JP2000156450A - Lead for electronic part - Google Patents

Lead for electronic part

Info

Publication number
JP2000156450A
JP2000156450A JP10329714A JP32971498A JP2000156450A JP 2000156450 A JP2000156450 A JP 2000156450A JP 10329714 A JP10329714 A JP 10329714A JP 32971498 A JP32971498 A JP 32971498A JP 2000156450 A JP2000156450 A JP 2000156450A
Authority
JP
Japan
Prior art keywords
lead
plating layer
alloy
plating
internal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10329714A
Other languages
Japanese (ja)
Inventor
Hisanori Akino
久則 秋野
Satoshi Chinda
聡 珍田
Osamu Yoshioka
修 吉岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Cable Ltd
Original Assignee
Hitachi Cable Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Cable Ltd filed Critical Hitachi Cable Ltd
Priority to JP10329714A priority Critical patent/JP2000156450A/en
Publication of JP2000156450A publication Critical patent/JP2000156450A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/42Wire connectors; Manufacturing methods related thereto
    • H01L24/43Manufacturing methods
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/43Manufacturing methods
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/43Manufacturing methods
    • H01L2224/438Post-treatment of the connector
    • H01L2224/43848Thermal treatments, e.g. annealing, controlled cooling
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • H01L2224/45001Core members of the connector
    • H01L2224/4501Shape
    • H01L2224/45012Cross-sectional shape
    • H01L2224/45015Cross-sectional shape being circular
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • H01L2224/45001Core members of the connector
    • H01L2224/45099Material
    • H01L2224/451Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
    • H01L2224/45138Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
    • H01L2224/45147Copper (Cu) as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • H01L2224/4554Coating
    • H01L2224/45565Single coating layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • H01L2224/4554Coating
    • H01L2224/4557Plural coating layers
    • H01L2224/45572Two-layer stack coating

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Lead Frames For Integrated Circuits (AREA)

Abstract

PROBLEM TO BE SOLVED: To suppress creation of whisker and discoloration by forming an internal plating layer that is made of Sn or Sn alloy on a lead base material and forming an external plating layer that is made of Ag on the internal plating layer. SOLUTION: An internal plating layer 2 that is made of Sn alloy is formed on a lead base material 1 using a wire that is composed of copper alloy or the like under the conditions of a current density of 4A/dm2 and plating time of 3 minutes using an organic sulfone acid plating liquid. Then, an external plating layer 3 is formed on the internal plating layer 2 under the conditions of a current density of 2A/dm2 and plating time of 10 seconds using a cyan plating liquid. After that, wire drawing annealing and skin path process are executed to obtain a prescribed lead for electronic parts, thus improving reliability by suppressing creation of whisker and discoloration.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、電子部品用リード
に関し、特に、電子機器配線用導体としてのリード、あ
るいは半導体装置のアウターリードなどとして好適な電
子部品用リードに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a lead for an electronic component, and more particularly to a lead for an electronic component suitable as a lead for a wiring of an electronic device or an outer lead of a semiconductor device.

【0002】[0002]

【従来の技術】ダイオード、抵抗器、コンデンサ、ある
いはトランジスタ等の電子部品に使用されるリードとし
て、たとえば、銅あるいは銅合金のワイヤー上にSn‐
Pb合金、つまり、はんだめっきを施したものが知られ
ている。
2. Description of the Related Art Leads used in electronic components such as diodes, resistors, capacitors, transistors, etc. are, for example, Sn-wires on copper or copper alloy wires.
Pb alloys, that is, those subjected to solder plating are known.

【0003】また、ICパッケージ等の半導体装置にお
いては、接続対象のプリント基板との接続性を良好にす
るために、電解法、あるいは溶解法によりアウターリー
ドの表面にはんだめっき層を形成することが行われてい
る。
In a semiconductor device such as an IC package, a solder plating layer may be formed on the surface of an outer lead by an electrolytic method or a dissolving method in order to improve the connectivity with a printed circuit board to be connected. Is being done.

