JP2000110077A - Liquid finish composition for textile product - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a liquid finish composition for textile product capable of decreasing wrinkles caused by washing the textile product or the like, preventing discoloration and having restorability even after subjected to freezing. SOLUTION: This composition is obtained by including (A) at least one kind of modified silicone selected from a polyether-modified silicone, an amino- modified silicone, an amido-modified silicone or an amino-polyether-modified silicone, (B) an amine compound having at least one saturated or unsaturated 6-26C hydrocarbon group in a molecule, its neutralized product, its quaternized product or their mixture, (C) a nonionic surfactant obtained by adding 15-150 mole alkylene oxide to a straight or branched chain 8-22C alcohol, amine, alkanol, amide, fatty acid or fatty acid ester, (D) a 2-6C monohydric alcohol and/or polyhydric alcohol and (E) a 2-6C alkanolamine and/or its salt.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a liquid finish used for textiles such as clothing. In particular, the present invention is suitable for use in textiles of colored patterns such as shirts, pants, blouses and the like in which the finish requires flexibility and natural firmness, and is stored under low-temperature conditions. Such a liquid finish composition for textile products.

[0002]

2. Description of the Related Art Conventionally, various textile finishing agents containing a quaternary ammonium salt as a main component have been used for the purpose of imparting flexibility to a textile product after washing. As the quaternary ammonium salt, a di-long chain type quaternary ammonium salt is generally used. However, the finishing agent for textile products containing a di-long chain type quaternary ammonium salt as a main component, although a good softening effect is obtained,
Depending on the type of textile or clothing, it may lose strength and firmness, which is not desirable. On the other hand, for the purpose of improving various properties of a finishing agent for textile products, attempts have been made to use a silicone compound in combination with a quaternary ammonium salt. For example, Japanese Patent Application Laid-Open No. 1-162878 discloses a conditioning formulation for aqueous base fabrics containing a water-dispersible cationic softener and a nonionic softener comprising a specific siloxane. In addition, Japanese Patent Application Laid-Open No. 2-191
No. 774 discloses a concentrated softening agent for clothing, which comprises a quaternary ammonium salt and a specific silicone derivative. However, at the present time, there has not been obtained a finishing agent for textile products that can impart favorable flexibility to textile products and maintain the firmness and firmness of the textile products. In addition, when finishing a colored textile product with a finishing agent, there has been a problem that the textile product fades. Furthermore, the liquid finish composition for textile products may be stored under low temperature conditions during distribution and process. However, when the finish is frozen at room temperature after use after the finish is frozen under low-temperature conditions, there is a problem that the viscosity increases and pearl-like unevenness occurs.

[0003]

SUMMARY OF THE INVENTION Accordingly, the present invention provides a textile product such as fiber or clothing with favorable flexibility and maintains the fibrous product firmness and stiffness.
A liquid finish composition for textiles that has the effect of reducing wrinkles due to washing, prevents fading when the textile is colored, and has good restorability when stored at low temperatures, especially when frozen. The purpose is to provide things.

[0004]

Means for Solving the Problems The present inventors have conducted intensive studies in order to achieve the above object, and have found that (A) a modified silicone, (B) an amine compound or a neutralized or quaternized product thereof, and (C) The present inventors have found that the above-mentioned objects can be achieved by a specific combination of a) nonionic surfactant, (D) alcohol and (E) alkanolamine or a salt thereof, and have accomplished the present invention. That is, the present invention
(A) one or more modified silicones selected from polyether-modified silicones, amino-modified silicones, amide-modified silicones, and amide-polyether-modified silicones; (B) at least one saturated carbon atom having 6 to 26 carbon atoms in the molecule. Or an amine compound having an unsaturated hydrocarbon group, a neutralized product or a quaternized product thereof, or a mixture thereof; (C) a linear or branched alcohol having 8 to 22 carbon atoms, an amine, an alkanolamide, a fatty acid, or a fatty acid ester Alkylene oxide to a compound selected from
Nonionic surfactant obtained by adding 150 mol of (D) monohydric alcohol and / or polyhydric alcohol having 2 to 6 carbon atoms, and (E) alkanolamine having 2 to 6 carbon atoms and / or a salt thereof. A liquid finish composition for textile products is provided.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION The component (A) used in the present invention is a modified silicone selected from polyether-modified silicone, amino-modified silicone, amide-modified silicone, and amide-polyether-modified silicone. As the component (A), a single type of modified silicone may be used, or a plurality of different types of modified silicone may be used. Among these modified silicones, modified silicones represented by the following general formula (I) from the viewpoint of imparting flexibility and natural firmness to textiles and reducing wrinkles generated during washing and finishing processes. It is particularly preferred to use silicone.

