within the range of the present invention. To make the bonding boundary straight,
A high-viscosity component is introduced from the vertical direction, and a low-viscosity component is introduced from the horizontal direction, and can be obtained by adjusting the distance from the discharge unit.
To decenter the bonding surface, it is possible to adjust the merging position of the die, but in the case of polymers having a relatively small intrinsic viscosity difference, by introducing both polymers in parallel from the vertical direction and combining them. Can be easily obtained. Thus, an undrawn yarn of the conjugate fiber can be obtained.
【0028】この未延伸糸を用い通常の延伸機で所定の
破断伸度となるように延伸してポリエステル複合繊維を
得る。破断伸度が20%、30%、40%レベルの複合
繊維を得るにはそれぞれ所定の延伸倍率にすることで得
ることができる。The undrawn yarn is drawn by a normal drawing machine to a predetermined breaking elongation to obtain a polyester composite fiber. In order to obtain a conjugate fiber having a breaking elongation of 20%, 30%, or 40%, it is possible to obtain a conjugate fiber at a predetermined draw ratio.
【0029】破断伸度が10%未満になると延伸での糸
切れが多く発生するのでむやみに高倍率延伸は好ましく
ない。また破断伸度を例えば60%以上とすると本発明
の捲縮特性、強度が得られず実用に適さなくなる。If the elongation at break is less than 10%, many yarn breaks occur during stretching, so that high-magnification stretching is not preferred. If the elongation at break is, for example, 60% or more, the crimping properties and strength of the present invention cannot be obtained, which is not suitable for practical use.
【0030】本発明の複合繊維はこのまま単独で経糸、
緯糸に用いても良く、他の糸と混繊して用いても良い。
また仮撚加工を付与しても良く、仮撚混繊しても良い。
破断伸度が約30%レベル以下の比較的低伸度の複合繊
維についてはこのまま好適に生糸使用に用いることがで
きる。また、破断伸度が約40%レベル以上の比較的高
伸度の複合繊維については好適に仮撚加工に使用でき
る。また実撚を付与しても良く、実撚混繊しても良く、
またこれら任意の組み合わせでも良く、本発明の複合繊
維の特長を発揮させるいかなる方法を用いても何ら差し
支えない。The conjugate fiber of the present invention is used alone as it is for the warp,
It may be used for a weft, or may be used by mixing with other yarns.
In addition, false twisting may be applied, or false twist may be mixed.
A relatively low elongation composite fiber having a breaking elongation of about 30% or less can be suitably used for raw silk as it is. Further, conjugate fibers having a relatively high elongation at break elongation of about 40% or more can be suitably used for false twisting. Also, a real twist may be given, or a real twist may be mixed,
In addition, any combination of these may be used, and any method that exerts the characteristics of the conjugate fiber of the present invention may be used.
【0031】本発明のポリエステル複合繊維を用い織編
物を製造し、婦人用素材にはアルカリ減量処理が好適に
用いることができる。またスポーツ用途では特にアルカ
リ減量処理は必要でなく、減量処理は適宜用途により使
い分ければよい。このようにして得られた織編物はスト
レッチバック性を有し、大きな膨らみと反発性を兼ね備
えた従来技術では得ることのできなかった高級感のある
新規な織編物を製造することができる。A woven or knitted fabric is produced by using the polyester composite fiber of the present invention, and an alkali weight reduction treatment can be suitably used for a woman's material. Also, in sports applications, alkali reduction is not particularly required, and the weight reduction may be appropriately used depending on the application. The woven or knitted fabric thus obtained has a stretch-back property, and a high-grade new woven or knitted fabric that cannot be obtained by the conventional technology having both large swelling and resilience can be manufactured.
【0032】[0032]
【実施例】以下、実施例により本発明を詳細に説明す
る。なお、実施例において製品風合いの評価は以下の通
り行うものとし、表中◎・〇・△を合格、×を不合格と
する。 1.製品風合い ストレッチバック性、嵩高性、着用感、を主体に、適度
な張り・腰 反発感、 ドレープ性も加味し熟練者5名
による官能評価を行い、4段階判定法で評価し た。The present invention will be described below in detail with reference to examples. In the examples, the evaluation of the product texture is performed as follows. In the table, 〇, 〇, 表 is passed, and × is rejected. 1. Product texture A sensory evaluation was conducted by five skilled persons, mainly based on stretchback properties, bulkiness, and feeling of wearing, with appropriate tension, waist resilience, and drape properties.