【0004】このような構成のリードは、熱酸化に対す
る優れた耐性と良好なはんだ濡れ性を備えていることに
よって特徴づけられ、電子機器の配線、あるいは電子品
のプリント基板への実装等の用途において多用されてお
り、この種リードによる接合プロセスは、高密度な接合
技術を必要とする電子部品の分野においては完全に定着
している。
A lead having such a structure is characterized by having excellent resistance to thermal oxidation and good solder wettability, and is used for wiring of electronic equipment or mounting of electronic goods on a printed circuit board. This type of lead bonding process has been fully established in the field of electronic components requiring high-density bonding technology.

【0005】しかし、このようなはんだめっき層を形成
したリードによると、めっき層の中のPb成分が、酸性
雨などによって溶出される性質のものであることから、
地下水汚染、延いては人体への影響が懸念されており、
このため、環境保護上の観点から、その使用に制約が加
えられる傾向にある。
However, according to the lead having such a solder plating layer formed thereon, the Pb component in the plating layer has a property of being eluted by acid rain or the like.
There is concern about groundwater pollution and, in turn, its effects on the human body.
Therefore, from the viewpoint of environmental protection, there is a tendency that the use thereof is restricted.

【0006】このため、Pbを含有しないPbフリーの
はんだ合金の開発が各方面で進められており、その代表
的な例として、Snめっき層を形成したリードを挙げる
ことができる。このリードは、シンプルな材料系であ
り、Pbフリー合金との濡れ性もよく、強度的にも適し
ている。
For this reason, the development of Pb-free solder alloys containing no Pb has been promoted in various fields. A typical example thereof is a lead having an Sn plating layer formed thereon. This lead is a simple material, has good wettability with a Pb-free alloy, and is suitable for strength.

【0007】[0007]

【発明が解決しようとする課題】しかし、Snめっき層
を形成したリードによると、ウイスカーが発生しやす
く、また、変色する傾向があり、Sn‐Pb合金の代替
めっきとしては特性的に充分とは言えない。
However, according to the lead on which the Sn plating layer is formed, whiskers are liable to occur and discoloration tends to occur, so that the characteristics are not sufficient as an alternative plating for the Sn-Pb alloy. I can not say.

【0008】従って、本発明の目的は、これまで多用さ
れてきたSn‐Pb合金めっきのリードと同等の性能を
有しながら地下水を汚染せず、また、ウイスカーの発生
および変色を抑えた電子部品用リードを提供することに
ある。
Accordingly, an object of the present invention is to provide an electronic component which has the same performance as Sn-Pb alloy plating leads which have been frequently used, does not contaminate groundwater, and suppresses generation and discoloration of whiskers. To provide a lead for use.

【0009】[0009]

【課題を解決するための手段】本発明は、上記の目的を
達成するため、リード母材と、前記リード母材の上に形
成された内部めっき層と、前記内部めっき層の上に形成
された外部めっき層から構成されるリードにおいて、前
記内部めっき層をSnあるいはSn合金により構成し、
前記外部めっき層をAgにより構成したことを特徴とす
る電子部品用リードを提供するものである。
In order to achieve the above object, the present invention provides a lead base material, an internal plating layer formed on the lead base material, and an internal plating layer formed on the internal plating layer. Wherein the inner plating layer is made of Sn or a Sn alloy,
It is another object of the present invention to provide a lead for an electronic component, wherein the external plating layer is made of Ag.

【0010】上記のリード母材としては、たとえば、対
象が電子機器の配線に使用されるリードであれば、銅、
あるいは銅合金等から構成されたワイヤーが使用され
る。リードフレームを使用した半導体装置のアウターリ
ードが、本発明におけるリード母材を構成する用途は可
能であり、また、リードフレームの代わりに銅箔の配線
パターンと絶縁フィルムを積層したテープキャリアを使
用し、これにより構成される半導体装置のアウターリー
ドに本発明を適用することも可能である。
The above-mentioned lead base material may be, for example, copper or copper if the object is a lead used for wiring of electronic equipment.
Alternatively, a wire made of a copper alloy or the like is used. The outer lead of a semiconductor device using a lead frame can be used to constitute a lead base material in the present invention, and a tape carrier in which a copper foil wiring pattern and an insulating film are laminated in place of the lead frame is used. It is also possible to apply the present invention to the outer leads of the semiconductor device constituted by this.

