JP2000154082A - Granular accelerator for humification of organic substance and soil amendment - Google Patents

Granular accelerator for humification of organic substance and soil amendment

Info

Publication number
JP2000154082A
JP2000154082A JP32205998A JP32205998A JP2000154082A JP 2000154082 A JP2000154082 A JP 2000154082A JP 32205998 A JP32205998 A JP 32205998A JP 32205998 A JP32205998 A JP 32205998A JP 2000154082 A JP2000154082 A JP 2000154082A
Authority
JP
Japan
Prior art keywords
lime
iron oxide
humification
nitrogen
org
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP32205998A
Other languages
Japanese (ja)
Other versions
JP4033986B2 (en
Inventor
Takuji Naokawa
拓司 直川
Takahiro Yamamoto
恭弘 山本
Yoshifumi Nosaka
佳史 野坂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denka Co Ltd
Original Assignee
Denki Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denki Kagaku Kogyo KK filed Critical Denki Kagaku Kogyo KK
Priority to JP32205998A priority Critical patent/JP4033986B2/en
Publication of JP2000154082A publication Critical patent/JP2000154082A/en
Application granted granted Critical
Publication of JP4033986B2 publication Critical patent/JP4033986B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/20Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Organic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Fertilizers (AREA)

Abstract

PROBLEM TO BE SOLVED: To improve working property for spraying and to accelerate humification of org. matter such as rice straw by compounding each specified amt. of lime-nitrogen, urea, phosphate fertilizer, iron oxide-contg. substance and granulating the mixture. SOLUTION: This granular amendment is produced by compounding, by wt.%, >=20% lime-nitrogen, 10 to 20% urea, >=0.5% phosphate fertilizer calculated as phosphorus oxide (P2O5), <20% (not including 0) iron oxide-contg. substance calculated as iron oxide(Fe2O3), then heating and granulating the mixture by extrusion method or the like. The phosphate fertilizer is preferably fused magnesium phosphate. Fused magnesium phosphate has a neutralizing effect on org. acids produced by humification of the org. matter. It also contains magnesia, zinc or the like which is necessary as a nutrient even in a minute amt. for bacteria and further contains silicate which is sometimes used to prepare the soil in a field. The iron oxide-contg. substance is preferably steelmaking slag. Steelmaking slag contains silicate, lime, magnesia, phosphate and other minute components which are supposed to be effective for acceleration of humification, and the slag is useful to neutralize org. acids produced by humification of the org. matter.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、粒状の有機物腐熟
促進・土壌改良資材に関し、詳しくは、石灰窒素を主成
分とし、稲わら等の有機物の腐熟を促進するとともに鉄
分の補給等の土壌改良を一度に行うことができ、しかも
散布しやすい粒状の有機物腐熟促進・土壌改良資材に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a granular organic matter decay accelerating / soil improving material, and more particularly to a lime nitrogen-based material which promotes decay of organic matter such as rice straw and improves soil quality by replenishing iron. The present invention relates to a granular organic matter maturation promoting / soil improving material which can be applied at once and is easy to spray.

【0002】[0002]

【従来の技術】米麦作においてはコンバイン使用による
収穫が一般的であり、収穫にともない残査であるわら類
が圃場に排出される。排出されたわら類の一部は家畜の
飼料、敷料やわら加工品原料、堆肥原料として有効利用
されているが、大部分は焼却されるかそのまま圃場に放
置される。焼却される場合は貴重な有機質資源を無駄に
するとともに地域によっては煙による重大な交通障害の
問題を発生する恐れもある。一方、わら類が圃場に放置
された場合、含有する窒素分が炭素分の見合いに比べ少
なく腐熟化の進行が遅いため、腐熟不十分なわらによる
窒素飢餓を起こしたり、水田ではメタンなどの還元状態
で発生するガスによる障害、除草剤の薬害の助長などの
生育障害が発生することが知られている。
2. Description of the Related Art In rice and wheat cultivation, harvesting by use of a combine is common, and straws, which are residuals, are discharged to a field with the harvesting. Some of the discharged straw is effectively used as livestock feed, litter and raw materials for processed straw and compost, but most of it is incinerated or left in the field. When incinerated, it wastes valuable organic resources and in some areas can cause serious traffic problems due to smoke. On the other hand, when straw is left in the field, the nitrogen content is low compared to the carbon content, and the ripening progresses slowly, causing nitrogen starvation due to insufficiently ripened straw, and the reduction of methane etc. in paddy fields It is known that a growth disorder such as a disorder caused by gas generated in the state and a promotion of phytotoxicity of the herbicide occurs.

