JP2000197879A - Apparatus for treating particulate material to which pollutant is adhered - Google Patents

Apparatus for treating particulate material to which pollutant is adhered

Info

Publication number
JP2000197879A
JP2000197879A JP11223766A JP22376699A JP2000197879A JP 2000197879 A JP2000197879 A JP 2000197879A JP 11223766 A JP11223766 A JP 11223766A JP 22376699 A JP22376699 A JP 22376699A JP 2000197879 A JP2000197879 A JP 2000197879A
Authority
JP
Japan
Prior art keywords
granular material
particulate material
fine
contaminants
pollutant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11223766A
Other languages
Japanese (ja)
Other versions
JP4286990B2 (en
Inventor
Akio Tango
堯雄 反後
Kenji Kawaguchi
謙治 川口
Yutaka Shinoda
豊 信太
Hiroshi Nakayama
汎 中山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shinroku Seiki KK
Yoyu Shigen KK
Kumagai Gumi Co Ltd
Toshiba Plant Construction Corp
Original Assignee
Shinroku Seiki KK
Yoyu Shigen KK
Kumagai Gumi Co Ltd
Toshiba Plant Construction Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinroku Seiki KK, Yoyu Shigen KK, Kumagai Gumi Co Ltd, Toshiba Plant Construction Corp filed Critical Shinroku Seiki KK
Priority to JP22376699A priority Critical patent/JP4286990B2/en
Priority to SG1999005288A priority patent/SG73677A1/en
Priority to US09/422,782 priority patent/US6402064B1/en
Priority to KR1019990047392A priority patent/KR20000052354A/en
Priority to EP99120904A priority patent/EP0997202A3/en
Priority to IDP991005D priority patent/ID25768A/en
Priority to CN99123287A priority patent/CN1256977A/en
Priority to CA002287958A priority patent/CA2287958A1/en
Publication of JP2000197879A publication Critical patent/JP2000197879A/en
Priority to US09/950,936 priority patent/US20020079392A1/en
Application granted granted Critical
Publication of JP4286990B2 publication Critical patent/JP4286990B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To finely divide a particulate material to which a pollutant such as pollutant soil or incinerating ash is adhered and to efficiently separate the pollutant to remove the same and to reutilize the harmless particulate material from which the pollutant is separated. SOLUTION: A particulate material to which a pollutant is adhered subjected to rough crushing treatment by a finely dividing means 11 of a front stage is sent to a separation means 15 to be separated into a large particulate material with a particle size of 5-10 mm and a particulate material smaller than this particulate material and the separated smaller particulate material is charged in a finely dividing means 12 of a post stage to separate the pollutant strongly adhered to the surface of the particulate material.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、汚染土壌や焼却灰
等の汚染物質が付着された粒状体の無害化を実現するた
めの汚染物質が付着した粒状体の処理装置に関するもの
である。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an apparatus for treating particulate matter to which contaminants are adhered for realizing detoxification of the particulate matter to which contaminants such as contaminated soil and incineration ash are attached.

【0002】[0002]

【従来の技術】従来、リサイクルができない生ゴミ等の
可燃物は、主に、ストーカ式焼却炉あるいは流動床式焼
却炉において焼却され、焼却灰として廃棄物処分場に搬
出されて埋設される。実際の焼却灰には、上記可燃物に
混って焼却された金属屑やガラスあるいは陶器類の欠片
や土砂等も含まれているので、焼却灰の成分としては、
各種金属やシリカ,アルミナ,石灰等が混ざっている。
このような焼却灰は、廃棄量が多いことや、重金属類や
焼却過程で生じたダイオキシン等の有害物質が焼却灰に
付着していることから、焼却灰の減容化及び無害化の方
法あるいは再利用の技術の確立が望まれている。焼却灰
に含まれる鉛,亜鉛,銅,カドミウム等の有害な重金属
類を無害とする方法として、(1)溶融固化、(2)セ
メント固化、(3)薬剤処理、(4)酸やその他の溶媒
による安定化、(5)炭酸塩化処理、(6)水洗浄など
がある。これらの内で最も確実な方法は(1)の溶融固
化で、これは焼却灰を約1500℃以上の高温で溶融し
た後廃棄物処分場に廃棄、または粉砕して微粒片とし再
利用する方法で、この処理方法は現在実用化されてい
る。この処理方法では、重金属類は溶融物の内部に封じ
込められているので、上記溶融物が水に触れた場合でも
上記重金属類が溶出することはないといわれている。
(2)のセメント固化は、焼却灰にセメントを入れるた
め、廃棄物の量が増大してしまうという致命的な欠点が
ある。その上、セメントの混入によって処理された焼却
灰はアルカリ性が強くなり、かえって鉛などが溶出する
危険性が高い。(3)の薬剤処理では、pH調整が重要
であるが、焼却灰に含まれる物質が一定せずかつ多様な
ことからpH調整が難しく、不適切であると薬剤添加の
効果がないので疑問視されている。(4)の酸やその他
の溶媒による安定化は、重金属類を残存させた状態で安
定化させるので、長期的に溶出を防止することは難し
い。(5)の炭酸塩化処理は維持管理が難しく、その上
装置が複雑なので実用的ではない。(6)の水洗浄は、
酸性雨等で酸性環境にならなければ、比較的容易に重金
属類が除去できるといわれているが、その効果は粉体状
の飛灰で確認されているだけで、焼却灰の場合のよう
に、団粒状態にあるような粒状体に付着されている重金
属類やダイオキシン類に対しては、十分な効果が期待で
きない。また、上述した溶融固化は、焼却灰の処理温度
が高いため、ダイオキシン類を熱分解して無害化するこ
とができるので、現状では、この溶融固化による処理が
最も効果的であるといわれており、この溶融固化が焼却
灰の処理方法の主流となっている。
2. Description of the Related Art Conventionally, combustible materials such as garbage that cannot be recycled are mainly incinerated in a stoker-type incinerator or a fluidized-bed incinerator, carried out as incinerated ash to a waste disposal site and buried. The actual incineration ash contains metal scraps, glass or pottery shards, earth and sand, etc., which are incinerated with the above combustibles.
Various metals, silica, alumina, lime, etc. are mixed.
Such incinerated ash has a large amount of waste, and heavy metals and harmful substances such as dioxin generated in the incineration process adhere to the incinerated ash. The establishment of a reuse technology is desired. Methods to render harmful heavy metals such as lead, zinc, copper, and cadmium contained in incinerated ash harmless include (1) melt solidification, (2) cement solidification, (3) chemical treatment, (4) acid and other Stabilization with a solvent, (5) carbonation treatment, and (6) water washing. Of these, the most reliable method is the solidification of (1), which is a method of melting incinerated ash at a high temperature of about 1500 ° C or higher and then discarding it at a waste disposal site or pulverizing it and reusing it as fine particles. This processing method is currently in practical use. In this treatment method, since the heavy metals are sealed in the melt, it is said that the heavy metals do not elute even when the melt contacts water.
The cement solidification of (2) has a fatal disadvantage that the amount of waste increases because cement is put into incinerated ash. In addition, the incineration ash treated by the incorporation of cement has a high alkalinity and has a high risk of elution of lead and the like. In the chemical treatment of (3), pH adjustment is important, but it is difficult to adjust the pH because the substances contained in the incineration ash are not constant and various, and if it is inappropriate, there is no effect of adding the chemical, so it is questionable. Have been. The stabilization of (4) with an acid or other solvent is carried out in a state in which heavy metals remain, so that it is difficult to prevent elution over a long period of time. The carbonation treatment of (5) is difficult to maintain and, furthermore, impractical due to the complicated equipment. (6) water washing
It is said that heavy metals can be removed relatively easily if the environment does not become acidic due to acid rain, but the effect has only been confirmed with powdered fly ash. Sufficient effects cannot be expected on heavy metals and dioxins adhering to granular materials in a state of aggregate. Further, in the above-mentioned melt-solidification, since the processing temperature of incinerated ash is high, dioxins can be decomposed by thermal decomposition, and at present, this melt-solidification treatment is said to be the most effective. This melting and solidification is the mainstream of incineration ash processing methods.

