JP2000107906A - Coated head tool - Google Patents

Coated head tool

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Publication number
JP2000107906A
JP2000107906A JP28236398A JP28236398A JP2000107906A JP 2000107906 A JP2000107906 A JP 2000107906A JP 28236398 A JP28236398 A JP 28236398A JP 28236398 A JP28236398 A JP 28236398A JP 2000107906 A JP2000107906 A JP 2000107906A
Authority
JP
Japan
Prior art keywords
film
thickness
hard
cutting
coated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP28236398A
Other languages
Japanese (ja)
Other versions
JP4094746B2 (en
Inventor
Yusuke Iyori
裕介 井寄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Moldino Tool Engineering Ltd
Original Assignee
Hitachi Tool Engineering Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Tool Engineering Ltd filed Critical Hitachi Tool Engineering Ltd
Priority to JP28236398A priority Critical patent/JP4094746B2/en
Publication of JP2000107906A publication Critical patent/JP2000107906A/en
Application granted granted Critical
Publication of JP4094746B2 publication Critical patent/JP4094746B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Physical Vapour Deposition (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

PROBLEM TO BE SOLVED: To prevent the peeling of a film by thinly covering the innermost layer making contact with a base body with a TiN series having good adhesion with the base body, and applying a carbonitride layer thereon. SOLUTION: Since TiN is hard with a hardness of HV 2000 or more, it has the function of moderating the stress of a film, and V (CN) or (TiN) (CN) also has the function of moderating the stress with a proper hardness and is highly adhesive to TiN or (TiAl) N, (TiAlV) (CN). The main purpose of the TiN of the layer making contact with the base body is the adhesion with the base body, and the thickness is set to 0.1-5 μm. With respect to the V (CN) or (TiV) (CN) of the hard film, the proper thickness is 0.1-5 μm. With thickness <0.1 μm, the function as the stress moderating layer is insufficient, and with thickness >5 μm, a plastic flow is often caused according to the cutting condition to remove the film.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本願発明は、特に密着性および潤
滑性に優れた硬質皮膜を有する被覆硬質工具に関するも
ので、各種切削工具、型、治工具、機械構成部品など厳
しい摩擦摩耗を受ける部材に適用し性能向上が得られる
ものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coated hard tool having a hard film having particularly excellent adhesion and lubricity, and is a member which is subjected to severe friction and wear, such as various cutting tools, molds, jigs, and machine components. To improve the performance.

【0002】[0002]

【従来の技術】工具の耐摩耗皮膜としてはTiN、Ti
CNなどの皮膜が汎用的かつ一般的であったが、使用条
件の厳しさが増すにつれ耐摩耗性、耐酸化性のより優れ
た(TiAl)N皮膜が多く用いられるようになった。
しかしながら、最近は切削速度がさらに高速化する傾向
に加え、乾式での切削が環境上重要視されるようにな
り、工具表面と被切削材の間の摩擦の低下、自己潤滑性
向上および皮膜の剥離に対する抵抗、すなわち皮膜の基
体に対する密着性の向上が極めて重要となってきた。
2. Description of the Related Art TiN, Ti
Coatings such as CN have been used widely and generally, but as the conditions of use have increased, (TiAl) N coatings having more excellent wear resistance and oxidation resistance have come to be used in many cases.
However, recently, in addition to the tendency for cutting speed to be further increased, dry cutting has become more important in the environment, lowering the friction between the tool surface and the workpiece, improving self-lubricating properties, and improving the coating quality. It has become extremely important to improve the resistance to peeling, that is, the adhesion of the coating to the substrate.

【0003】[0003]

【発明が解決しようとする課題】本発明者らの研究によ
れば、現用のTiAlN皮膜においては鋼との摩擦係数
が0.4程度とかなり大きく切削中の発熱が大きいた
め、切削の高速化、乾式化に限界があることが確認され
た。従って、皮膜の潤滑性を向上させ、切削による熱の
発生を軽減させることが切削の高速化、乾式化を可能に
する不可欠な技術であると考えられる。また、工具の耐
摩耗性を上げ、工具寿命を増大させるには硬質皮膜の厚
さを増大することが最も好ましいが、皮膜厚さの増大は
皮膜と基体の界面に大きな残留応力を発生し、皮膜の剥
離をもたらす。それ故、硬質皮膜と基体の間に密着性が
良く、かつ残留応力を吸収する緩衝膜をつけると性能が
一層向上すると考えられる。
According to the study of the present inventors, the current TiAlN film has a considerably large friction coefficient with steel of about 0.4 and generates a large amount of heat during cutting. It was confirmed that the drying process had a limit. Therefore, it is considered that improving the lubricating properties of the film and reducing the generation of heat by cutting are indispensable technologies that enable high-speed cutting and dry cutting. In addition, it is most preferable to increase the thickness of the hard coating to increase the wear resistance of the tool and increase the tool life, but the increase in the thickness of the coating causes a large residual stress at the interface between the coating and the substrate, Causes peeling of the film. Therefore, it is considered that the performance is further improved by providing a buffer film having good adhesion between the hard film and the substrate and absorbing the residual stress.

