JP4727271B2 - Textile treatment composition - Google Patents

Description

  The present invention relates to a textile product treating agent composition and a textile product wrinkle removal method.

  Typical examples of the textile product treating agent used in general households include softeners and pastes. Softeners soften and soften textile products such as clothing, and glues add tension to textile products and give them a feeling close to that of new products. It has been properly used depending on the type of product. However, in recent years, the finish feeling of the softener tends to be favored over the paste, and the demand for the paste tends to decrease year by year. This is thought to be due to the tendency to avoid the crispness, stiffness, etc. of conventional glues. On the other hand, for the diversifying types of clothing, there is a situation where the user's preference cannot be satisfied only by the soft finish feeling of the softening agent. Therefore, there is a strong demand for a finishing agent that finishes a textile product with a smooth texture that feels that cannot be achieved by using only a softener or glue alone, that is, it has tension but is not stiff.

  Another reason why glue is avoided is that it takes time and effort during processing. In the conventional glue, it is necessary to sort the fiber product to be glued and the fiber product not to be treated in any scene during the washing process, which takes time and effort. In addition, all of the common paste bases are film-forming, and when using an automatic loading port of a washing machine, the polymer compound of the paste base adheres and the aesthetics are remarkably impaired. It is customary to avoid use. When the user puts the paste, it is necessary to manually put it in and to estimate the timing of feeding, which takes a lot of time and effort. Therefore, there is a demand for a treatment agent that does not require sorting during processing and that can use an automatic charging port of a washing machine without any particular problem.

  In addition, clothes such as shirts and polo shirts are formed with washing wrinkles through washing / rinsing / dehydration / drying, and especially wrinkles are formed on clothes mainly composed of cellulosic fibers such as cotton that cannot be worn without ironing. The In recent years, shirts and the like that have been subjected to form stabilization processing have become widespread. However, these effects have been reduced with repeated wearing / washing, and ironing has not been eliminated at all. However, since ironing is one of the most labor-intensive tasks, there is an eager desire for a method that can remove wrinkles as easily as possible without ironing.

The present inventors have disclosed a treatment agent that restores the original shape and texture of clothing containing a water-soluble polymer compound and a silicone compound in Patent Document 1, Patent Document 2 and Patent Document 3. However, these treatment agents tend to form a film, and the automatic charging port of the washing machine becomes dirty. Patent Document 4, Patent Document 5, Patent Document 6, Patent Document 7 and Patent Document 8 disclose a textile product treating agent containing a quaternary ammonium compound and a silicone compound as softener components. However, these techniques impart moderate tension and texture to clothing by combining a silicone compound with a compound selected from fatty acids, fatty acid alkyl or alkenyl esters, fatty alcohols and fatty acid glycerides having a melting point of 30 to 80 ° C. In addition, there is no suggestion about the effect of suppressing the formation of wrinkles. In addition to the above prior art, Patent Document 9, Patent Document 10, Patent Document 11, Patent Document 12, Patent Document 13, and Patent Document 14 disclose a technique using a silicone compound.
JP 2000-129577 A JP 2000-129578 A JP 2000-239970 A JP 2000-64179 A JP 2000-110068 A JP 2000-110077 A JP 2001-172878 A JP 2002-371474 A JP 2001-49582 A JP 2001-192773 A JP 2002-80603 A JP-A-8-209543 JP-A-10-131054 JP 11-343402 A

  The problem of the present invention is that there is no need for sorting in the washing process, and it can be applied to an automatic loading port of a washing machine, and furthermore, a textile product that imparts appropriate tension and texture to textile products such as clothing and suppresses the formation of wrinkles It is providing the processing agent composition.

  In the present invention, (a) at least one selected from fatty acids, fatty acid alkyl or alkenyl esters, aliphatic alcohols and fatty acid glycerides having a melting point of 30 to 100 ° C., and (b) a silicone compound, (a) component / ( b) Fiber product treating agent composition contained at a mass ratio of component = 4/1 to 1/4, and (c) 1 or 2 out of 3 groups bonded to a nitrogen atom have 10 carbon atoms At least one selected from a hydrocarbon group of ˜20, a tertiary amine which is a hydrocarbon group optionally substituted by a hydroxy group having 1 to 3 carbon atoms, an acid salt thereof or a quaternized product thereof ( Provided is a fiber product treating agent composition containing a) component / (c) component = 20/1 to 1/2 mass ratio.

  Moreover, this invention is a ratio with which the total amount of the said (a) component and (b) component is 0.02-4 mass% with respect to the mass of a textile product, (a) component / (b) component = Provided is a method for removing wrinkles of a fiber product, comprising a step of bringing the fiber product into contact with an aqueous solution containing a mass ratio of 4/1 to 1/4.

  The textile product treating agent composition of the present invention does not require sorting in the washing process, can be applied to an automatic loading port of a washing machine, and imparts appropriate tension and texture to textile products such as clothing, thereby forming wrinkles. Can be suppressed.

Component (a) used in the present invention is at least one compound selected from fatty acid (a1), fatty acid alkyl or alkenyl ester (a2), aliphatic alcohol (a3) and fatty acid glyceride (a4), and has a melting point. The compound is 30 to 100 ° C, preferably 40 to 80 ° C, particularly preferably 50 to 70 ° C.
The melting point of the present invention is a value measured by the following method.

<Measuring method of melting point>
0.5 g of sample is put into a glass screw tube (No. 3, 21 mm × 45 mm) having a capacity of 10 mL (5 pieces per sample) and sealed under atmospheric pressure. About one kind of sample, each one (total 8 pieces) is set up in a constant temperature bath of 30 ° C., 40 ° C., 50 ° C., 60 ° C., 70 ° C., 80 ° C., 90 ° C., 100 ° C. Store and observe condition after 24 hours. If the sample is a completely transparent liquid, the storage temperature is determined to be higher than the melting point, and the melting point range is determined for each sample. Next, prepare a temperature-adjustable water bath, and immerse more than half from the bottom of the container with each sample stored in a constant temperature room at 5 ° C. for 24 hours sealed. The temperature of the water bath is increased at a rate of 1 ° C. from 5 ° C. to 30 minutes below the lower limit of the expected temperature range. The temperature at which the sample becomes completely transparent is taken as the melting point.

  As fatty acid (a1) used for this invention, the compound represented by Formula (1) is preferable.

R ^1a COOH (1)
[Wherein, R ^1a represents an alkyl group or an alkenyl group having 13 to 35 carbon atoms, preferably 15 to 27 carbon atoms, more preferably 17 to 23 carbon atoms. ]
The fatty acid alkyl or alkenyl ester (a2) is preferably a compound represented by the formula (2).

R ^2a COOR ^2b (2)
[Wherein, R ^2a is an alkyl group or alkenyl group having 7 to 21, preferably 11 to 17, more preferably 13 to 15 carbon atoms, and R ^2b is an alkyl or alkenyl group having 1 to 22 carbon atoms. . ]
As the aliphatic alcohol (a3), a compound represented by the formula (3) is preferable.

R ^3a OH (3)
[Wherein, R ^3a is an alkyl or alkenyl group having 14 to 32 carbon atoms, preferably 16 to 28, more preferably 18 to 24 carbon atoms. ]
As fatty acid glyceride (a4), the compound represented by Formula (4) is preferable.

R ^4a COOCH ₂ CH (OR ^4b ) CH ₂ OR ^4c (4)
[Wherein, R ^4a is an alkyl group or alkenyl group having 7 to 21 carbon atoms, preferably 11 to 17 carbon atoms, more preferably 13 to 15 carbon atoms, and R ^4b and R ^4c are each independently a hydrogen atom or 6 to 6 carbon atoms. 22 saturated or unsaturated acyl groups. ].

