JP3021748B2 - Liquid soft finish - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a soft finish, and more particularly to a liquid soft finish for domestic use which can impart excellent flexibility and elasticity (fluffiness) to various fibers.

[0002]

2. Description of the Related Art
Most of the products marketed as household softeners are mostly 1
The composition is mainly composed of a quaternary ammonium salt having 1 to 2 long-chain alkyl groups in the molecule. The reason for this is that the quaternary ammonium salt has a good softening effect on various fibers in a small amount.

[0003] The above quaternary ammonium salts have a remarkable softening effect on cotton, but acrylic,
It is hard to say that the effect is sufficient for synthetic fibers such as polyester-based and polyamide-based fibers. If the treatment is performed at a higher concentration, the elasticity of the garment may be reduced and the texture may be impaired.

[0004] In the case of long-term storage, the viscosity may increase, the composition may become a gel, or may be separated, especially at low temperatures.

For this reason, various polyoxyethylene-based nonionic activators, electrolytes, and solvents other than the soft component are required, and many of them are blended for stabilization, but the effect is still insufficient.

[0006] The above-mentioned softening agents based on quaternary ammonium salts are usually marketed as 4-20% dispersions,
It is used.

However, since the quaternary ammonium salt has a strong hydrophobicity, when it is poured into rinse water, if the stirring power is weak, the quaternary ammonium salt has poor dispersibility in water, and may cause unevenness in clothing. Commercially available softeners incorporate various additives in addition to the above quaternary ammonium salts to improve dispersibility in water, but their effects are still insufficient.

[0008] In addition, conventionally, liquid softening agents containing various amines as softening bases are known. For example, JP-A-52-59
JP-A-7965 discloses a composition for imparting flexibility to a fiber containing a long-chain alkylamine such as methyldi (hardened tallowalkyl) amine. JP-A-58-60070 discloses an acylated alkanolamine, Japanese Patent Application Laid-Open No. Sho 61-167083 discloses a fiber material finishing agent which imparts smoothness and a comfortable hand to fibers containing a quaternary ammonium salt and a fatty acid ester. A good dispersing softener containing a polyamine polyglycol ether is disclosed in JP-A-61-275474. A stable aqueous dispersion for treating textiles containing a di (higher alkyl) cyclic amine and Bronsted acid is disclosed in JP-A-61-275474. , JP
JP-A 64-85368 discloses a softening composition comprising a dilong-chain alkylamine-anionic surfactant ion-pair complex, a non-silicone wax and a liquid carrier, and JP-A-2-6662 discloses a hydroxy lower alkyl group. A fabric conditioning composition containing an amine such as a condensate of an alkylenediamine and a higher fatty acid and an amphoteric fabric conditioning agent is disclosed in JP-A-2-14076. And fabric conditioning compositions that impart antistatic properties. Further, Japanese Patent Application Laid-Open No. 52-5394 describes a fabric conditioning composition containing an antistatic agent containing a mono- or dilong-chain alkylalkylenediamine and a quaternary ammonium softener.

Recently, there has been a growing worldwide concern about the impact on the environment, and a base material having excellent biodegradability and the like has also been desired for a soft finish.

[0010] However, the above-mentioned softeners containing amines are still not sufficiently effective in this regard.

[0011]

Means for Solving the Problems The inventors of the present invention have conducted intensive studies to solve the above-mentioned drawbacks, and have reached the present invention.

That is, the present invention provides the following (a) component and (b)
An object of the present invention is to provide a liquid softening finish characterized by containing a component as an essential component. (a) having 1 to 2 ester groups in the molecule and having 11 to 11 carbon atoms;
Neutralized inorganic or organic acids of amines containing two or more 23 linear or branched saturated or unsaturated hydrocarbon groups (b) alkyls represented by the following general formulas (I) to (III) One or more amine polyether compounds in an amount of 5 to 100% by weight based on component (a)

[0013]

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Representative examples of the component (a) used in the present invention include alkanolamines such as triethanolamine, tripropanolamine, N-methyldiethanolamine, N-methylpropanolamine and N-long-chain alkyldiethanolamine; Ester amines obtained by reaction with fatty acids or fatty acid methyl esters of several 12 to 24, inorganic acids such as hydrochloric acid and sulfuric acid, acetic acid, glycolic acid, lactic acid, citric acid, maleic acid, fumaric acid, toluenesulfonic acid and the like Compounds obtained by neutralization with an organic acid are exemplified. Fatty acids used in this reaction are generally derived from natural fats and oils such as coconut oil, palm oil, beef tallow, rapeseed oil and fish oil, but may be chemically synthesized fatty acids.