【0003】これらの生育障害を軽減するための腐熟促
進剤として、尿素、りん酸肥料、石灰を混合造粒した粒
状腐熟化促進資材(特開平2−208276号公報)
や、石灰窒素のもつ腐熟促進効果を利用しつつ、酸化鉄
の配合によって土壌の溶脱鉄分の補給を同時に可能とし
た有機物腐熟促進・土壌改良資材(特開平7−1260
93号公報)が提案されている。
As a maturation accelerator for reducing these growth disorders, a granular maturation accelerating material obtained by mixing and granulating urea, phosphate fertilizer and lime (Japanese Patent Laid-Open No. 2-208276).
And an organic matter maturation promoting / soil improving material that can simultaneously supplement the leached iron content of soil by blending iron oxide while utilizing the maturation promoting effect of lime nitrogen (Japanese Patent Application Laid-Open No. Hei 7-1260).
No. 93) has been proposed.

【0004】特開平2−208276号公報による発明
は、微生物の栄養源である窒素、りん酸分や稲わらの繊
維分の分解を促す作用を示す石灰を混合するなど、わら
類の腐熟促進に対しある程度有効な手段であった。しか
しながら、この発明の窒素源は、腐熟促進に最も関与す
る石灰窒素ではなく、流亡や揮散が起こりやすい硫安や
尿素であるため、ロスを見込んで単位面積当りの窒素施
用量を増量しなければ効果が発揮しにくいという欠点が
あった。また、水田によっては、しばしば問題となる硫
化水素による障害に対しては何の配慮もなされていない
ものであった。
The invention disclosed in Japanese Patent Application Laid-Open No. 2-208276 is intended to promote the maturation of straws by mixing lime, which is a nutrient source of microorganisms, which promotes the decomposition of nitrogen, phosphate, and rice straw fibers. On the other hand, it was an effective measure to some extent. However, the nitrogen source of the present invention is not lime nitrogen which is most involved in promoting ripening, but is ammonium sulfate or urea, which is liable to run off or volatilize. However, there was a drawback that it was difficult to exhibit. Also, in some paddy fields, no consideration was given to the often problematic damage caused by hydrogen sulfide.

【0005】これに対し、特開平7−126093号公
報による発明は、石灰窒素を主成分とし、しかも上記硫
化水素による障害軽減のための鉄分の補給が可能となっ
ている点で画期的なものであった。しかしながら、有効
な造粒化方法がなかったため、粉状で供給せざるを得
ず、腐熟促進効果は高いものの散布時の粉立ちや機械散
布に不適応など使用上の点で改良の余地があった。
On the other hand, the invention according to Japanese Patent Application Laid-Open No. 7-126093 is an epoch-making method in that lime nitrogen is a main component and iron can be replenished in order to reduce the above-mentioned trouble caused by hydrogen sulfide. Was something. However, since there was no effective granulation method, it had to be supplied in powder form, and although it had a high ripening promoting effect, there was room for improvement in terms of use such as dusting during spraying and inapplicability to mechanical spraying. Was.

【0006】[0006]

【発明が解決しようとする課題】本発明品を含め一般に
腐熟促進資材の使用法は、コンバイン収穫により圃場に
放置されたわら上に散布し、耕耘(鍬込み)する手順が
主として想定される。散布時の利便性のためには散布さ
れる迄は粒状の形態を保ち、かつ圃場に散布されあるい
は鍬込まれた段階では速やかに成分が分散し、有機物の
腐熟促進効果・土壌改良効果を発揮させる必要がある。
In general, the use of the material for promoting ripening, including the product of the present invention, is mainly supposed to be a procedure of spraying on a straw that has been left in a field by combine harvesting and tilling (plowing). For the convenience of spraying, it keeps granular form until sprayed, and when it is sprayed or plowed in the field, the components are quickly dispersed, and it has the effect of promoting the maturation of organic matter and soil improvement Need to be done.