【0003】しかしながら、長期的にみると、溶融固化
においても、処分場に埋設された溶融物の内部に封じ込
められいる重金属類が溶出する可能性は否定できない。
また、溶融固化では、焼却灰を高温で溶融するために、
溶融炉等の大型設備を必要とすることや、多大な燃料を
必要とすることから、設備の建設費や処理コストが高い
といった問題点がある。そこで、処分場に焼却灰を廃棄
する以前に重金属類やダイオキシン類等の有害性のもの
を除去した後、再利用可能な石,砂,微粒分等を抽出す
ることで廃棄量の減容化を図る技術の確立が望まれると
ころである。
However, in the long run, even in the case of melt-solidification, the possibility that heavy metals contained in the melt buried in the disposal site are eluted cannot be denied.
In addition, in the solidification, in order to melt incinerated ash at high temperature,
Since large equipment such as a melting furnace is required and a large amount of fuel is required, there is a problem that equipment construction costs and processing costs are high. Therefore, before removing the incinerated ash to the disposal site, after removing harmful substances such as heavy metals and dioxins, the volume of waste can be reduced by extracting reusable stones, sand, fine particles, etc. It is hoped that the establishment of technology to achieve this will be established.

【0004】一方、近年、化学工場や金属精錬工場等の
工場近辺の土壌が、重金属類や有機塩素化合物あるいは
油性分等で汚染されていることが問題視されている。ま
た、海難事故等により海に流出した原油で汚染された海
浜の土壌や、原油存在地盤のトンネル掘削に伴い搬出さ
れる掘削土には原油が付着しているため、その処理が困
難となることがしばしばある。更に、問題となる汚染物
質が付着した土壌(汚染土壌)としては、上述した焼却
灰の混入により汚染された土壌も含まれる。このような
汚染土壌に対しても、上記汚染物質を除去し、石,砂,
微粒分等を抽出して再利用する技術の確立が望まれてい
る。
On the other hand, in recent years, it has been considered that soil near factories such as chemical factories and metal refining factories is contaminated with heavy metals, organic chlorine compounds, oily components, and the like. In addition, the treatment of the soil on the beach contaminated with crude oil spilled into the sea due to a marine accident or the excavated soil carried out due to the excavation of the tunnel on the ground where crude oil exists is difficult because the crude oil adheres to it. There are often. Further, the soil (contaminated soil) to which the pollutant in question is attached includes the soil contaminated by the incineration ash. For such contaminated soil, the above contaminants are removed and stone, sand,
It is desired to establish a technique for extracting and reusing fine particles and the like.

【0005】一般に、焼却灰に付着しているダイオキシ
ン類は、焼却灰中の2mm以下の大きさの粒状体表面に
比較的強く付着しているといわれている。そこで、焼却
灰中の5mm以上の大きさの粒状体を分級し、上記粒状
体表面に比較的弱く付着しているダイオキシン類を取り
除く処理をすれば、この粒状体は無害であり再利用可能
と考えられる。しかしながら、粒状体同士が団粒状態に
あるような焼却灰を、個々の粒状体を破壊することなく
分離する方法や、ダイオキシン類の比較的強く付着して
いる2mm以下の大きさの粒状体からダイオキシン類を
離脱させる方法については、発明者の知るところでは提
案されていない。更に、焼却灰は軟らかい組織であるの
で、一般の破砕機では焼却灰に付着したダイオキシン類
を離脱させることが困難であるだけでなく、例えば、ボ
ールミル等を用いて焼却灰を粉砕すると、焼却灰の粒状
体も細粒化されしまい、ダイオキシン類の付着した粒状
体を分離できず、かえって減容化が難しくなってしま
う。一方、汚染土壌は、粒状体同士が団粒状態となって
いる部分は少ないものの、上記粒状体に付着している重
金属類や油性分等の汚染物質は粒径が極めて小さいの
で、上記焼却灰と同様に、一般の破砕機では上記汚染物
質を離脱させることが困難であるだけでなく、汚染土壌
の粒状体も細粒化されしまい、上記汚染物質を分離する
ことが困難となる。
In general, it is said that dioxins adhering to incinerated ash are relatively strongly attached to the surface of granular material having a size of 2 mm or less in the incinerated ash. Therefore, if the granular material having a size of 5 mm or more in the incineration ash is classified and the dioxins adhering relatively weakly to the surface of the granular material are removed, the granular material is harmless and can be reused. Conceivable. However, there is a method of separating incinerated ash in which the granular materials are in a state of aggregate without destruction of the individual granular materials, or from a granular material of 2 mm or less having relatively strong adhesion of dioxins. A method of releasing dioxins has not been proposed to the knowledge of the inventors. Furthermore, since incinerated ash has a soft structure, it is not only difficult to remove dioxins adhering to the incinerated ash with a general crusher, but also, for example, when the incinerated ash is pulverized using a ball mill or the like, Is also finely divided, and the granular material to which dioxins are adhered cannot be separated, which makes it difficult to reduce the volume. On the other hand, in the contaminated soil, although there are few portions where the granular materials are in the aggregated state, the contaminants such as heavy metals and oily substances attached to the granular materials have extremely small particle diameters. In the same manner as described above, it is difficult for a general crusher to separate the contaminants, and the granular material of the contaminated soil is also finely divided, making it difficult to separate the contaminants.

【0006】ところで、特開平8−164363号公報
には、砂礫や粘土等を含む浚渫土を粉砕することなく浚
渫土中の石等の鋭角部を取り除くとともに、土塊や砂塊
等を破砕する破砕機が開示されている。図7(a),
(b)は、この破砕機10の構成を示す図で、(a)図
は側面図、(b)図は(a)図のA−A断面図である。
破砕機10は、内周面に軸方向に沿って取付けられ、中
心方向に突出する複数の外羽根6Wを有する円筒状の回
転ドラム6と、外周面に軸方向に沿って取付けられ、径
方向に突出する複数の内羽根7Wを有し、上記回転ドラ
ム6の内部に偏心して取付けられたロータ7とを備え、
回転ドラム6の外周に設けられた環状歯車6aをモータ
8により、ロータ7に取付けられた回転軸7aを駆動機
構7bにより、それぞれ互いに逆方向に回転させ、破砕
機10に投入された浚渫土等の投入物に圧縮及びせん断
応力を作用させて上記投入物を破砕したり、破砕された
投入物間の相互摩擦により破砕物を研磨するものであ
る。なお、上記破砕機10による破砕処理は、砕石を研
磨する場合には乾式あるいは湿式で行い、砂礫や粘土等
を含む浚渫土等の土砂を細粒化する場合には、上記投入
物に加水しつつ行う。また、上記投入物に作用する応力
の大きさは、主に、回転ドラム6とロータ7との間隔
(ロータ7の偏心度)と、回転ドラム6及びロータ7の
それぞれの回転速度により調整する。
Japanese Patent Application Laid-Open No. 8-164363 discloses a crushing method that removes sharp corners of stones and the like in a dredged soil without crushing the dredged soil including gravel and clay, and crushes a lump of earth or sand. Machine is disclosed. FIG. 7 (a),
(B) is a figure which shows the structure of this crusher 10, (a) is a side view, (b) is AA sectional drawing of (a).
The crusher 10 is attached to the inner peripheral surface along the axial direction, and has a cylindrical rotary drum 6 having a plurality of outer blades 6W protruding in the center direction. A rotor 7 having a plurality of inner blades 7W protruding from the rotary drum 6 and eccentrically mounted inside the rotary drum 6.
The ring gear 6a provided on the outer periphery of the rotating drum 6 is rotated by the motor 8 and the rotating shaft 7a attached to the rotor 7 is rotated in the opposite directions by the driving mechanism 7b. The above-mentioned materials are subjected to compression and shear stress to crush the above-mentioned materials, or the crushed materials are polished by mutual friction between the crushed materials. The crushing process by the crusher 10 is performed in a dry or wet manner when grinding crushed stones, and when the sand is reduced into fine particles such as dredged soil including gravel and clay, the crushed water is added to the input material. While doing. The magnitude of the stress acting on the input material is adjusted mainly by the distance between the rotary drum 6 and the rotor 7 (the eccentricity of the rotor 7) and the respective rotational speeds of the rotary drum 6 and the rotor 7.