【0011】内部めっき層を構成するSn合金として
は、Sn‐Bi合金、Sn‐Sb合金、Sb‐In合金
などが使用される。内部および外部に、Sn系のめっき
層とAgのめっき層を形成した本発明の電子部品用リー
ドは、伸線アニールとスキンパス加工(塑性流動を起こ
させない加工)を施されることが好ましい。
As the Sn alloy constituting the internal plating layer, a Sn-Bi alloy, a Sn-Sb alloy, a Sb-In alloy or the like is used. It is preferable that the lead for electronic parts of the present invention in which the Sn-based plating layer and the Ag plating layer are formed inside and outside are subjected to wire drawing annealing and skin pass processing (processing that does not cause plastic flow).

【0012】外部めっき層を構成するAgには、伸線ア
ニールとスキンパス加工を経ることによって、Snある
いはSn合金めっき層の中に拡散する性質があり、従っ
て、これにより、リード母材の表面には、Sn‐Ag合
金、Sn‐Bi‐Ag合金、Sn‐Sb‐Ag合金、あ
るいはSn‐In‐Ag合金等のSn‐Ag系めっき層
が形成されることになる。
The Ag constituting the external plating layer has a property of diffusing into the Sn or Sn alloy plating layer through wire drawing annealing and skin pass processing. Means that a Sn-Ag-based plating layer such as a Sn-Ag alloy, a Sn-Bi-Ag alloy, a Sn-Sb-Ag alloy, or a Sn-In-Ag alloy is formed.

【0013】これらの合金めっき層は、リード母材への
密着性、はんだ濡れ性(はんだ付け性)、耐変色性、お
よびウイスカー性において、特に良好な特性を示し、S
n‐Pbめっきに劣らない特性を有することが確認され
た。
[0013] These alloy plating layers exhibit particularly good characteristics in adhesion to the lead base material, solder wettability (solderability), discoloration resistance, and whisker properties.
It was confirmed that it had characteristics not inferior to n-Pb plating.

【0014】[0014]

【発明の実施の形態】次に、本発明による電子部品用リ
ードの実施の形態について説明する。図1は、本実施形
態における電子部品用リードの断面構造を示したもの
で、1は外径0.6mmの銅合金ワイヤー、2は銅合金
ワイヤー1の上に形成された内部めっき層、3は内部め
っき層2の上に形成された外部めっき層を示す。
Next, an embodiment of an electronic component lead according to the present invention will be described. FIG. 1 shows a cross-sectional structure of an electronic component lead according to the present embodiment, wherein 1 is a copper alloy wire having an outer diameter of 0.6 mm, 2 is an internal plating layer formed on the copper alloy wire 1, Indicates an external plating layer formed on the internal plating layer 2.

【0015】[0015]

【実施例1】酸洗したワイヤー1の上に、厚さ6μmの
Snの内部めっき層2を電解法により形成し、次いで、
これに、同じく電解法により厚さ0.05μmのAgの
外部めっき層3を形成し、所定の電子部品用リードを得
た。
Example 1 An inner plating layer 2 of Sn having a thickness of 6 μm was formed on a pickled wire 1 by an electrolytic method.
An external plating layer 3 of Ag having a thickness of 0.05 μm was similarly formed thereon by the electrolytic method to obtain predetermined electronic component leads.

【0016】内部めっき層2は、有機スルフォン酸系の
めっき液を使用し、電流密度4A/dm2 およびめっき
時間3分の条件のもとで成膜させ、一方、外部めっき層
3は、シアン系のめっき液を使用し、電流密度2A/d
2 、めっき時間10秒の条件下で成膜させた。成膜
後、これに伸線アニールとスキンパス工程を施すことに
より、所定の電子部品用リードとした。
The inner plating layer 2 is formed by using an organic sulfonic acid-based plating solution under the conditions of a current density of 4 A / dm 2 and a plating time of 3 minutes. Current density 2A / d
The film was formed under the conditions of m 2 and a plating time of 10 seconds. After the film was formed, the wire was subjected to wire drawing annealing and a skin pass process to obtain a predetermined electronic component lead.

