JP2000144107A - Non-slip sheet for tape - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a sheet or a tape useful for rugs, or the like, for a kitchen, an entrance or a bathroom, capable of manifesting excellent non-slip properties even when a floor surface is wetted with water and having a non-slip layer without fouling the floor surface, or the like. SOLUTION: This non-slip sheet or tape has a non-slip layer prepared by coating a non-slip agent obtained by compounding an aqueous resin with inorganic hollow microparticles or the hollow microparticles coated with a coating of an inorganic powder and drying the non-slip agent on one surface of a substrate and a tacky agent layer on the other surface. The non-slip sheet or tape has non-slip layers prepared by coating the non-slip agent obtained by compounding the aqueous resin with the hollow microparticles or the hollow microparticles coated with a coating of the inorganic powder and drying the non-slip agent on both surfaces of a substrate. The aqueous resin is an emulsion obtained by carrying out an emulsion polymerization of an α,β-ethylenically unsaturated monomer. The glass transition temperature of the α,β-ethylenically unsaturated monomer is <=40 deg.C and the hollow microparticles are compounded in an amount of 0.1-30 pts. wt. based on 100 pts. wt. of the solid content of the aqueous resin.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a table cloth, a mat, a carpet or the like used in a kitchen, an entrance, a bathroom, etc., which is adhered to the back of a rug or sandwiched under a rug, and these are used as a table, floor material, etc. The present invention relates to an anti-slip sheet and a tape for preventing slipping from a predetermined position and deviation from a predetermined position.

[0002]

2. Description of the Related Art In order to prevent a rug or the like from deviating from a predetermined position on a floor surface, generally, a soft resin, rubber or a solution thereof having a large coefficient of friction is applied to the back of the rug,
A method of forming an anti-slip layer after drying has been performed. In order to impart such anti-slip property, generally, rubber or resin having strong adhesiveness is generally used, or an inorganic filler such as colloidal silica is often mixed with resin. Another slip prevention method is disclosed in JP-A-8-15.
No. 1478 discloses a method using a heat-expandable filler. This is a method in which a filler that expands by heat and becomes hollow is mixed in a polymer emulsion, and a film is formed on a target substrate surface by a heating operation, and at the same time, hollow fine particles are generated.

[0003]

When a rubber or resin having tackiness is used as an anti-slip agent, there is a disadvantage that the anti-slip agent adheres to an object surface such as a table or a floor in contact with the anti-slip agent and stains the surface. . In particular, when the temperature of the use environment is high or when a heavy object is left for a long time, the stain is remarkable. In addition, when a filler such as colloidal silica is used, the stain on the base material surface is reduced, but since the colloidal silica is more stabilized on the alkali side, the viscosity increases and gels when the aqueous resin is near neutrality. It was easy to handle. On the other hand, in the method using a heat-expandable filler, it is necessary to make the expansion start temperature of the heat-sensitive expansion filer or higher,
For example, heating as high as 130 ° C. was required. Therefore, there is a problem that the material of the rug used is limited. In addition, the anti-slip properties are such that fine protrusions formed on the surface are pushed in by the load and rubber and resin come into contact with the floor surface etc., and when the load is removed, the protrusions are reproduced and the protrusions are reproduced with the floor surface etc. This is a mechanism for reducing the contact area of the. Because of such a mechanism, it is necessary for the polymer emulsion itself to be considerably soft and sticky as in the prior art in order to exhibit the anti-slip property.

A rug using a conventional anti-slip agent generally has extremely low frictional resistance when used under high humidity or in a state where water is spilled, for example, in a dressing room, and has a low anti-slip property. There was also a drawback of lowering.

In the method of processing the anti-slip layer, generally, a sufficient temperature is required to heat the resin to a temperature higher than the film forming temperature after applying the anti-slip agent and to volatilize water and a solvent. At a temperature lower than the film forming temperature, the film does not become dense and does not function as a binder as an anti-slip layer. Further, there is also a problem that when heated, the material is deteriorated by temperature depending on the material of the rug. The formation of the anti-slip layer generally needs to be performed at the time of manufacturing the rug, and it has been difficult to easily apply the anti-slip layer later to the rug without the anti-slip layer.