[0006]

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Wherein R may be the same or different and each represents a saturated or unsaturated hydrocarbon group having 1 to 4 carbon atoms, and R ₁ represents a saturated or unsaturated hydrocarbon group having 1 to 4 carbon atoms. R ₂ represents a hydrogen atom or a carbon atom
Represents a saturated or unsaturated hydrocarbon group of 4 to 4, X represents a polyoxyalkylene group, L, M, and N represent an average value, L represents a number of 0 to 5, and M represents 1 to 100. Represents a number, and N represents a number from 10 to 1000. However, the weight ratio of the polyoxyethylene chain portion in the polyoxyalkylene group X is 10% to 50% based on the weight of the whole molecule.
%)

In the general formula (I), the substituents represented by R may be the same or different from each other, and each is a saturated or unsaturated linear or branched hydrocarbon group having 1 to 4 carbon atoms. is there. As the substituent R, a saturated hydrocarbon group such as a methyl group, an ethyl group, a propyl group, and a butyl group is preferable, and a methyl group is particularly preferable. The substituent represented by R ₁ is a saturated or unsaturated linear or branched hydrocarbon group having 1 to 4 carbon atoms. As the substituent R ₁ , a saturated hydrocarbon group such as a methylene group, an ethylene group, a propylene group, and a butylene group is preferable, and a propylene group is particularly preferable. The substituent represented by R ₂ is a hydrogen atom or a group having 1 carbon atom.
To 4 saturated or unsaturated linear or branched hydrocarbon groups. When the substituent R ₂ is a hydrocarbon group, a saturated hydrocarbon group such as a methyl group, an ethyl group, a propyl group, and a butyl group is preferred. It is particularly preferred that the substituent R ₂ is a hydrogen atom.

In the general formula (I), X represents a polyoxyalkylene group. Polyoxyalkylene group X
May be a polyoxyethylene, polyoxypropylene, polyoxybutylene group, or the like, or a group in which oxyethylene units, oxypropylene units, or oxybutylene units are arranged in a block or randomly. Is also good. Further, the weight ratio of the polyoxyethylene chain portion in the polyoxyalkylene group X is
From the viewpoint of imparting favorable flexibility to the fiber product and reducing washing wrinkles, 1 based on the weight of the whole molecule.
0% or more and less than 50%. The weight ratio of the polyoxyethylene chain portion in the polyoxyalkylene group X is preferably 15% to 45%, more preferably 20% to 3%, based on the weight of the whole molecule.
5%. The weight ratio of the polyoxyethylene chain portion based on the weight of the polyoxyalkylene group X is:
Preferably it is 50% to 100%. Further, in the general formula (I), L, M and N each represent the number of each repeating unit, L is 0 to 5, preferably 0 to 1, and M is 1 to 100, preferably 1 to 1. 50 and N is 10 to 1000, preferably 20 to 500. The modified silicone represented by the general formula (I) may have a structure of a block copolymer in which each repeating unit is arranged in a block shape, or may have a structure in which each repeating unit is randomly arranged. May have a random copolymer structure. The modified silicone represented by the general formula (I) is not particularly limited, but is generally obtained by an addition reaction between a silicone oil having a Si-H group and a polyether having a carbon-carbon double bond at a terminal. , Can be manufactured.

The molecular weight of the modified silicone of component (A) used in the present invention is preferably in the range of 3,000 to 200,000, and more preferably in the range of 5,000 to 100,000. The modified silicone of the component (A) is incorporated in the finishing composition of the present invention in an amount of 0.5 to 30% by weight from the viewpoint of obtaining a sufficient finishing effect and making the viscosity of the finishing agent appropriate. Is preferred, and more preferably 1 to 20% by weight.

