JP4633368B2 - Textile treatment composition - Google Patents

Description

  The present invention relates to a textile product treating agent composition.

  Typical examples of the textile product treating agent used in general households include softeners and pastes. Softeners soften and soften textile products such as clothing, and glues add tension to textile products and give them a feeling close to that of new products. It has been properly used depending on the type of product. However, in recent years, the finish feeling of the softener tends to be favored over the paste, and the demand for the paste tends to decrease year by year. This is thought to be due to the tendency to avoid the crispness, stiffness, etc. of conventional glues. On the other hand, for the diversifying types of clothing, there is a situation where the user's preference cannot be satisfied only by the soft finish feeling of the softening agent. Therefore, there is a strong demand for a finishing agent that finishes a textile product with a smooth texture that feels that cannot be achieved by using only a softener or glue alone, that is, it has tension but is not stiff.

  Another reason why glue is avoided is that it takes time and effort during processing. In the conventional glue, it is necessary to sort the fiber product to be glued and the fiber product not to be treated in any scene during the washing process, which takes time and effort. In addition, all of the common paste bases are film-forming, and when using an automatic loading port of a washing machine, the polymer compound of the paste base adheres and the aesthetics are remarkably impaired. It is customary to avoid use. When the user puts the paste, it is necessary to manually put it in and to estimate the timing of feeding, which takes a lot of time and effort. Therefore, there is a demand for a treatment agent that does not require sorting during processing and that can use an automatic charging port of a washing machine without any particular problem.

  In addition, clothes such as shirts and polo shirts are formed with washing wrinkles through washing / rinsing / dehydration / drying, and especially wrinkles are formed on clothing mainly composed of cellulosic fibers such as cotton that cannot be worn without ironing. The In recent years, shirts and the like that have been subjected to form stabilization processing have become widespread. However, these effects have been reduced with repeated wearing / washing, and ironing has not been eliminated at all. However, since ironing is one of the most labor-intensive tasks, there is an eager desire for a method that can remove wrinkles as easily as possible without ironing.

The present inventors disclose a treatment agent that restores the original shape and texture of clothing containing a water-soluble polymer compound, a silicone compound, and a nonionic surfactant in Patent Document 1, Patent Document 2, and Patent Document 3. is doing. Patent Document 4, Patent Document 5, Patent Document 6, Patent Document 7 and Patent Document 8 disclose a textile treatment agent containing a quaternary ammonium compound and a silicone compound, which are softener components, and a nonionic surfactant. Is disclosed. However, these technologies use a nonionic surfactant as a stabilizer or an anti-gelling agent, and a specific nonionic surfactant imparts appropriate tension and texture to clothing, and There is no effect of suppressing the formation of wrinkles. Furthermore, the water absorption performance is not fully satisfactory.
JP 2000-129577 A JP 2000-129578 A JP 2000-239970 A JP 2000-64179 A JP 2000-110068 A JP 2000-110077 A JP 2001-172878 A JP 2002-371474 A

  The problem of the present invention is that there is no need for sorting in the washing process, it can be applied to an automatic loading port of a washing machine, and it gives moderate tension and texture to textiles such as clothing, and suppresses the formation of wrinkles, An object of the present invention is to provide a textile product treating agent composition capable of imparting water absorption performance to clothing.

  In the present invention, (a) an HLB having 1 to 3 polyoxyalkylene groups having 50 to 200 number average added moles of oxyalkylene groups and 1 to 3 hydrocarbon groups having 14 to 32 carbon atoms, A non-ionic surfactant having a melting point of 30 to 80 ° C., (b) an amino-modified silicone compound and (c) a silicone compound having a polyoxyalkylene chain, and a textile product treating agent composition, and Further, (d) of the three groups bonded to the nitrogen atom, one or two of them may be substituted with a hydrocarbon group having 10 to 20 carbon atoms, and the rest may be substituted with a hydroxy group having 1 to 3 carbon atoms. Provided is a textile product treating agent composition containing at least one selected from a tertiary amine which is a hydrogen group, an acid salt thereof or a quaternized product thereof.

  The textile product treating agent composition of the present invention does not require sorting in the washing process, can be applied to an automatic loading port of a washing machine, and imparts appropriate tension and texture to textile products such as clothing, thereby forming wrinkles. Can be suppressed, and water absorption performance can be imparted to the clothing.

  The component (a) used in the present invention is a polyoxyalkylene group having a number average added mole number of oxyalkylene groups of 50 to 200, preferably 70 to 180, particularly preferably 90 to 160 (as the alkylene group, 2 to 4 alkylene groups are preferred, ethylene groups or propylene groups are more preferred, ethylene groups are particularly preferred) 1 to 3, preferably 1 or 2, particularly preferably 1, and 14 to 32 carbon atoms, Preferably it has 1 to 3, preferably 1 or 2, and particularly preferably 1 hydrocarbon group of 16 to 24, particularly preferably 16 to 18, and an HLB of 16 or more, preferably 17 to 19.8. Particularly preferred is a nonionic surfactant having a temperature of 18 to 19.6 and a melting point of 30 to 80 ° C, preferably 40 to 75 ° C, particularly preferably 50 to 70 ° C.

  In the present invention, HLB is HLB calculated by the Griffin method, and the melting point was measured by the following method.

<Measuring method of melting point>
Place 0.5 g of sample into a glass screw tube (No. 3, 21 mm x 45 mm) with a capacity of 10 mL (5 per sample) and seal tightly under atmospheric pressure. One sample is stored in a constant temperature bath at 30 ° C, 40 ° C, 50 ° C, 60 ° C, 70 ° C, one by one (5 in total) with the stoppers facing upward, and the state is observed 24 hours later To do. If the sample is a completely transparent liquid, the storage temperature is determined to be higher than the melting point, and the melting point range is determined for each sample. Next, prepare a temperature-adjustable water bath, and immerse more than half from the bottom of the container with each sample stored in a constant temperature room at 5 ° C. for 24 hours sealed. The temperature of the water bath is increased at a rate of 1 ° C from 5 ° C to 30 minutes below the lower limit of the expected temperature range. The temperature at which the sample becomes completely transparent is taken as the melting point.

  Usually, pastes that impart tenacity to textile products such as clothing are processed starch and water-soluble cellulose derivatives described in JP-A No. 2000-129777, and water-soluble polymer compounds described in JP-A No. 2000-129578. Is used as a paste base, but when these compounds are used, while imparting excellent tenacity, the fiber tends to be shrunken, such as being stiff. In the present invention, the component (a) is used in place of such a paste base, and it is used in combination with the component (b) described later, thereby imparting appropriate tenacity to the fiber product and obtaining an excellent texture. it can. In general, nonionic surfactants are used as stabilizers for fiber product treating agents or as anti-gelling agents, and it is possible for those skilled in the art to use component (a) as a paste base as in the present invention. It is not easily conceivable.

  Specific examples of the component (a) of the present invention include compounds represented by the general formula (1).