【0004】[0004]

【課題を解決するための手段】従って、本願発明は、皮
膜の密着性を改善し、皮膜自身の耐剥離性をより安定さ
せることにより性能向上を計るものであり、皮膜に発生
する大きな圧縮残留応力を緩和する中間層を設け、基体
と接する最内層には基体との密着性の良いTiN系を薄
く被覆し、その上に皮膜の内部応力を緩和する、やや軟
質の炭窒化物層を被覆することものである。また、切削
の高速化、乾式化に対応するには皮膜自体の潤滑性を増
し、刃先温度の上昇を抑えることが有効である。
SUMMARY OF THE INVENTION Accordingly, the present invention aims at improving the performance by improving the adhesion of the film and stabilizing the peeling resistance of the film itself. An intermediate layer for relaxing the stress is provided, and the innermost layer in contact with the substrate is coated with a thin TiN-based material with good adhesion to the substrate, and a slightly soft carbonitride layer is coated on it to relieve the internal stress of the film. Is what you do. Further, in order to cope with high-speed cutting and dry cutting, it is effective to increase the lubricity of the coating itself and to suppress an increase in the temperature of the cutting edge.

【0005】[0005]

【作用】TiNの硬さはHV2200以上と硬いため、
皮膜の応力緩和の機能があり、更にV(CN)あるいは
(TiV)(CN)が適度の硬さをもち応力緩和の働き
を持つとともに、TiNや(TiAl)N、(TiAl
V)(CN)に対し密着性が良いことを見出した。刃先
の耐摩耗性、耐熱性に対しては、現在多く用いられてい
る(TiAl)N、(TiAl)(CN)あるいは潤滑
性を加味した(TiAlV)(CN)を用いる。次に、
外層には潤滑性の優れたV(CN)を被覆する。外層の
皮膜に含まれるVは切削中に酸化してこれが低融点の酸
化物層を形成し、潤滑効果を与えるとともに被削材の溶
着を防ぎ硬質皮膜を保護するからである。
[Function] Since the hardness of TiN is as high as HV2200 or more,
V (CN) or (TiV) (CN) has an appropriate hardness and has a function of relaxing stress, and also has a function of relaxing stress, and TiN, (TiAl) N, (TiAl).
V) It was found that the adhesiveness to (CN) was good. For the wear resistance and heat resistance of the cutting edge, (TiAl) N, (TiAl) (CN) or (TiAlV) (CN) with lubricity taken into account is used. next,
The outer layer is coated with V (CN) having excellent lubricity. V contained in the outer layer coating is oxidized during cutting to form a low-melting oxide layer, which provides a lubricating effect and prevents welding of the work material to protect the hard coating.

【0006】次に、本発明に係わる数値の限定理由につ
いて述べる。基体と接する層のTiNは、基体との密着
性を主目的とするものであるから、厚さは薄くても良く
0.1〜5μmあれば十分であるが、2μm以下の方が
好ましい。硬質皮膜のV(CN)あるいは(TiV)
(CN)については、適当な厚さがある。好ましくは
0.1〜3μmである。0.1μm以下では応力緩和層
としての機能が十分でなく、3μm以上では切削条件に
よっては塑性流動を起こし皮膜が取り去られることがあ
るためである。尚、(CN)中のCとNの比は、外層の
厚さ、切削条件により適宜調整するものとする。C/N
の値が大きくなるほど硬くなり応力緩和の機能が減少す
る。同様に(TiV)(CN)におけるTi/Vの値が
大きいほど硬くなる。(TiV)(CN)を(Ti1-x
x)(C1-yy)と表した場合、x=0.2〜1.
0、y=0.3〜1.0程度が良い。
Next, reasons for limiting numerical values according to the present invention will be described. Since the main purpose of TiN of the layer in contact with the substrate is to mainly adhere to the substrate, the thickness of the layer may be as small as 0.1 to 5 μm, but is preferably 2 μm or less. V (CN) or (TiV) of hard coating
(CN) has an appropriate thickness. Preferably it is 0.1 to 3 μm. If the thickness is 0.1 μm or less, the function as a stress relaxation layer is not sufficient, and if it is 3 μm or more, depending on the cutting conditions, plastic flow may occur and the film may be removed. The ratio of C to N in (CN) is appropriately adjusted depending on the thickness of the outer layer and cutting conditions. C / N
As the value increases, the material becomes harder and the function of stress relaxation decreases. Similarly, the higher the value of Ti / V in (TiV) (CN), the harder it becomes. (TiV) (CN) to (Ti 1-x
V x ) (C 1-y N y ), where x = 0.2-1.
0 and y = about 0.3 to 1.0 are good.