The component (B) used in the present invention is a neutralized or quaternized amine compound having at least one saturated or unsaturated hydrocarbon group having 6 to 26 carbon atoms in the molecule, or a mixture thereof. It is. The neutralized product or quaternized product of the amine compound as the component (B) has at least one, preferably two, saturated carbon atoms having 6 to 26, preferably 12 to 24, and most preferably 14 to 22 carbon atoms. Alternatively, it has an unsaturated hydrocarbon group such as an alkyl group or an alkenyl group. The hydrocarbon group may have an ester group, reverse ester group, amide group, reverse amide group, or ether group in the chain. In addition, these hydrocarbon groups are typically used in industry, such as fatty acids obtained by hydrogenating or partially hydrogenating unhydrogenated fatty acids derived from beef tallow or unsaturated portions, and palm-derived and oil-derived plants. It can be introduced by using a fatty acid or a fatty acid ester obtained by hydrogenating or partially hydrogenating an unhydrogenated fatty acid, a fatty acid ester or an unsaturated portion.

Examples of the amine compound (B) or a neutralized or quaternized product thereof include, for example, amine compounds represented by the following general formulas (II) to (IV) or neutralized or quaternary compounds thereof. Compounds.

[0013]

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[0014]

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[0015]

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(In the formula, R ₃ is a saturated or unsaturated linear or branched hydrocarbon group having 8 to 22 carbon atoms which does not contain a splitting group such as an ester group, and is an unsaturated hydrocarbon group. In such a case, the cis / trans ratio is preferably 40/60 or more, R ₄ is R ₃ or R ₅ , and R ₅ is an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms or — (CH ₂ —CH (Y) —O) _n —H (wherein Y is hydrogen or CH ₃ , and n is a number of 2 to 10), and R ₆ is an ester group or a reverse ester 6 carbon atoms separated by a group, amide group, reverse amide group or ether group
To 26, a saturated or unsaturated linear or branched hydrocarbon group, and when it is an unsaturated hydrocarbon group, its cis /
The transformer ratio is preferably 40/60 or more, and R ₇
And R ₈ is R ₆ or R ₄ . )

The neutralization of the amine compound is carried out using a usual acid. Specific examples of the acid include inorganic acids such as hydrochloric acid, sulfuric acid, and phosphoric acid, and organic acids such as benzoic acid, citric acid, malic acid, succinic acid, and acrylic acid. The quaternized amine compound may be obtained by further bonding an alkyl group to a tertiary amine having a long-chain alkyl group by a peralkylation method. Dimethyl sulfate or benzyl chloride can be used as the peralkylating agent. In place of these peralkylating agents, lower alkyl halides such as methyl iodide, methyl chloride, ethyl chloride and butyl bromide, diethyl sulfate, epichlorohydrin and the like may be used. The quaternized amine compound may also be obtained by reacting a lower tertiary amine with a long-chain alkyl halide. The long-chain alkyl halide may have an ether bond in the chain. Instead of a long-chain alkyl halide, a chloroalkyl ester such as a chloromethyl ester, a chloroethyl ester or a chloropropyl ester of a fatty acid, or a chloromethylated acid amide may be used. As the component (B) used in the present invention, a neutralized or quaternized product of two or more different amine compounds can be used in combination. In this case, it is desirable to use a compound having one long-chain hydrocarbon group and a compound having two or more long-chain hydrocarbon groups in combination. Furthermore, from the viewpoint of suppressing the initial viscosity of the finishing agent to a low level and preventing the occurrence of thickening and pearl-like precipitates during freeze recovery, a compound having one long-chain hydrocarbon group and a compound having two or more long-chain hydrocarbon groups are used. , Preferably 3: 9
7 to 50:50, more preferably 5:95 to 40: 6
It is desirable to use them together in a weight ratio of 0.

The neutralized or quaternized amine compound of the component (B) is used as the finishing composition according to the present invention from the viewpoint of obtaining a sufficient finishing effect and of making the viscosity of the finishing agent appropriate. It is preferable to mix 3 to 50% by weight, and more preferably 5 to 30% by weight.

The weight ratio of component (A): component (B) in the finish composition for textile products of the present invention is from 5:95 to 50: 5.
It is preferably within the range of 0:10:90 to 40: 6.
More preferably, it is within the range of 0.