【0033】 ◎:優 〇:良 △:可 ×:不可 2.アルカリ溶解条件 筒編み地1重量部を水酸化ナトリウム(3重量%)の沸
騰水溶液50重量部中に浸漬し、攪拌しながら所定時間
処理した後水洗し、次いで1%酢酸水溶液で中和し、更
に水洗及び乾燥した。アルカリ溶解処理時間は、あらか
じめ予備検討し、所定の減量率になるように設定した。
なお、減量率の算出は、処理前後の筒編み地を100℃
の熱風中で20分間乾燥し、重量を測定[この時の重量
をA,Bとする]して、 式 {(A−B)/A}×100=減量率(%) より求めた。 3.製糸性 次の判定方法に従った。◎: excellent 〇: good Δ: acceptable ×: not acceptable Alkali dissolution condition 1 part by weight of the knitted fabric is immersed in 50 parts by weight of a boiling aqueous solution of sodium hydroxide (3% by weight), treated with stirring for a predetermined time, washed with water, and then neutralized with a 1% aqueous solution of acetic acid. Further, it was washed with water and dried. The alkali dissolution treatment time was preliminarily examined and set so as to have a predetermined weight loss rate.
In addition, the calculation of the weight loss rate is performed by setting the knitted tube before and after the treatment at 100 ° C
Was dried in hot air for 20 minutes, and the weight was measured [the weights at this time are A and B], and the weight was determined from the formula {(AB) / A} × 100 = weight loss rate (%). 3. Yarn-making properties The following judgment method was used.
【0034】 ◎: 糸切れ率が3%未満 〇: 糸切れ率が6%未満 △: 糸切れ率が10%未満 ×: 糸切れ率が10%以上 −: 評価不可 4.高次加工性 製編織時の織編機の糸切れ率から判定した。◎: Thread breakage rate of less than 3% 〇: Thread breakage rate of less than 6% △: Thread breakage rate of less than 10% ×: Thread breakage rate of 10% or more-: Not evaluated Higher workability Judged from the yarn breakage of the weaving machine during weaving.
【0035】 ◎: 製編織機の糸切れ率が3%未満 〇: 製編織機の糸切れ率が6%未満 △: 製編織機の糸切れ率が10%未満 ×: 製編織機の糸切れ率が10%以上 −: 評価不可 実施例1 極限粘度(IV)が0.75のポリエチレンテレフタレ
ート(PET)100%からなる高粘度成分(A)と、
IVが0.50のPET100%からなる低粘度成分
(B)とをAとBの重量複合比が50:50とし、サイ
ドバイサイドに複合紡糸した。複合紡糸の断面における
A、B境界面は実質的に直線であった。複合繊維のIV
は0.61であった。この複合繊維を伸度30%になる
ように延伸し30D−12Fの延伸糸を得た。原糸の物
性は収縮応力0.37g/d、発現捲縮数17コ/cm、
強度3.5g/dであった。上記複合糸と30D−72F
のポリエステルフィラメントの延伸糸と混繊交絡し60
D−84Fの混繊糸を得た。得られた混繊糸に200回
/mの撚りを与え混繊加撚糸とした。◎: Yarn breakage of the weaving machine is less than 3% 〇: Yarn breakage of the weaving machine is less than 6% △: Yarn breakage of the weaving machine is less than 10% ×: Yarn breakage of the weaving machine Rate: 10% or more-: not evaluated Example 1 A high-viscosity component (A) composed of 100% polyethylene terephthalate (PET) having an intrinsic viscosity (IV) of 0.75;
A low-viscosity component (B) composed of 100% PET having an IV of 0.50 was composite-spun side-by-side at a weight composite ratio of A and B of 50:50. The A, B interface in the cross section of the composite spinning was substantially straight. IV of composite fiber
Was 0.61. This composite fiber was drawn so as to have an elongation of 30% to obtain a drawn yarn of 30D-12F. The physical properties of the yarn are shrinkage stress 0.37 g / d, number of expressed crimps 17 / cm,
The strength was 3.5 g / d. The above composite yarn and 30D-72F
Entangled with drawn yarn of polyester filament of 60
A mixed fiber of D-84F was obtained. The obtained mixed fiber yarn was twisted at 200 times / m to give a mixed fiber twisted yarn.