  Usually, pastes that impart tenacity to textile products such as clothing are processed starch and water-soluble cellulose derivatives described in JP-A No. 2000-129777, and water-soluble polymer compounds described in JP-A No. 2000-129578. Is used as a paste base, but when these compounds are used, while imparting excellent tenacity, the fiber tends to be shrunken, such as being stiff. In the present invention, the component (a) is used in place of such a paste base, and it is used in combination with the component (b) described later, thereby imparting appropriate tenacity to the fiber product and obtaining an excellent texture. it can. In general, the component (a) of the present invention is known as a fiber softening aid, but the component (a) is used as a paste base as in the present invention, and is excellent when used in combination with the component (b). Obtaining a texture is not easily conceivable even by those skilled in the art.

  Specific examples of the component (a1) of the present invention include myristic acid, palmitic acid, stearic acid, petrothelic acid, petroceridic acid, elaidic acid, basenic acid, arachidic acid, behenic acid, erucic acid, brassic acid, lignoceric acid. , Ceracoleic acid, serotic acid or a mixture thereof.

  Specific examples of the component (a2) include caprylic acid, isononanoic acid, capric acid, lauric acid, myristic acid, palmitic acid, 2-palmitoleic acid, stearic acid, elaidic acid, petroceric acid, arachidic acid, behenic acid or theirs. Mixture with methanol, ethanol, propanol, isopropanol, butanol, pentanol, hexanol, octanol, 2-ethylhexyl alcohol, decanol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol , Eleisyl alcohol, Petrocerinyl alcohol, Linolyl alcohol, Linolenyl alcohol, Eleostearyl (β) alcohol, Arachidyl alcohol , Behenyl alcohol, erucyl alcohol, esters of brassidyl alcohol or mixtures thereof can be mentioned, tetradecyl myristate, tetradecyl palmitate, octadecyl palmitate, octyl stearate, octadecyl stearate, behenic acid docosyl are preferred.

  Specific examples of the component (a3) include myristyl alcohol, cetyl alcohol, 2-hexadecanol, stearyl alcohol, 2-octadecanol, elaidyl alcohol, petrocerinyl alcohol, eleostearyl (β) alcohol, and arachidyl. Examples include alcohol, 2-icosanol, behenyl alcohol, erucyl alcohol, and brassyl alcohol.

  Specific examples of the component (a4) include 1-monomyristin, 1-monopalmitin, 1-monostearin, 2-monolaurin, 2-monomyristin, 2-monostearin, 1,3-dilaurin, 1,3-distearin. 1,2-dipalmitin, 1,2-distearin, tripalmitin, tristearin, 2-stearoyl-1,3-dipalmitin, 2-myristoyl-1,3-distearin and the like.

  In the present invention, the component (a) acts as a paste base, and when the component (a) is used alone, it is possible to suppress wrinkling as compared with a water-soluble polymer compound usually used as a paste base. . However, since the level is not yet satisfactory, in the present invention, a silicone compound is used in combination as the component (b). The component (b) has an important role of further suppressing wrinkling, imparting moderate smoothness to the fiber product, and suppressing wrinkle formation.

(B) The preferred silicone compound as the component, a kinematic viscosity of preferably 15~20000mm ² / s at 25 ° C., more preferably 15~10000mm ² / s, particularly preferably 50~8000mm ² / s, 100~6000mm ² / s is most preferred. The component (b) of the present invention is preferably a silicone compound having low solubility in water, and preferably a compound that is insoluble or partially insoluble at 20 ° C. in a 5% aqueous solution. Here, insoluble or partially insoluble is a state in which the silicone compound is separated, precipitated, suspended or emulsified in water, and can be confirmed either visually or with a turbidimeter. More specifically, amino-modified silicones, polyether-modified silicones, alkyl-modified silicones, dimethylpolysiloxane (dimethicone), carboxy-modified silicones, alcohol-modified silicones, and phenylmethylsilicones can be mentioned, particularly amino-modified silicones and polyether-modified silicones. Silicone, alkyl-modified silicone and dimethicone are preferred.

Examples of the amino-modified silicone used in the present invention include those described in JP-A-2001-49582, JP-A-2001-192773, JP-A-2002-371474, JP-A-8-325952, JP-A-10-131054 and the like. . Kinematic viscosity at 25 ° C. of the amino-modified silicone is preferably 100~20000mm ² / s, more preferably 200~10000mm ² / s, particularly preferably from 500~5000mm ² / s, amino equivalent weight (nitrogen atom one per The molecular weight is determined by the formula: amino equivalent = molecular weight / number of atoms N. The molecular weight is a value obtained by gel permeation chromatography using polystyrene as a standard, and the number of nitrogen atoms can be determined by elemental analysis). It is 400-8000, More preferably, it is 600-5000, Most preferably, it is 800-3000.

  A preferred specific example of the amino-modified silicone is a compound represented by the general formula (5).

[Wherein R ^5a represents an alkyl group having 1 to 3 carbon atoms, a hydroxy group, —OR ^5d (where R ^5d is an alkyl group having 1 to 3 carbon atoms) or a hydrogen atom, and R ^5b represents 1 to 3 carbon atoms. An alkyl group, a hydroxy group or a hydrogen atom. A represents a side chain having at least one amino group, and R ^5c represents an alkyl group having 1 to 3 carbon atoms or a hydrogen atom. a represents a number of 10 to 10,000, b represents a number of 1 to 1,000, and represents a number having a weight average molecular weight of 2,000 to 1,000,000. R ^5a , R ^5b , R ^5c and R ^5d may be the same or different, and a plurality of R ^5b may be the same or different. ]
In the general formula (5), R ^5a is preferably a methyl group or a hydroxy group, R ^5b is preferably a methyl group or a hydroxy group, R ^5c is preferably a methyl group or a hydrogen atom, and R ^5d is preferably a methyl group. The weight average molecular weight is preferably 5,000 to 100,000, particularly preferably 8,000 to 50,000. Here, the weight average molecular weight can be determined by gel permeation chromatography using polystyrene as a standard. Examples of the side chain A having an amino group include the following.
-C ₃ H ₆ -NH _{2
-C 3 H 6 -NH-C 2} H 4 -NH 2
_{-C 3 H 6 -NH- [C 2} H 4 -NH] n1 -C 2 H 4 -NH 2
_{-C 3 H 6 -NH (CH 3} )
_{-C 3 H 6 -NH-C 2} H 4 -NH (CH 3)
_{-C 3 H 6 -NH- [C 2} H 4 -NH] n2 -C 2 H 4 -NH (CH 3)
_{-C 3 H 6 -N (CH 3} ) 2
_{-C 3 H 6 -N (CH 3} ) -C 2 H 4 -N (CH 3) 2
_{-C 3 H 6 -N (CH 3} ) - [C 2 H 4 -N (CH 3)] n3 -C 2 H 4 -N (CH 3) 2
_{-C 3 H 6 -NH-cyclo-} C 5 H 11
Here, n1, n2, and n3 are numbers from 1 to 30, respectively.

As the polyether-modified silicone used in the present invention, a compound having a cloud point of 1% aqueous solution of 80 ° C. or lower, preferably 70 ° C. or lower is suitable. A compound having a cloud point in such a range is likely to be adsorbed on a fiber product because of its relatively low water solubility, and the wrinkle removal effect of the present invention can be more effectively obtained. The viscosity at 25 ° C. of the polyether modified silicone is preferably 100~6000mm ² / s, still more preferably ^{200~6000mm 2 / s, 500~5500mm 2 /} s is particularly preferred.

  As the polyether group, a polyoxyethylene group, a polyoxypropylene group, a polyoxyalkylene group in which an oxyethylene group and an oxypropylene group are added in a block shape or at random are suitable, and a compound in which a polyether group is grafted to a silicone main chain A compound in which silicone and a polyether group are bonded in a block shape can be used.