The component (C) used in the present invention is obtained by adding an alkylene oxide to a compound selected from alcohols, amines, alkanolamides, fatty acids and fatty acid esters having a straight or branched chain having 8 to 22 carbon atoms, preferably 10 to 20 carbon atoms.
It is a nonionic surfactant obtained by adding 5 to 150 mol. As the alkylene oxide to be added to these compounds, one or more of ethylene oxide, propylene oxide, butylene oxide and the like can be used. The average number of moles of the alkylene oxide added is 1 from the viewpoint of preventing the finish from increasing in viscosity or gelling during storage.
It is 5-150 mol, preferably 30-80 mol. Examples of the nonionic surfactant that can be used as the component (C) include an ethylene oxide adduct of stearyl alcohol, an ethylene oxide adduct of tallowamine, an ethylene oxide adduct of stearyl monoethanolamide,
Examples include ethylene oxide adducts of octylphenol, ethylene oxide adducts of tallow fatty acid, ethylene oxide adducts of sorbitan tallow fatty acid, and ethylene oxide adducts of isotridecyl alcohol (obtained from trimers of butene or tetramers of propylene). Can be The nonionic surfactant of the component (C) is contained in the finishing composition of the present invention in an amount of 0.1 to 2 from the viewpoint of effectively preventing the viscosity increase and gelation of the finishing agent particularly during storage at a high temperature.
It is preferable to mix -5% by weight, more preferably 0.3-3% by weight.

The component (D) used in the present invention has 2 to 2 carbon atoms.
6, monohydric alcohol and / or polyhydric alcohol. Examples of the monohydric or polyhydric alcohol that can be used as the component (D) include ethanol, isopropanol, butanol, ethylene glycol, propylene glycol, glycerin, and hexylene glycol. From the viewpoint of effectively lowering the freezing temperature of the liquid finish, the monohydric or polyhydric alcohol of the component (D) is preferably incorporated in the finish composition of the present invention in an amount of 1 to 20% by weight, More preferably, the content is 2 to 10% by weight.

The component (E) used in the present invention has 2 to 2 carbon atoms.
6, alkanolamines and / or salts thereof. Examples of the alkanolamine or a salt thereof usable as the component (E) include monoethanolamine, diethanolamine, triethanolamine, methyldiethanolamine, dimethylethanolamine, diisopropanolamine, methyldiisopropanolamine, butanolamine, and these organic acids. Salts, inorganic acid salts and the like. The alkanolamine or a salt thereof of the component (E) is used in the finishing composition of the present invention from the viewpoint of suppressing the viscosity of the finishing agent to a low level and effectively improving the resilience of the finishing agent when frozen. It is preferable to add 0.05 to 5% by weight, more preferably 0.1 to 3% by weight.

In the finish composition of the present invention, additives and the like used in ordinary household finishes can be used as long as the effects of the present invention are not impaired. Specific examples of such additives include partial esterified products of hexanoic acid and glycerin or pentaurethritol, water-soluble salts such as sodium chloride, ammonium chloride, calcium chloride, magnesium chloride, and potassium chloride, solvents, and urea. Germicides, antioxidants, dyes, pigments, hydrocarbons, cellulose derivatives, ultraviolet absorbers, fluorescent brighteners, fragrances and the like.

The finishing composition for textiles of the present invention is prepared by dissolving or dispersing the components (A) to (E) and, if necessary, any components in water or an aqueous solvent.
Can be prepared. In addition, from the viewpoint of the usability of the finish, the finish composition for textile products of the present invention is 10 cP or more.
It is desirable that the viscosity be adjusted to have a viscosity of about 400 cP. Furthermore, the finish composition for textile products of the present invention,
For the total amount of water used when actually finishing textile products,
It is preferable to use the component (B) in an amount such that the concentration of the component is 20 ppm to 300 ppm, and 45 ppm to 200 p
More preferably, it is used in such an amount as to give pm.

[0025]

According to the present invention, (A) a modified silicone, (B) a neutralized or quaternized amine compound,
A specific combination of (C) a nonionic surfactant, (D) an alcohol and (E) an alkanolamine or a salt thereof imparts desirable flexibility to the textile product, while maintaining firmness and firmness and reducing wrinkles due to washing. In addition, it is possible to obtain an effect of improving the restorability of the finish during low-temperature storage, particularly during freezing.

[0026]

EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the present invention is limited thereto. [Modified Silicone] As modified silicones, modified silicones A-1 and A-2 of the present invention, which are the modified silicones represented by the general formula (I) and have the structures shown in Table 1 below, were prepared.