^{R 1a -A - [(R 1b} -O) a -R 1c] b (1)
[Wherein, R ^1a is an alkyl or alkenyl group having 14 to 32 carbon atoms, preferably 16 to 24, particularly preferably 16 to 18 carbon atoms, and R ^1b is an alkylene group having 2 or 3 carbon atoms. R ^1c is a hydrogen atom, an alkyl or alkenyl group having 14 to 32 carbon atoms, preferably 16 to 24, particularly preferably 16 to 18 carbon atoms, or 15 to 33 carbon atoms, preferably 17 to 25 carbon atoms, particularly preferably 17 to 19 carbon atoms. These are groups selected from alkanoyl groups or alkenoyl groups (preferably alkanoyl groups). A is a linking group selected from -O-, -COO-, -CON <, -N <, and when A is -O- or -COO-, b is 1, and A is -CON <or B is 2 when -N <. a is a number average value of 50 to 200, preferably 70 to 180, particularly preferably 90 to 160. Here, the plurality of R ^1b and R ^1c may be the same or different. ]
In the general formula (1), R ^1a is most preferably an alkyl group having 16 to 18 carbon atoms, R ^1b is most preferably an ethylene group, and R ^1c is most preferably a hydrogen atom. A is preferably -O- or -COO-, particularly -O-.

  As the component (a), the compound represented by the general formula (1-2) is most preferable.

R ^1a —O— (C ₂ H ₄ O) _a —H (1-2)
[Wherein, R ^1a and a have the same meaning as described above. ]
In the present invention, the component (a) acts as a paste base, and when the component (a) is used alone, it is possible to suppress wrinkling as compared with a water-soluble polymer compound usually used as a paste base. . However, since the level is not yet satisfactory, in the present invention, an amino-modified silicone compound is used in combination as the component (b). The component (b) has an important role of further suppressing wrinkling, imparting moderate smoothness to the fiber product, and suppressing wrinkle formation.

As the component (b), amino-modified silicone compounds described in JP 2001-49582, JP 2001-192773, JP 2002-371474, JP 8-325952, JP 10-131054, and the like are used. it can. As the component (b), a kinematic viscosity at 25 ° C. (which can be determined by an Ostwald viscometer) is preferably 100 to 20000 mm ² / s, more preferably 200 to 10,000 mm ² / s, and particularly preferably 500 to 5000 mm. ² / s, amino equivalent (molecular weight per nitrogen atom, amino equivalent = molecular weight / number of N atoms. Molecular weight is a value obtained by gel permeation chromatography with polystyrene as the standard, and the number of nitrogen atoms. Can be obtained by elemental analysis), but is preferably an amino-modified silicone compound of 400 to 8000, more preferably 600 to 5000, and particularly preferably 800 to 3000.

  (B) As a suitable specific example of a component, the compound represented by General formula (3) is mentioned.

[Wherein R ^3a represents an alkyl group having 1 to 3 carbon atoms, a hydroxy group, —OR ^3d (where R ^3d is an alkyl group having 1 to 3 carbon atoms) or a hydrogen atom, and R ^3b represents 1 to 3 carbon atoms. An alkyl group, a hydroxy group or a hydrogen atom. B represents a side chain having at least one amino group, and R ^3c represents an alkyl group having 1 to 3 carbon atoms or a hydrogen atom. c represents a number of 10 to 10,000, d represents a number of 1 to 1,000, and represents a number having a weight average molecular weight of 2,000 to 1,000,000. R ^3a , R ^3b , R ^3c and R ^3d may be the same or different, and a plurality of R ^3b may be the same or different. ]
In the general formula (3), R ^3a is preferably a methyl group or a hydroxy group, R ^3b is preferably a methyl group or a hydroxy group, R ^3c is preferably a methyl group or a hydrogen atom, and R ^3d is preferably a methyl group. The weight average molecular weight is preferably 5,000 to 100,000, particularly preferably 8,000 to 50,000. Here, the weight average molecular weight can be determined by gel permeation chromatography using polystyrene as a standard. Examples of the side chain B having an amino group include the following.
-C ₃ H ₆ -NH _{2
-C 3 H 6 -NH-C 2} H 4 -NH 2
_{-C 3 H 6 -NH- [C 2} H 4 -NH] e -C 2 H 4 -NH 2
_{-C 3 H 6 -NH (CH 3} )
_{-C 3 H 6 -NH-C 2} H 4 -NH (CH 3)
_{-C 3 H 6 -NH- [C 2} H 4 -NH] f -C 2 H 4 -NH (CH 3)
_{-C 3 H 6 -N (CH 3} ) 2
_{-C 3 H 6 -N (CH 3} ) -C 2 H 4 -N (CH 3) 2
_{-C 3 H 6 -N (CH 3} ) - [C 2 H 4 -N (CH 3)] g -C 2 H 4 -N (CH 3) 2
_{-C 3 H 6 -NH-cyclo-} C 5 H 11
Here, e, f, and g are numbers 1 to 30, respectively.

The component (b) of the present invention is, for example, the formula (4)
H ₂ N (CH ₂ ) ₂ NH (CH ₂ ) ₃ Si (CH ₃ ) (OCH ₃ ) ₂ (4)
The hydrolyzate obtained by hydrolyzing the organoalkoxysilane represented by the following formula with excess water and dimethylcyclopolysiloxane are heated to 80 to 110 ° C. using a basic catalyst such as sodium hydroxide. The reaction mixture is allowed to equilibrate and neutralize the basic catalyst with an acid when the reaction mixture reaches a desired viscosity (see JP-A-53-98499).

  The component (b) of the present invention may be blended in the form of an oil as it is, but blending it in the form of an aqueous emulsion in which the particles of the component (b) are dispersed in water may result in the composition of the present invention. This is preferable because it can be easily manufactured. In the aqueous emulsion of component (b), it is preferable to use a surfactant as an emulsifier. As the surfactant, alkylbenzene sulfonic acid or a salt thereof, alkyl sulfate ester salt, polyoxyalkylene alkyl ether sulfate, olefin sulfonate, Anionic surfactants such as alkane sulfonate and fatty acid salt, polyoxyalkylene alkyl or alkenyl ether not included in component (a), polyoxyalkylene alkyl phenyl ether, fatty acid alkanolamide or alkylene oxide adduct thereof, sucrose Use of nonionic surfactants such as fatty acid esters and alkyl glucosides, amphoteric surfactants such as amine oxides, sulfobetaines and carbobetaines, and cationic surfactants such as tri-long-chain alkyl quaternary ammonium salts Kill. However, when an anionic surfactant is used, care must be taken not to impair the effect of the component (d) in the present invention, and the blending molar ratio of the anionic surfactant to the component (d) is preferably 1. Less than, particularly preferably less than 0.5.

  The average particle size of the emulsified particles in the aqueous emulsion of component (b) is preferably 0.01 to 10 μm, more preferably 0.01 to 5 μm, and particularly preferably 0.01 to 1 μm from the viewpoint of obtaining a texture. As the emulsifier for the aqueous emulsion of component (b), a nonionic surfactant corresponding to component (a) can be used, but the total amount of component (a) in the composition of the present invention is (a ) Component / (b) component = It is preferable to mix | blend so that it may become mass ratio of 4/1-1/4.