  More specifically, a compound represented by the following general formula (6) and a compound represented by the general formula (7) can be exemplified.

[Wherein, R ^6a and R ^7c are each an alkyl group or hydroxy group having 1 to 3 carbon atoms, R ^6c and R ^7a are each a hydrogen atom or an alkyl group or hydroxy group having 1 to 3 carbon atoms, and EO Is an ethyleneoxy group, PO is a propyleneoxy group, and R ^6b and R ^7b are each an alkylene group having 2 to 5 carbon atoms. c, d, e, f, g, h, i, j, k, and l are selected so as to fall within the preferred viscosity and preferred cloud point range of the present invention. Note that d, e, and g + i are numbers of 1 or more. ]
Specific preferred compounds of the polyether-modified silicone include KF-351, KF-352, KF-353, KF-6009, KF-6011, KF-6012, KF-6015, KF-6017 manufactured by Shin-Etsu Chemical Co., Ltd. , KF-6025, Toray Dow Corning Silicone SH-3775M, SH-3748, SH-349, L-7001, FZ-2203, FZ-2222, GE Toshiba Silicone TSF-4445, Examples thereof include TSF-4446 and TSF-4460.

The alkyl-modified silicone used in the present invention preferably has a viscosity at 25 ° C. of 15 to 5000 mm ² / s, and more preferably 15 to 2000 mm ² / s. The alkyl group as the modifying group is preferably a branched or straight chain alkyl group having 8 to 45 carbon atoms, and preferably has a structure in which an alkyl group is grafted to the silicone main chain. The alkyl group may be directly bonded to the silicon atom of the silicone main chain, or may be bonded via an ester group. Specific preferred examples of the alkyl-modified silicone include KF-7002, KF-412, KF-413, KF-414, KF-910, KF-22-715, Toray Dow Corning, manufactured by Shin-Etsu Chemical Co., Ltd. Silicone SH203, SH230, SH8416, BY16-846 may be mentioned.

The dimethicone used in the present invention preferably has a viscosity at 25 ° C. of 15 to 5000 mm ² / s, and more preferably 500 to 5000 mm ² / s. Specific examples of preferred compounds include SH-200, CF2238, DC-1716, XS65-C0077, and XS65-C0104 manufactured by Toray Dow Corning Silicone Co., Ltd.

  In addition to the above, phenylmethyl silicone is also suitable as the component (b) of the present invention, and KF-53 and KF-56 manufactured by Shin-Etsu Chemical Co., Ltd. can be used.

The viscosity of the silicone of the present invention can be measured with an Ostwald viscometer.
The component (b) of the present invention may be blended in the form of an oil as it is, but blending it in the form of an aqueous emulsion in which the particles of the component (b) are dispersed in water may result in the composition of the present invention. This is preferable because it can be easily manufactured. In the aqueous emulsion of component (b), it is preferable to use a surfactant as an emulsifier. As the surfactant, alkylbenzene sulfonic acid or a salt thereof, alkyl sulfate ester salt, polyoxyalkylene alkyl ether sulfate, olefin sulfonate, Anionic surfactants such as alkane sulfonates and fatty acid salts (including salts obtained from fatty acids of component a1), polyoxyalkylene alkyls or alkenyl ethers, polyoxyalkylene alkyl phenyl ethers, fatty acid alkanolamides or alkylene oxides thereof Adducts, nonionic surfactants such as sucrose fatty acid esters and alkyl glucosides, amphoteric surfactants such as amine oxides, sulfobetaines and carbobetaines, and cationic surfactants such as tri-long-chain alkyl quaternary ammonium salts Agent can be used.

  The average particle diameter of the emulsified particles in the aqueous emulsion of component (b) is preferably 0.01 to 10 μm, more preferably 0.01 to 5 μm, and particularly preferably 0.01 to 1 μm from the viewpoint of obtaining a texture. As the emulsifier for the aqueous emulsion of component (b), it is possible to use a nonionic surfactant containing component (a3). However, the total amount of component (a) in the composition of the present invention is (a ) Component / (b) component = It is necessary to mix | blend so that it may become mass ratio of 4/1-1/4.

  In addition, as the aqueous emulsion of component (b) that can be used in the present invention, various emulsifiers (homomixers, high-pressure homogenizers, colloid mills, etc.) using the above oily-type emulsifiers such as surfactants. Although an emulsion dispersed in water may be used, an emulsion containing a desired silicone is prepared by conducting a polymerization reaction in water using an organoalkoxysilane and dimethylcyclopolysiloxane, and this is prepared as (b) You may use as an aqueous emulsion of an ingredient as it is.

  The composition of the present invention contains the component (a) and the component (b) at a ratio of (a) component / (b) component (mass ratio) = 4/1 to 1/4. It is possible to give moderate tension and a favorable texture to the product.

  Use of a commonly used softening agent or paste base in the composition of the present invention impairs the tenacity and texture of the fiber, which is the effect of the present invention, and therefore requires caution when blending. Of the three groups bonded to the nitrogen atom, which are known as general softeners, 1 or 2 is a hydrocarbon group having 10 to 20 carbon atoms, and the remainder is a hydroxy group having 1 to 3 carbon atoms. At least one [component (c)] selected from a tertiary amine which is a hydrocarbon group which may be substituted, an acid salt thereof or a quaternized product thereof, is used in a small amount in the present invention. However, when it is used in a large amount, the tenacity that is the characteristic of the present invention is lost, and the characteristic as a softening agent is strengthened. Therefore, the content ratio of the component (a) and the component (c) in the composition of the present invention is preferably (a) / (c) (mass ratio) = 20/1 to 1/2.

  Preferable specific examples of the component (c) of the present invention include a tertiary amine represented by the general formula (8), an acid salt thereof or a quaternized product thereof.

[Wherein, R ^8a is a hydrocarbon group having 10 to 20 carbon atoms, R ^8b is a hydrocarbon group which may be substituted with a hydrocarbon group having 10 to 20 carbon atoms or a hydroxy group having 1 to 3 carbon atoms, R ^8c represents a hydrocarbon group which may be substituted with a hydroxy group having 1 to 3 carbon atoms. ]
In the general formula (8), R ^8a is preferably an alkyl group and / or alkenyl group having 10 to 20 carbon atoms, particularly an alkyl group having 12 to 18 carbon atoms, and R ^8b is an alkyl group having 10 to 20 carbon atoms and An alkenyl group, particularly an alkyl group having 12 to 18 carbon atoms, or an alkyl group having 1 to 3 carbon atoms, particularly a methyl group is preferred. R ^8c is preferably an alkyl group having 1 to 3 carbon atoms, particularly a methyl group. Examples of the tertiary amine acid salt include inorganic acids such as hydrochloric acid, nitric acid, phosphoric acid, and sulfuric acid, and salts of organic acids such as acetic acid, lactic acid, glycolic acid, citric acid, succinic acid, and maleic acid. Examples of the quaternized product of the tertiary amine include those quaternized with an alkyl halide having 1 to 4 carbon atoms such as methyl chloride or a dialkyl sulfate having 2 to 6 carbon atoms.