【0007】[0007]

【発明が解決しようとする課題】しかしながら、上記破
砕機10では、礫や石などを含む浚渫土を破砕する例に
ついては開示されているが、生ゴミや可燃物等の有機物
源を燃焼させた焼却灰のような団粒化された粒状体を、
上記粒状体を破壊することなく分離する方法や、焼却灰
中の粒状体に付着している重金属類やダイオキシン類を
分離して、焼却灰を無害化する方法については何ら示唆
されてはいない。更に、上記破砕機10では、処理材料
がカーボンや油性分のような粘性の大きな汚染物質が付
着している汚染土壌である場合や、汚染物質である重金
属類が個々の粒状体に強く付着しているような場合に
は、上記粒子に付着している汚染物質を有効に離脱させ
ることが困難であった。
However, in the above-mentioned crushing machine 10, although an example of crushing dredged soil including gravels and stones is disclosed, organic sources such as garbage and combustibles are burned. Agglomerated granules such as incineration ash,
There is no suggestion about a method of separating the above-mentioned granules without destroying them, or a method of separating heavy metals and dioxins adhering to the granules in the incineration ash to make the incineration ash harmless. Furthermore, in the crushing machine 10, when the treatment material is a contaminated soil to which a highly viscous contaminant such as carbon or an oily substance is adhered, or when heavy metals as the contaminant strongly adhere to individual granules, In such a case, it has been difficult to effectively remove contaminants attached to the particles.

【0008】本発明は、従来の問題点に鑑みてなされた
もので、汚染土壌や焼却灰等の汚染物質の付着した粒状
体を細粒化するとともに、上記汚染物質を効率的に分離
して除去し、更に、上記汚染物質が分離された無害な粒
状体を再利用することのできる汚染物質が付着した粒状
体の処理装置を提供することを目的とする。
SUMMARY OF THE INVENTION The present invention has been made in view of the conventional problems, and is intended to reduce the size of particulate matter to which contaminants such as contaminated soil and incinerated ash are attached and to efficiently separate the contaminants. It is an object of the present invention to provide an apparatus for treating a granular material to which a contaminant has adhered, which can remove the contaminant and reuse the harmless granular material from which the contaminant has been separated.

【0009】[0009]

【課題を解決するための手段】本発明の請求項1に記載
の汚染物質が付着した粒状体の処理装置は、処理空隙内
に投入された汚染物質が付着した粒状体に、加水しなが
ら、圧縮及び粒状体相互間の擦り合わせの力を作用さ
せ、上記粒状体を独立した粒状体に分離するとともに、
上記粒状体の表面に付着している汚染物質を分離する細
粒化手段を複数段に渡って設け、上記粒状体が各細粒化
手段を順次通過するようにし、更に、前段の細粒化手段
から排出された粒状体の中から、5mm〜10mm径の
間の所定の径以上の大きさの粒状体と、上記粒状体より
も大きさの小さな粒状体を分離する分離手段を設け、上
記大きさの小さな方の粒状体を後段の細粒化手段に投入
するようにしたものである。なお、上記細粒化手段で行
う、汚染物質が付着した粒状体に圧縮応力を作用させ、
多数の粒状体同士が固着している団粒状の汚染物質が付
着した粒状体を、上記粒状体を破壊することなくほぼ独
立した粒状体に分離して細粒化する処理を以下では解砕
処理と呼ぶ。また、上記粒状体に加える応力を大きくし
て、粒状体相互間の擦り合わせの力を作用させて、粒状
体同士の摩擦による相互研磨を行わせ、上記粒状体の表
面に付着している汚染物質を分離する処理を以下では、
解膠処理と呼ぶ。
According to a first aspect of the present invention, there is provided an apparatus for treating particulate matter to which contaminants have adhered, the method comprising adding water to the particulate matter to which contaminants have been introduced into a processing space while adding water thereto. By applying the force of compression and rubbing between the granules, the granules are separated into independent granules,
Fine-graining means for separating contaminants adhering to the surface of the granular material is provided in a plurality of stages, so that the granular material sequentially passes through each fine-graining means, From among the granular materials discharged from the means, a granular material having a size of a predetermined diameter or more between 5 mm and 10 mm and a separating means for separating a granular material having a size smaller than the granular material are provided. The smaller-sized granular material is fed into the subsequent-stage fine-granulating means. In addition, the compressive stress is applied to the granular material to which the contaminant adheres, which is performed by the above-described grain refining means,
In the following, a process of separating the granular material to which the aggregated contaminants having a large number of the granular materials adhered into the substantially independent granular material without destroying the granular material and refining the granular material is described below. Call. In addition, the stress applied to the granules is increased, and the force of rubbing between the granules is applied to cause mutual polishing by the friction between the granules, so that the contamination adhering to the surface of the granules is performed. The process of separating substances is described below.
This is called peptization.

【0010】請求項2に記載の汚染物質が付着した粒状
体の処理装置は、上記大きさの小さな方の粒状体の中か
ら、重金属類やダイオキシン類等の汚染物質を含むの微
粒片と、大きさが上記微粒片よりも大きい無害な微粒片
とを分級する分級手段を設けたものである。
According to a second aspect of the present invention, there is provided an apparatus for treating particulate matter to which contaminants are adhered, comprising: a fine particle containing contaminants such as heavy metals and dioxins from the smaller ones; Classifying means is provided for classifying harmless fine particles having a size larger than the fine particles.

【0011】[0011]

【発明の実施の形態】以下、本発明の実施の形態につい
て、図面に基づき説明する。 実施の形態1.図1は、本発明の実施の形態1に係わる
汚染物質が付着した粒状体の処理装置の構成を示すブロ
ック図である。同図において、1は投入された処理材料
である汚染物質が付着した粒状体に加水し、上記粒状体
の粗い解砕を行うための第1の細粒化手段である一次細
粒化機11と、この一次細粒化機11で解砕処理された
上記粒状体に加水し、上記粒状体の解砕・解膠処理を行
うための第2の細粒化手段である二次細粒化機12とを
備えた細粒化装置、13は汚染物質が付着した粒状体を
投入する受け入れホッパ、14は一次細粒化機11の排
出口11aから排出された粒状体の中から、大型の金属
類や挟雑物等の固形物を捕獲するための約30mmの分
級用の網、15は上記網14を通過した粒状体中から5
mm径以上粒状体を選別して分離するとともに、5mm
以下の粒状体を二次細粒化機12に送出する分離手段、
16は液体サイクロンやシックナータンク等の分級手段
を備え、上記二次細粒化機12から送出されたスラリー
状の粒状体の中から種々の大きさの粒状体を分級するた
めの分級手段である。また、17は上記細粒化装置1及
び上記分級手段16に処理水を供給する給水部、18は
上記分級手段16から排出される処理水を浄化する汚水
処理部である。
Embodiments of the present invention will be described below with reference to the drawings. Embodiment 1 FIG. FIG. 1 is a block diagram illustrating a configuration of a processing apparatus for a granular material to which a contaminant adheres according to Embodiment 1 of the present invention. In the figure, reference numeral 1 denotes a primary granulating machine 11 which is first granulating means for adding water to a granular material to which a contaminant as a processing material is attached and coarsely crushing the granular material. Secondary granulation as second granulation means for adding water to the granules crushed by the primary granulator 11 and crushing and pulverizing the granules. A receiving hopper for charging granules to which contaminants are attached, and 14 a large-sized granule from among the granules discharged from the outlet 11a of the primary granulator 11. Classification nets of about 30 mm for capturing solids such as metals and contaminants.
5mm
Separation means for sending the following granules to the secondary granulator 12;
Reference numeral 16 denotes a classification means for classifying various-sized granules from the slurry-like granules sent out from the secondary granulation machine 12, which is provided with a classification means such as a liquid cyclone or a thickener tank. . Reference numeral 17 denotes a water supply unit for supplying treated water to the grain refiner 1 and the classifying unit 16, and reference numeral 18 denotes a sewage treatment unit for purifying treated water discharged from the classifying unit 16.

