IE65637B1 - Smoking article - Google Patents

Smoking article

Info

Publication number
IE65637B1
IE65637B1 IE205085A IE205085A IE65637B1 IE 65637 B1 IE65637 B1 IE 65637B1 IE 205085 A IE205085 A IE 205085A IE 205085 A IE205085 A IE 205085A IE 65637 B1 IE65637 B1 IE 65637B1
Authority
IE
Ireland
Prior art keywords
article according
fuel element
generating means
article
aerosol generating
Prior art date
Application number
IE205085A
Other versions
IE852050L (en
Inventor
Jr Andrew Jackson Sensabaugh
Henry Thomas Ridings
Iv John Hughes Reynolds
Michael David Shannon
Chandra Kumar Banerjee
Ernest Gilbert Farrier
Original Assignee
Reynolds Tobacco Co R
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/650,604 external-priority patent/US4793365A/en
Application filed by Reynolds Tobacco Co R filed Critical Reynolds Tobacco Co R
Priority to IE940573A priority Critical patent/IE65679B1/en
Priority to IE940574A priority patent/IE65680B1/en
Priority to IE950598A priority patent/IE80788B1/en
Priority to IE950597A priority patent/IE79075B1/en
Publication of IE852050L publication Critical patent/IE852050L/en
Publication of IE65637B1 publication Critical patent/IE65637B1/en

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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40Constructional details, e.g. connection of cartridges and battery parts
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10Chemical features of tobacco products or tobacco substitutes
    • A24B15/16Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • A24B15/165Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10Chemical features of tobacco products or tobacco substitutes
    • A24B15/16Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/04Cigars; Cigarettes with mouthpieces or filter-tips
    • A24D1/042Cigars; Cigarettes with mouthpieces or filter-tips with mouthpieces
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/18Selection of materials, other than tobacco, suitable for smoking
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/22Cigarettes with integrated combustible heat sources, e.g. with carbonaceous heat sources
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F42/00Simulated smoking devices other than electrically operated; Component parts thereof; Manufacture or testing thereof
    • A24F42/60Constructional details

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Seasonings (AREA)
  • Portable Nailing Machines And Staplers (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
  • Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
  • Saccharide Compounds (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Materials For Medical Uses (AREA)
  • Seal Device For Vehicle (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The cigarette has a carbonaceous fuel element. A separate aerosol generator has a substrate bearing an aerosol forming material. The fuel element and substrate are arranged in a conductive relationship, so that the heat-stable substrate receives conductive heat transfer throughout the burning time of the fuel element. The fuel element is less than 30mm in length, with a density of at least 5 g/cc. An insulation material can surround part of the fuel element. The insulation is resilient and at least 15 mm thick. The cigarette also has a mouthpiece.