As the component (b) that can be used in the present invention, TSF4703 (viscosity 1000 mm ² / s (25 ° C.), amino equivalent 1600) manufactured by GE Toshiba Silicone Co., Ltd., TSF 4707 (viscosity 10000 mm ² / s (25 ° C.)), Amino equivalent 7000), TSF4708 (viscosity 1000 mm ² / s (25 ° C.), amino equivalent 2800), Nippon Unicar Co., Ltd. SS-3551 (viscosity 1000 mm ² / s (25 ° C.), amino equivalent 1600), SS- 3552 (viscosity 700 mm ² / s (25 ° C), amino equivalent 7000), FZ-3705 (viscosity 250 mm ² / s (25 ° C), amino equivalent 4000), FZ-319 (viscosity 2000 mm ² / s (25 ° C)), Amino equivalent 4000), SF8451C (viscosity 600 mm) manufactured by Toray Dow Corning Silicone Co., Ltd. ² / s (25 ° C.), amino equivalent 1700), SF8452C (viscosity 700 mm ² / s (25 ° C.), amino equivalent 6400), SF8457C (viscosity 1200 mm ² / s (25 ° C.), amino equivalent 1800), SF8417 (viscosity) 1200 mm ² / s (25 ° C.), amino equivalent 1800), BY16-849 (viscosity 1300 mm ² / s (25 ° C.), amino equivalent 600), BY16-850 (viscosity 1100 mm ² / s (25 ° C.), amino equivalent 1100 ), BY16-892 (viscosity 1000 mm ² / s (25 ° C.), amino equivalent 2000), BY16-879B (viscosity 1190 mm ² / s (25 ° C.), amino equivalent 8000), BY16-872 (viscosity 20000 mm ² / s ( 25 ° C.), amino equivalent 1800), KF857, KF85 manufactured by Shin-Etsu Chemical Co., Ltd. , KF859, KF862, KF8001, KF880 , manufactured by Asahi Kasei Wacker Silicone (Ltd.) WR300 (viscosity ^{600mm 2 / s (25 ℃)} , amino eq 3300), WR1100 (viscosity ^{5000mm 2 / s (25 ℃)} , amino equivalent 7000) WR 1600 (viscosity 1000 mm ² / s (25 ° C.), amino equivalent 1700), WT 1650 (viscosity 1000 mm ² / s (25 ° C.), amino equivalent 1700), and the like.

  In addition, as the aqueous emulsion of component (b) that can be used in the present invention, various emulsifiers (homomixers, high-pressure homogenizers, colloid mills, etc.) using the above oily-type emulsifiers such as surfactants. Although it may be used that dispersed in water using an organoalkoxysilane and dimethylcyclopolysiloxane, an emulsion containing a desired amino-modified silicone is prepared by conducting a polymerization reaction in water. You may use as an aqueous emulsion of b) component as it is. Specifically, FZ-4632, FZ-4635, FZ-4640, FZ-4645, FZ-4658 manufactured by Nihon Unicar Co., Ltd., SM8702, SM8704C, SM8709, BY22- manufactured by Toray Dow Corning Silicone Co., Ltd. 812, BY22-816, BY22-819, BY22-823, Polon MF-14, Polon MF-14D, Polon MF-14EC, Polon MF-29, Polon MF-39, Polon MF- manufactured by Shin-Etsu Chemical Co., Ltd. 44, Polon MF-52, and the like.

  The composition of the present invention contains the component (a) and the component (b) at a ratio of (a) component / (b) component (mass ratio) = 4/1 to 1/4. It is possible to give moderate tension and a favorable texture to the product.

  The component (c) used in the present invention is a silicone compound having a polyoxyalkylene chain, and the polyoxyalkylene chain has 2 to 4 carbon atoms, particularly 2 to 3 carbon atoms, and per silicone compound molecule. The ratio of the average added mole number of the oxyalkylene group to the average contained mole number of silicon atoms in the molecule is preferably 5 to 50%, more preferably 5 to 40%, and particularly preferably 10 to 30%. Addition of the oxyalkylene group to the silicone chain can be in any form such as a pendant type or a block type, and the mass ratio of the oxyethylene group in the oxyalkylene group is preferably 50% or more.

  As the component (c), a compound represented by the general formula (2) is particularly preferable.

[Wherein x is a number from 100 to 600, and x, y and z are numbers such that x: y = 100: 1 to 10: 1 and y: z = 1: 10 to 10: 1. R ¹¹ is an alkyl group having 1 to 4 carbon atoms, and a plurality of R ¹¹ may be the same or different. R < ¹² > is a C1-C4 alkyl group, a hydroxyalkyl group, or an alkoxy group, and two R < ¹² > may be the same or different. D is a group represented by the following formula (i) or a mixed group of a group represented by the formula (i) and a group represented by the formula (ii). In the latter case, D is a group represented by the formula (ii) in D The proportion of the group represented is 50 mol% or less.

(In the formula, p is a number of 2 to 6, R ¹³ is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, q is a number of 1 to 6, r is a number of 1 to 20, and s is a number of 0 to 20. R ¹⁴ represents an alkyl group having 1 to 18 carbon atoms, and the oxyethylene group and the oxypropylene group may be added randomly or in blocks.)
E represents the formula (iii)
_{- (CH 2) t -O- (} C 2 H 4 O) u - (C 3 H 6 O) v -R 15 (iii)
(In the formula, R ¹⁵ is an alkyl group having 1 to 20 carbon atoms, t is a number of 2 to 6, u is a number of 1 to 20, v is a number of 0 to 20, and an oxyethylene group and an oxypropylene group are Random addition or block addition may be used.) Or an alkyl group having 1 to 4 carbon atoms. ]
The composition of the present invention contains the component (b) and the component (c) at a ratio of (b) component / (c) component (mass ratio) = 1/2 to 10/1. Appropriate water absorption can be imparted to the product.

  Use of a commonly used softening agent or paste base in the composition of the present invention impairs the tenacity and texture of the fiber, which is the effect of the present invention, and therefore requires caution when blending. Of the three groups bonded to the nitrogen atom, which are known as general softeners, 1 or 2 is a hydrocarbon group having 10 to 20 carbon atoms, and the remainder is a hydroxy group having 1 to 3 carbon atoms. At least one [component (d)] selected from a tertiary amine which is a hydrocarbon group which may be substituted, an acid salt thereof or a quaternized product thereof, is used in a small amount in the present invention. However, when it is used in a large amount, the tenacity that is the characteristic of the present invention is lost, and the characteristic as a softening agent is strengthened. Therefore, the content ratio of the component (a) and the component (d) in the composition of the present invention is preferably (a) / (d) (mass ratio) = 20/1 to 1/1.

  Preferable specific examples of the component (d) of the present invention include a tertiary amine represented by the general formula (5), an acid salt thereof or a quaternized product thereof.

[In the formula, R ^4a is a hydrocarbon group having 10 to 20 carbon atoms, R ^4b is a hydrocarbon group that may be substituted with a hydrocarbon group having 10 to 20 carbon atoms or a hydroxy group having 1 to 3 carbon atoms, R ^4c represents a hydrocarbon group which may be substituted with a hydroxy group having 1 to 3 carbon atoms. ]
In the general formula (5), R ^4a is preferably an alkyl group and / or alkenyl group having 10 to 20 carbon atoms, particularly an alkyl group having 12 to 18 carbon atoms, and R ^4b is an alkyl group having 10 to 20 carbon atoms and An alkenyl group, particularly an alkyl group having 12 to 18 carbon atoms, or an alkyl group having 1 to 3 carbon atoms, particularly a methyl group is preferred. R ^4c is preferably an alkyl group having 1 to 3 carbon atoms, particularly a methyl group. Examples of the tertiary amine acid salt include inorganic acids such as hydrochloric acid, nitric acid, phosphoric acid, and sulfuric acid, and salts of organic acids such as acetic acid, lactic acid, glycolic acid, citric acid, succinic acid, and maleic acid. Examples of the quaternized product of the tertiary amine include those quaternized with an alkyl halide having 1 to 4 carbon atoms such as methyl chloride or a dialkyl sulfate having 2 to 6 carbon atoms.