【0017】[0017]

【実施例2】実施例1において、内部めっき層2の構成
材をSn‐Bi合金とした以外、他を同一条件とするこ
とにより所定の電子部品用リードを得た。
Example 2 A predetermined lead for an electronic component was obtained under the same conditions as in Example 1 except that the constituent material of the internal plating layer 2 was an Sn—Bi alloy.

【0018】[0018]

【実施例3】実施例1において、内部めっき層2の構成
材をSn‐Sb合金とした以外、他を同一条件とするこ
とにより所定の電子部品用リードを得た。
Example 3 A predetermined electronic component lead was obtained under the same conditions as in Example 1 except that the constituent material of the internal plating layer 2 was an Sn—Sb alloy.

【0019】[0019]

【実施例4】実施例1において、内部めっき層2の構成
材をSn‐In合金とした以外、他を同一条件とするこ
とにより所定の電子部品用リードを得た。
Example 4 A predetermined lead for an electronic component was obtained under the same conditions as in Example 1 except that the constituent material of the internal plating layer 2 was an Sn-In alloy.

【0020】[0020]

【従来例】図2において、銅合金ワイヤー1の上に厚さ
6μmのSn‐Pb合金めっき層4を電解法により形成
し、所定の電子部品用リードを得た。
2. Prior Art Referring to FIG. 2, a Sn-Pb alloy plating layer 4 having a thickness of 6 .mu.m was formed on a copper alloy wire 1 by an electrolytic method to obtain predetermined leads for electronic parts.

【0021】[0021]

【参考例】図2において、めっき層4を電解法による厚
さ6μmのSnめっきにより形成し、所定の電子部品用
リードを得た。
REFERENCE EXAMPLE In FIG. 2, a plating layer 4 was formed by Sn plating with a thickness of 6 μm by an electrolytic method to obtain predetermined electronic component leads.

【0022】表1に、以上の実施例、従来例、および参
考例により得られた電子部品用リードの特性試験結果を
示す。試験項目としては、めっき層の密着性、はんだ濡
れ性、耐変色性、およびウイスカーの発生有無を選択し
た。
Table 1 shows the characteristic test results of the leads for electronic parts obtained in the above Examples, Conventional Examples and Reference Examples. As test items, adhesion of the plating layer, solder wettability, discoloration resistance, and presence or absence of whiskers were selected.

【0023】めっき層の密着性は、水素雰囲気中におい
てサンプルを350℃で15分間加熱し、引き続きこれ
を大気中において250℃で2時間加熱した後、自己径
巻き付けを行ったときのめっき層の剥離の有無によって
評価した。
The adhesion of the plating layer was determined by heating the sample in a hydrogen atmosphere at 350 ° C. for 15 minutes, subsequently heating the sample in the air at 250 ° C. for 2 hours, and then performing self-diameter winding. The evaluation was based on the presence or absence of peeling.

【0024】自己径巻き付けは、サンプルの一端をバイ
スに挟み、他端を90°に曲げた状態で固定することに
よりサンプルを所定の個所に張り、これに90°に曲げ
た部分を支点としてサンプルを数10回巻き付けること
によって行った。この試験で、めっき層に剥離が発生し
ない場合を1、若干の剥離発生を2、完全な剥離発生を
3とした。
The self-diameter winding is performed by sandwiching one end of a sample between vise and fixing the other end in a state bent at 90 ° so that the sample is stretched at a predetermined position, and the sample bent at 90 ° is used as a fulcrum. Was wound several tens of times. In this test, the case where no peeling occurred in the plating layer was designated as 1, the slight peeling occurred as 2, and the complete peeling occurred as 3.

【0025】はんだ濡れ性は、MIL−STD−202
D−208Bの試験法に基づき、フラックスなしの状態
で密着性試験におけるのと同じ加熱処理を施したとき
の、はんだ濡れ面積によって評価した。濡れ面積が90
%以上を1、70〜90%未満を2、70%未満を3と
した。
The solder wettability was determined by MIL-STD-202.
Based on the test method of D-208B, the evaluation was made based on the solder wetting area when the same heat treatment as in the adhesion test was performed in the state of no flux. 90 wet area
% Or more, 1, 70 to less than 90% was 2, and less than 70% was 3.