  Many common paste bases are polymer compounds that are provided in the form of an aqueous solution or dispersion and are excellent in film-forming properties when dried at room temperature. This film-forming property at room temperature drying is the main cause of the stickiness of the glue, and is a characteristic to be avoided in the composition of the present invention. That is, among the polymer compounds not corresponding to the component (a) and the component (b) [hereinafter referred to as the component (d)], a polymer compound excellent in the film-forming property at room temperature (25 ° C.) drying (hereinafter referred to as ( The component d1)] may be used in a small amount in the composition of the present invention for the purpose of improving storage stability, controlling rheology, etc., but it is necessary to keep the content low. Therefore, the content ratio of [(a) component and (b) component total content] and (d1) component in the composition of the present invention is preferably [(a) + (b)] / (d1). (Mass ratio) = 100/0 to 80/20, more preferably 100/0 to 90/10, and particularly preferably 100/0 to 95/5. On the other hand, among the component (d), a polymer compound that hardly forms a film when dried at room temperature (25 ° C.) (hereinafter referred to as the component (d2)) has no problem in the use of a small amount in the composition of the present invention. Although it is possible to use it within a range that does not affect the effect, the content should be less than the component (a). Therefore, the content ratio of [(a) component and (b) component total content] and (d2) component in the composition of the present invention is preferably [(a) + (b)] / (d2). (Mass ratio) = 100/0 to 80/20, more preferably 95/5 to 80/20, particularly preferably 95/5 to 85/15, and the content ratio of the component (a) and the component (d2) Is preferably (a) / (d2) (mass ratio) = 95 / 5-60 / 40, more preferably 95 / 5-70 / 30, and particularly preferably 95 / 5-80 / 20.

  The polymer compound referred to in the present invention is a compound having a weight average molecular weight of 2000 or more, and the molecular weight is measured by gel permeation chromatography using polyethylene glycol as a standard when the polymer compound is water-soluble. When the polymer compound is water-insoluble, it can be obtained by gel permeation chromatography using polystyrene as a standard.

  The component (d1) is not particularly limited as long as it is a polymer compound having excellent film-forming properties at room temperature drying. For example, carboxymethyl cellulose, carboxyethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, ethyl cellulose, sodium carboxymethyl cellulose , Cationized cellulose, polyvinyl alcohol, polyvinyl alcohol maleic acid copolymer, polymethyl methacrylic acid, polyacrylic acid, sodium polyacrylate, vinyl acetate acrylic acid copolymer, vinyl acetate methacrylic acid copolymer, vinyl acetate maleic acid copolymer, sodium polystyrene sulfonate , Polyvinylpyrrolidone, polyacrylamide, water-soluble nylon, polyethylene oxide (however, weight average molecule 100,000 or more), alginic acid, sodium alginate, corn starch, amylose, dextrin, wheat starch, potato starch, tapioca starch, pregelatinized starch, acid-treated starch, oxidized starch, starch acetate, carboxymethyl starch, carboxyethyl starch, hydroxyethyl starch , Hydroxypropyl starch, phosphate starch, cationized starch, amphoteric starch, dialdehyde starch, cross-linked starch, starch organic acid ester, starch inorganic acid ester, pullulan, xanthan gum, deacetylated xanthan gum and the like.

  The component (d2) is not particularly limited as long as it is a polymer compound that hardly forms a film when dried at room temperature. For example, polyethylene glycol, polypropylene glycol or copolymers thereof having a weight average molecular weight of 10,000 or less, and a weight average molecular weight of 10,000 or less. Polyethyleneimine or polyethyleneimine polyethylene oxide adduct (number average addition mole number per N atom 1-30), liquid polyglycerol or polyglycerin oxide adduct of polyglycerol at room temperature, ethylenediamine liquid at room temperature Examples include polyalkylene oxide adducts.

  In the present invention, a surfactant (hereinafter referred to as component (e)) can be used in combination for the purpose of improving storage stability, but in the case of a large amount, component (e) adheres to the fiber product and becomes stiff. Use of this product requires caution in order to damage the texture. Examples of the surfactant that can be used include an anionic surfactant, a nonionic surfactant, and an amphoteric surfactant.

  Examples of the anionic surfactant include an alkylbenzene sulfonate having 10 to 15 carbon atoms, an alkyl sulfate ester salt having 10 to 16 carbon atoms, an alkyl group having 10 to 16 carbon atoms, and an oxy having a number average added mole number of 1 to 6 Examples thereof include polyoxyethylene lauryl sulfate having an ethylene group, an α-olefin sulfonate having 10 to 15 carbon atoms, and an α-sulfo fatty acid methyl ester salt having 10 to 16 carbon atoms. As the nonionic surfactant, a polyoxyethylene (and / or polyoxypropylene) alkyl ether type nonionic surfactant having a number average addition mole number of oxyalkylene groups of 4 to 50 and an alkyl group of 8 to 18 carbon atoms. Surfactants, alkyl polyglucosides having an alkyl group having 8 to 16 carbon atoms and an average degree of condensation of 1 to 5 and fatty acid sorbitan esters having 10 to 16 carbon atoms can be exemplified. Examples of the amphoteric surfactant include alkyldimethylamine oxide having 10 to 18 carbon atoms in the alkyl group, alkanoylamidopropyldimethylamine oxide having 10 to 18 carbon atoms in the alkanoyl group, and N- Alkyl-N, N-dimethyl-N- (2-hydroxy-3-sulfopropyl) ammonium betaine, N-alkyl-N, N-dimethyl-N-carboxymethylammonium betaine, alkanoyl group having 10 to 18 carbon atoms Examples include N-alkanoylaminopropyl-N, N-dimethyl-N- (2-hydroxy-3-sulfopropyl) ammonium betaine, N-alkanoylaminopropyl-N, N-dimethyl-N-carboxymethylammonium betaine. it can.

  In the present invention, a polyoxyethylene (and / or polyoxypropylene) alkyl ether type nonionic surfactant having a number average addition mole number of oxyalkylene groups of 4 to 20 and an alkyl group of 8 to 14 carbon atoms, and A surfactant selected from alkyl polyglucosides having an alkyl group with 8 to 16 carbon atoms and an average degree of condensation of 1 to 3 is preferred.

  In the present invention, it is preferable to contain a water-soluble organic solvent [hereinafter referred to as component (f)] for the purpose of obtaining a preferred appearance and improving the storage stability. The content of the component (f) is preferably 0.5 to 40% by mass, more preferably 1 to 30% by mass, particularly preferably 1.5 to 25% by mass, and most preferably 2 in the composition of the present invention. ˜20 mass%. Component (f) is preferably a water-soluble organic solvent having a hydroxyl group and / or an ether group. (F) The following are mentioned as a component, It is preferable to use 1 or more types of these.

  (I) alkanols such as ethanol, propanol, isopropanol, 1-butanol, (ii) polyhydric alcohols such as ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, glycerin, (iii) diethylene glycol, triethylene glycol, Polyglycols such as tetraethylene glycol, polyethylene glycol having an average molecular weight of about 200, polyethylene glycol having an average molecular weight of about 400, dipropylene glycol, tripropylene glycol, polypropylene glycol having an average molecular weight of about 1000, (iv) diethylene glycol monomethyl ether, diethylene glycol dimethyl ether , Triethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol Recall diethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, tripropylene glycol monomethyl ether, 1-methoxy-2-propanol, 1-ethoxy-2-propanol, 1-methylglyceryl ether, 2-methylglyceryl ether 1,3-dimethylglyceryl ether, 1-ethylglyceryl ether, 1,3-diethylglyceryl ether, triethylglyceryl ether, 1-pentylglyceryl ether, 2-pentylglyceryl ether, 1-octylglyceryl ether, 2-ethylhexylglyceryl ether Alkyl ethers such as diethylene glycol monobutyl ether, (v) 2-phenoxyethanol, diethylene glycol monophenol Aromatic ethers such as ruether, triethylene glycol monophenyl ether, polyethylene glycol monophenyl ether having an average molecular weight of about 480, 2-benzyloxyethanol, diethylene glycol monobenzyl ether, (vi) 2-aminoethanol, N-methylethanolamine N, N-dimethylethanolamine, N, N-diethylethanolamine, diethanolamine, N-methyldiethanolamine, N-butyldiethanolamine, triethanolamine, triisopropanolamine, isopropanolamine mixture (mixture of mono-, di-, and tri) Alkanolamines.