【0007】従って、本発明の目的は、粒状化により散
布時の作業性を大幅に向上させることができ、しかも稲
わらなどの有機物の腐熟を更に促進するとともに、土壌
改良効果をも有する有機物腐熟促進・土壌改良資材を提
供することにある。
[0007] Accordingly, an object of the present invention is to improve the workability at the time of spraying by granulation, and to further promote the maturation of organic matter such as rice straw and also have the effect of improving soil quality. To provide accelerating and soil improvement materials.

【0008】[0008]

【課題を解決するための手段】すなわち、本発明は、石
灰窒素20重量%以上、尿素10〜20重量%、りん酸
肥料をりん酸分(P25)として0.5重量%以上、酸
化鉄含有物を酸化鉄分(Fe23)として20重量%未
満(0を含まず)を含有してなることを特徴とする粒状の
有機物腐熟促進・土壌改良資材である。特に、りん酸肥
料がようりんであり、酸化鉄含有物が製鋼スラグである
ことを特徴とするものである。
That is, according to the present invention, lime nitrogen is 20% by weight or more, urea is 10 to 20% by weight, and a phosphate fertilizer is 0.5% by weight or more as a phosphoric acid content (P 2 O 5 ). iron oxide-containing material is an organic substance maturity promote soil improving material in particulate, characterized by containing as less than 20% oxidized iron (Fe 2 0 3) (0 not including). Particularly, the phosphate fertilizer is yorin and the iron oxide-containing material is steelmaking slag.

【0009】以下、更に詳しく本発明を説明する。Hereinafter, the present invention will be described in more detail.

【0010】本発明の粒状の有機物腐熟促進・土壌改良
資材(以下、「本発明品」ともいう。)は、石灰窒素を
20重量%以上を含む。石灰窒素が20重量%未満であ
ると腐熟促進効果が著しく低下する。石灰窒素の割合の
上限については特に制約はないが、本発明品にはバイン
ダーとしての尿素を含ませる必要があり、全窒素をいた
ずらに多くすると却って窒素過剰による障害の発生の恐
れが心配されるので、その上限は60重量%程度である
ことが望ましい。特に望ましくは30〜50重量%であ
る。
The granular organic matter maturation accelerating / soil improving material of the present invention (hereinafter, also referred to as the "product of the present invention") contains at least 20% by weight of lime nitrogen. When the amount of lime nitrogen is less than 20% by weight, the effect of promoting ripening is remarkably reduced. There is no particular upper limit on the proportion of lime nitrogen, but it is necessary to include urea as a binder in the product of the present invention. Therefore, the upper limit is desirably about 60% by weight. Particularly desirable is 30 to 50% by weight.

【0011】本発明品に使用する石灰窒素は、全窒素1
9.0重量%以上、アルカリ分50重量%以上のものが
好適であるがこれに限られることはない。この石灰窒素
に、生石灰、消石灰、炭酸石灰等の石灰質物質等を更に
配合し、全窒素を10重量%以上にしたものであっても
よい。石灰窒素の粒度については、500ミクロン以下
とすることによって、造粒が容易となる。
The lime nitrogen used in the product of the present invention is 1% of total nitrogen.
Those having 9.0% by weight or more and an alkali content of 50% by weight or more are suitable, but not limited thereto. A calcareous substance such as quicklime, slaked lime and carbonated lime may be further added to this lime nitrogen to make the total nitrogen 10% by weight or more. By setting the particle size of lime nitrogen to 500 microns or less, granulation becomes easy.

【0012】次に、本発明品においては、10〜20重
量%の尿素を含んでいる。尿素は、本発明品を製造する
際のバインダーとしての役割を果たすものである。造粒
は、混合原料を常温もしくは適温に加温し、押し出し、
打錠等の加圧成型をすることによって行われる。
Next, the product of the present invention contains 10 to 20% by weight of urea. Urea plays a role as a binder when producing the product of the present invention. For granulation, warm the mixed raw material to room temperature or appropriate temperature, extrude,
This is performed by press molding such as tableting.