【0036】この混繊加撚糸を経糸と緯糸に用いて平織
物とした。次いで通常のポリエステル染色工程によって
捲縮発現処理、15%のアルカリ減量処理、染色仕上げ
加工を行った。得られた平織物は優れたストレッチバッ
ク性と嵩高性、張り・腰と反発性、およびドレープ性を
有しており高級感のある織物であった。次いでIV差を
変更して水準1と同様方法で水準2から水準5を得た。
得られた織物を用いてブラウスを縫製し、熟練者5名に
よる着用試験を行い着用感を判定した。評価結果を表1
にまとめた。水準1はすべての面で優れていた。水準2
はΔIVを小さくした実験で発現捲縮数、収縮応力が少
なく製品風合いも充分ではないが許容範囲内であった。
水準3はΔIVを大きくした実験で、紡糸時の吐出線曲
がりが大きく製糸性、および高次加工性の低下をきたし
たが製品風合いは良好であった。 比較例1 水準4は本発明を明確にするための比較例である。水準
4はΔIVを0.1未満にした実験で本発明の狙いとす
るストレッチバック性は得られなかった。結果を表1に
示した。A plain woven fabric was prepared by using the mixed fiber twisted yarn as a warp and a weft. Next, a crimp development treatment, a 15% alkali weight reduction treatment, and a dye finishing treatment were performed in a usual polyester dyeing process. The obtained plain woven fabric had excellent stretch-back properties and bulkiness, upholstery and waist and resilience, and drape properties, and was a luxurious fabric. Next, the IV difference was changed, and levels 2 to 5 were obtained in the same manner as level 1.
A blouse was sewn using the obtained woven fabric, and a wearing test was performed by five skilled persons to determine a feeling of wearing. Table 1 shows the evaluation results.
Summarized in Level 1 was excellent in all aspects. Level 2
In the experiment in which ΔIV was reduced, the number of crimps expressed and the shrinkage stress were small and the feeling of the product was not sufficient, but was within the allowable range.
Level 3 was an experiment in which ΔIV was increased. In the experiment, the bending of the discharge line at the time of spinning was large, and the spinning property and the high-order workability were lowered. However, the texture of the product was good. Comparative Example 1 Level 4 is a comparative example for clarifying the present invention. At level 4, in the experiment in which ΔIV was less than 0.1, the stretchback property aimed at by the present invention could not be obtained. The results are shown in Table 1.
【0037】[0037]
【表1】 実施例2 実施例1の複合糸の吐出量を30Dから50Dに変更
し、30D−72Fのポリエステルフィラメントの延伸
糸の代わりに50D−120Fのポリエステルフィラメ
ントの延伸糸を用い、その他は水準1に準じた。水準5
はすべての面で優れていた。水準6は伸度20%とした
実験で捲縮特性、製品風合いは良好であった。製糸性、
高次加工性において水準5に比べやや見劣りしたが許容
範囲内であった。水準7は伸度40%とした実験で製糸
性、高次加工性は良好であった。捲縮特性、製品風合い
は水準5に比べやや見劣りしたが許容範囲内であった。 比較例2 水準8、9は本発明を明確にするための比較例である。
水準8は伸度20%としたが、所定の糸物性が得られな
かった。製品風合いも本発明の狙いとするストレッチバ
ック性は得られなかった。水準9は伸度40%としたが
所定の糸物性が得られなかった。製品風合いも本発明の
狙いとするストレッチバック性は得られなかった。結果
を表2に示した。[Table 1] Example 2 The discharge amount of the composite yarn of Example 1 was changed from 30D to 50D, a drawn yarn of a 50D-120F polyester filament was used in place of a drawn yarn of a 30D-72F polyester filament, and the others were in accordance with Level 1. Was. Level 5
Was excellent in all aspects. Level 6 was an experiment in which the elongation was 20%, and the crimping property and product texture were good. Spinning,
Although it was slightly inferior to the level 5 in high-order workability, it was within the allowable range. Level 7 was an experiment in which the elongation was 40%, and the yarn formability and high order workability were good. Although the crimping characteristics and the feeling of the product were slightly inferior to the level 5, they were within the allowable range. Comparative Example 2 Levels 8 and 9 are comparative examples for clarifying the present invention.