  Many common paste bases are polymer compounds that are provided in the form of an aqueous solution or dispersion and are excellent in film-forming properties when dried at room temperature. This film-forming property at room temperature drying is the main cause of the stickiness of the glue, and is a characteristic to be avoided in the composition of the present invention. That is, among the polymer compounds not corresponding to the components (a) to (c) [hereinafter referred to as the component (e)], the polymer compounds excellent in the film-forming property when dried at room temperature (25 ° C.) [hereinafter referred to as (e1 ) Component] may be used in a small amount in the composition of the present invention for the purpose of improving storage stability and controlling rheology, but it is necessary to keep the content low. Therefore, the content ratio of [(a) to (c) total content] and (e1) component in the composition of the present invention is preferably [(a) + (b) + (c)] / (E1) (mass ratio) = 100/0 to 80/20, more preferably 100/0 to 90/10, and particularly preferably 100/0 to 95/5. On the other hand, among the component (e), a polymer compound that hardly forms a film upon drying at room temperature (25 ° C.) [hereinafter referred to as component (e2)] has no problem in the use of a small amount in the composition of the present invention. Although it is possible to use it within a range that does not affect the effect, the content should be less than the component (a). Therefore, the content ratio of [(a) to (c) total content] and (e2) component in the composition of the present invention is preferably [(a) + (b) + (c)] / (E2) (mass ratio) = 100/0 to 80/20, more preferably 95/5 to 80/20, particularly preferably 95/5 to 85/15, and (a) component and (e2) component The content ratio is preferably (a) / (e2) (mass ratio) = 95 / 5-60 / 40, more preferably 95 / 5-70 / 30, and particularly preferably 95 / 5-80 / 20. .

  The polymer compound referred to in the present invention is a compound having a weight average molecular weight of 2000 or more, and the molecular weight is measured by gel permeation chromatography using polyethylene glycol as a standard when the polymer compound is water-soluble. When the polymer compound is water-insoluble, it can be obtained by gel permeation chromatography using polystyrene as a standard.

  The component (e1) is not particularly limited as long as it is a polymer compound that is excellent in film-forming properties at room temperature drying. For example, carboxymethyl cellulose, carboxyethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, ethyl cellulose, sodium carboxymethyl cellulose , Cationized cellulose, polyvinyl alcohol, polyvinyl alcohol maleic acid copolymer, polymethyl methacrylic acid, polyacrylic acid, sodium polyacrylate, vinyl acetate acrylic acid copolymer, vinyl acetate methacrylic acid copolymer, vinyl acetate maleic acid copolymer, sodium polystyrene sulfonate , Polyvinylpyrrolidone, polyacrylamide, water-soluble nylon, polyethylene oxide (however, weight average molecule 100,000 or more), alginic acid, sodium alginate, corn starch, amylose, dextrin, wheat starch, potato starch, tapioca starch, pregelatinized starch, acid-treated starch, oxidized starch, starch acetate, carboxymethyl starch, carboxyethyl starch, hydroxyethyl starch , Hydroxypropyl starch, phosphate starch, cationized starch, amphoteric starch, dialdehyde starch, crosslinked starch, starch organic acid ester, starch inorganic acid ester, pullulan, xanthan gum, deacetylated xanthan gum and the like.

  The component (e2) is not particularly limited as long as it is a polymer compound that hardly forms a film when dried at room temperature. For example, polyethylene glycol, polypropylene glycol or copolymers thereof having a weight average molecular weight of 10,000 or less, polydimethyl liquid at room temperature Silicone or polyalkylene oxide-modified polydimethylsilicone, polyethyleneimine having a weight average molecular weight of 10,000 or less, or polyethylene oxide adduct of polyethyleneimine (number average addition mole number per N atom 1 to 30), liquid polyglycerol at room temperature Or the polyalkylene oxide adduct of polyglycerin, the polyalkylene oxide adduct of ethylenediamine liquid at normal temperature, etc. are mentioned.

  In the present invention, for the purpose of improving storage stability, a surfactant other than the component (a) [hereinafter referred to as the component (f)] can be used in combination. However, its use requires caution in order to damage the texture such as stiffness. Examples of the surfactant that can be used include an anionic surfactant, a nonionic surfactant other than the component (a), and an amphoteric surfactant.

  Examples of the anionic surfactant include an alkylbenzene sulfonate having 10 to 15 carbon atoms, an alkyl sulfate ester salt having 10 to 16 carbon atoms, an alkyl group having 10 to 16 carbon atoms, and an oxy having a number average added mole number of 1 to 6 Examples thereof include polyoxyethylene lauryl sulfate having an ethylene group, an α-olefin sulfonate having 10 to 15 carbon atoms, and an α-sulfo fatty acid methyl ester salt having 10 to 16 carbon atoms. The nonionic surfactant is a polyoxyethylene (and / or polyoxypropylene) alkyl ether type nonionic surfactant having a number average addition mole number of oxyalkylene groups of 4 to 30 and an alkyl group of 8 to 14 carbon atoms. Surfactants, alkyl polyglucosides having an alkyl group having 8 to 16 carbon atoms and an average degree of condensation of 1 to 5 and fatty acid sorbitan esters having 10 to 16 carbon atoms can be exemplified. Examples of the amphoteric surfactant include alkyldimethylamine oxide having 10 to 18 carbon atoms in the alkyl group, alkanoylamidopropyldimethylamine oxide having 10 to 18 carbon atoms in the alkanoyl group, and N- Alkyl-N, N-dimethyl-N- (2-hydroxy-3-sulfopropyl) ammonium betaine, N-alkyl-N, N-dimethyl-N-carboxymethylammonium betaine, alkanoyl group having 10 to 18 carbon atoms Examples include N-alkanoylaminopropyl-N, N-dimethyl-N- (2-hydroxy-3-sulfopropyl) ammonium betaine, N-alkanoylaminopropyl-N, N-dimethyl-N-carboxymethylammonium betaine. it can.

  In the present invention, a polyoxyethylene (and / or polyoxypropylene) alkyl ether type nonionic surfactant having a number average addition mole number of oxyalkylene groups of 4 to 20 and an alkyl group of 8 to 14 carbon atoms, and A surfactant selected from alkyl polyglucosides having an alkyl group with 8 to 16 carbon atoms and an average degree of condensation of 1 to 3 is preferred.

  In the present invention, it is preferable to contain a water-soluble organic solvent [hereinafter referred to as component (g)] for the purpose of obtaining a preferable appearance and improving the storage stability. The content of the component (g) is preferably 0.5 to 40% by mass, more preferably 1 to 30% by mass, particularly preferably 1.5 to 25% by mass, and most preferably 2 in the composition of the present invention. ˜20 mass%. The component (g) is preferably a water-soluble organic solvent having a hydroxyl group and / or an ether group. (G) The following are mentioned as a component, It is preferable to use 1 or more types of these.