  The component (f) contains two or more selected from the above (i) alkanols, (ii) polyhydric alcohols, (iv) alkyl ethers, (v) aromatic ethers, and (vi) alkanolamines. It is preferably used in combination, more preferably two or more selected from (i), (ii), (iv), (v), and particularly preferably two selected from (i), (ii), (iv) The combined use of the above can effectively improve the appearance and storage stability of the composition.

  As the component (f), ethanol, propanol, isopropanol, ethylene glycol, propylene glycol, glycerin, 1-pentyl glyceryl ether, 2-pentyl glyceryl ether, 2-ethylhexyl glyceryl ether, and diethylene glycol monobutyl ether are preferable. , Ethylene glycol, propylene glycol, 2-ethylhexyl glyceryl ether, and diethylene glycol monobutyl ether are preferred.

  In the present invention, it is preferable to contain a water-soluble acid (hereinafter referred to as component (g)) for the purpose of obtaining a preferable appearance and improving storage stability, and includes hydrochloric acid, acetic acid, citric acid, succinic acid, fumaric acid. Examples of the acid include benzoic acid, lactic acid, butyric acid, phosphoric acid, and sulfuric acid, and these acids can be used alone or in combination. Of these, hydrochloric acid, acetic acid, citric acid and lactic acid are preferred, and hydrochloric acid and citric acid are particularly preferred.

  In this invention, (a) component with respect to the aqueous solution and textiles which diluted the composition containing said (a) component, (b) component, and optionally (c)-(g) component in water directly or in water And (b) component at a ratio of 0.02 to 4% by mass, preferably 0.04 to 2% by mass, particularly preferably 0.1 to 1% by mass, with component (a) / component (b) = 4/1 to 1/4, preferably 3/1 to 1/3, particularly preferably 2/1 to 1/2 Wrinkle removal of the fiber product including the step of bringing the fiber product into contact with the aqueous solution Regarding the method. Moreover, various forms can be employ | adopted for the textiles processing agent composition of this invention with a processing method. Specifically, a method of directly immersing the target fiber product in the fiber product treating agent composition of the present invention (hereinafter referred to as method 1), a target fiber product in a diluted solution obtained by diluting the fiber product treating agent composition of the present invention in water. And a method of spraying and adhering the textile product treating agent composition of the present invention to a target garment using a sprayer (hereinafter referred to as Method 3). Here, the immersion refers to a state in which the target fiber is completely immersed in the composition of the present invention or an aqueous solution obtained by diluting the composition of the present invention.

  The fiber product treating agent composition of the present invention (hereinafter referred to as composition (I) group) used in Method 1 is preferably 20 to 1000 ppm, more preferably 40 to 800 ppm, particularly preferably 60 to 600 parts (a) component. 600 ppm, the component (b) is preferably 10 to 800 ppm, more preferably 20 to 600 ppm, particularly preferably 40 to 400 ppm, and the mass ratio of (a) component / (b) component is 4/1 to 1/4. , Preferably 3/1 to 1/2, particularly preferably 2/1 to 1/1. In the composition (I) group, the component (c) and the component (d) may not necessarily be contained, but when the component (c) is contained, the component (a) and the component (c) The content ratio with the component is preferably (a) / (c) (mass ratio) = 20/1 to 1/1, more preferably 15/1 to 3/1, particularly preferably 10/1 to 4/1. It is. Moreover, when it contains (d) component, it is necessary to restrain content low with respect to (d1) component, [(a) component and (b) component in the composition (I) group of this invention] The total content of] and the content ratio of the component (d1) is preferably [(a) + (b)] / (d1) (mass ratio) = 100/0 to 80/20, more preferably 100/0. ~ 90/10, particularly preferably 100/0 to 95/5. In addition, for the component (d2), there is no problem in the use of a small amount, and [the total content of the component (a) and the component (b)] and the component (d2) in the composition (I) group of the present invention The content ratio of [(a) + (b)] / (d2) (mass ratio) = 100/0 to 80/20, more preferably 95/5 to 80/20, and particularly preferably 95/5. The content ratio of the component (a) to the component (d2) is preferably (a) / (d2) (mass ratio) = 95/5 to 60/40, more preferably 95/5. ˜70 / 30, particularly preferably 95 / 5˜80 / 20.

  The total content of the component (c) and / or the component (d) in the composition (I) group is preferably 200 ppm or less, more preferably 150 ppm or less, and particularly preferably 100 ppm or less. [Total content of (a) component and (b) component] / [Total content of (c) component and (d) component] in the composition (I) group is a mass ratio, preferably 100/0. -80/20, more preferably 95 / 5-80 / 20, particularly preferably 95 / 5-85 / 15.

  The component (e) and the component (f) in the composition (I) group can be appropriately contained for the purpose of preparing a uniform solution of the component (a) and the component (b). When used in the above, the texture is affected. The content of the component (e) should preferably be 200 ppm or less, more preferably 150 ppm or less, and particularly preferably 100 ppm or less. Since the component (f) has no particular influence on the effect of the composition (I) group of the present invention, it can be optionally contained. However, since there are problems of flash point and odor, the content is preferably 5 It is -600 ppm, More preferably, it is 10-400 ppm, Most preferably, it is 20-300 ppm.

  The composition (I) group used in Method 1 is in the form of an aqueous solution or dispersion in which the above components are dissolved or dispersed in water, and each component is prepared by individually dissolving or dispersing a predetermined amount in water. be able to. From the viewpoint of dissolution or dispersion stability, the pH of the solution is preferably 2 to 9, more preferably 3 to 8, particularly preferably 4 to 7. In order to adjust to such pH, ordinary sulfuric acid or hydrochloric acid is used. Acids such as phosphoric acid, acetic acid, citric acid, lactic acid, and succinic acid, and alkali agents such as sodium hydroxide, potassium hydroxide, sodium carbonate, and potassium carbonate can be used.

  In Method 1, the fiber product is immersed directly in the fiber product treating agent composition of the present invention. Specifically, the composition of the present invention is placed in a container such as a talai, a wash basin, or a bat, and the textile product is immersed in the composition. The ratio of the fiber product to the composition is such that the amount of the composition of the present invention per 500 g of the fiber product is preferably 3 to 15 L, more preferably 4 to 13 L, and particularly preferably 5 to 10 L. The temperature of the composition when immersed is preferably 5 to 40 ° C., more preferably 10 to 30 ° C., and the immersion time is preferably 1 to 30 minutes, more preferably 3 to 20 minutes, and particularly preferably 5 ~ 15 minutes. After soaking, it is dehydrated and dried naturally or by a rotary heat dryer. The dried fiber product is less wrinkled to the extent that it does not need to be ironed, but it can be ironed if the finish is more important.

  The fiber product treating agent composition of the present invention (hereinafter referred to as composition (II) group) to be used in Method 2 is preferably 1 to 60% by mass, more preferably 2 to 40% by mass, especially the component (a). Preferably 5 to 30% by mass, component (b) is preferably 0.5 to 30% by mass, more preferably 1 to 20% by mass, particularly preferably 2 to 15% by mass, and (a) component / (b ) Component mass ratio is 4/1 to 1/4, preferably 3/1 to 1/2, particularly preferably 2/1 to 1/1.