【0013】尿素をバインダーとして造粒された本発明
品は、散布時の利便性を有するとともに、散布された後
は、尿素が土壌から水分を吸収して急激かつ極端に崩壊
し、降雨や耕耘等の若干の刺激によって速やかに各成分
に分散する。
The product of the present invention granulated using urea as a binder has the convenience of spraying, and after being sprayed, urea absorbs moisture from the soil and rapidly and extremely disintegrates, causing rainfall and tilling. Disperse promptly in each component by a slight stimulus.

【0014】尿素が10重量%未満であると、バインダ
ーとしての役割が十分でなくなり、所期した造粒物に成
型することが困難となる。造粒物の硬さ、大きさは適宜
調整が可能であるが、本発明の目的からは圧壊加重5〜
15kg、直径3mm程度の柱状体が望ましい。
When the amount of urea is less than 10% by weight, the role as a binder is not sufficient, and it is difficult to mold the desired granulated product. The hardness and size of the granulated material can be appropriately adjusted, but for the purpose of the present invention, the crushing load is 5 to 5.
A columnar body of 15 kg and a diameter of about 3 mm is desirable.

【0015】一方、尿素の上限を20重量%に限定した
理由は、次のとおりである。すなわち、一般に腐熟促進
資材に含有させることができる全窒素には上限があり、
わら腐熟に必要な量以上に窒素を含有していた場合、窒
素は無機態窒素として土壌に残留し翌年の作付けに悪影
響を与えることがある。尿素は、それ自体が窒素分を含
有しているため、その使用によって、有機物腐熟促進用
途の窒素源として最も効果の優れているとされる石灰窒
素の割合を相対的に減じざるを得ない。そこで本発明に
おいては、尿素の割合は、造粒を行うのに必要最小限に
止めておくことが望ましく、20重量%以内とした。
On the other hand, the reason why the upper limit of urea is limited to 20% by weight is as follows. That is, there is generally an upper limit to the total nitrogen that can be contained in the ripening promoting material,
If the nitrogen content is higher than that required for straw ripening, the nitrogen may remain in the soil as inorganic nitrogen and adversely affect planting in the following year. Since urea itself contains nitrogen, its use has to relatively reduce the proportion of lime nitrogen, which is considered to be the most effective nitrogen source for organic matter maturation. Therefore, in the present invention, the ratio of urea is desirably kept to a minimum necessary for performing granulation, and is set within 20% by weight.

【0016】以上のように、本発明においては窒素分と
して石灰窒素と尿素を併用するものであるがこれによっ
て有機物腐熟促進効果は減少してしまう。そこで、この
減少を補うため本発明では新たにりん酸肥料をりん酸分
として0.5重量%以上を含有させたものである。りん
酸肥料の作用機作は不明であるが、必要量は小さいもの
の、窒素と同様微生物の栄養源であるりん酸分を補って
やることにより、石灰窒素の効果を助長させるものと考
えている。りん酸肥料の割合が、りん酸分として0.5
重量%未満であると上記効果が不十分となる。その上限
については特に制限はないが、10重量%程度までが望
ましい。
As described above, in the present invention, lime nitrogen and urea are used in combination as the nitrogen content, but the effect of promoting organic maturation is reduced. Therefore, in order to compensate for this decrease, in the present invention, a phosphate fertilizer is newly added to contain 0.5% by weight or more as a phosphoric acid content. The mechanism of action of phosphate fertilizer is unknown, but although the required amount is small, it is thought that supplementing phosphate, which is a nutrient source of microorganisms like nitrogen, will promote the effect of lime nitrogen. . The ratio of phosphate fertilizer is 0.5
If the amount is less than 10% by weight, the above effect becomes insufficient. The upper limit is not particularly limited, but is preferably up to about 10% by weight.