  (i) alkanols such as ethanol, propanol, isopropanol, 1-butanol, (ii) polyhydric alcohols such as ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, glycerin, (iii) diethylene glycol, triethylene glycol, Polyglycols such as tetraethylene glycol, polyethylene glycol having an average molecular weight of about 200, polyethylene glycol having an average molecular weight of about 400, dipropylene glycol, tripropylene glycol, polypropylene glycol having an average molecular weight of about 1000, (iv) diethylene glycol monomethyl ether, diethylene glycol dimethyl ether , Triethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol Diethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, tripropylene glycol monomethyl ether, 1-methoxy-2-propanol, 1-ethoxy-2-propanol, 1-methylglyceryl ether, 2-methylglyceryl Ether, 1,3-dimethylglyceryl ether, 1-ethylglyceryl ether, 1,3-diethylglyceryl ether, triethylglyceryl ether, 1-pentylglyceryl ether, 2-pentylglyceryl ether, 1-octylglyceryl ether, 2-ethylhexylglyceryl Ethers, alkyl ethers such as diethylene glycol monobutyl ether, (v) 2-phenoxyethanol, diethylene glycol monopheny Ethers, triethylene glycol monophenyl ether, polyethylene glycol monophenyl ether having an average molecular weight of about 480, aromatic ethers such as 2-benzyloxyethanol, diethylene glycol monobenzyl ether, (vi) 2-aminoethanol, N-methylethanolamine N, N-dimethylethanolamine, N, N-diethylethanolamine, diethanolamine, N-methyldiethanolamine, N-butyldiethanolamine, triethanolamine, triisopropanolamine, isopropanolamine mixture (mixture of mono-, di-, and tri) Alkanolamines.

  The component (g) contains two or more selected from the above (i) alkanols, (ii) polyhydric alcohols, (iv) alkyl ethers, (v) aromatic ethers, and (vi) alkanolamines. It is preferably used in combination, more preferably two or more selected from (i), (ii), (iv) and (v), particularly preferably two selected from (i), (ii) and (iv) The combined use of the above can effectively improve the appearance and storage stability of the composition.

  As the component (g), ethanol, propanol, isopropanol, ethylene glycol, propylene glycol, glycerin, 1-pentyl glyceryl ether, 2-pentyl glyceryl ether, 2-ethylhexyl glyceryl ether, and diethylene glycol monobutyl ether are preferable. , Ethylene glycol, propylene glycol, 2-ethylhexyl glyceryl ether, and diethylene glycol monobutyl ether are preferred.

  In the present invention, for the purpose of obtaining a preferable appearance and improving the storage stability, it is preferable to contain a water-soluble acid (hereinafter referred to as the component (h)), and include hydrochloric acid, acetic acid, citric acid, succinic acid, fumaric acid. Examples of the acid include benzoic acid, lactic acid, butyric acid, phosphoric acid, and sulfuric acid, and these acids can be used alone or in combination. Of these, hydrochloric acid, acetic acid, citric acid and lactic acid are preferred, and hydrochloric acid and citric acid are particularly preferred.

  The fiber product treating agent composition of the present invention can adopt various forms depending on the treatment method. Specifically, a method of directly immersing the target fiber product in the fiber product treating agent composition of the present invention (hereinafter referred to as method 1), a target fiber product in a diluted solution obtained by diluting the fiber product treating agent composition of the present invention in water. And a method of spraying and adhering the textile product treating agent composition of the present invention to a target garment using a sprayer (hereinafter referred to as Method 3). Here, the immersion refers to a state in which the target fiber is completely immersed in the composition of the present invention or an aqueous solution obtained by diluting the composition of the present invention.

  The fiber product treating agent composition of the present invention (hereinafter referred to as composition (I) group) used in Method 1 is preferably 20 to 1000 ppm, more preferably 40 to 800 ppm, particularly preferably 60 to 600 parts (a) component. The component (b) is preferably 10 to 800 ppm, more preferably 20 to 600 ppm, particularly preferably 40 to 400 ppm, and the component (c) is preferably 1 to 400 ppm, more preferably 2 to 200 ppm, and particularly preferably 4 to 400 ppm. 100 ppm is contained, and the mass ratio of component (a) / component (b) is 4/1 to 1/4, preferably 3/1 to 1/2, particularly preferably 2/1 to 1/1, (b) The mass ratio of the component / (c) component is 1/2 to 10/1, preferably 1/1 to 10/1, particularly preferably 2/1 to 8/1. In the composition (I) group, the component (d) and the component (e) may not necessarily be contained, but when the component (d) is contained, the component (a) and the component (d) The content ratio with the component is preferably (a) / (d) (mass ratio) = 20/1 to 2/1, more preferably 15/1 to 3/1, particularly preferably 10/1 to 4/1. It is. Moreover, when it contains (e) component, it is necessary to suppress content low with respect to (e1) component, and [(a)-(c) component in the composition (I) group of this invention] The content ratio between the total content] and the component (e1) is preferably [(a) + (b) + (c)] / (e1) (mass ratio) = 100/0 to 80/20, more preferably 100/0 to 90/10, particularly preferably 100/0 to 95/5. In addition, for the component (e2), there is no problem in the use of a small amount, and the [total content of the components (a) to (c)] and the component (e2) The content ratio is preferably [(a) + (b) + (c)] / (e2) (mass ratio) = 100/0 to 80/20, more preferably 95/5 to 80/20, particularly preferably. The content ratio of the component (a) and the component (e2) is preferably (a) / (e2) (mass ratio) = 95/5 to 60/40, more preferably 95/5 to 70/30, particularly preferably 95/5 to 80/20.

  The total content of the component (d) and / or the component (e) in the composition (I) group is preferably 200 ppm or less, more preferably 150 ppm or less, and particularly preferably 100 ppm or less. [Total content of (a) to (c) component] / [Total content of (d) component and (e) component] in the composition (I) group is a mass ratio, preferably 100/0 to 80/20, more preferably 95/5 to 80/20, particularly preferably 95/5 to 85/15.

  The component (f) and the component (g) in the composition (I) group can be appropriately contained for the purpose of preparing a uniform solution of the components (a) to (c). When used, it affects the texture, so the content of the component (f) should be preferably 200 ppm or less, more preferably 150 ppm or less, particularly preferably 100 ppm or less. Since the component (g) has no particular influence on the effects of the composition (I) group of the present invention, it can be optionally contained. However, since there are flash point and odor problems, the content is preferably 5 It is -600 ppm, More preferably, it is 10-400 ppm, Most preferably, it is 20-300 ppm.

  The composition (I) group used in Method 1 is in the form of an aqueous solution in which the above components are dissolved in water, and each component can be prepared by individually dissolving or dispersing a predetermined amount in water. From the viewpoint of dissolution or dispersion stability, the pH of the solution is preferably 2 to 9, more preferably 3 to 8, particularly preferably 4 to 7. In order to adjust to such pH, ordinary sulfuric acid or hydrochloric acid is used. Acids such as phosphoric acid, acetic acid, citric acid, lactic acid, and succinic acid, and alkali agents such as sodium hydroxide, potassium hydroxide, sodium carbonate, and potassium carbonate can be used.

