IL43880A - Process for the production of N-phosphonomethyl glycines - Google Patents
Process for the production of N-phosphonomethyl glycinesInfo
- Publication number
- IL43880A IL43880A IL43880A IL4388073A IL43880A IL 43880 A IL43880 A IL 43880A IL 43880 A IL43880 A IL 43880A IL 4388073 A IL4388073 A IL 4388073A IL 43880 A IL43880 A IL 43880A
- Authority
- IL
- Israel
- Prior art keywords
- acetic acid
- medium
- aqueous electrolytic
- carbon
- aqueous
- Prior art date
Links
- 150000002333 glycines Chemical class 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 8
- 239000002609 medium Substances 0.000 claims 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 6
- -1 2,2,2-tri-phenylethyl Chemical group 0.000 claims 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 4
- 229910002804 graphite Inorganic materials 0.000 claims 4
- 239000010439 graphite Substances 0.000 claims 4
- 239000012736 aqueous medium Substances 0.000 claims 3
- 125000000579 2,2-diphenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(C1=C([H])C([H])=C([H])C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 2
- 230000002378 acidificating effect Effects 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 125000004343 1-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- KOJRWLCMBRYCBJ-UHFFFAOYSA-N 2-[benzyl(phosphonomethyl)amino]acetic acid Chemical compound OC(=O)CN(CP(O)(O)=O)CC1=CC=CC=C1 KOJRWLCMBRYCBJ-UHFFFAOYSA-N 0.000 claims 1
- AZIHIQIVLANVKD-UHFFFAOYSA-N N-(phosphonomethyl)iminodiacetic acid Chemical compound OC(=O)CN(CC(O)=O)CP(O)(O)=O AZIHIQIVLANVKD-UHFFFAOYSA-N 0.000 claims 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- WBLIXGSTEMXDSM-UHFFFAOYSA-N chloromethane Chemical compound Cl[CH2] WBLIXGSTEMXDSM-UHFFFAOYSA-N 0.000 claims 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 229960002449 glycine Drugs 0.000 claims 1
- 235000013905 glycine and its sodium salt Nutrition 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 229910000510 noble metal Inorganic materials 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/23—Oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31749872A | 1972-12-21 | 1972-12-21 | |
| US00385932A US3835000A (en) | 1972-12-21 | 1973-08-06 | Electrolytic process for producing n-phosphonomethyl glycine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL43880A0 IL43880A0 (en) | 1974-03-14 |
| IL43880A true IL43880A (en) | 1976-05-31 |
Family
ID=26980991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL43880A IL43880A (en) | 1972-12-21 | 1973-12-20 | Process for the production of N-phosphonomethyl glycines |
Country Status (23)
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1494197A (en) * | 1973-11-30 | 1977-12-07 | Ici Ltd | Electrochemical process for the preparation of n-phosphonomethyl glycine |
| US3991095A (en) * | 1975-12-29 | 1976-11-09 | Monsanto Company | N-thiolcarbonyl derivatives of N-phosphonomethylglycine |
| US4047927A (en) * | 1976-08-13 | 1977-09-13 | Monsanto Company | N-(2-hydroxyalkyl) derivatives of N-phosphonomethylglycine and the herbicidal use thereof |
| US4063922A (en) * | 1976-08-13 | 1977-12-20 | Monsanto Company | N-(2-hydroxyalkyl) derivatives of N-phosphonomethylglycine for treatment of sugarcane |
| MX4703E (es) * | 1976-12-20 | 1982-08-04 | Monsanto Co | Procedimiento mejorado para la preparacion de mono y disales de n-fosfonometilglicina |
| US4105432A (en) * | 1977-07-18 | 1978-08-08 | Monsanto Company | Cyclized derivatives of N-(2-hydroxyalkyl)-N-phosphonomethylglycine compounds |
| US4218235A (en) * | 1978-07-10 | 1980-08-19 | Monsanto Company | Ester derivatives of n-trifluoroacetyl-n-phosphonomethylglycine and the herbicidal use thereof |
| US4180394A (en) * | 1978-07-10 | 1979-12-25 | Monsanto Company | Derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates and the herbicidal use thereof |
| US4300942A (en) * | 1978-09-29 | 1981-11-17 | Monsanto Company | N-(Substituted carbonyl) derivatives of N-phos-phinylmethylglycinates and the herbicidal use thereof |
| US4251258A (en) * | 1978-09-29 | 1981-02-17 | Monsanto Company | N-(Substituted carbonyl) derivatives of N-phosphinylmethylglycinates and the herbicidal use thereof |
| US4251256A (en) * | 1978-12-22 | 1981-02-17 | Monsanto Company | Herbicidal N-substituted ethylene derivatives of N-phosphonomethylglycine |
| US4261727A (en) * | 1979-08-02 | 1981-04-14 | Monsanto Company | Herbicidal N-substituted triesters of N-phosphonomethylglycine |
| US4315765A (en) * | 1980-12-04 | 1982-02-16 | Stauffer Chemical Company | Trialkylsulfonium salts of n-phosphonomethylglycine and their use as plant growth regulators and herbicides |