【0012】図2は、細粒化装置1の一構成例を示す図
で、細粒化装置1は、上述した従来の破砕機10と同様
の構成の一次細粒化機11と二次細粒化機12とを1つ
のシェル2内に組み込み、共通の動力機3により稼動す
るように構成されている。上記一次細粒化機11及び上
記二次細粒化機12における解砕・解膠の条件は、粒状
体同士が固着されて団粒状態となっている汚染物質が付
着した粒状体を、上記各粒状体を破壊することなく分離
し、かつ上記粒状体中の粒状体に付着している重金属類
あるいはダイオキシン類を上記粒状体から剥離するよう
な条件にそれぞれ設定してある。また、4は処理材料で
ある汚染土壌や焼却灰などを投入する処理材料投入口、
5は一次細粒化機11及び二次細粒化機12のそれぞれ
の処理空隙内で順次解砕・解膠された処理材料を排出す
る処理材料排出口である。なお、上記細粒化装置1に設
けられる、分離手段15へ送出口及び分離手段15から
の送入口については省略した。汚染物質が付着した粒状
体に対して粗い解砕処理を行う一次細粒化機11は、図
3(a)に示すように、ロータ7の偏心量を小さくして
回転ドラム6とロータ7との間隔D1を比較的広くする
とともに、回転速度を低速としている。また、上記粒状
体に対して解膠を主体とする処理を行う二次細粒化機1
2では、図3(b)に示すように、ロータ7の偏心量を
大きくして回転ドラム6とロータ7との間隔D2を狭く
するとともに、回転速度を高速にしている。
FIG. 2 is a view showing an example of the structure of the fine-graining apparatus 1. The granulator 12 and the granulator 12 are incorporated in one shell 2, and are operated by a common power unit 3. The conditions of pulverization and deflocculation in the primary granulator 11 and the secondary granulator 12 are as follows. The conditions are set so that each granular material is separated without breaking, and heavy metals or dioxins adhering to the granular material in the granular material are separated from the granular material. 4 is a processing material input port for inputting contaminated soil or incinerated ash, which is a processing material,
Reference numeral 5 denotes a processing material discharge port for discharging the processing material which has been sequentially pulverized and deflocculated in the respective processing gaps of the primary granulator 11 and the secondary granulator 12. It should be noted that the outlets to the separating means 15 and the inlets from the separating means 15 provided in the granulating apparatus 1 are omitted. As shown in FIG. 3 (a), the primary fine-granulating machine 11 that performs a coarse crushing process on the granular material to which the contaminant adheres reduces the amount of eccentricity of the rotor 7 so that the rotary drum 6 and the rotor 7 with relatively wide spacing D 1 of the a rotation speed and low speed. Further, a secondary fine-granulating machine 1 for performing a process mainly based on peptization of the granular material 1
In 2, as shown in FIG. 3 (b), as well as narrowing the distance D 2 between the rotary drum 6 and the rotor 7 eccentricity greatly to the rotor 7, and the rotational speed at a high speed.

【0013】一次細粒化機11または二次細粒化機12
中では、図4に示すように、処理空隙である回転ドラム
6とロータ7との間隙に投入された汚染物質が付着した
粒状体Sは、回転ドラム6の外羽根6Wによって上方に
掻き上げられるとともに、ロータ7の内羽根7Wによっ
て下方に引き下げられるので、上記粒状体Sには圧縮応
力とともにせん断応力が作用し上記粒状体Sは解砕・解
膠処理される。すなわち、図5(a)に示すように、粒
状体同士が固着面rで固着されて団粒状態となっている
汚染物質が付着した粒状体の各粒状体pあるいは粒状体
同士が固着してはいないが大きさの大きい粒状体pに圧
縮応力及びせん断応力が作用し、上記団粒状の各粒状体
が上記固着面rのところから分かれてほぼ独立した細か
な粒状体pに細粒化される(解砕)とともに、図5
(b)に示すように、粒状体同士に擦り合わせ方向の力
が作用し、粒状体p相互の摩擦により各粒状体の表面に
付着された重金属類やダイオキシン類などの汚染物質q
の粒状片が剥離され粒状体pから分離される(解膠)。
なお、上記汚染物質qは、団粒状の粒状体の表面だけで
なく、各粒状体pの表面である上記固着面rにも付着さ
れている(図5(a)参照)。したがって、解砕時に
は、団粒状の粒状体の表面に付着されている汚染物質q
の一部は剥離されることもあるが、ほとんどは上記解膠
処理の際に粒状体pの表面から分離される。また、一部
の大きさの大きい粒状体の中には破砕されて細粒化され
るものもある。このとき、上記一次細粒化機11及び二
次細粒化機12には、給水部17からの処理水が図示し
ない給水口を通って供給される。細粒化装置1に投入さ
れた汚染物質が付着した粒状体は、この処理水が加水さ
れた状態で解砕・解膠されるので、上記剥離された汚染
物質のうち、重金属類やダイオキシン類は、上記処理水
中に溶解したりあるいは微粒片として浮遊する。
[0013] Primary grain refiner 11 or secondary grain refiner 12
In the inside, as shown in FIG. 4, the granular material S attached to the gap between the rotating drum 6 and the rotor 7, which is the processing gap, to which the contaminant adheres is scraped upward by the outer blades 6 </ b> W of the rotating drum 6. At the same time, since the granular material S is pulled down by the inner blades 7W of the rotor 7, a compressive stress and a shear stress act on the granular material S, and the granular material S is pulverized and peptized. That is, as shown in FIG. 5 (a), the granular materials p or the granular materials adhered to the aggregated contaminants are adhered to each other at the adhered surface r. However, compressive stress and shear stress act on the large-sized granular material p, and the aggregated granular materials are separated from the fixing surface r to be finely divided into almost independent fine granular materials p. Fig. 5
As shown in (b), a force in the rubbing direction acts on the granular materials, and contaminants q such as heavy metals and dioxins attached to the surface of each granular material due to friction between the granular materials p.
Is separated from the granular material p (peptization).
The contaminant q is attached not only to the surface of the aggregated granular material, but also to the fixing surface r, which is the surface of each granular material p (see FIG. 5A). Therefore, at the time of crushing, the contaminant q attached to the surface of the aggregated granular material q
May be peeled off, but most are separated from the surface of the granular material p during the peptization. Some large-sized granular materials are crushed and refined. At this time, the treated water from the water supply unit 17 is supplied to the primary granulator 11 and the secondary granulator 12 through a water supply port (not shown). Since the granular material to which the contaminant is attached and which is attached to the granulation device 1 is crushed and deflocculated in a state in which the treated water is added, heavy metals and dioxins among the separated contaminants are used. Is dissolved in the above treated water or floats as fine particles.

【0014】次に、処理材料が焼却灰である場合を例に
とって、上記処理装置による汚染物質が付着した粒状体
の処理方法について説明する。まず、受け入れホッパ1
3に投入された焼却灰は、細粒化装置1の処理材料投入
口4から一次細粒化機11に投入される。一次細粒化機
11では、処理水と混合された焼却灰に対して粗い解砕
を行い、焼却灰の表面に弱く付着しているダイオキシン
等の微粒片を剥離させて上記処理水中に浮遊させたり、
容易に溶解する重金属類を上記処理水中に溶解させると
ともに、粒状体同士が固着された焼却灰を、上記粒状体
を破壊することなく分離しつつ、焼却灰を一次細粒化機
11の下流側に移動させ、分離手段15に送出する。こ
のとき、焼却灰にかかる応力は上述した破砕機10より
も十分低く設定してあるので、焼却灰に混入されている
土砂や陶器片等の粒状体は破砕されずに排出される。
Next, a method of treating particulate matter to which contaminants adhere by the above-described processing apparatus will be described, taking as an example a case where the processing material is incinerated ash. First, receiving hopper 1
The incinerated ash introduced into 3 is introduced into the primary granulator 11 from the treatment material inlet 4 of the granulating apparatus 1. In the primary granulating machine 11, coarse incineration is performed on the incinerated ash mixed with the treated water, and fine particles such as dioxin that are weakly adhered to the surface of the incinerated ash are separated and floated in the treated water. Or
While dissolving the easily dissolvable heavy metals in the above treated water, the incinerated ash, to which the particulate matter is fixed, is separated without breaking the particulate matter, and the incinerated ash is downstream of the primary granulator 11. And sent to the separating means 15. At this time, since the stress applied to the incinerated ash is set sufficiently lower than that of the crusher 10 described above, the particulate matter such as earth and sand and pottery pieces mixed in the incinerated ash is discharged without being crushed.

