IL92779A - Preparations in the form of a stable emulsion of water-insoluble organic pesticides, their use and preparation - Google Patents
Preparations in the form of a stable emulsion of water-insoluble organic pesticides, their use and preparationInfo
- Publication number
- IL92779A IL92779A IL9277989A IL9277989A IL92779A IL 92779 A IL92779 A IL 92779A IL 9277989 A IL9277989 A IL 9277989A IL 9277989 A IL9277989 A IL 9277989A IL 92779 A IL92779 A IL 92779A
- Authority
- IL
- Israel
- Prior art keywords
- formulation
- emulsion
- pesticide
- water
- nonionic
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 59
- 239000000575 pesticide Substances 0.000 title claims description 55
- 238000009472 formulation Methods 0.000 title claims description 41
- 239000000839 emulsion Substances 0.000 title claims description 28
- 238000002360 preparation method Methods 0.000 title description 3
- 239000002245 particle Substances 0.000 claims description 49
- 229920000126 latex Polymers 0.000 claims description 42
- 239000004816 latex Substances 0.000 claims description 36
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- 239000004094 surface-active agent Substances 0.000 claims description 21
- 239000000178 monomer Substances 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 19
- 239000005944 Chlorpyrifos Substances 0.000 claims description 13
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical group CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 claims description 13
- 230000000087 stabilizing effect Effects 0.000 claims description 12
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical group CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 claims description 10
- 230000000361 pesticidal effect Effects 0.000 claims description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 7
- 125000003010 ionic group Chemical group 0.000 claims description 7
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- 238000000034 method Methods 0.000 claims description 5
- 241000607479 Yersinia pestis Species 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical group CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 claims description 2
- 239000007771 core particle Substances 0.000 claims description 2
- 230000000063 preceeding effect Effects 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 15
- 239000007787 solid Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 13
- 230000002209 hydrophobic effect Effects 0.000 description 8
- 239000003090 pesticide formulation Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 230000008878 coupling Effects 0.000 description 6
- 238000010168 coupling process Methods 0.000 description 6
- 238000005859 coupling reaction Methods 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 239000002917 insecticide Substances 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
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- 239000004009 herbicide Substances 0.000 description 4
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- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 4
- WJJBIYLGJUVNJX-UHFFFAOYSA-N pyrimidine-2-sulfonamide Chemical compound NS(=O)(=O)C1=NC=CC=N1 WJJBIYLGJUVNJX-UHFFFAOYSA-N 0.000 description 4
- 238000013112 stability test Methods 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- XJFIKRXIJXAJGH-UHFFFAOYSA-N 5-chloro-1,3-dihydroimidazo[4,5-b]pyridin-2-one Chemical group ClC1=CC=C2NC(=O)NC2=N1 XJFIKRXIJXAJGH-UHFFFAOYSA-N 0.000 description 2
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- 235000007320 Avena fatua Nutrition 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 239000005945 Chlorpyrifos-methyl Substances 0.000 description 2
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- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
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- 125000005325 aryloxy aryl group Chemical group 0.000 description 2
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- DFYKHEXCUQCPEB-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)C(C)=C DFYKHEXCUQCPEB-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
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- 238000011156 evaluation Methods 0.000 description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
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- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229920000847 nonoxynol Polymers 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
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- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
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- 241000209764 Avena fatua Species 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
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- 241000633318 Culex pipiens molestus Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
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- 239000005977 Ethylene Substances 0.000 description 1
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- 239000004165 Methyl ester of fatty acids Substances 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28656988A | 1988-12-19 | 1988-12-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL92779A0 IL92779A0 (en) | 1990-09-17 |