【0007】耐摩耗性を与えるための外層の(TiA
l)(CN)あるいは(TiAlV)(CN)はなるべ
く厚いほうが望ましい。0.5μm以下では耐摩耗性が
不足であり、上限の5μmは皮膜全体の厚さを15μm
としたケースで、内、硬質層の上限の厚さを考慮し5μ
mとした。外層のV(CN)は潤滑性を与えるためのも
のである。0.1μm以下ではその効果が十分でなく、
2μm以上はその効果が増大しないので上限を2μmと
した。V(CN)をV(Cz1-z)と表せば、z=0〜
0.5が好ましい。(CN)中、N量の多いほど潤滑性
は良い。
The outer layer (TiA) to provide abrasion resistance
1) It is desirable that (CN) or (TiAlV) (CN) be as thick as possible. If the thickness is 0.5 μm or less, the wear resistance is insufficient.
In consideration of the upper limit thickness of the hard layer,
m. V (CN) of the outer layer is to provide lubricity. If the thickness is less than 0.1 μm, the effect is not sufficient.
If the thickness is 2 μm or more, the effect is not increased, so the upper limit is set to 2 μm. When V (CN) is expressed as V (C z N 1-z ), z = 0 to z
0.5 is preferred. In (CN), the greater the amount of N, the better the lubricity.

【0008】本発明の構成において、皮膜の耐摩耗性、
耐剥離性を十分発揮するためには、皮膜の硬さは次の順
になることが必要である。 外層{TiAl(CN)、TiAlV(CN)} >内層{TiN} >硬質層{V(CN)、TiV(CN)} 以下、実施例について本発明を説明する。
[0008] In the constitution of the present invention, the wear resistance of the film,
In order to sufficiently exhibit peel resistance, the hardness of the film needs to be in the following order. Outer layer {TiAl (CN), TiAlV (CN)}> Inner layer {TiN}> Hard layer {V (CN), TiV (CN)} Hereinafter, the present invention will be described with reference to examples.

【0009】[0009]

【実施例】小型アークイオンプレーティング装置を用い
第1表に示す条件で本発明例、比較例のコーティングを
行い被覆超硬エンドミルを試作した。皮膜の組成はTi
−Al合金ターゲットおよびTi−Vターゲットならび
に純Ti、純Vターゲットを用いて調整した。
EXAMPLES Coatings of the present invention and comparative examples were made by using a small-sized arc ion plating apparatus under the conditions shown in Table 1 to produce prototype coated carbide end mills. The composition of the film is Ti
The adjustment was performed using an Al alloy target, a Ti-V target, a pure Ti, and a pure V target.

【0010】[0010]

【表1】 [Table 1]

【0011】試作したエンドミルを用い以下の切削条件
で切削試験を行い、折損するまで切削を行った。折損が
発生した時点の切削長は表1に併記した。切削諸元は、
エンドミル(φ8mm、6枚刃)を用いて、被削材SK
D11(硬さHRC60)、切削速度150m/mi
n、送り量0.06mm/刃、切り込み量12mm×
0.2mm、切削油なし、にて行った。
A cutting test was carried out under the following cutting conditions using a prototype end mill, and cutting was performed until breakage occurred. The cutting length at the time when the breakage occurred is also shown in Table 1. Cutting specifications are
Work material SK using end mill (φ8mm, 6 blades)
D11 (hardness HRC60), cutting speed 150m / mi
n, feed amount 0.06 mm / tooth, cutting amount 12 mm x
0.2 mm, without cutting oil.