【0026】耐変色性は、40℃/95%RHの恒温恒
湿の雰囲気にサンプルを10日間放置したときの変色の
有無により評価し、変色なしを1、若干変色を2、変色
を3とした。
The discoloration resistance was evaluated by the presence or absence of discoloration when the sample was allowed to stand for 10 days in an atmosphere of constant temperature and humidity of 40 ° C./95% RH. did.

【0027】ウイスカーの発生有無は、121℃/60
%RHの恒温恒湿の雰囲気にサンプルを24時間放置し
た後の目視判定によって確認した。発生なしを1、若干
発生を2、発生を3とした。
The presence or absence of whiskers is determined at 121 ° C./60.
The sample was allowed to stand in a constant temperature and constant humidity atmosphere of% RH for 24 hours, and was confirmed by visual judgment. No occurrence was set to 1, slight occurrence was set to 2, and occurrence was set to 3.

【0028】[0028]

【表1】 [Table 1]

【0029】表1によれば、実施例による電子部品用リ
ードが、めっき層の密着性、はんだ濡れ性、耐変色性、
およびウイスカー発生有無のいずれにおいても従来例と
同じ1の評価を得ている。
According to Table 1, the lead for an electronic component according to the embodiment has a good adhesion of a plating layer, solder wettability, discoloration resistance, and the like.
Regarding the occurrence of whiskers and the presence / absence of whiskers, the same evaluation as the conventional example was obtained.

【0030】これらの項目は、従来、長い間にわたって
電子部品の接合プロセスに定着してきたSn‐Pb合金
めっきリードの特性を評価するための試験項目であり、
従って、これらの試験項目において、Sn‐Pb合金め
っきリードと遜色のない試験結果を示していることは、
本発明によるリードが、Sn‐Pb合金めっきリードに
代わる電子部品用リードとして、有効に活用可能なこと
を意味している。Snめっき層を形成した参考例のリー
ドの場合には、ウイスカー発生有無のテスト結果が悪
く、実用性において問題がある。
These items are test items for evaluating the characteristics of Sn—Pb alloy plating leads that have long been established in the joining process of electronic components for a long time.
Therefore, in these test items, it shows that the test results are comparable to those of Sn-Pb alloy plating leads.
This means that the lead according to the present invention can be effectively used as a lead for electronic components instead of a Sn-Pb alloy plating lead. In the case of the lead of the reference example in which the Sn plating layer is formed, the test result of the presence or absence of whisker is poor, and there is a problem in practicality.

【0031】[0031]

【発明の効果】以上説明したように、本発明による電子
部品用リードによれば、リード母材の上にSnあるいは
Sn合金の内部めっき層と、Agの外部めっき層を順に
形成したため、これまで多用されてきたSn‐Pb合金
めっきリードと同等の特性を有しながら地下水を汚染す
ることもなく、また、ウイスカーの発生および変色の抑
制によって信頼性を高めることができる。
As described above, according to the lead for electronic parts of the present invention, the inner plating layer of Sn or Sn alloy and the outer plating layer of Ag are sequentially formed on the lead base material. It has the same characteristics as the Sn-Pb alloy plating lead, which has been widely used, without polluting groundwater, and can improve reliability by suppressing generation of whiskers and discoloration.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明による電子部品用リードの実施の形態を
示す説明図。
FIG. 1 is an explanatory view showing an embodiment of an electronic component lead according to the present invention.

【図2】従来の電子部品用リードの説明図。FIG. 2 is an explanatory view of a conventional electronic component lead.

【符号の説明】[Explanation of symbols]

2 内部めっき層 3 外部めっき層 2 Internal plating layer 3 External plating layer

───────────────────────────────────────────────────── フロントページの続き (72)発明者 吉岡 修 茨城県土浦市木田余町3550番地 日立電線 株式会社システムマテリアル研究所内 Fターム(参考) 4K024 AA10 AA21 AB02 BA09 BB09 BB10 BC03 DA03 DB01 DB07 GA14 GA16 5F067 AA04 AA09 DC12 DC18 EA04 ──────────────────────────────────────────────────続 き Continued on the front page (72) Osamu Yoshioka, 3550 Kida Yomachi, Tsuchiura-shi, Ibaraki F-term in the System Materials Research Laboratory, Hitachi Cable, Ltd. AA04 AA09 DC12 DC18 EA04