Description

The present invention relates to a smoking article having a front end and a rear end and comprising a fuel element having a lighting end, and a physically separate aerosol generating . means comprising at least one aerosol forming material and being disposed between the lighting end of the fuel element and said rear end. More particularly, the present invention relates to such a smoking article which produces an aerosol that resembles tobacco smoke, and which contains no more than a minimal amount of incomplete combustion or pyrolysis θ products.
Many smoking articles have been proposed through the years, especially over the last 20 to 30 years, but none of these products has ever realized any commercial success.
US-A-4 340 072 describes a proposed cigarette type smoking article with a rod-like fuel element having a cigarette paper overwrap and a central axial passage, an aerosol generating means defined by a chamber and a short filter tip all of which are arranged one behind another. The overall length of the smoking article is 70 mm, and its diameter is 7 mm. The fuel element is a moulding or extrusion of reconstituted tobacco and/or tobacco substitute, e. g. of a mixture of carbon and a binder (SCMC), and the front end of its axial passage may be closed by a plug made from the same material and serving the purpose of closing the central axial passage of the fuel element and thereby assisting even lighting of the article. The chamber of the aerosol generating means contains inhalant material which, when contacted by hot gases produced by the burning fuel element and sucked through its axial passage and through the chamber of the aerosol generating means, purportedly forms an aerosol for inhalation by the smoker. According to the drawings of US-A-4 340 072 the length of the rod-like fuel element is about 73 % of the overall length of the cigaretty type smoking article and therefore about 51 mm.
EP-A-0 117 355 describes a proposed cigarette type smoking article having a carbon heat source with an axial passageway and a separate flavor generator. The heat source (page 2, line 23 to page 7, line 14) is formed by pyrolyzing a preformed, tube-shaped ligno-cellulosic material of e. g. mm or 65 mm length (see Comparative Example 1 and Example 4, respectively) under specified conditions, followed by at least one additional specified process step. The purported flavor generator (page 8, lines 8 to 27) comprises a substrate material, which may be tobacco, alumina, etc., adjacent the mouth end, which is impregnated with or inherently contains at least one thermally releasable flavorant. The flavor generator also may comprise a flavored, foamed core inside the heat source. A conventional filter may be placed after the flavor generator. The purported formation of an aerosol during use is described from page 8, line 28 to page 9, line 8. During pyrolysis the tube-shaped ligno-cellulosic material experiences a maximum dimensional shrinkage of 37,5 % (see page 12, lines 3 and 4) so that from a tube-shaped ligno-cellulosic material with a length of mm a carbon heat source with a length of more than 40 mm is obtained.
Despite decades of interest and effort, there is still no smoking article on the market which provides the benefits and SO advantages associated with conventional cigarette smoking, without delivering considerable quantities of incomplete combustion and pyrolysis products3 It is the object of the present invention to provide a smoking article of the type having a fuel element and a separate aerosol generator which is more efficient during smoking.
According to subject invention this object is achieved by providing a smoking article as defined at the beginning with a resilient insulating member, surrounding at least a portion of the fuel element and comprising inorganic fibers and being at least 0,5 mm thick, and with an overwrap for the insulating member.
In such a smoking article the heat generated by the fuel 'element during smoking is more efficiently used for producing an aerosol resembling the smoke of a conventional smoking article.
The inventive smoking article is capable of producing substantial quantities of aerosol, both initially and over the useful life of the product, without significant thermal, degradation of the aerosol former and without the presence of substantial pyrolysis or incomplete. combustion products, and preferably without substantial quantities of sidestream smoke. Smoking articles in accordance with the present invention are capable of providing the user with the sensations and benefits of cigarette smoking, without burning tobacco.
Preferably, the fuel element is less than about 30 mm in length, more preferably less than 15 mm in length, has a density of at least 0.5 g/cc, and is provided with one or more longitudinal passages. Advantageously, the aerosol generating means includes a heat stable substrate including one or more aerosol forming substances.
Preferably, the heat exchange relationship between the fuel and the aerosol generator is achieved by providing a heat conducting member, such as a metal foil, which efficiently conducts or transfers heat from the addition. provided with member, such as a jacket - being thick, which reduces burning fuel element to the aerosol generating means. This heat conducting member preferably contacts the fuel element and the aerosol generating means around at least a portion of their peripheral surfaces. In at least a part of the fuel element is a peripheral insulating jacket of insulating fibers, the resilient and at least 0.5 mm radial heat loss and assists in retaining and directing heat from the fuel element toward the aerosol generating means. The insulating member preferably overwraps at least part of the fuel element, and advantageously at least part of the aerosol generating means.