  In the method 2, the method of adding the composition (II) group of the present invention to the rinsing water at the rinsing stage of the washing process is a typical method of use, but compared with the method 1, the component (a) in the rinsing water and (B) The density | concentration of a component becomes low. For this reason, in composition (II) group, it is suitable to contain (c) ingredient in order to promote adsorption to textiles of (a) ingredient and (b) ingredient. However, since a large amount of blending impairs the texture, when the component (c) is contained, the content ratio of the component (a) to the component (c) in the composition (II) group is preferably (a) / (c ) (Mass ratio) = 20/1 to 1/2, more preferably 15/1 to 2/1, and particularly preferably 10/1 to 3/1. The content of the component (c) in the composition (II) group is preferably 0.2% by mass or more and less than 5% by mass, more preferably 0.5% by mass or more and less than 3% by mass, particularly preferably. Is 0.8 mass% or more and less than 2 mass%. In addition, the content ratio of [(a) component and (b) component total content] and (c) component in the composition (II) group of the present invention efficiently adsorbs the active ingredient to the fiber product, For the purpose of improving the effect of the present invention, [(a) + (b)] / (c) (mass ratio) = 40/1 to 2/1, more preferably 30/1 to 4/1, particularly Preferably it is 20/1-6/1. Further, when the component (d) is contained, it is necessary to keep the content low particularly for the component (d1), and the content of the component (d1) in the composition (II) group of the present invention is as follows: Preferably it is 2 mass% or less, More preferably, it is 1 mass% or less, Most preferably, it is 0.5 mass% or less. The content ratio of [(a) component and (b) component total content] and (d1) component in the composition (II) group of the present invention is preferably [(a) + (b)] / (d1 ) (Mass ratio) = 100/0 to 80/20, more preferably 100/0 to 90/10, and particularly preferably 100/0 to 95/5. In addition, for the component (d2), there is no problem in the use of a small amount, and [the total content of the component (a) and the component (b)] and the component (d2) in the composition (II) group of the present invention The content ratio of [(a) + (b)] / (d2) (mass ratio) = 100/0 to 80/20, more preferably 95/5 to 80/20, and particularly preferably 95/5. The content ratio of the component (a) to the component (d2) is preferably (a) / (d2) (mass ratio) = 95/5 to 60/40, more preferably 95/5. ˜70 / 30, particularly preferably 95 / 5˜80 / 20.

  In particular, when the composition of the present invention is used in a washing machine inlet, the total content of the components (a) and (b) is increased from the viewpoint of the capacity of the inlet and the effect of reducing wrinkles. On the other hand, since it is necessary to make low from the point which suppresses the residue to an inlet, the total content of (a) component and (b) component in the composition of this invention becomes like this. Preferably it is 2-60. It is 4 mass%, More preferably, it is 4-50 mass%, Most preferably, it is 8-40 mass%.

  [Total content of (a) component and (b) component] / [Total content of (c) component and (d) component] in the composition (II) group is a mass ratio, preferably 98/2 to 80 / 20, more preferably 95/5 to 80/20, particularly preferably 90/10 to 80/20.

  The component (e) and the component (f) in the composition (II) group can be appropriately contained for the purpose of improving the appearance of the composition of the present invention and for the purpose of improving storage stability. Since a large amount of the component e) affects the texture, the content of the component (e) should preferably be 20% by mass or less, more preferably 15% by mass or less, and particularly preferably 10% by mass or less. is there. Since the component (f) has no particular influence on the effect of the composition (II) group of the present invention, it can be optionally contained. However, since there are flash point and odor problems, the content is preferably 0. 0.5 to 40% by mass, more preferably 1 to 30% by mass, and particularly preferably 2 to 20% by mass.

  The composition (II) group used in Method 2 is in the form of an aqueous solution or dispersion in which the above components are dissolved or dispersed in water, and the water content is preferably 20 to 90% by mass, more preferably 30%. It is -80 mass%, Most preferably, it is 40-70 mass%. The pH of the composition and the pH adjusting method are the same as those of the composition (I) group used in Method 1.

  In Method 2, the method of adding the composition of the present invention to rinsing water at the rinsing stage of the washing process is suitable, and the amount of the composition of the present invention is 7 to 40 mL, more preferably 10 to 30 mL, especially 1 kg of clothing. 15-25 mL is preferable when exhibiting the effect of this invention. The temperature of the rinsing water is preferably 5 to 40 ° C., more preferably 10 to 30 ° C., and the treatment time is preferably 1 to 30 minutes, more preferably 3 to 20 minutes, particularly preferably 5 to 15 minutes. is there. After soaking, it is dehydrated and dried by natural drying or a rotary heat dryer. The dried fiber product is less wrinkled to the extent that it does not need to be ironed, but it can be ironed if the finish is more important.

  Method 3 is a method in which a container having a sprayer is filled with the composition of the present invention and sprayed onto the target fiber product, and the problem of sprayer clogging arises. In the product treating agent composition (hereinafter referred to as composition (III) group), the concentration of each component needs to be lower than that in Method 2. Specifically, the component (a) is preferably 0.05 to 3% by mass, more preferably 0.1 to 2.5% by mass, particularly preferably 0.2 to 2% by mass, and the component (b) is preferably 0.05 to 3% by mass, more preferably 0.1 to 2.5% by mass, particularly preferably 0.2 to 2% by mass, and the mass ratio of (a) component / (b) component is 4 / 1 to 1/4, preferably 3/1 to 1/3, particularly preferably 2/1 to 1/2.

  In Method 3, since the composition of the present invention directly adheres to clothing, there is no problem of insufficient adsorption efficiency to the textiles to be processed by the component (a) and component (b) as in Method 2. In the group (III), it is not always necessary to include the component (c), and the blending of the component (c) is allowed as long as it does not impair the texture of the textile product expected by processing with the composition of the present invention. For this reason, content of (c) component becomes like this. Preferably it is less than 2 mass%, More preferably, it is less than 1 mass%. Moreover, it is necessary to suppress content low with respect to (d1) component among (d) component, and [total content of (a) component and (b) component in the composition (III) group of this invention ] And the content ratio of the component (d1) are preferably [(a) + (b)] / (d1) (mass ratio) = 100/0 to 80/20, more preferably 100/0 to 90/10. Particularly preferred is 100/0 to 95/5. In addition, for the component (d2), there is no problem in the use of a small amount, and [the total content of the components (a) and (b)] and the component (d2) in the composition (III) group of the present invention The content ratio of [(a) + (b)] / (d2) (mass ratio) = 100/0 to 80/20, more preferably 95/5 to 80/20, and particularly preferably 95/5. The content ratio of the component (a) to the component (d2) is preferably (a) / (d2) (mass ratio) = 95/5 to 60/40, more preferably 95/5. ˜70 / 30, particularly preferably 95 / 5˜80 / 20.

  The total content of the component (c) and / or the component (d) in the composition (III) group is preferably 5% by mass or less, more preferably 3% by mass or less, and particularly preferably 1% by mass or less. [Total content of (a) component and (b) component] / [Total content of (c) component and (d) component] in the composition (III) group is a mass ratio, preferably 100/0. -80/20, more preferably 95/5 to 80/20, particularly preferably 95/5 to 85/15.

  The components (e) and (f) in the composition (III) group are for the purpose of making the appearance of the composition of the present invention favorable, for the purpose of improving storage stability, and for the purpose of suppressing clogging of the sprayer nozzle. However, the amount of the component (e) is preferably 10% by mass or less, more preferably 5% by mass or less, and particularly preferably. It should be kept below 3% by weight. Since the component (f) has no particular influence on the effect of the present invention, it can be optionally contained. However, since there are flash point and odor problems, the content is preferably 0.5 to 20% by mass, More preferably, it is 1-15 mass%, Most preferably, it is 2-10 mass%.

  The composition (III) group used in Method 3 is in the form of an aqueous solution or dispersion in which the above components are dissolved or dispersed in water, and the water content is preferably 40 to 99% by mass, more preferably 60%. It is -98 mass%, Most preferably, it is 80-95 mass%. The pH of the composition and the pH adjusting method are the same as those of the composition (I) group used in Method 1.