In view of the above circumstances, the present invention provides excellent anti-slip properties by sticking to a rug or the like or sandwiching it under a rug, and has no dirt on a floor surface or the like to which the anti-slip layer contacts. Further, the present invention provides an anti-slip sheet and tape which exhibit high anti-slip properties even under high humidity and in the presence of water. The use of the sheet or tape makes it possible to easily provide the rug or the like with slip resistance later.

[0007]

Means for Solving the Problems As a result of diligent efforts to achieve the above object, an anti-slip agent comprising an aqueous resin mixed with inorganic hollow fine particles or hollow fine particles coated with inorganic powder is applied and dried. It has been found that the tape exhibits excellent anti-slip properties and low contamination on the substrate surface under normal conditions or under high humidity and in the presence of water. It has also been found that, by using the hollow fine particles, unlike a conventional sheet or tape having an anti-slip layer, excellent anti-slip properties can be exhibited even when the aqueous resin serving as a binder has low adhesiveness.

[0008] That is, the first invention is to apply an anti-slip agent comprising a water-based resin mixed with inorganic hollow fine particles or hollow fine particles coated with an inorganic powder, and to apply a dried anti-slip layer to one surface of the substrate. And a non-slip sheet or tape having an adhesive layer on the other surface. The second invention is an anti-slip sheet having an aqueous resin mixed with an inorganic hollow fine particle or a hollow fine particle coated with an inorganic powder, coated with an anti-slip agent, and having a dried anti-slip layer on both surfaces of the substrate. Or tape. In the third invention, the aqueous resin is α, β
The anti-slip sheet or tape according to the first or second invention, which is an aqueous emulsion obtained by emulsion polymerization of an ethylenically unsaturated monomer.

A fourth invention is the anti-slip sheet or tape according to the third invention, wherein the α, β ethylenically unsaturated monomer has a glass transition point of 40 ° C. or less. The fifth invention is the anti-slip sheet or tape according to any one of the first to fourth inventions, wherein the hollow fine particles are compounded in an amount of 0.1 to 30 parts by weight based on 100 parts by weight of the solid content of the aqueous resin. is there.

[0010]

BEST MODE FOR CARRYING OUT THE INVENTION

The aqueous resin used in the present invention includes, in its resin form, 1) a water-soluble resin, 2) a hydrosol,
3) It is classified into an emulsion, but any one may be used as long as it forms a film on the surface of the substrate. Resin types include acrylic emulsion, acrylic / styrene copolymer emulsion, acrylic / vinyl acetate copolymer emulsion, ethylene /
Acrylic copolymer emulsions, vinyl chloride emulsions, synthetic rubber emulsions such as SBR, urethane resin emulsions, acrylic / urethane composite resin emulsions, epoxy resin emulsions, natural rubber latex, etc. These can be selected in consideration of the adhesion to the base material, the adhesion to the target surface in contact with the anti-slip agent, the physical properties of the coating film under the use environment, and the like. Among them, an aqueous emulsion obtained by emulsion polymerization of an α, β ethylenically unsaturated monomer is particularly preferred in that it can obtain adhesion to a substrate, compatibility with hollow fine particles, and an arbitrary glass transition point.

The α, β ethylenically unsaturated monomers include:
Known monomers can be used. For example, unsaturated monomers having a carboxyl group such as (meth) acrylic acid, itaconic acid and crotonic acid; 2-hydroxyethyl (meth)
(Meth) acrylates having a hydroxyl group such as acrylate, hydroxypropyl (meth) acrylate, and 4-hydroxybutyl acrylate; methyl (meth) acrylate, N-methylol (meth) acrylamide, and ethyl (meth) acrylate; Propyl (meth) acrylate, isopropyl (meth) acrylate, butyl (meth) acrylate, pentyl (meth) acrylate, hexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, octyl (meth) acrylate (Meth) such as nonyl methacrylate, lauryl (meth) acrylate, methoxyethyl (meth) acrylate, methoxybutyl (meth) acrylate, and ethoxybutyl (meth) acrylate
Alkyl acrylate; unsaturated monomer having an epoxy group such as glycidyl (meth) acrylate, allyl glycidyl ether; acrylamide, N-butoxymethyl (meth) acrylamide, N-methylacrylamide, N, N-dimethylacrylamide, N An unsaturated monomer having an amide group such as isopropylacrylamide;
N, N-dimethylaminoethyl methacrylate, N, N
(Meth) acrylic acid having a tertiary amino group such as -diethylaminoethyl methacrylate, N, N-dimethylaminopropyl methacrylate; N-vinylpyrrolidone, N
-Nitrogen-containing unsaturated monomers such as vinylimidazole and N-vinylcarbazole; alicyclic (meth) acrylates such as cyclopentyl (meth) acrylate, cyclohexyl (meth) acrylate and isobornyl (meth) acrylate; styrene, α-methyl Aromatic unsaturated monomers such as styrene and phenyl methacrylate; silicon-containing unsaturated monomers such as vinyltriethoxysilane and γ-methacryloyloxypropyltrimethoxysilane; octafluoropentyl (meth) acrylate, perfluorocyclohexyl ( There are monomers having one unsaturated group, such as a fluorinated unsaturated monomer such as meth) acrylate and an unsaturated monomer in which an isocyanate group is blocked. Further, bifunctional unsaturated monomers such as divinylbenzene and polyethylene glycol di (meth) acrylate can also be used.