【0017】本発明品で使用されるりん酸肥料には特に
制限はなく、市販されている一般のりん酸質肥料が使用
される。具体的には、ようりん、焼成りん肥、重焼り
ん、過燐酸石灰、重過燐酸石灰等であるが、特にようり
んが好適である。その理由は、ようりんは有機物の腐熟
にともなって産生される有機酸の中和能力を持ち、しか
もりん酸分の他に微量だがこれも微生物の養分として必
要な苦土、亜鉛などを含むとともに、圃場の土づくりの
ために施用されることがあるケイ酸分を含んでいるから
である。
The phosphate fertilizer used in the product of the present invention is not particularly limited, and commercially available general phosphate fertilizer is used. Specific examples include yorin, calcined phosphorus manure, heavy burnt phosphorus, lime superphosphate, lime heavy superphosphate, etc., with yorin being particularly preferred. The reason is that yorin has the ability to neutralize the organic acids produced by the ripening of organic matter. This is because it contains silicic acid which may be applied for soil preparation in the field.

【0018】次に、本発明品においては、酸化鉄含有物
を酸化鉄として20重量%以下(0を含まない)を含ん
でおり、これによって硫化水素による上記障害を軽減さ
せることができる。酸化鉄含有物が上記よりも多いと、
造粒において比重の大きな原料である酸化鉄含有物資材
の割合が過多となり、強度的に満足できる粒状物が得ら
れずに粉化が大きくなる。
Next, the product of the present invention contains the iron oxide-containing material in an amount of not more than 20% by weight (excluding 0) as iron oxide, whereby the above-mentioned obstacles caused by hydrogen sulfide can be reduced. If the iron oxide content is higher than the above,
In the granulation, the ratio of the iron oxide-containing material, which is a raw material having a large specific gravity, becomes excessive, so that a granular material having satisfactory strength cannot be obtained and powdering increases.

【0019】本発明品で使用される酸化鉄含有物につい
ては、ボーキサイトさい、パイライトさい、ミルスケー
ル等であるが、特に好ましくは平炉さい、転炉さいとい
った製鋼スラグである。これらの製鋼スラグは、目的と
する酸化鉄を含有する他、腐熟促進用途にも有効と考え
られるケイ酸、石灰、苦土、りん酸及びその他の微量成
分を含むとともに、ようりんと同様アルカリ分を含むた
め有機物の腐熟にともない産生する有機酸の中和にも役
立つ。
The iron oxide-containing material used in the product of the present invention includes bauxite, pyrite and mill scale, and particularly preferably steelmaking slag such as open hearth and converter furnace. These steelmaking slags contain not only the target iron oxide, but also silicic acid, lime, magnesia, phosphoric acid and other trace components which are considered to be effective for maturation promotion. It also helps neutralize the organic acids produced as the organic matter matures.

【0020】本発明の粒状の有機物腐熟促進・土壌改良
資材は、上記石灰窒素、尿素、りん酸肥料及び酸化鉄含
有物を混合造粒する際、生石灰、消石灰、炭酸石灰、ケ
イ酸石灰等の有機物の腐熟に有効とされている肥料成分
を更に混合し、各成分濃度を希釈して造粒することもで
きる。
The granular organic matter maturation accelerating / soil improving material of the present invention can be used for mixing and granulating the above-mentioned lime nitrogen, urea, phosphate fertilizer and iron oxide-containing materials, such as quicklime, slaked lime, carbonated lime, silicate lime and the like. It is also possible to mix the fertilizer components which are considered to be effective for the maturation of organic substances, to dilute the concentrations of the components, and to granulate.

【0021】[0021]

【実施例】以下、実施例、比較例をあげて更に具体的に
本発明を説明する。
The present invention will be described below more specifically with reference to examples and comparative examples.

【0022】実施例1〜2 比較例1 石灰窒素(全窒素24重量%)、尿素(全窒素46重量
%)、ようりん(りん酸分19重量%)及び転炉石灰
(酸化鉄分20重量%)を、表1に示す割合で混合した
後、115℃に加熱し、押し出し造粒機により直径3m
m×高さ3〜7mmの円柱状に成型し、粒状の有機物腐
熟促進・土壌改良資材を製造した。
Examples 1-2 Comparative Example 1 Lime nitrogen (24% by weight of total nitrogen), urea (46% by weight of total nitrogen), yorin (19% by weight of phosphoric acid) and converter lime (20% by weight of iron oxide) ) Was mixed at a ratio shown in Table 1, heated to 115 ° C., and extruded with a granulator to a diameter of 3 m.
It was molded into a column having a size of mx 3 to 7 mm in height to produce a granular organic matter maturation promoting / soil improving material.