Level 8 was set to an elongation of 20%, but the desired yarn properties could not be obtained. The stretch back property aimed at by the present invention could not be obtained for the product texture. Level 9 was set to an elongation of 40%, but the desired yarn properties could not be obtained. The stretch back property aimed at by the present invention could not be obtained for the product texture. The results are shown in Table 2.
【0038】[0038]
【表2】 実施例3 高粘度成分と低粘度成分の複合比を変更した以外は実施
例2の水準6に準じて実験を行った。水準10はすべて
の面で優れていた。 水準11は高粘度成分を40%ま
で低下させた実験、水準12は逆に高粘度成分を70%
まで増加させた実験である。製糸性、高次通過性、製品
風合とも水準10に比べると物足りないが本発明の許容
範囲内であった。 比較例3 水準13、14は本発明を明確にするための比較例であ
る。水準13は高粘度成分の複合比率を35%とした実
験で製糸性、高次加工性、製品風合とも不良であった。
水準14は高粘度成分を75%とした実験で製糸性、製
品風合いとも不良であった。結果を表3に示した。[Table 2] Example 3 An experiment was performed according to the level 6 of Example 2 except that the composite ratio of the high viscosity component and the low viscosity component was changed. Level 10 was excellent in all aspects. Level 11 was an experiment in which the high-viscosity component was reduced to 40%, and level 12 was a conversely 70% in the high-viscosity component.
The experiment was increased to All of the spinning properties, higher passability, and the feeling of the product were unsatisfactory as compared with level 10, but were within the allowable range of the present invention. Comparative Example 3 Levels 13 and 14 are comparative examples for clarifying the present invention. Level 13 was an experiment in which the compounding ratio of the high-viscosity component was 35%, and the yarn-making properties, high-order workability, and product feeling were poor.
Level 14 was an experiment in which the high-viscosity component was 75%. The results are shown in Table 3.
【0039】[0039]
【表3】 実施例4 高粘度成分と低粘度成分の限界値を決めるための実験で
ある。ポリマを変更した以外は実施例3の水準10に準
じた。水準15はすべての面で優れていた。水準16、
17は製糸性、高次通過性、製品風合とも水準15に比
べるとやや物足りないが本発明の許容範囲内であった。 比較例4 水準18は低粘度成分のIVを0.40まで低下させた
実験で収縮応力が小さく、強度も低く、また紡糸時糸切
れが多発した。製品風合いも不足していた。結果を表4
に示した。[Table 3] Example 4 This is an experiment for determining a limit value of a high viscosity component and a low viscosity component. Except that the polymer was changed, it was in accordance with the level 10 of Example 3. Level 15 was excellent in all aspects. Level 16,
17 was slightly unsatisfactory in terms of the spinning properties, higher passability, and product feeling compared to Level 15, but was within the allowable range of the present invention. Comparative Example 4 Level 18 was an experiment in which the IV of the low-viscosity component was reduced to 0.40, the shrinkage stress was small, the strength was low, and yarn breakage occurred frequently during spinning. The product texture was also insufficient. Table 4 shows the results
It was shown to.
【0040】[0040]
【表4】 [Table 4]
【0041】[0041]
【発明の効果】ポリエステル複合繊維からなり製糸性が
良好で、織編物用にした際にポリウレタン系糸条を用い
ることなく快適なストレッチバック性を有し、大きな膨
らみと反発性を兼ね備えた高級織編物を得ることができ
る。The high-grade woven fabric which is made of polyester composite fiber, has good yarn-making properties, has a comfortable stretch-back property without using a polyurethane yarn when used for woven or knitted fabric, and has both large swelling and resilience. A knit can be obtained.
───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4L041 AA07 BA02 BA05 BA09 BA59 BC04 BC05 BC20 BD14 CA06 DD01 DD04 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4L041 AA07 BA02 BA05 BA09 BA59 BC04 BC05 BC20 BD14 CA06 DD01 DD04
Claims (6)
わせた複合繊維で、破断伸度と収縮応力が下式の関係に
あることを特徴とするポリエステル複合繊維。 Y≧{6.0×(1/X)} ただし、Yは収縮応力(g/d) Xは破断伸度(%)1. A polyester composite fiber comprising two components having different viscosities bonded in the fiber axis direction, wherein the elongation at break and the shrinkage stress have the following relationship. Y ≧ {6.0 × (1 / X)} where Y is shrinkage stress (g / d) X is elongation at break (%)
徴とする請求項1記載のポリエステル複合繊維。2. The polyester composite fiber according to claim 1, wherein the number of expressed crimps is 5 / cm or more.