The surfactant used in the emulsion polymerization includes anionic surfactants such as fatty acid salts, alkyl sulfate salts, alkyl benzene sulfonates, naphthalene sulfonates, alkyl sulfosuccinates; and polyoxyethylene alkyls. There are nonionic surfactants such as ether, polyoxyethylene alkyl ester, polyoxyethylene alkyl phenyl ether, and polyoxyethylene alkyl phenyl ester. It is also possible to use a reactive activator in combination to suppress a decrease in water resistance.

The emulsion polymerization can be carried out by a known method. For example, there is a method in which a pre-emulsion composed of water, a surfactant, and an unsaturated monomer is prepared in advance, and the whole pre-emulsion is charged, the whole amount is dropped, or the remaining portion is dropped by partially charging. As the polymerization initiator, both a water-soluble initiator and an oil-soluble initiator can be used. When using the oil-soluble initiator, it is preferable to dissolve it in the unsaturated monomer in advance, and to further refine the pre-emulsion by mechanical stirring. As a method for making finer, it is possible to disperse in water using a normal stirrer. In order to obtain a stable aqueous dispersion, forcible dispersion under a high shearing force using a homomixer, a homogenizer, or a microfluidizer (manufactured by Mizuho Industry Co., Ltd.) is preferable.

The polymerization initiator used in the emulsion polymerization is suitably used in the range of 0.05 to 5% based on the amount of the unsaturated monomer. The temperature is preferably from 40 to 100C, and 80C or less is sufficient for a redox initiator. As the polymerization initiator, azo compounds such as azobisisobutyronitrile, azobisisobutylvaleronitrile, benzoyl peroxide,
Isobutyryl peroxide, octanoyl peroxide, cumyl peroxy octate, t-butyl peroxy-2-ethylhexanoate, t-butyl peroxy acetate, lauryl peroxide, di-t-butyl peroxide, di- Organic peroxides such as 2-ethylhexylperoxyzine carbonate, potassium persulfate,
There are inorganic peroxide compounds such as ammonium persulfate and hydrogen peroxide. Organic or inorganic peroxide compounds can also be used as redox initiators in combination with reducing agents. As the reducing agent used,
L-ascorbic acid, L-sorbic acid, sodium metabisulfite, ferric sulfate, ferric chloride, Rongalite and the like can be mentioned.

When the unsaturated monomer is polymerized, use of a known chain transfer agent such as octyl mercaptan, lauryl mercaptan, 2-mercaptoethanol, terchardodecyl mercaptan, thioglycolic acid, etc. for the purpose of controlling the molecular weight. Is also possible.

When a carboxyl group-containing unsaturated monomer is used, it is preferable to neutralize with a basic compound after emulsion polymerization. Neutralization also improves the mechanical stability of the emulsion. As the basic compound used for aqueous conversion,
Sodium hydroxide, potassium hydroxide, ammonia, methylamine, ethylamine, propylamine, butylamine, hexylamine, octylamine, ethanolamine, propanolamine, diethanolamine, N-methyldiethanolamine, dimethylamine, diethylamine, triethylamine, N, N- Dimethylethanolamine, 2-dimethylamino-2-methyl-1-propanol, 2-amino-2-methyl-1-propanol,
Examples include morpholine and the like, which are used alone or in combination. In neutralization, 0.6 to 1 equivalent of carboxyl group is used.
1.2 equivalents are preferred.