【0023】比較例2 ようりんの全量を転炉石灰に置き換えてりん酸を0.0
重量%としたこと以外は、実施例1と同様な方法で粒状
の有機物腐熟促進・土壌改良資材を製造した。
Comparative Example 2 Phosphoric acid was changed to 0.0 by replacing the entire amount of yorin with converter lime.
A granular organic matter maturing promotion / soil improvement material was produced in the same manner as in Example 1 except that the content was changed to wt%.

【0024】比較例3 転炉石灰38重量%をミルスケール(酸化鉄分70重量
%)30重量%とケイ酸石灰8重量%に置き換えて酸化
鉄分を21重量%としたこと以外は、実施例1と同様な
方法で粒状の有機物腐熟促進・土壌改良資材を製造し
た。
COMPARATIVE EXAMPLE 3 Example 1 was repeated except that 38% by weight of converter lime was replaced by 30% by weight of mill scale (70% by weight of iron oxide) and 8% by weight of lime silicate to make 21% by weight of iron oxide. In the same manner as described above, a granular organic matter maturation promoting / soil improving material was produced.

【0025】以上の実施例、比較例で製造された粒状の
有機物腐熟促進・土壌改良資材について、以下に従う、
硬度、粉化率及び腐熟効果を測定した。それらの結果を
表2に示す。
The granular organic matter ripening promoting and soil improving materials produced in the above Examples and Comparative Examples are as follows:
Hardness, powdering rate and ripening effect were measured. Table 2 shows the results.

【0026】(1)硬度:木屋式硬度計により測定(2
mm長)した。 (2)粉化率:ロータップシェーカー3分間運転による
0.3mm篩下の割合を算出(重量%)した。 (3)腐熟効果:圃場に寒冷紗を敷き、上位3節目を中
心に約7cmにカットした稲わら20.0gを広げ、所
定量のサンプルを散布した後、更に寒冷紗をかけ3cm
程度覆土した。その後、所定期日にわらを回収し、その
残存重量とC/N比を測定した。なお、散布量は、いず
れも窒素が3.3g/m2となる量とした。
(1) Hardness: Measured with a Kiya type hardness meter (2
mm length). (2) Powdering ratio: The ratio under a 0.3 mm sieve operated by a low tap shaker for 3 minutes was calculated (% by weight). (3) Ripening effect: Spreading cold gauze on the field, spreading 20.0 g of rice straw cut to about 7 cm centering on the upper third joint, spraying a predetermined amount of sample, and then applying cold gauze for 3 cm
The soil was covered to a certain extent. Thereafter, the straw was collected on a predetermined date, and the remaining weight and C / N ratio were measured. In addition, the spraying amount was set to an amount at which nitrogen became 3.3 g / m 2 .

【0027】[0027]

【表1】 [Table 1]

【0028】[0028]

【表2】 [Table 2]

【0029】[0029]

【発明の効果】本発明品によれば、粉立ち等が少なく作
業性に優れた粒状の有機物腐熟促進材が得られる。本発
明品は、有機物腐熟促進材としての効果のみならず、施
用により鉄分の補給という土壌化学性の改善効果も得ら
れる省力的な農業資材として農業の生産性向上に寄与す
る。
According to the product of the present invention, a granular organic substance maturation promoting material which has less dusting and is excellent in workability can be obtained. INDUSTRIAL APPLICABILITY The product of the present invention contributes to the improvement of agricultural productivity as a labor-saving agricultural material capable of obtaining not only an effect as an organic matter maturation promoter but also an effect of improving soil chemistry such as supplementation of iron by application.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C05C 9:00 C05D 3:04 9:02 C05B 13:02) C09K 101:00 Fターム(参考) 4H026 AA01 AA05 AA07 AB04 4H061 AA01 AA10 BB13 BB15 BB21 BB44 DD01 DD14 DD20 EE12 EE16 EE25 EE41 EE43 FF08 HH11 HH34 JJ01 KK01 LL25 LL26 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C05C 9:00 C05D 3:04 9:02 C05B 13:02) C09K 101: 00 F term (reference) 4H026 AA01 AA05 AA07 AB04 4H061 AA01 AA10 BB13 BB15 BB21 BB44 DD01 DD14 DD20 EE12 EE16 EE25 EE41 EE43 FF08 HH11 HH34 JJ01 KK01 LL25 LL26