  In Method 1, the fiber product is immersed directly in the fiber product treating agent composition of the present invention. Specifically, the composition of the present invention is placed in a container such as a talai, a wash basin, or a bat, and the textile product is immersed in the composition. The ratio of the fiber product to the composition is such that the amount of the composition of the present invention per 500 g of the fiber product is preferably 3 to 15 L, more preferably 4 to 13 L, and particularly preferably 5 to 10 L. The temperature of the composition when immersed is preferably 5 to 40 ° C., more preferably 10 to 30 ° C., and the immersion time is preferably 1 to 30 minutes, more preferably 3 to 20 minutes, and particularly preferably 5 ~ 15 minutes. After soaking, it is dehydrated and dried naturally or by a rotary heat dryer. The dried fiber product is less wrinkled to the extent that it does not need to be ironed, but it can be ironed if the finish is more important.

  The fiber product treating agent composition of the present invention (hereinafter referred to as composition (II) group) to be used in Method 2 is preferably 1 to 60% by mass, more preferably 2 to 40% by mass, especially the component (a). Preferably 5 to 30% by mass, component (b) is preferably 0.5 to 30% by mass, more preferably 1 to 20% by mass, particularly preferably 2 to 15% by mass, and component (c) is preferably 0.00. 1 to 30% by mass, more preferably 0.5 to 20% by mass, particularly preferably 1 to 15% by mass, and the mass ratio of (a) component / (b) component is 4/1 to 1/4, It is preferably 3/1 to 1/2, particularly preferably 2/1 to 1/1, and the mass ratio of component (b) / component (c) is 1/2 to 10/1, preferably 1/1 to 10/1, particularly preferably 2/1 to 8/1.

  In the method 2, the method of adding the composition (II) group of the present invention to the rinsing water at the rinsing stage of the washing process is a typical method of use, but compared with the method 1, (a) to ( c) The concentration of the component is lowered. For this reason, in the composition (II) group, it is preferable to contain the component (d) for the purpose of promoting the adsorption of the components (a) to (c) to the fiber product. However, since a large amount of blending impairs the texture, when the component (d) is contained, the content ratio of the component (a) and the component (d) in the composition (II) group is preferably (a) / (d ) (Mass ratio) = 20/1 to 1/1, more preferably 15/1 to 2/1, and particularly preferably 10/1 to 3/1. Further, the content of the component (d) in the composition (II) group is preferably 0.2% by mass or more and less than 5% by mass, more preferably 0.5% by mass or more and less than 3% by mass, particularly preferably. Is 0.8 mass% or more and less than 2 mass%. In addition, the content ratio of [(a) to (c) component total content] and (d) component in the composition (II) group of the present invention is such that the active ingredient is efficiently adsorbed to the fiber product. For the purpose of improving the effects of the invention, preferably, [(a) + (b) + (c)] / (d) (mass ratio) = 40/1 to 2/1, more preferably 30/1 to 4 /. 1, particularly preferably 20/1 to 6/1. In addition, when the component (e) is contained, it is necessary to keep the content low especially for the component (e1), and the content of the component (e1) in the composition (II) group of the present invention is: Preferably it is 2 mass% or less, More preferably, it is 1 mass% or less, Most preferably, it is 0.5 mass% or less. The content ratio of [(a) to (c) component total content] and (e1) component in the composition (II) group of the present invention is preferably [(a) + (b) + (c)]. / (E1) (mass ratio) = 100/0 to 80/20, more preferably 100/0 to 90/10, and particularly preferably 100/0 to 95/5. In addition, for the component (e2), there is no problem in the use of a small amount, and the [total content of the components (a) to (c)] in the composition (II) group of the present invention and the component (e2) The content ratio is preferably [(a) + (b) + (c)] / (e2) (mass ratio) = 100/0 to 80/20, more preferably 95/5 to 80/20, particularly preferably. The content ratio of the component (a) and the component (e2) is preferably (a) / (e2) (mass ratio) = 95/5 to 60/40, more preferably 95/5 to 70/30, particularly preferably 95/5 to 80/20.

  [Total content of components (a) to (c)] / [Total content of components (d) and (e)] in the composition (II) group is a mass ratio, preferably 98/2 to 80 / 20, more preferably 95/5 to 80/20, particularly preferably 90/10 to 80/20.

  The component (f) and the component (g) in the composition (II) group can be appropriately contained for the purpose of improving the appearance of the composition of the present invention or for the purpose of improving storage stability. Since a large amount of component f) affects the texture, the content of component (f) is preferably 20% by mass or less, more preferably 15% by mass or less, and particularly preferably 10% by mass or less. is there. Since the component (g) has no particular influence on the effects of the composition (II) group of the present invention, it can be optionally contained. However, since there are flash point and odor problems, the content is preferably 0. 0.5 to 40% by mass, more preferably 1 to 30% by mass, and particularly preferably 2 to 20% by mass.

  The composition (II) group used in Method 2 is in the form of an aqueous solution in which the above components are dissolved in water, and the water content is preferably 20 to 90% by mass, more preferably 30 to 80% by mass, Especially preferably, it is 40-70 mass%. The pH of the composition and the pH adjusting method are the same as those of the composition (I) group used in Method 1.

  In Method 2, the method of adding the composition of the present invention to rinsing water at the rinsing stage of the washing step is suitable, and the amount of the composition of the present invention is 7 to 40 ml, more preferably 10 to 30 ml, especially 1 kg of clothing. 15 to 25 ml is preferable for exhibiting the effects of the present invention. The temperature of the rinsing water is preferably 5 to 40 ° C., more preferably 10 to 30 ° C., and the treatment time is preferably 1 to 30 minutes, more preferably 3 to 20 minutes, particularly preferably 5 to 15 minutes. is there. After soaking, it is dehydrated and dried by natural drying or a rotary heat dryer. The dried fiber product is less wrinkled to the extent that it does not need to be ironed, but it can be ironed if the finish is more important.

  Method 3 is a method in which a container having a sprayer is filled with the composition of the present invention and sprayed onto the target fiber product, and the problem of sprayer clogging arises. In the product treating agent composition (hereinafter referred to as composition (III) group), it is necessary to lower the concentration of each component as compared with Method 2. Specifically, the component (a) is preferably 0.05 to 3% by mass, more preferably 0.1 to 2.5% by mass, particularly preferably 0.2 to 2% by mass, and the component (b) is preferably 0.05 to 3% by mass, more preferably 0.1 to 2.5% by mass, particularly preferably 0.2 to 2% by mass, and component (c) is preferably 0.01 to 3% by mass, more The content is preferably 0.02 to 2.5% by mass, particularly preferably 0.04 to 2% by mass, and the mass ratio of component (a) / component (b) is 4/1 to 1/4, preferably 3 / 1 to 1/3, particularly preferably 2/1 to 1/2, and the mass ratio of component (b) / component (c) is 1/2 to 10/1, preferably 1/1 to 10/1. Especially preferably, it is 2/1 to 8/1.

  In Method 3, since the composition of the present invention directly adheres to the clothing, there is no problem of insufficient adsorption efficiency to the textiles that are the target of the components (a) to (c) as in Method 2. In the group III), it is not always necessary to include the component (d), and the blending of the component (d) is allowed as long as the texture of the textile product expected by the treatment with the composition of the present invention is not impaired. For this reason, content of (d) component becomes like this. Preferably it is less than 2 mass%, More preferably, it is less than 1 mass%. Moreover, it is necessary to suppress content low with respect to (e1) component among (e) component, and [the total content of (a)-(c) component] in the composition (III) group of this invention] And (e1) component content is preferably [(a) + (b) + (c)] / (e1) (mass ratio) = 100/0 to 80/20, more preferably 100/0. 90/10, particularly preferably 100/0 to 95/5. In addition, for the component (e2), there is no problem in the use of a small amount, and the [total content of components (a) to (c)] in the composition (III) group of the present invention and the component (e2) The content ratio is preferably [(a) + (b) + (c)] / (e2) (mass ratio) = 100/0 to 80/20, more preferably 95/5 to 80/20, particularly preferably. The content ratio of the component (a) and the component (e2) is preferably (a) / (e2) (mass ratio) = 95/5 to 60/40, more preferably 95/5 to 70/30, particularly preferably 95/5 to 80/20.