| US4376644A (en) * | 1980-12-04 | 1983-03-15 | Stauffer Chemical Company | Tri-mixed alkylsulfonium salts of N-phosphonomethylglycine and their use as plant growth regulators and herbicides |
| US4384880A (en) * | 1980-12-04 | 1983-05-24 | Stauffer Chemical Company | Trialkylsulfonium salts of N-phosphonomethyl-glycine and their use as plant growth regulators and herbicides |
| US4328027A (en) * | 1981-04-16 | 1982-05-04 | Stauffer Chemical Company | Di-triethylamine salt of N,N'-bis-carboethoxymethyl-N,N'-bis-phosphonomethylurea and its use as a plant growth regulator |
| US4437874A (en) | 1981-11-25 | 1984-03-20 | Stauffer Chemical Company | Tri-mixed alkylsulfonium salts of N-phosphonomethylgylcine and their use as plant growth regulators and herbicides |
| IL65187A (en) * | 1982-03-08 | 1985-03-31 | Geshuri Lab Ltd | N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them |
| US4472189A (en) * | 1982-12-27 | 1984-09-18 | Stauffer Chemical Co. | Stannic N-phosphonomethyglycine and its use as a herbicide |
| FR2560198B1 (fr) * | 1984-02-23 | 1987-05-07 | Rhone Poulenc Agrochimie | Esters de la famille de la n-phosphonomethylglycine et leur utilisation pour la preparation d'herbicides connus |
| ES8603901A1 (es) * | 1983-07-27 | 1986-01-01 | Rhone Poulenc Agrochimie | Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico |
| IL77364A (en) * | 1984-12-28 | 1991-01-31 | Monsanto Co | Thermal dealkylation of n-alkyl n-phosphono-methylglycine |
| US4921991A (en) * | 1985-02-22 | 1990-05-01 | Guy Lacroix | Preparation of esters of the N-phosphonomethylglycine and the N-phosphonomethyl glycines |
| US4804500A (en) * | 1985-04-22 | 1989-02-14 | Monsanto Company | Amine dealkylation process |
| US4684483A (en) * | 1985-09-23 | 1987-08-04 | Monsanto Company | Preparation of N-substituted amino acids |
| FR2635522B1 (fr) * | 1988-08-18 | 1990-11-16 | Rhone Poulenc Agrochimie | N-sulfonomethylglycinate procede de preparation, utilisation dans la preparation d'herbicides de type glyphosate |
| US5187292A (en) * | 1988-08-18 | 1993-02-16 | Rhone-Poulenc Agrochimie | N-sulfomethylglycinate, use in the preparation of herbicides of the glyphosate type |
| US6232494B1 (en) | 1998-02-12 | 2001-05-15 | Monsanto Company | Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine |
| JP2002510305A (ja) * | 1998-02-12 | 2002-04-02 | モンサント カンパニー | Ｎ―置換グリホサートの酸化によるグリホサートの製造方法 |
| US6417133B1 (en) | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
| AR038654A1 (es) * | 2000-05-22 | 2005-01-26 | Monsanto Technology Llc | Sistemas de reaccion para producir compuestos de n-(fosfonometil) glicina |
| AR051926A1 (es) * | 2004-09-15 | 2007-02-21 | Monsanto Technology Llc | Catalizadores de oxidacion, procedimientos de preparacion de dichos catalizadores y proceso para la elaboracion de n-( fosfonometil)glicina o una sal de la misma |
| EP1863824B1 (en) | 2005-04-01 | 2016-10-19 | Monsanto Technology, LLC | Control of n-(phosphonomethyl) iminodiacetic acid conversion in manufacture of glyphosate |
| US8252953B2 (en) | 2008-05-01 | 2012-08-28 | Monsanto Technology Llc | Metal utilization in supported, metal-containing catalysts |
-
1973
- 1973-08-06 US US00385932A patent/US3835000A/en not_active Expired - Lifetime
- 1973-11-21 PH PH15246A patent/PH10205A/en unknown
- 1973-11-30 BR BR9442/73A patent/BR7309442D0/pt unknown
- 1973-12-18 RO RO7377044A patent/RO64474A/ro unknown
- 1973-12-19 ES ES421614A patent/ES421614A1/es not_active Expired
- 1973-12-19 NL NL7317370.A patent/NL163218C/xx not_active IP Right Cessation
- 1973-12-20 BG BG025303A patent/BG24411A3/xx unknown
- 1973-12-20 PL PL1973167559A patent/PL94988B1/pl unknown
- 1973-12-20 FR FR7345835A patent/FR2211468B1/fr not_active Expired
- 1973-12-20 DK DK694073AA patent/DK134559B/da not_active IP Right Cessation
- 1973-12-20 HU HUMO891A patent/HU168961B/hu not_active IP Right Cessation
- 1973-12-20 JP JP48142934A patent/JPS5111094B2/ja not_active Expired
- 1973-12-20 SE SE7317193A patent/SE403379B/xx unknown
- 1973-12-20 IT IT3554/73A patent/IT1001432B/it active
- 1973-12-20 AR AR251626A patent/AR216882A1/es active
- 1973-12-20 YU YU3305/73A patent/YU37363B/xx unknown
- 1973-12-20 CA CA188,637A patent/CA1001992A/en not_active Expired
- 1973-12-20 IE IE2308/73A patent/IE38667B1/xx unknown
- 1973-12-20 IL IL43880A patent/IL43880A/en unknown
- 1973-12-20 CH CH1796673A patent/CH592105A5/xx not_active IP Right Cessation
- 1973-12-20 EG EG480/73A patent/EG11507A/xx active
- 1973-12-20 GB GB5908373A patent/GB1428499A/en not_active Expired
- 1973-12-20 DD DD175538A patent/DD110503A5/xx unknown
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