[0027]

Table 1 Chemical structure Weight ratio of POE chain in RR ₁ R ₂ LM N group X to the whole molecule (%) ^{* 1} A-1 CH ₃ C ₃ H ₆ H 0 3 75 20 (POE / POP = 100/0) A-2 CH ₃ C ₃ H ₆ H 0 10 115 32 (POE / POP = 50/50) * 1: () indicates the molar ratio of the polyalkylene group. POE: polyoxyethylene group, POP: polyoxypropylene group

[Neutralized or quaternized amine compound]
As a neutralized or quaternized amine compound, the following Table 2
The neutralized or quaternized products B-1 to B-10 of the amine compound of the present invention having the structure shown in the following were prepared.

[0029]

Table 2 Chemical structure B-1 The amine compound represented by the general formula (II) is quaternized with methyl chloride (provided that R ₃ and R ₄ are hydrocarbon groups having 18 carbon atoms). There, R ₅ is a methyl group) B-2 general formula (II) represented by amine compounds, those quaternized with methyl chloride (provided that, R ₃ is a hydrocarbon of a linear carbon atoms 18 B-3 , wherein R ₄ and R ₅ are methyl groups. B-3 A quaternized amine compound represented by the general formula (III) with methyl chloride (where R ₆ and R ₇ are all an acyl-oxyethyl group of 20 carbon atoms, the R ₈ is a methyl group) represented by amine compounds B-4 formula (III), those quaternized with dimethyl sulfate (wherein, R ₆ is the total an acyl oxyethyl group of 20 carbon atoms, R ₇ is C ₂ H ₄ OH group, R ₈ is a methyl group) B-5 general Of the amine compound represented by (II), hydrochloride salt (wherein, R ₃ and R ₄ is a hydrocarbon group having a carbon number of 18, R ₅ is a methyl group) B-6 formula (III) Hydrochloride of the amine compound represented (where R ₆ and R ₇ are an acyloxyethyl group having 20 carbon atoms , and R ₈ is a methyl group)

The long-chain hydrocarbon groups described in B-1, B-2, and B-5 are a saturated fatty acid having 18 carbon atoms and a fatty acid having 1 carbon atom.
Synthesized from a mixture of an unsaturated fatty acid having one unsaturated group of 8 and finally a ratio of saturated hydrocarbon group / unsaturated hydrocarbon group is 80/20 by weight, and
The cis / trans ratio of the stereoisomer of the unsaturated hydrocarbon group is 4
It was 5/55. The acyloxyethyl groups (B-3, B-4 and B-6) described above are obtained by mixing a saturated fatty acid having 18 carbon atoms with an unsaturated fatty acid having one unsaturated group having 18 carbon atoms. As a raw material, finally, the ratio of saturated acyl / unsaturated acyl was 60/40 by weight, and the cis / trans ratio of the stereoisomer of unsaturated acyl was 75/25.

[Nonionic Surfactants] As nonionic surfactants, the nonionic surfactants C-1 to C-3 of the present invention shown in Table 3 below were prepared.

[0032]

Table 3 C-1 Isotridecyl alcohol ethylene oxytoadduct (average 40 mol addition) ^{* 2} C-2 Isotridecyl alcohol ethylene oxyto adduct (average 60 mol addition) ^{* 3} C-3 Tallow alkylamine ethylene oxyto adduct things (average 60 moles added) * 2: using Isotorite Bu sill alcohols derived from butene trimer. * 3: Isotridecyl alcohol derived from propylene tetramer was used.

[Monohydric or polyhydric alcohol] As the monohydric or polyhydric alcohol, those shown in the following Table 4 were prepared.

[0034]

Table 4 D-1 Ethanol (Industrial synthetic grade Brucine modified ethanol) D-2 Ethylene glycol

[Alkanolamine salts] As alkanolamine salts, those shown in Table 6 below were prepared.

[0036]

Table 5 E-1 Monoethanolamine hydrochloride E-2 Diethanolamine hydrochloride E-2 Triethanolamine hydrochloride

[Preparation of Finishing Composition] Modified silicone (A), neutralized or quaternized amine compound (B), nonionic surfactant (C), monovalent, having the composition shown in Table 6 below. Or, in a polyhydric alcohol (D) and an alkanolamine salt (E), as optional components, 0.3% by weight of calcium chloride, 0.6% by weight of a fragrance, 6 ppm of a dye (Acid Red 138), and 6 ppm of a dye (Acid Yellow 14)
1) 25 ppm, an appropriate amount of hydrochloric acid (for adjusting the pH of the composition to 3), 0.07% by weight of benzoic acid as a preservative, and 0.01% by weight of an isothiazolone solution (Caisson CG manufactured by Rohm and Haas Co.) , And emulsified and dispersed in a balanced amount of water to prepare a finish composition.