  The total content of the component (d) and / or the component (e) in the composition (III) group is preferably 5% by mass or less, more preferably 3% by mass or less, and particularly preferably 1% by mass or less. [Total content of (a) to (c) components] / [Total content of (d) and (e) components] in the composition (III) group is a mass ratio, preferably 100/0 to 80/20, more preferably 95/5 to 80/20, particularly preferably 95/5 to 85/15.

  The component (f) and the component (g) in the composition (III) group are for the purpose of making the appearance of the composition of the present invention favorable, for the purpose of improving storage stability, and for the purpose of suppressing clogging of the nozzle of the sprayer. However, the amount of the component (f) is preferably 10% by mass or less, more preferably 5% by mass or less, particularly preferably. It should be kept below 3% by weight. Since the component (g) has no particular influence on the effect of the present invention, it can be optionally contained. However, since there are flash point and odor problems, the content is preferably 0.5 to 20% by mass, More preferably, it is 1-15 mass%, Most preferably, it is 2-10 mass%.

  The composition (III) group used in Method 3 is in the form of an aqueous solution in which the above components are dissolved in water, and the water content is preferably 40 to 99% by mass, more preferably 60 to 98% by mass, Most preferably, it is 80-95 mass%. The pH of the composition and the pH adjusting method are the same as those of the composition (I) group used in Method 1.

  The spray container used in Method 3 is preferably a trigger type spray container, and in particular, it is preferable to use a pressure accumulation type trigger excellent in liquid dripping and spray uniformity as shown in FIG. 1 of Japanese Utility Model Laid-Open No. 4-37554. It is.

Preferred trigger type spray containers of the present invention are those that eject 0.2 g to 2.0 g, preferably 0.25 to 1.5 g, particularly preferably 0.3 to 1.0 g in one stroke. In particular, a container in which the area where the liquid is applied when sprayed from a place 15 cm away in the horizontal direction on a target surface (flat surface) installed perpendicular to the ground is 100 to 800 cm ² , preferably 150 to 600 cm ² is preferable. Further, the total amount of the components (a) to (c) of the present invention is preferably 0.01 to 4 g, more preferably 0.05 to 3 g, and particularly preferably 0.1 to ² g per 100 cm ² of the fiber product. It is preferable to spray the fiber product uniformly.

  Although there are various options for the timing of spraying the textile product in Method 3, the wet textile product after the dehydration in the washing process is suspended on a hanger and the like, and the composition (III) group of the present invention is in a wet state. Sprayed uniformly, dried naturally after washing, or sprayed uniformly on a fiber product dried with a rotary heat dryer and dried again, and put the fiber product into the rotary heat dryer Thereafter, a method of spraying the fiber product and drying by heating can be employed. The dried fiber product after the treatment has less wrinkle formation to the extent that it is not necessary to iron, but it can be ironed if the finish is more important.

  The composition used in Method 1 to Method 3 of the present invention can contain components to be added to a general liquid composition, such as preservatives, fragrances, pigments, dyes, hydrotropes, thickeners, gels. An antioxidant, an antioxidant and the like can be contained.

The compounding components used in the examples are summarized below.
-(A) Component (a) -1: Calcoal 8688 (manufactured by Kao Co., Ltd., containing 87% by mass of alcohol having 18 carbon atoms, 13% by mass of alcohol having 16 carbon atoms, 14 alcohols having 14 carbon atoms) Nonionic surfactant (HLB 18.5, melting point 54.9 ° C.) obtained by adding an average of 75 moles of ethylene oxide per mole of alcohol to a linear primary alcohol having a content of less than 0.1% by mass
(A) -2: Nonionic surfactant (HLB19.1, melting point 61.2 ° C.) obtained by adding an average of 125 moles of ethylene oxide per mole of alcohol to Calcoal 8688 (manufactured by Kao Corporation)
(A) -3: A nonionic surfactant (HLB 19.3, melting point 61.3 ° C.) obtained by adding an average of 150 moles of ethylene oxide per mole of alcohol to Calcoal 8688 (manufactured by Kao Corporation)
(B) Component (b) -1: TSF4707 (GE Toshiba Silicone Amino-modified silicone, viscosity 10000 mm ² / s, amino equivalent 7000)
(B) -2: KF-864 (Amino-modified silicone manufactured by Shin-Etsu Chemical Co., Ltd., viscosity 1700 mm ² / s, amino equivalent 3800)
(B) -3: DC2-8630 (amino modified silicone manufactured by Toray Dow Corning Silicone, viscosity 1500 mm ² / s, amino equivalent 4300)
(C) Component (c) -1: In the formula (2), x is the number of 300, y is 7, z is 4, R ¹¹ and R ¹² are methyl groups, and D is (i)-(CH ₂ ) ₃ —NH—CO—CH ₂ —O— (CH ₂ CH ₂ O) ₅ —C ₁₂ H ₂₅ and (ii) — (CH ₂ ) ₃ —NH ₂ mixed group [(i) / (ii) = 7 / 3 (molar ratio)] and E is — (CH ₂ ) ₃ —O— (CH ₂ CH ₂ O) ₁₀ —CH ₃ Silicone compound (c) -2: FZ2203 (manufactured by Nippon Unicar Co., Ltd.)
(C) -3: KF6012 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(D) Component (d) -1: Dialkyl chloride (C12-14) dimethylammonium (d) -2: Cotamine 86W (Kao Co., Ltd., stearyltrimethylammonium chloride)
-(E1) Component (e1) -1: Poise C-60H (cationized cellulose, molecular weight of about 600,000, manufactured by Kao Corporation)
(E1) -2: PVA-217 (manufactured by Kuraray Co., Ltd., partially saponified polyvinyl alcohol)
(E2) Component (e2) -1: PEG 6000 (polyethylene glycol, average molecular weight 6000)
(E2) -2: PEG 13000 (polyethylene glycol, average molecular weight 13000)
-(F) Component (f) -1: Softanol 30 (manufactured by Nippon Shokubai Co., Ltd., C12-14 secondary alcohol added with an average of 3 moles of ethylene oxide)
(F) -2: a nonionic surfactant obtained by adding an average of 5 moles of ethylene oxide, an average of 2 moles of propylene oxide, and an average of 3 moles of ethylene oxide to a linear primary alcohol having 12 to 14 carbon atoms (G) Component (g) -1: Diethylene glycol monobutyl ether (g) -2: Ethanol (g) -3: Dipropylene glycol (g) -4: Propylene glycol (h) Component (h) -1: Lactic acid (H) -2: hydrochloric acid (HCl effective portion 20%)
Other antibacterial agent: Proxel IB (Avicia Co., Ltd., 20% aqueous solution)
Dye: Purple No. 401 Examples 1-5 and Comparative Examples 1-2
Each component shown in Table 1 was dissolved in 5 L of tap water at the ratio shown in Table 1 to obtain a textile product treating agent composition. About the obtained composition, water absorption was evaluated by the following method. The results are shown in Table 1.