  The spray container used in Method 3 is preferably a trigger type spray container, and in particular, it is preferable to use a pressure accumulation type trigger excellent in liquid dripping and spray uniformity as shown in FIG. 1 of Japanese Utility Model Laid-Open No. 4-37554. It is.

Preferred trigger type spray containers of the present invention are those that eject 0.2 g to 2.0 g, preferably 0.25 to 1.5 g, particularly preferably 0.3 to 1.0 g in one stroke. In particular, a container in which the area where the liquid is applied when sprayed from a place 15 cm away in the horizontal direction on a target surface (flat surface) installed perpendicular to the ground is 100 to 800 cm ² , preferably 150 to 600 cm ² is preferable. Moreover, the total amount of the component (a) and the component (b) of the present invention is preferably 0.01 to 4 g, more preferably 0.05 to 3 g, particularly preferably 0.1 to ² g per 100 cm ² of the fiber product. It is preferable to spray the fiber product uniformly.

  There are various options for the timing of spraying the textile product in Method 3, but the wet textile product after the dehydration in the washing process is suspended on a hanger or the like, and the composition (III) group of the present invention is in a wet state. Sprayed uniformly, dried naturally after washing, or sprayed uniformly on a fiber product dried with a rotary heat dryer and dried again, and put the fiber product into the rotary heat dryer Thereafter, a method of spraying the fiber product and drying by heating can be employed. The dried fiber product after the treatment has less wrinkle formation to the extent that it is not necessary to iron, but it can be ironed if the finish is more important.

  The composition used in Method 1 to Method 3 of the present invention can contain components to be added to a general liquid composition, such as preservatives, fragrances, pigments, dyes, hydrotropes, thickeners, gels. An antioxidant, an antioxidant and the like can be contained.

The compounding components used in the examples are summarized below.
-(A) Component (a) -1: Myristic acid (melting point 53.9 ° C)
(A) -2: Myristyl myristate (melting point: 31.5 ° C.)
(A) -3: Calcoal 8688 (manufactured by Kao Corporation) (melting point 57.8 ° C.)
(B) Component (b) -1: SM8704C (Amino-modified silicone emulsion; effective content 40% (manufactured by Dow Corning Toray Silicone Co., Ltd.))
(B) -2: FZ2222 (polyether-modified silicone oil (manufactured by Toray Dow Corning Silicone Co., Ltd.))
(B) -3: LE-463 (dimethyl silicone emulsion; effective content 35% (manufactured by Toray Dow Corning Silicone))
-(C) Component (c) -1: Cotamine D86P (manufactured by Kao Corporation, distearyldimethylammonium chloride)
(C) -2: Cotamine 86W (manufactured by Kao Corporation, stearyltrimethylammonium chloride)
-(D1) component (d1) -1: Poise C-60H (cationized cellulose, molecular weight of about 600,000, manufactured by Kao Corporation)
(D1) -2: PVA-217 (manufactured by Kuraray Co., Ltd., partially saponified polyvinyl alcohol)
(D2) Component (d2) -1: PEG 6000 (polyethylene glycol, average molecular weight 6000)
-(E) Component (e) -1: Nonionic surfactant obtained by adding an average of 20 moles of ethylene oxide per mole of alcohol to Calcoal 80 (manufactured by Kao Corporation) (e) -2: 12 to 12 carbon atoms Nonionic surfactant (e) -3: Softanol 70 ((14), an average of 5 mol of ethylene oxide, an average of 2 mol of propylene oxide, and an average of 3 mol of ethylene oxide were added to 14 linear primary alcohols. (Made by Nippon Shokubai Co., Ltd.)
(F) Component (f) -1: Polyethylene glycol monophenyl ether (average number of EO added moles 3)
(F) -2: ethanol (f) -3: propylene glycol (g) component (g) -1: citric acid (g) -2: lactic acid (g) -3: hydrochloric acid (HCl effective portion 35%)
-Other antibacterial agents: Proxel IB (manufactured by Arch Chemicals, 20% aqueous solution)
Chelating agent: Ethylene diamine tetraacetic acid 4Na
Color: Purple No. 201.

Example 1
8 g of myristyl myristate ((a) -2), 5 g of softanol 70 ((e) -3) and 1 g of Cotamine D86P ((c) -1) were mixed by heating (50 ° C.), and this was heated to 40 ° C. The mixture was mixed with a homogenizer (5000 r / min.) While dropping into 86 g of water. After completion of the dropping, the homogenizer was further mixed for 5 minutes. After the mixing was stopped, the mixture was allowed to stand and allowed to cool to 20 ° C. 10 g of the obtained white emulsion, 1 g of SM8704C ((b) -1) and 1 g of citric acid ((g) -1) were dissolved in 5 L of tap water to obtain a textile product treating agent composition.

  One piece of a shirt (a form-stabilized shirt (SSP), BLUE RIVER made by Flex Japan, 100% cotton) pretreated by the following method was immersed in the obtained composition (20 ° C. solution). . The immersion time is 10 minutes. Thereafter, it was dehydrated for 3 minutes using a dehydrator of a washing machine (NAF80SP1 manufactured by National), hung on a hanger in the shade, and dried for 12 hours. The dried shirt was evaluated for texture and wrinkle according to the following method. The results are shown in Table 1.

<Pretreatment method for textile products for evaluation>
Shirt (form stable processing shirt (SSP), BLUE RIVER made by Flex Japan, white, 100% cotton) using a commercially available weak alkaline detergent (Kao Co., Ltd. Attack), two-tank washing machine (Toshiba Galaxy VH- 360S1) was repeatedly washed 10 times (detergent concentration: 0.0667% by weight, 40 L of tap water (20 ° C.) used, 10 minutes for washing—3 minutes for dehydration—8 minutes for rinsing (rinsing with running water, 15 L / min.)). After rinsing of the last treatment was completed, the product was dehydrated for 5 minutes, and air-dried in a constant temperature and humidity chamber of 25 ° C. to 65 RH to be naturally dried to obtain a textile product for evaluation.

<Texture evaluation method>
After treating with each treating agent composition, hanging and drying for 12 hours, and keeping the humidity controlled by leaving still in a constant temperature and humidity room at 25 ° C.-65 RH for 24 hours, the treating agent is treated after pretreatment. A textile product treated with tap water without using it and similarly conditioned in a constant temperature and humidity room of 25 ° C-65RH was used as a control, with 5 panelists each for softness, tenacity, stiffness and smoothness. A score was given according to the following criteria, and an average score was obtained. The average score is greater than 1.0 and less than or equal to 2.0, ◎, greater than 0 and less than or equal to 1.0, ○, 0, Δ, −1.0 to less than 0 ×, −2.0 to less than −1.0 Judged as xx.
・ Softness The control product is softer: +2 points The control product is slightly softer: +1 point Equivalent to the control product: 0 points Slightly softer than the control product: -1 point Softer than the control product: -2 points Tighter than product: +2 points Slightly more tensioned than control product: +1 point Equivalent to control product: 0 points The control product has slightly more tension: -1 point The control product has more tension: -2 points・ Contrast product is more stiff: +2 Contrast product is slightly stiff: +1 point Contrast product: 0 points Stiffer than control product: -1 point Stiffer than control product: +1 point -2 points / smoothness Smoother than the control product: +2 points Slightly smoother than the control product: +1 point Equivalent to the control product: 0 points The control product is slightly smoother: -1 point The control product is smoother: -2 points < Wrinkle evaluation method>
For textile products treated with each treatment composition and hung and dried for 12 hours, after the pretreatment, treated with only tap water without using a treatment agent and dried similarly, Five panelists scored according to the following criteria to obtain an average score. The average score is greater than 1.0 and less than or equal to 2.0, ◎, greater than 0 and less than or equal to 1.0, ○, 0, Δ, −1.0 to less than 0 ×, −2.0 to less than −1.0 Judged as xx.
-Wrinkles Less wrinkles than the control product: +2 points Slightly less wrinkles than the control product: +1 point Equivalent to the control product: 0 points The control product has less wrinkles: -1 point The control product has less wrinkles: -2 comparative example 1
In place of (a) -2 and (c) -1 in the composition of Example 1, stearyltrimethylammonium chloride ((c) -2) was added (1 g was dissolved in 200 g of hot water in terms of effective component, The temperature was adjusted to 20 ° C. and then added to the composition. Using the composition, the same evaluation as in Example 1 was performed. The results are shown in Table 1.