[0038]

Table 6 Table 6 A B C D E (wt%) (wt%) (wt%) (wt%) (wt%) Comparative Example 1 A-1 2.0 B-1 8.0 C-1 1.0 B-5 0.1 Example 1 A-1 2.0 B-1 7.5 C-1 1.0 D-1 2.0 E-2 0.3 B-2 0.5 D-2 5.0 B-5 0.1 2 A-2 2.0 B-1 7.5 C-2 1.0 D- 1 5.0 E-1 0.1 B-2 0.5 D-2 2.0 B-5 0.1 3 A-1 2.0 B-1 7.5 C-3 1.0 D-2 8.0 E-2 0.2 B-2 0.5 B-5 0.1 4 A- 1 2.0 B-3 4.5 C-1 1.0 D-1 2.0 E-1 0.2 B-4 3.0 D-2 5.0 B-6 0.5 5 A-2 2.0 B-3 4.5 C-2 1.0 D-1 2.0 E-2 0.2 B-4 3.0 D-2 5.0 B-6 0.5 6 A-1 2.0 B-3 10.0 C-3 1.0 D-1 2.0 E-3 0.3 B-4 2.0 D-2 5.0 B-6 1.0

[Evaluation of Finishing Composition] (1) Finishing Effect A commercially available dungaree shirt (100% cotton) was washed with a commercially available detergent “Super Top” (manufactured by Lion Corporation) using an electric washing machine. . Next, at the third rinse, 20 g of the finish composition of Examples 1 to 6 was added to 30 liters of water to finish the clothing. Thereafter, the garment was hung on a hanger, air-dried under the conditions of 20 ° C. and 40% RH, and the softness of the garment, the elasticity, and the degree of wrinkles were evaluated. The results were good for all finish compositions. (2) Evaluation of Freezing Restorability After the finish compositions prepared in Comparative Example 1 and Examples 1 to 7 were frozen at −15 ° C. for 1 day, returned to 25 ° C.
The viscosity was measured with an L-type viscometer, and the appearance was observed. In addition, the viscosity of all finish compositions immediately after preparation is 30 to 10
It was 0 cP. The results are shown in Table 7 below.

[0040]

Table 7 freezing post-restore viscosity (cP) freezing restore Appearance Comparative Example 1 2,500 pearl shape change Example 1 150 Change No 2 250 change No 3 100 4 300 Change No 5 250 Change No change after None 6 150 No change

When the compositions according to the present invention of Examples 1 to 6 were used, it was also observed that the fading of the colored and patterned clothing due to the chlorine contained in the tap water during the finishing treatment was suppressed.

Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI Theme coat II (Reference) D06M 13/46 D06M 13/46 15/53 15/53 (72) Inventor Yoshikazu Fukumoto 1-chome, Sumida-ku, Tokyo 3-7 Inside Lion Corporation (72) Inventor Takehiko Miyahara 1-3-7 Honjo, Sumida-ku, Tokyo F-Term Inside Lion Corporation (Reference) 4L033 AB01 AC02 AC15 BA11 BA12 BA14 BA45 BA46 BA62 BA71 BA85 CA48 CA59

Claims (1)

[Claims] 1. A polyether modified silicone, amino modified silicone, amide modified silicone, amide
One or more modified silicones selected from polyether-modified silicones, (B) an amine compound having at least one saturated or unsaturated hydrocarbon group having 6 to 26 carbon atoms in the molecule, or a neutralized product thereof; (C) linear or branched C8-C22 alcohols, amines, alkanolamides, fatty acids, fatty acid esters and alkylene oxides of 15-
Nonionic surfactant obtained by adding 150 moles (D) Monohydric alcohol and / or polyhydric alcohol having 2 to 6 carbon atoms, and (E) alkanolamine having 2 to 6 carbon atoms and / or a salt thereof A liquid finish composition for textiles, characterized by the following.