0.35であることを特徴とする請求項1または2項記
載のポリエステル複合繊維。3. The limiting viscosity difference ΔIV of the two components is 0.12 to 0.12.
The polyester composite fiber according to claim 1 or 2, wherein the polyester fiber is 0.35.
5であることを特徴とする請求項1〜3のいずれか1項
記載のポリエステル複合繊維。4. The low viscosity component has an intrinsic viscosity of 0.45 to 0.5.
The polyester composite fiber according to any one of claims 1 to 3, wherein
5であることを特徴とする請求項1〜4のいずれか1項
記載のポリエステル複合繊維。5. The high viscosity component has an intrinsic viscosity of 0.60 to 0.8.
The polyester composite fiber according to any one of claims 1 to 4, wherein
比率で40:60〜70:30であることを特徴とする
請求項1〜5のいずれか1項記載のポリエステル複合繊
維。6. The polyester composite fiber according to claim 1, wherein the composite ratio of the high-viscosity component to the low-viscosity component is 40:60 to 70:30 by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1955099A JP2000220033A (en) | 1999-01-28 | 1999-01-28 | Polyester conjugate fiber |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1955099A JP2000220033A (en) | 1999-01-28 | 1999-01-28 | Polyester conjugate fiber |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2000220033A true JP2000220033A (en) | 2000-08-08 |
Family
ID=12002436
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1955099A Pending JP2000220033A (en) | 1999-01-28 | 1999-01-28 | Polyester conjugate fiber |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2000220033A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115449923A (en) * | 2022-07-29 | 2022-12-09 | 浙江恒创先进功能纤维创新中心有限公司 | Preparation method of bi-component heat-humidity comfortable polyester composite elastic fiber |
-
1999
- 1999-01-28 JP JP1955099A patent/JP2000220033A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115449923A (en) * | 2022-07-29 | 2022-12-09 | 浙江恒创先进功能纤维创新中心有限公司 | Preparation method of bi-component heat-humidity comfortable polyester composite elastic fiber |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3859672B2 (en) | Composite fiber and method for producing the same | |
WO2002086211A1 (en) | False twist yarn of polyester composite fiber and method for production thereof | |
JP2006214056A (en) | Woven fabric | |
JP2003113554A (en) | Composite fabric and method for producing the same | |
JP2002061031A (en) | Bulky polyester conjugate yarn, method for producing the same and fabric thereof | |
JP2003328248A (en) | Worsted-like cloth and method for producing the same | |
JP2002180332A (en) | Polyester-based conjugated yarn, method for producing the same and fabric | |
JP7476619B2 (en) | Polyester composite fiber | |
JP3988422B2 (en) | Method for producing composite fabric | |
JP2006077338A (en) | Stretchable shirting fabric | |
JP2017179653A (en) | Sea-island composite fiber | |
JP2000220033A (en) | Polyester conjugate fiber | |
JP3972631B2 (en) | Polyester composite false twisted yarn and method for producing the same | |
JP3506129B2 (en) | False twisted yarn and method for producing the same | |
JP2007247107A (en) | Bulky polyester conjugate fiber | |
JP2003239151A (en) | Conjugated fiber and fabric utilizing the same | |
JP2019123970A (en) | Woven fabric | |
JP2000136440A (en) | Latent crimp-expressing polyester fiber and its production | |
JP2006257632A (en) | Composite fabric | |
JP2001040537A (en) | Polyester fiber yarn and fabric | |
JP2005068593A (en) | Covered yarn and method for producing the same | |
JP2000248430A (en) | Latent crimp-expressing polyester fiber and production | |
WO2023100570A1 (en) | Eccentric core-sheath composite false twisted yarn and woven/knitted fabric using same | |
JP4733879B2 (en) | Polyester composite patchy yarn with latent crimp performance | |
JP2009144277A (en) | Composite yarn, woven/knitted fabric using the same, and method for producing the composite yarn |