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 石灰窒素20重量%以上、尿素10〜2
0重量%、りん酸肥料をりん酸分(P25)として0.
5重量%以上、酸化鉄含有物を酸化鉄分(Fe23)と
して20重量%未満(0を含まず)を含有してなることを
特徴とする粒状の有機物腐熟促進・土壌改良資材。
1. Lime nitrogen 20% by weight or more, urea 10-2
0% by weight, phosphate fertilizer as phosphate content (P 2 O 5 )
5 wt% or more, particulate organic matter maturity promoting soil improving material which is characterized by containing less than 20 wt% (not including 0) iron oxide-containing material as an oxidizing iron (Fe 2 0 3).
【請求項2】 りん酸肥料がようりんであり、酸化鉄含
有物が製鋼スラグであることを特徴とする請求項1記載
の粒状の有機物腐熟促進・土壌改良資材。
2. The granular organic matter maturation accelerating and soil improving material according to claim 1, wherein the phosphate fertilizer is yorin and the iron oxide-containing material is steelmaking slag.
JP32205998A 1998-11-12 1998-11-12 Promotion of granular organic matter ripening and soil improvement Expired - Fee Related JP4033986B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP32205998A JP4033986B2 (en) 1998-11-12 1998-11-12 Promotion of granular organic matter ripening and soil improvement

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP32205998A JP4033986B2 (en) 1998-11-12 1998-11-12 Promotion of granular organic matter ripening and soil improvement

Publications (2)

Publication Number Publication Date
JP2000154082A true JP2000154082A (en) 2000-06-06
JP4033986B2 JP4033986B2 (en) 2008-01-16

Family

ID=18139464

Family Applications (1)

Application Number Title Priority Date Filing Date
JP32205998A Expired - Fee Related JP4033986B2 (en) 1998-11-12 1998-11-12 Promotion of granular organic matter ripening and soil improvement

Country Status (1)

Country Link
JP (1) JP4033986B2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100485446B1 (en) * 2002-09-05 2005-04-27 주식회사 협화 Complex fertilizer containing soil-conditioning elements and manufacturing method therefor
JP2006193368A (en) * 2005-01-13 2006-07-27 Denki Kagaku Kogyo Kk Nitrogenous fertilizer composition
JP2007022834A (en) * 2005-07-14 2007-02-01 Denki Kagaku Kogyo Kk Nitrogen fertilizer composition
CN104045399A (en) * 2014-06-06 2014-09-17 山东锦鸿源生态农业有限责任公司 Soil repair agent and preparation method thereof
CN104140322A (en) * 2014-07-29 2014-11-12 杭州市植保土肥总站 Hickory soil acidification modifier and preparation method and application
CN107963946A (en) * 2017-12-12 2018-04-27 昆山合纵生态科技有限公司 A kind of preparation method with the bio-feritlizer of soil remediation

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5585490A (en) * 1978-12-23 1980-06-27 Kenji Ishihara Compost producing aid compost manufacture using it
JPS6437485A (en) * 1987-08-03 1989-02-08 Tosoh Corp Rot promoter and manufacture
JPH02133384A (en) * 1988-11-10 1990-05-22 Ryohei Oshikiri Highly basic material for improving soil environment
JPH02208276A (en) * 1989-02-06 1990-08-17 Tosoh Corp Humification-promoting agent and production thereof
JPH07126093A (en) * 1993-10-27 1995-05-16 Denki Kagaku Kogyo Kk Organic matter humification promoter/soil modifier
JPH07157385A (en) * 1993-12-02 1995-06-20 Denki Kagaku Kogyo Kk Production of granular fertilizer
JPH1017388A (en) * 1996-06-28 1998-01-20 Shinetsu Kasei Kk Fertilizer for promoting humification ripening of organic matter and preparing soil and its production