The glass transition point of the aqueous emulsion comprising the α, β ethylenically unsaturated monomer thus obtained is also important for exhibiting excellent anti-slip properties. As a result of the present invention, it becomes possible to use a resin having a higher glass transition point than a binder resin used in a conventional anti-slip agent by incorporating hollow fine particles. The preferred glass transition point is 40 ° C. or less. At a temperature of 40 ° C. or higher, unnecessary adhesion and adhesive residue to the floor surface or the like with which the anti-slip agent comes into contact will not be a problem, but the anti-slip property will start to deteriorate. The glass transition point is determined by a known calculation formula. In the present invention, the reciprocal of the glass transition point of each unsaturated monomer homopolymer was weighted by its weight fraction.

The inorganic hollow fine particles used in the present invention include:
Commercially available products include FILITE (manufactured by Nippon FILITE Co., Ltd.). Examples of the hollow fine particles coated with inorganic powder include Matsumoto Microsphere-MFL Series (manufactured by Matsumoto Yushi Seiyaku Co., Ltd.).

As a method for producing hollow fine particles coated with an inorganic powder, a method in which hollow fine particles are first produced and then an inorganic coating is applied.
A method for producing hollow fine particles is described in, for example, JP-A-56-32
No. 513, a method in which a shell layer is emulsion-polymerized using an alkali-affinity polymer as a core, and then the core component is swelled and hollowed with ammonia or the like.
A method utilizing a W / O / W type multilayer emulsion disclosed in Japanese Patent No. 93901 is known. Also,
As commercial products, VONCOATP is used as organic hollow fine particles.
P-1100 (manufactured by Dainippon Ink and Chemicals, Inc.) and the like can be used.

Since the specific gravity is small when the hollow fine particles are used, the fine particles can be effectively ubiquitously present on the surface. Further, since the particles have inorganic protrusions on the surface thereof, the frictional force with the floor surface or the like in contact with the anti-slip agent is increased, and the anti-slip effect can be exhibited even when the aqueous resin has low tackiness when a load is applied. The particle diameter of the hollow fine particles also becomes a factor of anti-slip property, and particularly preferably 10 to 400 μm. More preferably, it is 20 to 100 μm. If it is 10 μm or less, the uneven distribution on the surface is small and the anti-slip property is not sufficient, and if it is 400 μm or more, the contact area is small and sufficient anti-slip property cannot be exhibited. There is a need to.

A further feature of the present invention is anti-slip properties under high humidity or in the presence of water. When the hollow fine particles having an inorganic powder are used, the anti-slip property is not reduced unlike the conventional anti-slip agent. This is presumably because the presence of inorganic protrusions on the particle surface makes it difficult for the frictional force to decrease even in the presence of water. As the inorganic powder used in the present invention, titanium oxide, calcium carbonate, silica, alumina, zirconium and the like are preferably used. Of these, titanium oxide and calcium carbonate are particularly preferred in terms of anti-slip properties under normal conditions and anti-slip properties in the presence of water.

The amount of the anti-slip agent to be incorporated in the aqueous resin is preferably 0.1 to 30 parts by weight based on 100 parts by weight of the solid content of the aqueous resin. When the amount is less than 0.1 part by weight, a sufficient anti-slip effect is hardly exerted. When the amount is more than 30 parts by weight, the anti-slip effect is saturated, and the function of the aqueous resin as a binder resin is reduced.

In the anti-slip agent of the present invention, various organic solvents, thickeners, defoamers, coloring agents,
Surfactants and the like can be used.

A sheet having an anti-slip layer according to the present invention;
The tape needs to have an anti-slip layer on one or both sides of the sheet or the base material surface of the tape.
When the anti-slip layer is provided only on one side, an adhesive layer is formed on the other side. The adhesive layer can be attached to a rug or the like. Further, sheets and tapes having an anti-slip layer on both sides can be cut and cut into a predetermined size, and laid under a rug or the like, thereby increasing the frictional force between the rug and the floor. In the latter case, since the anti-slip layer is not directly formed on the rug, there is an advantage that some rugs can be used upside down. The production of the sheet and the tape can be performed by a known method. To give an example, a roll coater, a spray coater, and a brush are applied to a sheet substrate, and dried,
Further, a sheet having an intended anti-slip layer is obtained by forming an anti-slip layer on the other surface by the same method, or by bonding an adhesive layer applied to a release material and dried to a substrate.