As the amine compound which is a precursor of the component (a), a compound having one or two ester groups is preferable.
Particularly preferred are the compounds represented by the following formulas (IV) to (VII). Two or more compounds may be used in combination.

[0016]

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Wherein R ₁ and R ₂ are linear or branched saturated or unsaturated hydrocarbon groups having 11 to 23 carbon atoms, and R is an alkyl group having 1 to 3 carbon atoms, hydroxyethyl group or hydroxypropyl group. , M represents 2 or 3. ]

[0018]

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Wherein R ₁ and R ₂ are a straight-chain or branched saturated or unsaturated hydrocarbon group having 11 to 23 carbon atoms, and R is an alkyl group having 1 to 3 carbon atoms, hydroxyethyl group, hydroxypropyl group. , M, n represents 2 or 3. ]

[0020]

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[In the formula, R ₄ and R _{5 each} represent a linear or branched saturated or unsaturated hydrocarbon group having 11 to 23 carbon atoms or a β-hydroxyalkyl group. ]

[0022]

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Wherein R ₁ and R ₂ are linear or branched saturated or unsaturated hydrocarbon groups having 11 to 23 carbon atoms, and R is an alkyl group having 1 to 3 carbon atoms, hydroxyethyl group, hydroxypropyl group. , M represents 2 or 3. Among the above, amine compounds in which R ₁ and R ₂ are alkyl groups or alkenyl groups having 15 or more carbon atoms are preferable.

In the present invention, component (a) contains 1
To 30% by weight, preferably 4 to 30% by weight, particularly preferably
It is desirable to add 10 to 25% by weight.

Since the component (a) used in the present invention has an ester group in the molecule, it is excellent in biodegradability and is a base which does not have any problem even in the natural environment. One.

The alkylamine polypropylene glycol polyethylene glycol ether compound as the component (b) of the liquid softener of the present invention can be obtained by subjecting the corresponding amine to propylene oxide or ethylene oxide addition reaction. In this case, either order may be used first, but the compound obtained by the addition reaction of propylene oxide first is preferred from the viewpoint of ease of synthesis. Component (b) is 5 to 100% by weight, preferably 6% by weight, based on component (a).
It is in the range of from 70 to 70% by weight, particularly preferably from 20 to 35% by weight (economically preferred is 20 to 35% by weight).

The liquid softening agent of the present invention can be obtained, for example, by slowly adding a melt or a concentrated solution of an amine compound to an aqueous solution containing a neutralizing agent under stirring or shear mixing. However, it is also possible to obtain a neutralized product in advance or to obtain a neutralized product by post-addition.

The soft finish of the present invention may further comprise a silicone compound such as dimethylpolysiloxane, dimethylpolysiloxane partially modified with an amino group or a polyoxyalkylene group, particularly preferably partially modified with a polyoxyalkylene group. By blending the dimethylpolysiloxane thus obtained, it is possible to improve the feel of soft-treated clothing without impairing water absorption. These silicone compounds
It is preferable to add 0.3 to 5% by weight based on the component (a).

The softening agent of the present invention has almost the same softening effect as that of hardened tallow alkyldimethylammonium chloride which has been widely used in the past, but surprisingly, elastic softness can be obtained. Do you get it.

When the composition of the present invention is used as an aqueous liquid softening agent, an inorganic electrolyte such as sodium chloride, calcium chloride, magnesium chloride or the like is used in an amount of 0.05 to 0.4 to adjust the viscosity.
It is desirable to add by weight.

Although the liquid softener of the present invention has high stability for long-term storage, it is also preferable to use polyoxyethylene (5 to 50 mol) alkyl or alkenyl (C ₁₂ ) for stabilization under severe storage conditions. ~ C ₂₄ ) A nonionic surfactant such as ether, a solvent such as ethanol, propylene glycol or ethylene glycol, or urea can be blended. Further, known esters, nonionic or cationic compounds, long-chain alcohols, long-chain fatty acids and the like may be used in combination as a soft base.

It is also possible to incorporate a pigment or dye for the appearance of the product, a fluorescent whitening agent for the whiteness of the finish, and a fragrance for improving the taste at the time of use and after the finish. .

[0033]

As described above, the softening agent of the present invention can impart sufficient flexibility and antistatic properties to various fibers, can provide excellent elasticity, and is excellent in biodegradability.

