IT1064997B - FLUORINATED MEMBRANE AT CATION EXCHANGE AND ITS USE IN THE ELECTROLYSIS OF AN ALKALINE METAL HALIDE - Google Patents

FLUORINATED MEMBRANE AT CATION EXCHANGE AND ITS USE IN THE ELECTROLYSIS OF AN ALKALINE METAL HALIDE

Info

Publication number
IT1064997B
IT1064997B IT2656676A IT2656676A IT1064997B IT 1064997 B IT1064997 B IT 1064997B IT 2656676 A IT2656676 A IT 2656676A IT 2656676 A IT2656676 A IT 2656676A IT 1064997 B IT1064997 B IT 1064997B
Authority
IT
Italy
Prior art keywords
electrolysis
copolymer
cation exchange
metal halide
alkaline metal
Prior art date
Application number
IT2656676A
Other languages
Italian (it)
Inventor
Ukihashi Hiroshi
Asawa Tatsuro
Yamabe Masaaki
Miyake Haruhisa
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP10412275A external-priority patent/JPS5228587A/en
Priority claimed from JP10412175A external-priority patent/JPS5228586A/en
Priority claimed from JP11433775A external-priority patent/JPS5238486A/en
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Application granted granted Critical
Publication of IT1064997B publication Critical patent/IT1064997B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Urology & Nephrology (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1518387 Membranes for chloralkali cells ASAHI GLASS CO Ltd 24 Aug 1976 [29 Aug 1975(2) 23 Sept 1975] 35210/76 Heading C7B [Also in Division C3] Chloralkali electrolysis is conducted in a cell having a fluorinated membrane formed of a copolymer of a fluorovinyl ether having the formula wherein 1 is 0 to 3; m is 0 to 6; n is 0 to 4 and one of 1 and m is not zero; X, X' and X" are the same or different and represent -F or -CF 3 ; A represents -CN, -COF, -COOH, COOR 1 , -COOM or -CONR 2 R 3 ; R 1 represents C 1 to C 10 -alkyl; R 2 and R 3 represent -H or C 1 to C 10 -alkyl and M represents an alkali metal or a quaternary ammonium group and a fluorinated olefin, or a hydrolyzed copolymer thereof. Other fluorovinyl ethers, e.g. perfluoro methyl or perfluoropropyl vinyl ether, fluoroketones, fluoronitroso compounds and fluorothio carbonyl compounds may also be used in the production of the copolymer.
IT2656676A 1975-08-29 1976-08-26 FLUORINATED MEMBRANE AT CATION EXCHANGE AND ITS USE IN THE ELECTROLYSIS OF AN ALKALINE METAL HALIDE IT1064997B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP10412275A JPS5228587A (en) 1975-08-29 1975-08-29 Method for manufacturing an improved fluoropolymer having cation excha nge groups
JP10412175A JPS5228586A (en) 1975-08-29 1975-08-29 Method for manufacturing an improved fluoropolymer having cation excha nge groups
JP11433775A JPS5238486A (en) 1975-09-23 1975-09-23 Fluorine-containing cation exchange resin membrane

Publications (1)

Publication Number Publication Date
IT1064997B true IT1064997B (en) 1985-02-25

Family

ID=27310159

Family Applications (1)

Application Number Title Priority Date Filing Date
IT2656676A IT1064997B (en) 1975-08-29 1976-08-26 FLUORINATED MEMBRANE AT CATION EXCHANGE AND ITS USE IN THE ELECTROLYSIS OF AN ALKALINE METAL HALIDE

Country Status (4)