【0012】表1より、外層にV(CN)を被覆したも
のは、切削時の刃先温度が630〜650℃と低く切削
長も約50mと極めて良好な結果を示している。外層の
V(CN)膜が無くても硬質皮膜層にVを含むTiAl
V(CN)を被覆したものは刃先温度も比較的低く、切
削長も約40mと長い。皮膜の内部応力緩和層である内
層のV(CN)又はTiAlV(CN)が無い場合、刃
先温度への影響は少ないが切削長はやや低下する。特に
試料番号13の例のように層の厚さが厚い場合、膜剥離
により切削長を著しく短くする。
From Table 1, it can be seen that the case where the outer layer is coated with V (CN) has a very good result with a low cutting edge temperature of 630 to 650 ° C. and a cutting length of about 50 m during cutting. TiAl containing V in hard coating layer without V (CN) film as outer layer
Those coated with V (CN) have a relatively low cutting edge temperature and a long cutting length of about 40 m. When there is no V (CN) or TiAlV (CN) in the inner layer, which is the internal stress relaxation layer of the coating, the effect on the cutting edge temperature is small, but the cutting length is slightly reduced. In particular, when the thickness of the layer is large as in the example of the sample No. 13, the cutting length is remarkably shortened due to the peeling of the film.

【0013】本発明の有効性をドリルで実証するため
に、前記例と同じ製法により超硬合金製ドリルを製作し
切削性能を比較した。ドリルの切削諸元は刃径φ8mm
のドリルを用い、深さ24mmの穴明け加工を被削材S
CM440、切削速度80m/min、送り量0.2m
m/rev、水溶性切削油を用いて行った。切削性能は
折損までの穴明け数によって比較した。試験結果を第2
表に示す。なお、試料番号については第1表と同じ製法
のドリルは第1表のエンドミルと同じ番号とした。
In order to demonstrate the effectiveness of the present invention with a drill, a cemented carbide drill was manufactured by the same manufacturing method as in the above example, and the cutting performance was compared. Drilling specifications are 8mm in diameter.
Drilling 24mm deep using a drill
CM440, cutting speed 80m / min, feed amount 0.2m
m / rev, using water-soluble cutting oil. The cutting performance was compared by the number of holes until breakage. Second test result
It is shown in the table. The sample numbers of the drills having the same manufacturing method as those in Table 1 were the same as those of the end mills in Table 1.

【0014】[0014]

【表2】 [Table 2]

【0015】表2より、外層にV(CN)膜を被覆する
ことにより工具寿命が増大することを示している。ま
た、外層にV(CN)膜が無い場合でも、硬質皮膜層に
Vを含む(TiAlV)(CN)層を用いれば比較的寿
命低下が少ないことが分かる。これは外層にVを含む化
合物層があると切削時に低融点のV酸化物が生成し、そ
の潤滑効果によって刃先温度が減少し、結果としてドリ
ル寿命が延長したものと考えられる。外層のV(CN)
あるいは(TiV)(CN)が無い場合は、有る場合と
較べて相対的に寿命が低下している。特に外層にV(C
N)を被覆していない場合や試料番号22のごとく外層
にV(CN)を付けず、かつ硬質皮膜層がVを含まない
TiAlNであるときはその低下が大きい。比較例の試
料番号26の硬質皮膜層の厚さを10μmと大きくした
場合であるが、ドリル寿命が大きく低下している。寿命
後の刃先を観察すると、皮膜の剥離により刃先が局部的
に大きくえぐられており、切削不能に陥ったことが分か
った。内層の応力緩和層の存在は刃先の摩耗に対し直接
的な影響は無いが、皮膜の局部的な剥離を抑制してい
る。
Table 2 shows that the tool life is increased by coating the outer layer with a V (CN) film. Further, even when the outer layer does not have a V (CN) film, it can be seen that the use of a (TiAlV) (CN) layer containing V in the hard coating layer causes a relatively small reduction in life. This is presumably because if a compound layer containing V is present in the outer layer, a low-melting V oxide is generated during cutting, and the lubricating effect reduces the cutting edge temperature, resulting in an extended drill life. V (CN) of outer layer
Alternatively, when there is no (TiV) (CN), the life is relatively shorter than when there is. In particular, V (C
N) is not coated, or when V (CN) is not added to the outer layer as in Sample No. 22 and the hard coating layer is TiAlN containing no V, the decrease is large. In the case where the thickness of the hard coating layer of the sample No. 26 of the comparative example is increased to 10 μm, the drill life is greatly reduced. Observation of the cutting edge after the service life revealed that the cutting edge had been locally largely hollowed out due to peeling of the coating, and that cutting was impossible. The presence of the inner layer of the stress relaxation layer has no direct effect on the wear of the cutting edge, but suppresses local peeling of the film.