With respect to the tape, an anti-slip layer is formed on one side of the base material by the above-mentioned method and the like, and is wound and temporarily made into an intermediate raw material. By forming a layer or laminating a release material having an adhesive layer, a tape having an intended anti-slip layer can be obtained. Paper, plastic film, cloth, etc. can be used as the base material of the sheet or tape. The amount of the anti-slip agent applied to the substrate is preferably from 10 to 500 g / m ² .

[0027]

The present invention will be described in detail with reference to the following Examples, but it should not be construed that the present invention is limited thereto. In addition,
In the following Examples, Comparative Examples and Synthesis Examples, "parts" means parts by weight unless otherwise specified.

Synthesis Example 1 4 equipped with a reflux cooling pipe, a gas introduction pipe, a stirrer, and a thermometer
200 ml of distilled water was charged into a 2,000 ml-necked flask, and the temperature was raised to 80 ° C. while purging with nitrogen while stirring. While maintaining the internal temperature at 80 ° C., 4 parts of ammonium persulfate was added as a polymerization initiator, and 204 parts of MMA (methyl methylate) and BA (butyl acrylate) 90 prepared in advance were added.
, A pre-emulsion consisting of 6 parts of AA (acrylic acid), 500 parts of water and 9 parts of SDS (sodium dodecyl sulfonate) was added dropwise over 1 hour. After further reacting for 3 hours, an aqueous emulsion (C) was obtained. Glass transition point 36 ° C.

Synthesis Example 2 4 equipped with a reflux cooling pipe, a gas introduction pipe, a stirrer, and a thermometer
200 ml of distilled water was charged into a 2,000 ml-necked flask, and the temperature was raised to 80 ° C. while purging with nitrogen while stirring. While maintaining the internal temperature at 80 ° C., 4 parts of ammonium persulfate was added as a polymerization initiator to prepare MMA216 prepared in advance.
, 78 parts of AA, 6 parts of AA, 500 parts of water, and 9 parts of SDS were dropped over 1 hour. After further reacting for 3 hours, an aqueous emulsion (D) was obtained. Glass transition point 44 ° C.

The aqueous resin used in the present invention is as follows: Resin A: SBR emulsion (Nicol LX426, manufactured by Zeon Corporation) Resin B: MMA / butadiene emulsion (Croslen 2M36, manufactured by Takeda Pharmaceutical Co., Ltd.) Resin C: synthesis Emulsion C obtained in Example 1 Resin D: Emulsion D obtained in Synthesis Example 2

As inorganic hollow fine particles, fine particles a: Filite 200/7 (manufactured by Nippon Filite Co., Ltd.) As fine particles coated with inorganic powder, fine particles b: Microsphere FL80CA (manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.) Fine particles c: Microsphere-MFL30STI (manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.) Fine particles d: Microsphere-F50 (manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.) were used as heat-expandable fine particles.

Examples 1 to 4 The aqueous resins A to D prepared to a solid content of 30%, inorganic hollow fine particles, and fine particles a coated with inorganic powder a
To c were mixed with resin / fine particles / antifoaming agent = 100/5 / 0.1 / to obtain an anti-slip agent. The anti-slip agent was applied on one side of the vinyl chloride sheet and dried at 60 ° C. Next, the same anti-slip agent was applied to the back surface and dried to obtain a sheet having an anti-slip layer. Examples 5 and 6 The aqueous resins A and C prepared with a solid content of 30%, the inorganic hollow fine particles, and the fine particles a and c obtained by coating the inorganic powder were resin / fine particles / antifoaming agent = 100/5/0. .1 /
To obtain an anti-slip agent. After the anti-slip agent was applied to one side of the polyethylene terephthalate film, the film was passed through an oven at 90 ° C. and wound up. Next, while unwinding the wound film, the film was adhered to a release material having an adhesive layer to obtain a tape having an anti-slip layer.

Comparative Examples 1 to 4 The above-mentioned aqueous resins A to D resin / antifoaming agent = 100 / 0.1 were mixed to obtain an anti-slip agent. Using the anti-slip agent, a vinyl chloride sheet having anti-slip layers on both sides was obtained in the same manner as in Examples 1 to 4. Comparative Example 5 Resin / Microsphere-F50 /
The mixture was mixed at an antifoaming agent = 100/5 / 0.1 to obtain an anti-slip agent. After applying the anti-slip agent to the vinyl chloride sheet,
And dried. The same process was performed on the back surface to obtain a sheet having an anti-slip layer.