[0034]

Next, the present invention will be described in detail with reference to examples, but the present invention is not limited to these examples.

Examples 1 to 11 and Comparative Examples 1 to 3 Table 3 containing the component (a) shown in Table 1 and the component (b) shown in Table 2
The following evaluations were performed using the soft finish shown in Table 1.

[0036]

[Table 1]

[0037]

[Table 2]

1) Evaluation of storage stability The soft finishes shown in Table 3 were sealed and kept at -10 ° C, room temperature and 50 ° C.
For 20 days, and the appearance and fluidity under sealed conditions were measured. The results are shown in Table 3. All of the liquid softeners for clothing of the present invention were good with little change over time. 2) Evaluation of flexibility and elasticity (1) Treatment method 2 kg of commercially available cotton towel and 1 kg of acrylic jersey are 3.5 °
Repeatedly wash (30 liter washing machine) 5 times with a commercially available detergent attack (manufactured by Kao Corporation, registered trademark) in DH hard water,
After removing the fiber treating agent attached to each fiber, 1.5 g of the composition shown in Table 3 was added as an active ingredient, and the mixture was treated at 25 ° C. for 1 minute with stirring. (2) Evaluation method The cloth treated by the above method was air-dried in a room, and then left in a constant temperature and humidity room at 25 ° C and 65% RH for 24 hours. These fabrics were evaluated for flexibility and elasticity. For evaluation of flexibility and elasticity, a pair of comparison was performed using a cloth treated with 10 cc of a soft finish containing 15% by weight of dihydrogenated tallow alkyldimethylammonium chloride as a control. The evaluation is expressed as follows. +2; softer or more elastic than control +1; slightly softer or slightly more elastic than control 0; same as control -1; control slightly softer or slightly less elastic than control -2; control Is soft or less elastic than control

[0039]

[Table 3]

──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-1-26788 (JP, A) JP-A-58-109681 (JP, A) JP-A-60-239570 (JP, A) (58) Field (Int.Cl. ⁷ , DB name) D06M 13/00-13/535

Claims (3)

(57) [Claims] 1. A liquid softening finish comprising the following components (a) and (b) as essential components. (a) having 1 to 2 ester groups in the molecule and having 11 to 11 carbon atoms;
Neutralized inorganic or organic acids of amines containing two or more 23 linear or branched saturated or unsaturated hydrocarbon groups (b) alkyls represented by the following general formulas (I) to (III) One or more amine polyether compounds are used in an amount of 5 to 100% by weight based on the component (a). [Wherein R ₃ is a linear or branched saturated or unsaturated hydrocarbon group having 8 to 24 carbon atoms, p ₁ + p ₂ + p ₃ + p ₄ is 0 to 60, and q ₁ + q ₂ + q ₃ +
q ₄ represent the number of _{0~60 p 1 + p 2 + p} 3 + p 4 + q 1 + q 2 + q 3 + q 4
≧ 1. ] 2. The component (a) has an ester group in the molecule. A neutralized inorganic or organic acid of an amine having two or more linear and branched saturated or unsaturated hydrocarbon groups having 11 to 23 carbon atoms having 1 to 2 carbon atoms. Liquid soft finish. 3. The liquid softener according to claim 1, wherein the component (a) is one or more neutralized inorganic or organic acids of the compounds represented by the following general formulas (IV) to (VII). Finishing agent. Embedded image [Wherein, R ₁ and R ₂ are linear or branched saturated or unsaturated hydrocarbon groups having 11 to 23 carbon atoms, R is an alkyl group having 1 to 3 carbon atoms,
A hydroxyethyl group, a hydroxypropyl group, and m represent 2 or 3. [Formula 4] [Wherein, R ₁ and R ₂ are linear or branched saturated or unsaturated hydrocarbon groups having 11 to 23 carbon atoms, R is an alkyl group having 1 to 3 carbon atoms,
A hydroxyethyl group, a hydroxypropyl group, m and n represent 2 or 3. [Chemical formula 5] [In the formula, R ₄ and R ₅ represent a straight-chain or branched saturated or unsaturated hydrocarbon group having 11 to 23 carbon atoms. [Formula 6] [Wherein, R ₁ and R ₂ are linear or branched saturated or unsaturated hydrocarbon groups having 11 to 23 carbon atoms, R is an alkyl group having 1 to 3 carbon atoms,
A hydroxyethyl group, a hydroxypropyl group, and m represent 2 or 3. ]