【0016】[0016]

【発明の効果】本発明を適用することにより、皮膜内部
応力の緩和による皮膜の耐剥離性の向上、皮膜の潤滑効
果による切削中の刃先温度の低下の相乗効果の結果、苛
酷な切削条件に耐える優れた切削工具とすることがて
き、本発明は超硬合金工具のみならず、高速度工具鋼や
TiCN基サーメットなどの被覆硬質工具に適用出来
る。
By applying the present invention, the peeling resistance of the coating is improved by relaxing the internal stress of the coating, and the synergistic effect of lowering the cutting edge temperature during cutting by the lubricating effect of the coating results in a severe cutting condition. The present invention can be applied not only to cemented carbide tools but also to coated hard tools such as high-speed tool steel and TiCN-based cermet.

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 TiとAlを主成分とする窒化物、炭窒
化物もしくは炭酸窒化物からなる硬質皮膜を被覆した被
覆硬質合金において、前記硬質皮膜と被覆基体の間に内
層としてTiN膜、さらに、前記硬質皮膜の外層にV
(CN)又は(TiV)(CN)膜を被覆したことを特
徴とする被覆硬質工具。
1. A coated hard alloy coated with a hard coating composed of a nitride, carbonitride or carbonitride containing Ti and Al as main components, wherein a TiN film is provided as an inner layer between the hard coating and the coated substrate. V is applied to the outer layer of the hard coating.
A coated hard tool coated with a (CN) or (TiV) (CN) film.
【請求項2】 請求項1記載の被覆硬質工具において、
前記硬質皮膜の厚さが0.5乃至5μm、基体と接する
内層のTiN膜の厚さが0.1乃至5μm、外層の膜の
厚さが0.1乃至3μmであることを特徴とする被覆硬
質工具。
2. The coated hard tool according to claim 1, wherein
The coating, wherein the thickness of the hard coating is 0.5 to 5 μm, the thickness of the inner TiN film in contact with the substrate is 0.1 to 5 μm, and the thickness of the outer layer is 0.1 to 3 μm. Hard tool.
【請求項3】 請求項1乃至2記載の被覆硬質工具にお
いて、前記硬質皮膜を(TiAl)(CN)又は(Ti
AlV)(CN)としたことを特徴とする被覆硬質工
具。
3. The coated hard tool according to claim 1, wherein said hard coating is made of (TiAl) (CN) or (Ti).
A coated hard tool made of AlV) (CN).
【請求項4】 請求項1乃至3記載の被覆硬質工具にお
いて、前記外層をV(CN)としたことを特徴とする被
覆硬質工具。
4. The coated hard tool according to claim 1, wherein the outer layer is V (CN).
【請求項5】 請求項1乃至4記載の被覆硬質工具にお
いて、前記外層のV(CN)膜の厚さが0.1乃至2μ
mであることを特徴とする被覆硬質工具。
5. The coated hard tool according to claim 1, wherein a thickness of the V (CN) film of the outer layer is 0.1 to 2 μm.
m. A coated hard tool characterized in that m.
JP28236398A 1998-10-05 1998-10-05 Coated hard tool Expired - Fee Related JP4094746B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28236398A JP4094746B2 (en) 1998-10-05 1998-10-05 Coated hard tool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28236398A JP4094746B2 (en) 1998-10-05 1998-10-05 Coated hard tool

Publications (2)

Publication Number Publication Date
JP2000107906A true JP2000107906A (en) 2000-04-18
JP4094746B2 JP4094746B2 (en) 2008-06-04

Family

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008188737A (en) * 2007-02-06 2008-08-21 Mitsubishi Materials Corp Surface coated cutting tool having hard coating layer showing excellent chipping resistance in heavy cutting of difficult-to-cut material
WO2009104273A1 (en) * 2008-02-22 2009-08-27 ユケン工業株式会社 Iron base alloy product with composite coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008188737A (en) * 2007-02-06 2008-08-21 Mitsubishi Materials Corp Surface coated cutting tool having hard coating layer showing excellent chipping resistance in heavy cutting of difficult-to-cut material
WO2009104273A1 (en) * 2008-02-22 2009-08-27 ユケン工業株式会社 Iron base alloy product with composite coating

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