Country Link
DE (1) DE2638791B2 (en)
FR (1) FR2333824A1 (en)
GB (1) GB1518387A (en)
IT (1) IT1064997B (en)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4147599A (en) * 1977-07-19 1979-04-03 Diamond Shamrock Corporation Production of alkali metal carbonates in a cell having a carboxyl membrane
FR2359220A2 (en) * 1976-07-21 1978-02-17 Diamond Shamrock Corp Electrolytic prodn. of alkali metal carbonate - using two-compartment cell with fluorinated copolymer membrane
JPS5349090A (en) * 1976-10-15 1978-05-04 Asahi Glass Co Ltd Preparation of fluorinated plymer containing ion exchange group
FR2388012A1 (en) * 1977-04-20 1978-11-17 Du Pont FLUORINE POLYMER ION EXCHANGER CONTAINING CARBOXYL GROUPS AND FILMS AND MEMBRANES CONSTITUTED OF THIS POLYMER
FR2388014A1 (en) * 1977-04-20 1978-11-17 Du Pont Fluoro-polymer ion exchangers contg. carboxylic gps. - esp. for chlorine-alkali electrolysis cells giving high current yields
NL7804322A (en) * 1977-05-04 1978-11-07 Asahi Glass Co Ltd PROCESS FOR PREPARING SODIUM HYDROXIDE BY ELECTROLYZING SODIUM CHLORIDE.
JPS53149881A (en) * 1977-06-03 1978-12-27 Asahi Glass Co Ltd Strengthened cation exchange resin membrane and production thereof
US4281092A (en) 1978-11-30 1981-07-28 E. I. Du Pont De Nemours And Company Vulcanizable fluorinated copolymers
US4329434A (en) * 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated cation exchange membrane and process for producing the same
US4233122A (en) * 1979-06-01 1980-11-11 Olin Corporation Electrolytic process for potassium hydroxide
JPS5629685A (en) * 1979-08-14 1981-03-25 Asahi Glass Co Ltd Fluorine containing cation exchange membrane for electrolysis
JPS5655577A (en) 1979-10-06 1981-05-16 Toyo Soda Mfg Co Ltd Electrolyzing method for alkali metal halide
DE3071223D1 (en) * 1980-02-05 1985-12-19 Asahi Glass Co Ltd Process for producing fluorinated polymer ion-exchange membranes
US5023362A (en) * 1980-04-03 1991-06-11 E. I. Du Pont De Nemours And Company Alkyl perfluoro(2-methyl-5-oxo-3-oxahexanoate)
JPS5831394B2 (en) * 1980-04-30 1983-07-05 旭硝子株式会社 Method for producing alkali hydroxide
US4515989A (en) * 1980-06-11 1985-05-07 The Dow Chemical Company Preparation decarboxylation and polymerization of novel acid flourides and resulting monomers
US4470889A (en) * 1980-06-11 1984-09-11 The Dow Chemical Company Electrolytic cell having an improved ion exchange membrane and process for operating
US4330654A (en) * 1980-06-11 1982-05-18 The Dow Chemical Company Novel polymers having acid functionality
US4337137A (en) * 1980-06-11 1982-06-29 The Dow Chemical Company Composite ion exchange membranes
US4358412A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Preparation of vinyl ethers
US4804727A (en) * 1980-06-11 1989-02-14 The Dow Chemical Company Process to produce novel fluorocarbon vinyl ethers and resulting polymers
US4337211A (en) 1980-06-11 1982-06-29 The Dow Chemical Company Fluorocarbon ethers having substituted halogen site(s) and process to prepare
CA1214433A (en) * 1980-11-05 1986-11-25 Toyo Soda Manufacturing Co., Ltd. Method for manufacturing cation exchange membrane
FR2545495B1 (en) * 1983-05-02 1987-02-06 Du Pont MEMBRANES CONSISTING OF A FLUORINATED ION EXCHANGER POLYMER CONTAINING CARBOXYLIC GROUPS, ELECTROLYSIS METHOD AND ELECTROCHEMICAL CELL USING THE SAME
US4859745A (en) * 1987-12-22 1989-08-22 The Dow Chemical Company Stratified fibrous fluoropolymer compositions and process for forming such fluoropolymers
IT1230714B (en) * 1989-02-10 1991-10-29 Solvay PROCESS OF MANUFACTURING A SULPHIDE OF AN ALKALINE METAL.
IT1251419B (en) * 1991-10-23 1995-05-09 Solvay ELECTROLYSIS CELL FOR THE PRODUCTION OF A GAS
US5252193A (en) * 1991-11-04 1993-10-12 E. I. Du Pont De Nemours And Company Controlled roughening of reinforced cation exchange membrane
EP0545068A3 (en) * 1991-11-08 1993-12-22 Du Pont Wetting of diaphragms
BE1005716A3 (en) * 1992-03-09 1993-12-28 Solvay Fabricatiion process of sodium hydroxide.
AU4576893A (en) * 1992-07-30 1994-03-03 Imperial Chemical Industries Plc Fluorinated polymers
US7071271B2 (en) 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7074841B2 (en) 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7265162B2 (en) 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7179847B2 (en) 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7259208B2 (en) 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7060756B2 (en) 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
JP2012505948A (en) 2008-10-22 2012-03-08 ダイキン工業株式会社 Perfluoroelastomer composition

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL96474C (en) * 1949-07-09
US2827426A (en) * 1954-02-12 1958-03-18 Rohm & Haas Cationic permselective membranes and their use in electrolysis
US3257334A (en) * 1963-01-21 1966-06-21 American Mach & Foundry Electrodialysis membrane from perhalogenated fluorocarbons
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
JPS5141678B1 (en) * 1964-08-07 1976-11-11
GB1145445A (en) * 1966-02-16 1969-03-12 Du Pont Fluorinated perfluorovinylethers, their preparation and copolymers thereof
US3484503A (en) * 1967-06-19 1969-12-16 Du Pont Blends of fluorinated polymers
US3692569A (en) * 1970-02-12 1972-09-19 Du Pont Surface-activated fluorocarbon objects
US3657104A (en) * 1970-11-05 1972-04-18 Ionics Bifunctional cation exchange membranes and their use in electrolyticcells
JPS5414596B2 (en) * 1974-02-04 1979-06-08
JPS551351B2 (en) * 1974-03-07 1980-01-12

Also Published As

Publication number Publication date
FR2333824A1 (en) 1977-07-01
FR2333824B1 (en) 1980-12-26
GB1518387A (en) 1978-07-19
DE2638791A1 (en) 1977-03-03
DE2638791B2 (en) 1979-07-19

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