<Water absorption evaluation method>
1) Pretreatment of textile products for evaluation 24 white towels (T.W220 manufactured by Takei Towel Co., Ltd.) were prepared, and a fully automatic washing machine (National NA) using a commercially available weak alkaline detergent (Kao Co., Ltd. Attack). -F55A2) was repeatedly washed 5 times (detergent concentration: 0.0667% by mass, use of tap water (20 ° C.) 48 L, washing 10 minutes—rinsing once with pouring water—dehydration 3 minutes). After the final treatment was completed, washing was further performed twice without detergent (use of tap water (20 ° C.) 48 L, washing 10 minutes—rinsing twice with water—dehydration 3 minutes). After dehydration of the last treatment round was completed, the product was air-dried indoors by hanging and dried to obtain a fiber product for evaluation (pretreated).

  16 sheets of underwear (Gunze Co., Ltd. YG, 100% cotton) were prepared and repeated 10 times with a two-bath washing machine (Toshiba Galaxy VH-360S1) using a commercially available weak alkaline detergent (Kao Inc. Attack). Washing was performed (detergent concentration: 0.0667% by mass, tap water (20 ° C.) 40 L used, washing 10 minutes-dehydration 3 minutes-rinse 8 minutes (rinsing with running water, amount of water 15 L / min.)). After rinsing of the last treatment was completed, the product was dehydrated for 5 minutes, and was air-dried indoors by hanging to make a fiber product for evaluation (pretreated).

2) Model washing machine treatment Weigh the two pre-treated towels and one pre-treated undergarment, weigh the tap water (20 ° C) so that the bath ratio is 20, and then use an electric bucket (National N-BK2). ). A commercially available weak alkaline detergent (Kao Co., Ltd. Attack) was weighed to a detergent concentration of 0.0667% by mass and washed (6 minutes). Next, it was dehydrated for 1 minute in a dewatering tank of a two-tank washing machine (Toshiba Galaxy VH-360S1). Next, after rinsing with an electric bucket (3 minutes), it was again dehydrated with a two-tank washing machine for 1 minute. Thereafter, a treatment agent composition shown in Table 1 was weighed to a concentration of 0.167% by mass and stirred for 3 minutes. After stopping the stirring, dehydrated for 1 minute using a dewatering tank of a two-tank washing machine, air-dried in a constant temperature and humidity room of 25 ° C.-65% RH, and then dried for evaluation (finished) It was.

3) Water absorption evaluation (Bilec method)
The plain weave portion of the towel and underwear that were subjected to the above-described treatment was cut into a 2 cm × 25 cm band, and the water absorption was evaluated according to the Bayrek method. The measurement was performed in a constant temperature and humidity chamber at 25 ° C.-65% RH. The upper end of the belt-like cloth is fixed and hung in the vertical direction, and the time (min.) After dipping the portion of the lower end of 1 cm in water at 25 ° C. and the water absorption height (cm) due to the capillary phenomenon are visually observed and recorded. did.

The water absorption height 1 minute after immersion in water was compared with an untreated cloth (the same treatment operation as in the main treatment described above was performed without using a treatment agent), and was determined according to the following criteria.
×: Water absorption height (after 1 minute) is less than 10% in proportion to untreated product Δ: Water absorption height (after 1 minute) is in proportion to untreated product is 10% or more but less than 20% ▽: Water absorption height ( After 1 minute) is 20% to less than 30% in proportion to the untreated product ○: Water absorption height (after 1 minute) is 30% to less than 50% in proportion to the untreated product ◎: Water absorption height (1 minute) After) is more than 50% of untreated products

Claims (4)

(A) The number average added mole number of oxyalkylene groups is 1 to 3 polyoxyalkylene groups having 50 to 200 and 1 to 3 hydrocarbon groups having 14 to 32 carbon atoms, the HLB is 16 or more, And a nonionic surfactant having a melting point of 30 to 80 ° C., (b) an amino-modified silicone compound , (c) a silicone compound having a polyoxyalkylene chain , and (d) three groups bonded to a nitrogen atom A tertiary amine, an acid salt thereof or a quaternized product thereof, wherein one or two is a hydrocarbon group having 10 to 20 carbon atoms and the remaining hydrocarbon group may be substituted with a hydroxy group having 1 to 3 carbon atoms At least one selected from the group consisting of (a) component and (b) component having a mass ratio of (a) component / (b) component = 1/4 to 4/1, and (b) component and (c ) Component mass ratio is (b) component / (c) component = 1/2 The fiber product treating agent composition, wherein the mass ratio of the component (a) to the component (d) is (a) component / (d) component = 20/1 to 1/1 . Component (a), the general formula (1) is a compound represented by the claims 1 Symbol placement textile treatment composition.
^{R 1a -A - [(R 1b} -O) a -R 1c] b (1)
[Wherein, R ^1a is an alkyl group or alkenyl group having 14 to 32 carbon atoms, R ^1b is an alkylene group having 2 or 3 carbon atoms, R ^1c is a hydrogen atom, an alkyl group or alkenyl group having 14 to 32 carbon atoms, or An alkanoyl or alkenoyl group having 15 to 33 carbon atoms, A is —O—, —COO—, —CON <or —N <, and b is 1 when A is —O— or —COO—, B is 2 when A is -CON <or -N <. a is a value of 50 to 200 in number average. Here, the plurality of R ^1b and R ^1c may be the same or different. ] The fiber product treating agent composition according to claim 1 or 2 , wherein the component (b) is a compound having a kinematic viscosity at 25 ° C of 100 to 20000 mm ² / s and an amino equivalent of 400 to 8000. (C) The textiles processing agent composition in any one of Claims 1-3 whose component is a compound represented by General formula (2).

[Wherein x is a number from 100 to 600, and x, y and z are numbers such that x: y = 100: 1 to 10: 1 and y: z = 1: 10 to 10: 1. R ¹¹ is an alkyl group having 1 to 4 carbon atoms, and a plurality of R ¹¹ may be the same or different. R < ¹² > is a C1-C4 alkyl group, a hydroxyalkyl group, or an alkoxy group, and two R < ¹² > may be the same or different. D is a group represented by the following formula (i) or a mixed group of a group represented by the formula (i) and a group represented by the formula (ii). In the latter case, D is a group represented by the formula (ii) in D The proportion of the group represented is 50 mol% or less.

(In the formula, p is a number of 2 to 6, R ¹³ is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, q is a number of 1 to 6, r is a number of 1 to 20, and s is a number of 0 to 20. R ¹⁴ represents an alkyl group having 1 to 18 carbon atoms, and the oxyethylene group and the oxypropylene group may be added randomly or in blocks.)
E represents the formula (iii)
_{- (CH 2) t -O- (} C 2 H 4 O) u - (C 3 H 6 O) v -R 15 (iii)
(In the formula, R ¹⁵ is an alkyl group having 1 to 20 carbon atoms, t is a number of 2 to 6, u is a number of 1 to 20, v is a number of 0 to 20, and an oxyethylene group and an oxypropylene group are Random addition or block addition may be used.) Or an alkyl group having 1 to 4 carbon atoms. ]