| IL92779A true IL92779A (en) | 1994-06-24 |
Family
ID=23099204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL9277989A IL92779A (en) | 1988-12-19 | 1989-12-18 | Preparations in the form of a stable emulsion of water-insoluble organic pesticides, their use and preparation |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0374796B1 (da) |
| JP (1) | JPH02282302A (da) |
| AU (1) | AU620953B2 (da) |
| BR (1) | BR8906686A (da) |
| CA (1) | CA2005883C (da) |
| DE (1) | DE68918923T2 (da) |
| DK (1) | DK642789A (da) |
| FI (1) | FI97852C (da) |
| IL (1) | IL92779A (da) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4005153A1 (de) * | 1990-02-17 | 1991-08-22 | Hoechst Ag | Hochkonzentrierte emulgierbare konzentrate von neophanen und azaneophanen zur anwendung im pflanzenschutz |
| DE4005154A1 (de) * | 1990-02-17 | 1991-08-22 | Hoechst Ag | Wasserdispergierbare granulate von neophanen und azaneophanen zur anwendung im pflanzenschutz |
| FR2696006B1 (fr) * | 1992-09-21 | 1995-04-28 | Alcatel Cable | Dispositif de contrôle de qualité d'un gainage du type polyéthylène. |
| AU685827B2 (en) * | 1994-06-24 | 1998-01-29 | Dow Chemical Company, The | Novel amphipathic graft copolymers, their preparation, compositions thereof, and methods of their use |
| JP3914288B2 (ja) * | 1995-09-20 | 2007-05-16 | 住化武田農薬株式会社 | 安定化された水性乳化懸濁状農薬組成物およびその製造法 |
| AU5133399A (en) * | 1998-07-28 | 2000-02-21 | Stepan Company | Polymer latexes prepared from ethylenically unsaturated amine salts |
| GB0114197D0 (en) | 2001-06-11 | 2001-08-01 | Syngenta Ltd | Reactive polymeric surfactants |
| FR2826593B1 (fr) * | 2001-06-27 | 2004-04-16 | Rhodia Chimie Sa | Dispersion comprenant une emulsion dont la phase aqueuse est de force ionique elevee, preparation et utilisation |
| JP5972530B2 (ja) | 2008-02-04 | 2016-08-17 | ダウ アグロサイエンシィズ エルエルシー | 農業上の有効成分を含有する安定化された水中油型エマルション |
| AR079413A1 (es) * | 2009-10-07 | 2012-01-25 | Basf Se | Uso de particulas polimericas que comprenden insecticida para mejorar la movilidad en el suelo de insecticidas, formulaciones insecticidas, particulas polimericas que comprenden insecticida, y metodos para controlar plagas |
| WO2013090501A1 (en) * | 2011-12-15 | 2013-06-20 | Dow Agrosciences Llc | High load aqueous suspension concentrate of an active ingredient |
| NZ630039A (en) | 2012-03-08 | 2016-05-27 | Dow Agrosciences Llc | Organic colloid-stabilized emulsion for controlling pesticide spray drift |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1079432A (en) * | 1974-09-17 | 1980-06-10 | Tsang J. Chen | Uniform, efficient distribution of hydrophobic materials through hydrophilic colloid layers, and products useful therefor |
| US4303642A (en) * | 1980-05-07 | 1981-12-01 | The Dow Chemical Company | Stable insecticide containing latexes, method of making and method of distributing insecticide |
| US4337185A (en) * | 1980-06-23 | 1982-06-29 | The Dow Chemical Company | Process for making cationic structured particle latexes using reactive polymeric surfactants |
| JPS58140001A (ja) * | 1982-02-09 | 1983-08-19 | Toagosei Chem Ind Co Ltd | 液状農薬 |
| JPS5927801A (ja) * | 1982-08-06 | 1984-02-14 | Tanabe Seiyaku Co Ltd | 防虫ラテツクス組成物およびその製法 |
| DE3541266A1 (de) * | 1985-11-22 | 1987-05-27 | Gerd Adamy | Schuh mit beheizbarer schuhsohle |
| JP2517718B2 (ja) * | 1987-02-07 | 1996-07-24 | 義之 大串 | 硼酸を用いた白蟻・ゴキブリ退治用塗布剤 |
| GB8710105D0 (en) * | 1987-04-29 | 1987-06-03 | Ici Plc | Pesticidal formulations |
| IL91421A0 (en) * | 1988-09-01 | 1990-04-29 | Dow Chemical Co | Stable concentrate formulations and emulsions of water-insoluble organic pesticides,their use and preparation |
-
1989
- 1989-12-18 IL IL9277989A patent/IL92779A/en unknown
- 1989-12-18 CA CA002005883A patent/CA2005883C/en not_active Expired - Fee Related
- 1989-12-18 JP JP1326193A patent/JPH02282302A/ja active Pending
- 1989-12-18 DK DK642789A patent/DK642789A/da not_active Application Discontinuation
- 1989-12-18 AU AU46934/89A patent/AU620953B2/en not_active Ceased
- 1989-12-18 FI FI896049A patent/FI97852C/fi not_active IP Right Cessation
- 1989-12-18 DE DE68918923T patent/DE68918923T2/de not_active Expired - Fee Related
- 1989-12-18 EP EP89123389A patent/EP0374796B1/en not_active Expired - Lifetime
- 1989-12-19 BR BR898906686A patent/BR8906686A/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FI97852C (fi) | 1997-03-10 |
| DK642789D0 (da) | 1989-12-18 |
| AU620953B2 (en) | 1992-02-27 |
| FI97852B (fi) | 1996-11-29 |
| DK642789A (da) | 1990-06-20 |
| IL92779A0 (en) | 1990-09-17 |
| BR8906686A (pt) | 1990-09-11 |
| EP0374796A2 (en) | 1990-06-27 |
| CA2005883A1 (en) | 1990-06-19 |
| EP0374796B1 (en) | 1994-10-19 |
| AU4693489A (en) | 1990-06-21 |
| FI896049A0 (fi) | 1989-12-18 |
| DE68918923D1 (de) | 1994-11-24 |
| JPH02282302A (ja) | 1990-11-19 |
| DE68918923T2 (de) | 1995-02-23 |
| CA2005883C (en) | 1999-10-05 |
| EP0374796A3 (en) | 1992-03-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| KB | Patent renewed | ||
| KB | Patent renewed |