The method for evaluating the anti-slip property of a sheet or tape having an anti-slip layer will be described below. The evaluation results are shown in Table 1.

Evaluation items a) Anti-slip property of sheet The anti-slip property was examined from the viewpoint of frictional force. Examples 1-4,
The sheets obtained in Comparative Examples 1 to 5 were cut into 10 cm × 10 cm, placed on a plywood surface, and a 10 cm × 10 cm nonwoven fabric was placed thereon. An additional 1500 g weight was placed. Next, pull one end of the nonwoven fabric with a spring and read the scale.
The friction force (g) was used. The measurement was performed under two kinds of conditions. Normal 25 ° C., Humidity 40% Wet 25 ° C., Spray water on the plywood in contact with the anti-slip layer by spraying, 10 g / m ² b) Anti-slip property of the tape The tape obtained in Examples 5 and 6 was a 10 cm × 10 cm non-woven fabric. It was stuck on the surface and placed so that the anti-slip layer side was in contact with the plywood surface, and a 1500 g weight was placed thereon. Next, one end of the non-woven fabric was pulled with a spring and the scale was read to determine the frictional force (g). The measurement was performed under two kinds of conditions.

Water is sprayed on the plywood in contact with the anti-slip layer by spraying at a temperature of 25 ° C. under normal conditions of 25 ° C. and a humidity of 40%. The adhesiveness to flooring is 10 g / m ² c) Examples 1 to 4 and Comparative Examples 1 to 5 Was sandwiched between plywood and a nonwoven fabric. The nonwoven fabric to which the tapes obtained in Examples 5 and 6 were attached was placed on plywood such that the anti-slip layer was on the lower side. Next, the sample was placed in a thermostat at 60 ° C., and a 1500 g weight was placed thereon and held for 5 hours. The adhesion between the plywood surface and the anti-slip layer was examined according to the following criteria.

◎ easily peeled off from the plywood surface ○ peeled off from the plywood surface with no adhesive residue △ separated from the plywood surface but with a little adhesive residue × considerable adhesive residue even when gradually separated from the plywood surface

[0038]

[Table 1]

The above examples show that sheets and tapes having an anti-slip layer containing inorganic hollow fine particles and hollow fine particles coated with inorganic powder give excellent anti-slip properties to rugs. Also, it shows excellent performance even when the surface is wet with water.

On the other hand, as shown in Comparative Examples 1 to 4, when there is no hollow fine particle, the frictional force is normal, but when the surface is wet with water, the frictional force is significantly reduced. Further, the adhesiveness to the floor material surface may be too strong, and adhesive residue may occur. Even if the hollow fine particles do not have an inorganic substance on the surface, as shown in Comparative Example 5, the anti-slip property in the presence of water is significantly reduced.

[0041]

【The invention's effect】

As described above, sheets and tapes having an anti-slip layer containing the inorganic hollow fine particles of the present invention and the hollow fine particles coated with the inorganic powder impart excellent anti-slip properties to rugs and the like. . A particularly outstanding feature is that it exerts its effect even on a floor surface whose surface is wetted with water, and at the same time, strongly adheres to the floor surface, and does not stain the surface. Since the sheet or tape having the anti-slip layer of the present invention imparts excellent anti-slip properties to rugs and the like, it can be suitably used for rugs used in kitchens, entrances, and bathrooms.

Claims (5)

[Claims] 1. An anti-slip agent comprising an aqueous resin mixed with inorganic hollow fine particles or hollow fine particles coated with inorganic powder, and a dried anti-slip layer coated on one side of the substrate and an adhesive on the other side. Anti-slip sheet or tape having a layer. 2. An anti-slip sheet comprising an aqueous resin and an anti-slip agent comprising a mixture of an inorganic hollow fine particle or a hollow fine particle coated with an inorganic powder, and a dried anti-slip layer on both surfaces of the substrate. tape. 3. The anti-slip sheet or tape according to claim 1, wherein the aqueous resin is an aqueous emulsion obtained by emulsion polymerization of α, β ethylenically unsaturated monomers. 4. The anti-slip sheet or tape according to claim 3, wherein the α, β ethylenically unsaturated monomer has a glass transition point of 40 ° C. or lower. 5. The anti-slipping sheet or tape according to claim 1, wherein 0.1 to 30 parts by weight of hollow fine particles are blended with respect to 100 parts by weight of the solid content of the aqueous resin.