Comparative Example 2
Instead of (a) -2 and (c) -1 in Example 1, 1 g of Poise C-60H ((d1) -1) was added (1 g in terms of effective component was dissolved in 200 g of warm water, and 20 ° C. The composition was added to the composition after the temperature was adjusted to the same value as in Example 1. The results are shown in Table 1.

  As is apparent from the results in Table 1, the sample treated with the treating agent composition of Example 1 was not soft compared to the control product (equivalent to the control product), but was not sticky, smooth, and slightly stretched. there were. Moreover, the shirt after hanging and drying had less wrinkles, less wrinkles than the control product, and was a level that could be worn without ironing. On the other hand, those treated with the treatment composition of Comparative Example 1 have a soft texture that is not stiff compared to the control product, are smooth and smooth, and have a unique texture when using a softening agent. The tenacity which is the object of the present invention was not shown at all, and the effects of the present invention were not exhibited. The shirt after hanging and drying had less wrinkles, less wrinkles than the control product, and was a level that could be worn enough without ironing. The material treated with the treating agent composition of Comparative Example 2 exhibits tenacity compared to the control product, but has a unique wrinkle when using a paste, and is neither smooth nor soft, and the preferred texture of the present invention. Did not have. Moreover, the shirt after hanging and drying was formed with wrinkles, more wrinkles than the control product, and could not be worn without ironing.

Examples 2-6 and Comparative Examples 3-4
Using each component shown in Table 2, 150 g of the fiber product treating agent composition having the composition shown in Table 2 was prepared. At that time, a plastic plastic cup (capacity 200 mL) was used as a mixing container, and a homogenizer was used as a mixing method. First, the components (e) and (f) were weighed and mixed in a container, and then the component (a) heated to the melting point or higher was added and further mixed. Water corresponding to 10% by mass of the entire composition was added thereto and further mixed. Next, a predetermined amount was added while mixing the component (b) at a rate of about 2 g / min, and mixed for about 30 minutes after completion of the addition. The remainder of the blended water was added to this and mixed, and component (c) was added. While mixing, the component (d) was added and the other components were added, and then adjusted to a predetermined pH with the component (g) to obtain each composition. About the obtained composition, the performance was evaluated by the following method. The results are shown in Table 2.

<Evaluation method>
New cut-and-sew (9 to 5 made by Chikuma Co., Ltd., beige, cotton / polyester = 50/50%) and new shirts (formally-stabilized shirt (SSP), BLUE RIVER made by Flex Japan, white, 100 cotton) %)) And 0.9kg of underwear (100% cotton) and 0.6kg of shirt (white, cotton / polyester = 60/40%) as a weight-adjustable fabric. Was washed 10 times in a two-tank washing machine (Toshiba Ginga VH-360S1) using a commercially available weakly alkaline detergent (Kao Corp. Attack) (detergent concentration 0.0667 mass%, tap water (20 ° C.) 36 L). Use, washing 10 minutes-dehydration 3 minutes-rinsing 8 minutes (rinsing with running water, amount of water 15 L / min.)). At the time when 5 minutes have passed since the rinsing of the last treatment time (the 10th time) has started, running water was stopped, and after draining, dewatering was performed for 3 minutes. Next, 36 L of tap water (20 ° C.) was poured, 23.33 g of each treatment agent composition in Table 2 was added, and the mixture was stirred for 3 minutes. After the stirring was stopped, it was dehydrated for 3 minutes, and a cut-and-sew and a shape-stabilized shirt were taken out as evaluation clothes, each hung on a hanger in the shade, and hung and dried for 12 hours. This was evaluated for texture (tension, stiffness, smoothness) and wrinkles in the same manner as in Example 1. Both cut-and-sew and shape-stabilized shirts were evaluated against the control, but the trend was the same. Table 2 shows the results for the form-stabilized shirt. Moreover, the washing machine insertion port evaluation was performed about each processing agent composition with the following method.
-Washing machine inlet evaluation method Using a fully automatic washing machine (National three-stage washing method NAF80SP1) with a tray type softener inlet, cumulative use (normal course, tap water 20 ° C, amount of water passing through the inlet about 1L, each The condition in the charging port by treating agent 40g / time, 5 times accumulation (once per day) was observed and evaluated according to the following criteria.

No deposit on the inner wall of the inlet and the liquid outlet: ○
There is a deposit on the inner wall of the inlet or the liquid outlet: △
There are deposits on both the inlet wall and the liquid outlet: ×

Claims (4)

(A) At least one selected from fatty acids, fatty acid alkyl or alkenyl esters, aliphatic alcohols and fatty acid glycerides having a melting point of 30 to 100 ° C., (b) amino-modified silicone, polyether-modified silicone, alkyl-modified silicone, and dimethyl Containing at least one silicone compound selected from polysiloxanes in a mass ratio of (a) component / (b) component = 4/1 to 1/4, and (c) three bonded to nitrogen atoms Of the groups, 1 or 2 is a hydrocarbon group having 10 to 20 carbon atoms, the remaining is a tertiary amine which is a hydrocarbon group optionally substituted with a hydroxy group having 1 to 3 carbon atoms, its acid salt or its At least one selected from quaternized products is contained at a mass ratio of (a) component / (c) component = 20/1 to 2/1, and [the sum of (a) component and (b) component Content ratio of Yuryou] and (c) component, [(a) + (b)] / (c) (mass ratio) = 20 / 1-2 / 1 textile treatment composition is. The component (a) is a fatty acid represented by the general formula (1), a fatty acid alkyl or alkenyl ester represented by the general formula (2), an aliphatic alcohol represented by the general formula (3), and the general formula (4). The fiber product treating agent composition according to claim 1, which is at least one selected from fatty acid glycerides represented by:
R ^1a COOH (1)
[Wherein, R ^1a represents an alkyl group or alkenyl group having 13 to 35 carbon atoms. ]
R ^2a COOR ^2b (2)
[Wherein, R ^2a is an alkyl group or alkenyl group having 7 to 21 carbon atoms, and R ^2b is an alkyl group or alkenyl group having 1 to 22 carbon atoms. ]
R ^3a OH (3)
[Wherein, R ^3a represents an alkyl group or alkenyl group having 14 to 32 carbon atoms. ]
R ^4a COOCH ₂ CH (OR ^4b ) CH ₂ OR ^4c (4)
[Wherein, R ^4a is an alkyl group or alkenyl group having 7 to 21 carbon atoms, and R ^4b and R ^4c are each independently a hydrogen atom or a saturated or unsaturated acyl group having 6 to 22 carbon atoms. ] The fiber product treating agent composition according to claim 1 or 2, wherein the total content of the component (a) and the component (b) is 4 to 40% by mass.   In a ratio that the total amount of the component (a) and the component (b) according to claim 1 is 0.02 to 4% by mass with respect to the mass of the fiber product, (a) component / (b) component = 4 / A method for removing wrinkles of a textile product, comprising a step of bringing the textile product into contact with an aqueous solution containing a mass ratio of 1-1 / 4.