【0015】焼却灰に付着しているダイオキシン類は、
一般に焼却灰中の2mm以下の大きさの粒状体に付着し
ているといわれているので、焼却灰中の5mm以上の大
きさの粒状体は無害であると考えられる。そこで、分離
手段15として、焼却灰中の5mm以上の大きさの粒状
体を分離する装置、例えば、5mm程度の選別振動スク
リーンを用いて、上記焼却灰から5mm以上の粒状体を
篩い分けして分離し、篩い分けされた5mm以下の焼却
灰を二次細粒化機12に送出する。一方、5mm〜30
mm程度の粒状体は、分離手段15より搬出され再利用
または廃棄される。
The dioxins adhering to the incinerated ash are:
Generally, it is said that the particles having a size of 5 mm or more in the incineration ash are harmless because they are attached to the particles having a size of 2 mm or less in the incineration ash. Therefore, as the separation means 15, a device for separating granular materials having a size of 5 mm or more in the incinerated ash, for example, a screening vibrating screen of about 5 mm, is used to screen 5 mm or more granular materials from the incinerated ash. The separated and sieved incineration ash of 5 mm or less is sent to the secondary granulator 12. On the other hand, 5mm-30
The granular material of about mm is carried out from the separating means 15 and reused or discarded.

【0016】分離手段15を通過した焼却灰は、概ね5
mm以下の粒状体となっているので、二次細粒化機12
では回転ドラム6とロータ7との間隔が狭く、かつ高速
回転とし、焼却灰を更に細かい粒状体に分離したり、大
きさの大きい粒状体の一部を細粒化するとともに、焼却
灰に強く付着している重金属類やダイオキシンの微粒片
を粒状体相互の摩擦により離脱させつつ上記焼却灰を下
流側に移動させる。二次細粒化機12で解砕・解膠され
た焼却灰は処理材料排出口5から分級手段16に送出さ
れ、種々の大きさの粒状体に分級される。上記粒状体か
ら離脱した重金属類やダイオキシン類は、処理水ととも
に分級手段16に送られ処理されたり、分級手段16を
経由して汚水処理部18に送られ処理される。
The incinerated ash that has passed through the separation means 15 is approximately 5
mm or less, so that the secondary refiner 12
In this case, the interval between the rotating drum 6 and the rotor 7 is narrow and the rotation speed is high, so that the incineration ash can be separated into finer granules, and a part of the large-sized granules can be finely granulated, and the ash-resistant ash is strong. The incinerated ash is moved to the downstream side while the attached heavy metals and dioxin fine particles are separated by friction between the particles. The incinerated ash pulverized and pulverized by the secondary granulator 12 is sent out from the treated material discharge port 5 to the classification means 16 and classified into various-sized granules. The heavy metals and dioxins released from the granular material are sent to the classification means 16 together with the treated water for treatment, or sent to the sewage treatment unit 18 via the classification means 16 for treatment.

【0017】分級手段16では、5mm以下の粒状体を
含む泥状の焼却灰から、砂分や微粒砂や灰の成分である
細かな粒状体等の種々の大きさの粒状体を分級する。な
お、分級手段16で分級した約20μm以下の微粒片は
ダイオキシン類を多く含む微粒片と見做し、例えば溶融
固化するなどの処理を行う。一方、溶出した重金属類を
含んだ処理水は、汚水処理部18において薬品処理など
を施し、上記重金属類を処理して浄化した後、循環水と
して再利用される。また、約20μm以上の粒状体を含
んだ泥土は、重金属類やダイオキシン類が取り除かれて
無害化されているので再利用される。
The classification means 16 classifies various sizes of granules such as sand, fine sand and fine granules which are components of ash from mud-like incinerated ash containing granules of 5 mm or less. The fine particles having a size of about 20 μm or less classified by the classification means 16 are regarded as fine particles containing a large amount of dioxins, and are subjected to a process such as melting and solidification. On the other hand, the treated water containing the eluted heavy metals is subjected to chemical treatment or the like in the sewage treatment section 18 to treat and purify the heavy metals, and then reused as circulating water. In addition, mud containing particulate matter of about 20 μm or more is reused because heavy metals and dioxins are removed and made harmless.

【0018】汚染土壌の処理方法も、上記焼却灰の場合
と同様であるが、土粒子は団粒化していることが少ない
と思われるので、一次細粒化機11,二次細粒化機12
ともに、上記図5(b)に示す解膠作用が主となる。な
お、焼却灰を含んだ汚染土壌の場合には、一次細粒化機
11では粗い解砕を行い、二次細粒化機12では解砕及
び解膠を行う。
The method of treating the contaminated soil is the same as that of the above incinerated ash. However, since it is considered that the soil particles are less likely to be agglomerated, the primary finer 11 and the secondary finer 12
In both cases, the peptizing action shown in FIG. In the case of contaminated soil containing incinerated ash, the primary pulverizer 11 performs coarse pulverization, and the secondary pulverizer 12 performs pulverization and pulverization.

【0019】実施の形態2.図6は、本発明の実施の形
態2に係わる焼却灰の連続処理システムの処理フローを
示す図で、本実施の形態2では、上述した実施の形態1
と同様の細粒化装置1を用いて投入された焼却灰を連続
的に処理し、焼却灰を細粒化するとともに、効率良く焼
却灰中の有害物を除去し、排出された無害な粒状体を再
利用するようにしたものである。まず、受け入れホッパ
13に投入された焼却灰をベルトコンベアにより搬送
し、一次細粒化機11に投入する。一次細粒化機11で
は、給水部17の後述する二次処理水槽53からの処理
水を上記焼却灰に加水し、上記焼却灰に対して粗い解砕
を行い、焼却灰を種々の大きさの粒状体に分離するとと
もに、焼却灰の表面に弱く付着しているダイオキシン類
や重金属類を上記処理水中に浮遊あるいは溶解した状態
で離脱させつつ、上記焼却灰を下流側に移動させ、一次
細粒化機11の排出口11aから排出する。一次細粒化
機11では、回転ドラム6とロータ7との間隔が広く、
かつ低速回転であるので、大型の金属類や挟雑物等の固
形物は解砕されずに排出される。この大型の固形物は、
上記排出口11aに設けられた約30mmの分級用の網
14により捕獲されて除去され、ベルトコンベアにより
搬出される。一方、約30mm以下の粒状体となった焼
却灰は、5mm〜10mm程度(例えば、10mm)の
一次選別振動スクリーン20により篩い分けされる。篩
い分けされた10mm以下の焼却灰は、磁気式金属除去
機21において、焼却灰中の金属片を取り除いた後に、
二次細粒化機12に送られる。一方、10mm〜30m
m程度の粒状体はベルトコンベアにより搬出され再利用
または廃棄される。なお、一次選別振動スクリーン20
には給水部17から水が供給され、一次選別振動スクリ
ーン20を通過した水は、後述する第1のフィードサン
プ23に送られる。この一次選別振動スクリーン20が
上記実施の形態1の分離手段15に相当する手段であ
る。
Embodiment 2 FIG. 6 is a diagram showing a processing flow of the continuous incineration ash processing system according to the second embodiment of the present invention. In the second embodiment, the above-described first embodiment is used.
The incineration ash supplied is continuously treated by using the same granulation apparatus 1 as described above, and the incineration ash is finely divided, the harmful substances in the incineration ash are efficiently removed, and the discharged harmless granules are discharged. It is designed to reuse the body. First, the incinerated ash supplied to the receiving hopper 13 is transported by a belt conveyor, and is supplied to the primary granulating machine 11. In the primary granulator 11, treated water from a secondary treatment water tank 53, which will be described later, of the water supply unit 17 is added to the incinerated ash, and the incinerated ash is coarsely crushed, and the incinerated ash is reduced in size. While separating dioxins and heavy metals that are weakly adhering to the surface of the incinerated ash while floating or dissolving them in the treated water, the incinerated ash is moved to the downstream side, It is discharged from the discharge port 11a of the granulator 11. In the primary grain refiner 11, the distance between the rotary drum 6 and the rotor 7 is wide,
Since the rotation speed is low, solids such as large metals and contaminants are discharged without being crushed. This large solid is
It is captured and removed by a classification net 14 of about 30 mm provided at the outlet 11a, and is carried out by a belt conveyor. On the other hand, the incinerated ash which has become a granular material of about 30 mm or less is sieved by the primary screening vibrating screen 20 of about 5 mm to 10 mm (for example, 10 mm). The sieved incineration ash of 10 mm or less is removed by a magnetic metal remover 21 after removing metal pieces in the incineration ash.
It is sent to the secondary granulator 12. On the other hand, 10mm-30m
Granules of about m are carried out by a belt conveyor and reused or discarded. The primary screening vibrating screen 20
Is supplied from the water supply unit 17, and the water that has passed through the primary sorting vibrating screen 20 is sent to a first feed sump 23 described later. The primary sorting vibrating screen 20 is a unit corresponding to the separating unit 15 of the first embodiment.