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5585490A (en) * 1978-12-23 1980-06-27 Kenji Ishihara Compost producing aid compost manufacture using it
JPS6437485A (en) * 1987-08-03 1989-02-08 Tosoh Corp Rot promoter and manufacture
JPH02133384A (en) * 1988-11-10 1990-05-22 Ryohei Oshikiri Highly basic material for improving soil environment
JPH02208276A (en) * 1989-02-06 1990-08-17 Tosoh Corp Humification-promoting agent and production thereof
JPH07126093A (en) * 1993-10-27 1995-05-16 Denki Kagaku Kogyo Kk Organic matter humification promoter/soil modifier
JPH07157385A (en) * 1993-12-02 1995-06-20 Denki Kagaku Kogyo Kk Production of granular fertilizer
JPH1017388A (en) * 1996-06-28 1998-01-20 Shinetsu Kasei Kk Fertilizer for promoting humification ripening of organic matter and preparing soil and its production

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100485446B1 (en) * 2002-09-05 2005-04-27 주식회사 협화 Complex fertilizer containing soil-conditioning elements and manufacturing method therefor
JP2006193368A (en) * 2005-01-13 2006-07-27 Denki Kagaku Kogyo Kk Nitrogenous fertilizer composition
JP2007022834A (en) * 2005-07-14 2007-02-01 Denki Kagaku Kogyo Kk Nitrogen fertilizer composition
CN104045399A (en) * 2014-06-06 2014-09-17 山东锦鸿源生态农业有限责任公司 Soil repair agent and preparation method thereof
CN104045399B (en) * 2014-06-06 2016-04-27 山东锦鸿源生态农业有限责任公司 A kind of soil-repairing agent and preparation method thereof
CN104140322A (en) * 2014-07-29 2014-11-12 杭州市植保土肥总站 Hickory soil acidification modifier and preparation method and application
CN104140322B (en) * 2014-07-29 2016-06-15 杭州市植保土肥总站 Semen Caryae Cathayensis soil acidification modifying agent and preparation method and application
CN107963946A (en) * 2017-12-12 2018-04-27 昆山合纵生态科技有限公司 A kind of preparation method with the bio-feritlizer of soil remediation

Also Published As

Publication number Publication date
JP4033986B2 (en) 2008-01-16

Similar Documents

Publication Publication Date Title
US20070295046A1 (en) Method for Treating Extinguisher Powder Wastes, and Fertilizer Obtained from Such a Method
EP2882825B1 (en) . product and process for the intensification of plant cultivation and increase plant fertillity
US5228895A (en) Fertilizer and limestone product
CA2493215C (en) Agrochemical composition containing phosphite and process for the preparation thereof
JP2012082111A (en) Mineral replenishing material and method for producing the same
JP3273158B2 (en) Manufacturing method of granular organic maturation accelerator
JP2000154082A (en) Granular accelerator for humification of organic substance and soil amendment
US5085681A (en) Fertilizer materials based on metallurgical slags and methods of making the same
JP5105322B2 (en) Silica phosphate fertilizer raw material and method for producing the same
US3303016A (en) Fertilizing metallurgical slag with nitrogen salts for aglomeration and powdering resistance
JP2616580B2 (en) Humic formation promoter and method for producing the same
JPH1017388A (en) Fertilizer for promoting humification ripening of organic matter and preparing soil and its production
JPS6335598B2 (en)
DE3721012C1 (en) Process for producing a granular soil conditioner by treating particles of a porous material with a water glass solution and use
JPH03237082A (en) Granular phosphatic fertilizer containing humid acid
JP2006143509A (en) Highly water-absorbing granular fertilizer and method for manufacturing the same
CN1229070A (en) Compound and mixed fertilizer and preparation method thereof
JPH1161118A (en) Preventive agent against soil acidification by acid rain
JP4417466B2 (en) Organic matter ripening promoter
WO2003018512A1 (en) Fertiliser
KR20040060838A (en) Raw material for silicate phosphate fertilizer and method for production thereof
JPH0383881A (en) Compound fertilizer and its production
JPH06104595B2 (en) Humus accelerator and method for producing the same
JPH07126093A (en) Organic matter humification promoter/soil modifier
JPH09157077A (en) Granular mixed fertilizer containing granular oyster shell

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20040420

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20050222

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050404

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20061010

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20061124

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20071023

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20071024

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101102

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101102

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111102

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121102

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131102

Year of fee payment: 6

LAPS Cancellation because of no payment of annual fees