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】リード母材と、前記リード母材の上に形成
された内部めっき層と、前記内部めっき層の上に形成さ
れた外部めっき層から構成されるリードにおいて、 前記内部めっき層をSnあるいはSn合金により構成
し、 前記外部めっき層をAgにより構成したことを特徴とす
る電子部品用リード。
1. A lead comprising a lead base material, an internal plating layer formed on the lead base material, and an external plating layer formed on the internal plating layer, wherein the internal plating layer is A lead for an electronic component, wherein the lead is made of Sn or a Sn alloy, and the external plating layer is made of Ag.
【請求項2】前記Sn合金は、Sn‐Bi合金、Sn‐
Sb合金、Sn‐In合金のいずれかであることを特徴
とする請求項第1項記載の電子部品用リード。
2. The Sn alloy according to claim 1, wherein the Sn alloy is an Sn—Bi alloy,
2. The lead according to claim 1, wherein the lead is one of an Sb alloy and a Sn-In alloy.
【請求項3】前記リード母材は、銅、あるいは銅合金等
から構成されるワイヤーであることを特徴とする請求項
第1項あるいは第2項記載の電子部品用リード。
3. The electronic component lead according to claim 1, wherein said lead base material is a wire made of copper, a copper alloy, or the like.
【請求項4】前記リードは、伸線アニールとスキンパス
加工を施されたことを特徴とする請求項第1項ないし第
3項のいずれかに記載の電子部品用リード。
4. The lead for an electronic component according to claim 1, wherein said lead has been subjected to wire drawing annealing and skin pass processing.
【請求項5】前記リード母材は、半導体装置のアウター
リードであることを特徴とする請求項第1項ないし第3
項のいずれかに記載の電子部品用リード。
5. The semiconductor device according to claim 1, wherein said lead base material is an outer lead of a semiconductor device.
Item 14. An electronic component lead according to any one of the above items.
JP10329714A 1998-11-19 1998-11-19 Lead for electronic part Pending JP2000156450A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10329714A JP2000156450A (en) 1998-11-19 1998-11-19 Lead for electronic part

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10329714A JP2000156450A (en) 1998-11-19 1998-11-19 Lead for electronic part

Publications (1)

Publication Number Publication Date
JP2000156450A true JP2000156450A (en) 2000-06-06

Family

ID=18224457

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10329714A Pending JP2000156450A (en) 1998-11-19 1998-11-19 Lead for electronic part

Country Status (1)

Country Link
JP (1) JP2000156450A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005002368A (en) * 2003-06-09 2005-01-06 Ishihara Chem Co Ltd Tin plating bath for preventing whisker
JP2007046150A (en) * 2005-04-06 2007-02-22 Misuzu:Kk Lead wire for electronic part and flat cable comprising the same
JP2007100148A (en) * 2005-10-03 2007-04-19 C Uyemura & Co Ltd Whisker-suppressive surface treating method
US7501578B2 (en) * 2002-12-18 2009-03-10 Paolo Agostinelli Electric conductors
WO2015147213A1 (en) * 2014-03-26 2015-10-01 新日鉄住金マテリアルズ株式会社 Conductor, and solar-cell interconnector
WO2020071002A1 (en) * 2018-10-01 2020-04-09 富山住友電工株式会社 Method and device for manufacturing plated wire

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7501578B2 (en) * 2002-12-18 2009-03-10 Paolo Agostinelli Electric conductors
JP2005002368A (en) * 2003-06-09 2005-01-06 Ishihara Chem Co Ltd Tin plating bath for preventing whisker
JP2007046150A (en) * 2005-04-06 2007-02-22 Misuzu:Kk Lead wire for electronic part and flat cable comprising the same
JP2007100148A (en) * 2005-10-03 2007-04-19 C Uyemura & Co Ltd Whisker-suppressive surface treating method
WO2015147213A1 (en) * 2014-03-26 2015-10-01 新日鉄住金マテリアルズ株式会社 Conductor, and solar-cell interconnector
WO2020071002A1 (en) * 2018-10-01 2020-04-09 富山住友電工株式会社 Method and device for manufacturing plated wire

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