【0020】一次選別振動スクリーン20を通過した焼
却灰は、概ね10mm以下の粒状体となっているので、
二次細粒化機12では、給水部17からの処理水を上記
焼却灰に加水するともに、回転ドラム6とロータ7との
間隔を狭くしかつ回転速度を高速にし、焼却灰に対して
主に粒状体同士の摩擦による相互研磨を行わせ、焼却灰
に強く付着している重金属類やダイオキシン類を離脱さ
せつつ上記焼却灰を下流側に移動させ、二次細粒化機1
2の排出口12aから、二次選別振動スクリーン22に
送る。二次選別振動スクリーン22は、上記焼却灰から
5mm以下の粒状体を確実に篩い分けるもので、上記二
次選別振動スクリーン22から排出される5mm以下の
砂分や細粒化された灰粒子等の粒状体を含んだ泥状の焼
却灰は、第1のフィードサンプ23に一時貯蔵され後、
分級手段16により種々の大きさの粒状体に分級され
る。また、上記一次選別振動スクリーン20及び二次選
別振動スクリーン22で篩い分けされた5mm〜30m
m程度の砂礫や細かい陶器片を主とした粒状体は、搬出
され再利用あるいは廃棄される。
The incinerated ash that has passed through the primary sorting vibrating screen 20 is in the form of granular material having a size of approximately 10 mm or less.
In the secondary grain refiner 12, the treated water from the water supply unit 17 is added to the incineration ash, the interval between the rotary drum 6 and the rotor 7 is reduced, and the rotation speed is increased. Are subjected to mutual polishing by friction between the granular materials, and the incinerated ash is moved to the downstream side while separating heavy metals and dioxins strongly attached to the incinerated ash.
The liquid is sent to the secondary sorting vibrating screen 22 from the second discharge port 12a. The secondary sorting vibrating screen 22 is for surely sieving a granular material having a size of 5 mm or less from the incinerated ash. The mud-like incineration ash containing the granular material of the above is temporarily stored in the first feed sump 23,
The particles are classified into various sizes by the classification means 16. Also, 5 mm to 30 m sieved by the primary sorting vibrating screen 20 and the secondary sorting vibrating screen 22.
Granules mainly composed of sand and small ceramic pieces of about m are carried out and reused or discarded.

【0021】次に、分級手段16における分級処理につ
いて詳細に説明する。第1のフィードサンプ23に貯蔵
された5mm以下の粒状体を含んだ泥状の焼却灰は、第
1の液体サイクロン30に送られ分級される。第1の液
体サイクロン30では、約100μm以下の粒状体を処
理水中に浮遊させて分離する。上記第1の液体サイクロ
ン30の上部から排出された約100μm以下の粒状体
を含んだ処理水は、第1のフィードサンプ23に一時貯
蔵された後、第2のフィードサンプ33に送られる。一
方、第1の液体サイクロン30の底部から排出された粒
径が100μmを越える粒状体を含むスラリーは、第1
のスピゴットタンク31に送られた後、第1の脱水振動
スクリーン32で約100μm以上の砂分を主体とした
粒状体が分離されて、第2のフィードサンプ33に送ら
れる。同様に、第2のフィードサンプ33に貯蔵された
約100μm以下の粒状体となった焼却灰は、第2の液
体サイクロン34と第2の脱水振動スクリーン36とに
より、20〜100μmの微粒砂を主とした粒状体と2
0μm以下の微粒片とに分級される。すなわち、第2の
液体サイクロン34の上部から排出された約20μm以
下の微粒片を含んだ処理水は、第2のフィードサンプ3
3に一時貯蔵された後、ゴミ処理トロンメル37を介し
てシックナータンク40に送られる。また、一方、第1
の液体サイクロン30の底部から排出された粒径が20
μmを越える粒状体を含むスラリーは、第2のスピゴッ
トタンク35に送られた後、第2の脱水振動スクリーン
36により、約20μm以上の微粒砂を主体とした粒状
体が分離されて、シックナータンク40に送られる。
Next, the classification process in the classification means 16 will be described in detail. The mud-like incinerated ash containing the granular material of 5 mm or less stored in the first feed sump 23 is sent to the first liquid cyclone 30 and classified. In the first hydrocyclone 30, particles having a size of about 100 μm or less are separated by being suspended in treated water. The treated water containing particulate matter of about 100 μm or less discharged from the upper part of the first hydrocyclone 30 is temporarily stored in the first feed sump 23 and then sent to the second feed sump 33. On the other hand, the slurry containing the particulate matter having a particle diameter exceeding 100 μm discharged from the bottom of the first hydrocyclone 30 is the first liquid cyclone 30.
After being sent to the spigot tank 31, the first dewatering vibrating screen 32 separates the granular material mainly composed of sand of about 100 μm or more, and sends it to the second feed sump 33. Similarly, the incinerated ash stored in the second feed sump 33 in the form of granules having a particle size of about 100 μm or less is subjected to a second liquid cyclone 34 and a second dehydration vibrating screen 36 to remove fine sand of 20 to 100 μm. Main granular material and 2
Classified into fine particles of 0 μm or less. That is, the treated water containing fine particles of about 20 μm or less discharged from the upper part of the second hydrocyclone 34 is supplied to the second feed sump 3.
After being temporarily stored in the tank 3, it is sent to the thickener tank 40 via the trash disposal trommel 37. On the other hand, the first
Particle diameter discharged from the bottom of the hydrocyclone 30
After the slurry containing the particulate matter exceeding μm is sent to the second spigot tank 35, the particulate matter mainly composed of fine sand of about 20 μm or more is separated by the second dewatering vibration screen 36, and the thickener tank is separated. Sent to 40.

【0022】シックナータンク40では、上記約20μ
m以下の微粒片を含んだ処理水と泥状の焼却灰とをタン
ク内でゆっくりと回転させ、粒状体等の固形物を凝集沈
殿させる固液分離を行う。上記シックナータンク40の
上澄み液には、上述したように、焼却灰から分離された
重金属類が溶解あるいは浮遊しているので、汚水処理部
18の一次処理水槽50に送られ処理される。この一次
処理水槽50では、キレート剤等の添加によって上記重
金属類の不溶化塩を形成させ重金属類を不溶化すること
により、上記重金属類を上記処理液から分離する。一
方、シックナータンク40の底部に沈殿したスラリー状
の焼却灰は、第1のスラリータンク41に貯蔵された
後、遠心分離器42において、ダイオキシン類等の微粒
片を除去した後、第2のスラリータンク43に送られ貯
蔵される。遠心分離器42で分離された、ダイオキシン
類等の微粒片を多く含む有害な汚泥は、溶融固化等の処
理を施すなどして廃棄される。一方、スラリータンク4
3に貯蔵されたスラリーは、重金属類やダイオキシン類
が除去されて無害化されているので、脱水機44に送
り、このスラリーから、図示しないフィルタプレスによ
り脱水ケーキを作製するなどして再利用することができ
る。
In the thickener tank 40, about 20 μm
The treated water containing fine particles of m or less and the mud-like incinerated ash are slowly rotated in a tank to perform solid-liquid separation for coagulating and sedimenting solids such as particulates. As described above, since the heavy metals separated from the incineration ash are dissolved or suspended in the supernatant liquid of the thickener tank 40, they are sent to the primary treatment water tank 50 of the sewage treatment section 18 for treatment. In the primary treatment water tank 50, the heavy metals are separated from the treatment liquid by adding a chelating agent or the like to form an insolubilizing salt of the heavy metals and insolubilize the heavy metals. On the other hand, the slurry-like incineration ash that has settled at the bottom of the thickener tank 40 is stored in the first slurry tank 41, and after removing fine particles such as dioxins in the centrifuge 42, the second slurry It is sent to the tank 43 and stored. The harmful sludge containing a large amount of fine particles such as dioxins separated by the centrifugal separator 42 is discarded by performing a process such as melting and solidification. On the other hand, slurry tank 4
Since the slurry stored in 3 is detoxified by removing heavy metals and dioxins, it is sent to the dehydrator 44, and the slurry is reused by producing a dehydrated cake by a filter press (not shown). be able to.

【0023】なお、脱水機44で脱水された水は濾過水
返却用タンク51に送られ一時貯蔵され、その後、一次
処理水槽50で重金属類を不溶化した後、液体濾過装置
52に送られる。液体濾過装置52では、上記処理水を
活性炭等の吸着材で濾過して重金属類やダイオキシン類
を除去して浄化する。この浄化された処理水は給水部で
ある二次処理水槽53に送られる。また、シックナータ
ンク40から一次処理水槽50に送られた処理水も、上
記液体濾過装置52で浄化された後、二次処理水槽53
に送られる。二次処理水槽53に戻された処理水は、補
給用の清水と混合されて、再び、一次細粒化機11,二
次細粒化機12及び一次選別振動スクリーン20等に供
給される。
The water dehydrated by the dehydrator 44 is sent to a filtered water return tank 51 for temporary storage. After that, heavy metals are insolubilized in a primary treatment water tank 50 and then sent to a liquid filtration device 52. In the liquid filtration device 52, the treated water is filtered with an adsorbent such as activated carbon to remove heavy metals and dioxins to purify the treated water. The purified treated water is sent to a secondary treated water tank 53 that is a water supply unit. Further, the treated water sent from the thickener tank 40 to the primary treatment water tank 50 is also purified by the liquid filtration device 52, and then the secondary treatment water tank 53.
Sent to The treated water returned to the secondary treatment water tank 53 is mixed with fresh water for replenishment, and supplied again to the primary granulator 11, the secondary granulator 12, the primary sorting vibrating screen 20, and the like.

【0024】なお、上記実施の形態2においては、焼却
灰の処理システムについて説明したが、汚染土壌につい
ても、上記処理システムと同様の処理システムにより、
土粒子に付着した汚染物質を効率よく取り除くことがで
きるとともに、汚染土壌中の石,砂,微粒分等を抽出し
て再利用することができる。
In the second embodiment, the incineration ash treatment system has been described. However, contaminated soil can be treated by the same treatment system as the above treatment system.
The contaminants attached to the soil particles can be efficiently removed, and stones, sand, fine particles and the like in the contaminated soil can be extracted and reused.

【0025】[0025]

【発明の効果】以上説明したように、請求項1に記載の
発明によれば、処理空隙内に投入された汚染物質が付着
した粒状体に、加水しながら、圧縮及び粒状体相互間の
擦り合わせの力を作用させ、上記粒状体を独立した粒状
体に分離するとともに、上記粒状体の表面に付着してい
る汚染物質を分離する細粒化手段を複数段に渡って設
け、上記粒状体が各細粒化手段を順次通過するようにす
るとともに、前段の細粒化手段から排出された粒状体の
中から、5mm〜10mm径の間の所定の径以上の大き
さの粒状体とそれより大きさの小さな粒状体とを分離す
る分離手段を設け、大きさの小さな方の粒状体を後段の
細粒化手段に投入するようにしたので、後段の細粒化手
段では最大粒径が規制された粒状体を処理できる。した
がって、汚染物質が付着した粒状体の解砕・解膠を効率
的に行うことができ、上記粒状体の分級を容易にするこ
とができる。更に、上記分離された5mm径以上の大き
さの粒状体は無害な粒状体なので、再利用可能である。
As described above, according to the first aspect of the present invention, the granules to which the contaminants charged into the processing space are adhered are compressed and rubbed between the granules while adding water. By applying a force of matching, the granular material is separated into independent granular materials, and fine-graining means for separating contaminants adhering to the surface of the granular material is provided in a plurality of stages, and the granular material is provided. Are successively passed through each of the granulation means, and among the granules discharged from the preceding granulation means, granules having a size of a predetermined diameter or more between 5 mm and 10 mm in diameter, and Separation means for separating the smaller-sized granular material is provided, and the smaller-sized granular material is supplied to the subsequent-stage fine-graining means. Regulated granules can be processed. Therefore, the granular material to which the contaminant adheres can be efficiently crushed and peptized, and the classification of the granular material can be facilitated. Further, the separated granules having a diameter of 5 mm or more are harmless granules and can be reused.

【0026】請求項2に記載の発明によれば、上記大き
さの小さな方の粒状体の中から、重金属類やダイオキシ
ン類等の汚染物質を含むの微粒片と、大きさが上記微粒
片よりも大きい無害な微粒片とを分級する分級手段を設
けて、上記汚染物質を含む有害性の微粒片を取り除くよ
うにしたので、無害化された大きい方の粒状体を脱水ケ
ーキ等のリサイクル可能な資源に再使用することができ
るとともに、汚染物質が付着した粒状体の無害化及び減
容化に対して著しい効果をもたらすことができる。
According to the second aspect of the present invention, fine particles containing contaminants such as heavy metals and dioxins are selected from the smaller particles, and the fine particles are smaller than the fine particles. Classifying means for classifying large harmless fine particles is also provided so as to remove the harmful fine particles containing the contaminants, so that the larger harmless granular material can be recycled such as a dehydrated cake. It can be reused as a resource, and can have a remarkable effect on detoxification and volume reduction of the particulate matter to which contaminants adhere.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 本発明の実施の形態1に係わる汚染物質が付
着した粒状体の処理装置の構成を示すブロック図であ
る。
FIG. 1 is a block diagram showing a configuration of an apparatus for treating particulate matter to which contaminants adhere according to a first embodiment of the present invention.

【図2】 本実施の形態1に係わる細粒化手段を示す側
面図である。
FIG. 2 is a side view showing the grain refiner according to the first embodiment.

【図3】 本実施の形態1の細粒化手段の設定条件を示
す図である。
FIG. 3 is a diagram showing setting conditions of the grain refiner according to the first embodiment.

【図4】 本実施の形態1の解砕・解膠作用を説明する
ための図である。
FIG. 4 is a diagram for explaining the crushing and peptizing action of the first embodiment.

【図5】 本実施の形態1の解砕・解膠作用を説明する
ための図である。
FIG. 5 is a diagram for explaining a crushing / deflocculating action of the first embodiment.

【図6】 本発明の実施の形態2に係わる焼却灰の連続
処理システムの処理フローを示す図である。
FIG. 6 is a diagram showing a processing flow of a continuous incineration ash processing system according to Embodiment 2 of the present invention.

【図7】 従来の破砕機の構造を示す図である。FIG. 7 is a view showing the structure of a conventional crusher.

【符号の説明】[Explanation of symbols]

1 細粒化装置、2 シェル、3 動力機、4 処理材
料投入口、5 処理材料排出口、6 回転ドラム、6W
外羽根、7 ロータ、7W 内羽根、11 一次細粒
化機、12 二次細粒化機、13 受け入れホッパ、1
4 網、15 分離手段、16 分級手段、17 給水
部、18 汚水処理部、20 一次選別振動スクリー
ン、21 磁気式金属除去機、22 二次選別振動スク
リーン、23 第1のフィードサンプ、30 第1の液
体サイクロン、31 第1のスピゴットタンク、32
第1の脱水振動スクリーン、33 第2のフィードサン
プ、34 第2の液体サイクロン、35 第2のスピゴ
ットタンク、36 脱水振動スクリーン、37 ゴミ処
理トロンメル、40 シックナータンク、41 第1の
スラリータンク、42 遠心分離器、43 第2のスラ
リータンク、44 脱水機、50 一次処理水槽、51
濾過水返却用タンク、52 液体濾過装置、53 二
次処理水槽。
1 Atomizer, 2 shell, 3 motor, 4 processing material inlet, 5 processing material outlet, 6 rotating drum, 6W
Outer blade, 7 rotor, 7W inner blade, 11 primary granulator, 12 secondary granulator, 13 receiving hopper, 1
4 Net, 15 Separation means, 16 Classification means, 17 Water supply section, 18 Sewage treatment section, 20 Primary sorting vibrating screen, 21 Magnetic metal remover, 22 Secondary sorting vibrating screen, 23 First feed sump, 30 First Liquid cyclone, 31 first spigot tank, 32
1st dehydration vibrating screen, 33 2nd feed sump, 34 2nd hydrocyclone, 35 2nd spigot tank, 36 dehydration vibrating screen, 37 waste treatment trommel, 40 thickener tank, 41 first slurry tank, 42 Centrifugal separator, 43 second slurry tank, 44 dehydrator, 50 primary treatment water tank, 51
Filtration water return tank, 52 liquid filtration device, 53 secondary treatment water tank.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) B09B 3/00 B09B 5/00 ZABN 5/00 ZAB (71)出願人 390014568 東芝プラント建設株式会社 東京都大田区蒲田五丁目37番1号 (72)発明者 反後 堯雄 東京都新宿区新宿2丁目3番13号 溶融資 源株式会社内 (72)発明者 川口 謙治 東京都新宿区津久戸町2番1号 株式会社 熊谷組東京本社内 (72)発明者 信太 豊 埼玉県大里郡寄居町桜沢265番地 新六精 機株式会社内 (72)発明者 中山 汎 東京都港区西新橋3丁目7番1号 東芝プ ラント建設株式会社内──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) B09B 3/00 B09B 5/00 ZABN 5/00 ZAB (71) Applicant 390014568 Toshiba Plant Construction Co., Ltd. Ota, Tokyo 5-71, Kamata-ku, Ward (72) Inventor Takao Sango 2-3-13-1, Shinjuku, Shinjuku-ku, Tokyo Inside the molten resources company (72) Inventor Kenji Kawaguchi 2-1 Tsukudo-cho, Shinjuku-ku, Tokyo No. Kumagaya Gumi Tokyo Head Office (72) Inventor Yutaka Shinta 265 Sakurazawa, Yorii-cho, Osato-gun, Saitama Prefecture Inside Shinrokuseiki Co., Ltd. (72) Inventor Pan Nakayama 3-7-1 Nishishinbashi, Minato-ku, Tokyo Toshiba Plant Construction Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 処理空隙内に投入された汚染物質が付着
した粒状体に、加水しながら、圧縮及び粒状体相互間の
擦り合わせの力を作用させ、上記粒状体を独立した粒状
体に分離するとともに、上記粒状体の表面に付着してい
る汚染物質を分離する細粒化手段を複数段に渡って設
け、上記粒状体が各細粒化手段を順次通過するようにす
るとともに、前段の細粒化手段から排出された粒状体の
中から、5mm〜10mm径の間の所定の径以上の大き
さの粒状体と、上記粒状体よりも大きさの小さな粒状体
とを分離する分離手段を設け、上記大きさの小さな方の
粒状体を後段の細粒化手段に投入するようにしたことを
特徴とする汚染物質が付着した粒状体の処理装置。
1. A compressive force and a rubbing force between granular materials are applied to a granular material to which a contaminant charged in a processing space is attached, while adding water, to separate the granular material into independent granular materials. And a plurality of stages of fine-graining means for separating contaminants adhering to the surface of the granular material are provided so that the granular material sequentially passes through each fine-graining means, and Separating means for separating, from the granular material discharged from the fine-granulating means, a granular material having a predetermined diameter of 5 mm to 10 mm or more and a granular material having a size smaller than the above-mentioned granular material. Wherein the smaller granular material having the above-mentioned size is supplied to a subsequent-stage fine-granulating means.
【請求項2】 上記大きさの小さな方の粒状体の中か
ら、重金属類やダイオキシン類等の汚染物質を含むの微
粒片と、大きさが上記微粒片よりも大きい無害な微粒片
とを分級する分級手段を設けたことを特徴とする請求項
1記載の汚染物質が付着した粒状体の処理装置。
2. Classifying fine particles containing contaminants such as heavy metals and dioxins, and harmless fine particles having a size larger than the fine particles from the smaller particles. The apparatus for treating particulate matter to which contaminants adhere according to claim 1, further comprising a classifying means for performing the classification.
JP22376699A 1998-10-30 1999-08-06 Processing equipment for particulate matter with contaminants Expired - Fee Related JP4286990B2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP22376699A JP4286990B2 (en) 1998-10-30 1999-08-06 Processing equipment for particulate matter with contaminants
SG1999005288A SG73677A1 (en) 1998-10-30 1999-10-20 Method and system for carrying out treatment of granular substances with pollutants adhered
US09/422,782 US6402064B1 (en) 1998-10-30 1999-10-21 Method and system for carrying out treatment of granular substances with pollutants adhered
EP99120904A EP0997202A3 (en) 1998-10-30 1999-10-29 Method and system for carrying out treatment of granular substances with pollutants adhered
KR1019990047392A KR20000052354A (en) 1998-10-30 1999-10-29 Method and system for carrying out treatment of granular substances with pollutants adhered
IDP991005D ID25768A (en) 1998-10-30 1999-10-29 METHODS AND SYSTEMS FOR IMPLEMENTING TREATMENT OF GRANTS SUBSTANCED BY POLLUTANTS
CN99123287A CN1256977A (en) 1998-10-30 1999-10-29 Method and equipment for processing particle with pollutant
CA002287958A CA2287958A1 (en) 1998-10-30 1999-10-29 Method and system for carrying out treatment of granular substances with pollutants adhered
US09/950,936 US20020079392A1 (en) 1998-10-30 2001-09-12 Method and system for carrying out treatment of granular substances with pollutants adhered

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP10-310448 1998-10-30
JP31044898 1998-10-30
JP22376699A JP4286990B2 (en) 1998-10-30 1999-08-06 Processing equipment for particulate matter with contaminants

Publications (2)

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JP2000197879A true JP2000197879A (en) 2000-07-18
JP4286990B2 JP4286990B2 (en) 2009-07-01

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* Cited by examiner, † Cited by third party
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JP2015512780A (en) * 2012-03-22 2015-04-30 ヒョンデ エンジニアリング アンド コンストラクション カンパニー リミテッド Selective purification system according to particle size of heavy metal contaminated soil by dry pulverization and purification method
JP2013242300A (en) * 2013-04-15 2013-12-05 Prefectural Univ Of Hiroshima Method and device for treating radioactive substance contaminant
WO2018134983A1 (en) * 2017-01-20 2018-07-26 環テックス株式会社 Sieving device
CN113083469A (en) * 2021-04-13 2021-07-09 安徽到家营养食品有限公司 Grinding device is smashed to raw materials for flour processing
CN113083469B (en) * 2021-04-13 2023-09-22 河北晨风面业有限公司 Grinding device is smashed with raw materials to flour processing

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