Because the preferred fuel element is relatively short, the hot, burning fire cone is always close to the aerosol generating means, which maximizes heat transfer thereto and maximizes the resultant .production of aerosol, especially in embodiments which are provided with a heat conducting member. The preferred use of a relatively short, low mass substrate or carrier as the aerosol generating means, in close proximity to the short fuel element, also increases aerosol production by minimizing the heat sink effect of the substrate. Because the aerosol forming substance is physically separate from the fuel element, it is exposed to substantially lower temperatures than are present in the burning fire cone, thereby minimizing the possibility of thermal degradation of the aerosol former. Moreover, the especially preferred use of a carbonaceous fuel element which is substantially free of volatile organic material eliminates the presence of substantial pyrolysis or incomplete combustion products and eliminates the generation of substantial sidestream smoke.
The smoking article of the present invention normally is provided with a mouthend piece including means, such as a longitudinal passage, for delivering the volatile material produced by the aerosol generating means to the user. Advantageously, the article has the same overall dimensions as a conventional cigarette, and as a result, the mouthend piece and the aerosol delivery means usually extend over more than half the . length of the article. Alternatively, the fuel element and the aerosol generating means may be produced without a built-in mouthend piece or aerosol delivery means, for use with a separate, disposable or reusable mouthend piece.
The smoking article of the present invention also may include a charge or plug of tobacco which may be used to add a tobacco flavor to the aerosol. .Preferably, the tobacco is placed at the mouth end of the aerosol generating means, or it may be mixed with the carrier for the aerosol forming substance. Flavoring agents also may be incorporated into the article to flavor the aerosol delivered to the user.
Preferred embodiments of the invention are capable of delivering at least 0.6 mg of aerosol, measured as wet total particulate matter, in the first 3 puffs, when smoked under FTC smoking conditions. (FTC smoking conditions consist of two seconds of puffing (35 ml total volume) separated by 58 seconds of smolder). More preferred embodiments of the invention are capable of delivering 1.5 mg or more of aerosol in the first 3 puffs. Most preferably, embodiments of the invention are capable of delivering 3 mg or more of aerosol in the first 3 puffs when smoked under FTC smoking conditions. Moreover, preferred embodiments of the invention deliver an average of at least about 0.8 mg of wet total particulate matter per puff for at least about 6 puffs, preferably at least about 10 . puffs, under FTC smoking conditions.
The smoking article of the present invention also is capable of providing an aerosol which is chemically simple, consisting essentially of oxides of carbon, air, water, and the aerosol which carries any desired flavorants or other desired volatile materials, and trace amounts of other materials. The aerosol preferably has no significant mutagenic activity according to the Ames test discussed hereinafter. In addition, the article may be made virtually ashless so that the user does not have to remove any ash during use.
As used herein, and only for the purposes of this application, aerosol is defined to include vapors, gases, particles, and the like, both visible and invisible, and especially those components perceived by the user to be smoke-like, generated by action of the heat from the burning fuel element upon substances contained within the aerosol generating means, or elsewhere in the article. As so defined, the term aerosol" also includes volatile flavoring agents and/or pharmacologically or physiologically active agents, irrespective of whether they produce a visible aerosol.
As used herein, the phrase conductive heat exchange relationship is defined as a physical arrangement of the aerosol generating means and the fuel element whereby heat is transferred by conduction from the burning fuel element to the aerosol generating means substantially throughout the burning period of the fuel element. Conductive heat exchange relationships can be achieved by locating the aerosol generating means in contact with the fuel element and in close proximity to the burning portion 5 of the fuel element, and/or by utilizing a conductive member to carry heat from the burning fuel to the aerosol generating means. Preferably both methods of providing conductive heat transfer are used.
As used herein, the term carbonaceous means 10 primarily comprising carbon.
As used herein, the term insulating means applies to all materials which act primarily as Preferably, these materials do not burn but they may include slow burning carbons and like materials, as well as materials which fuse during use, such as low temperature grades of glass fibers. The insulators have a thermal conductivity in g-cal/(sec) (cm2)(°C/cm), of less than about 0.05, preferably less than about 0.02, most preferably less 20 than *about 0.005. See, Hackh's Chemical Dictionary, (4th ed., 1969) and Lange's Handbook of Chemistry. 10, 272-274 (11th ed., 1973). insulators, during use, It is suggested to use a fuel element which has a plurality of longitudinally extending passages therethrough.
A preferred embodiment of the inventive article comprises a heat conducting member which contacts both the fuel element and the aerosol generator means. Preferably, the heat conducting member is metallic. It is then proposed to use as said metallic member a metallic foil which encompasses at least a portion of both the fuel element and the aerosol generator means. For such an article it is proposed to use a metallic member which encloses a substrate bearing the aerosol forming material. In an alternative embodiment the metallic member is a metallic rod embedded within at least a portion of both the fuel element and the aerosol generator means.
It may be advantageous to have the aerosol generating means at least partially contained within a cavity in the fuel element.
. Preferably, the aerosol generating means comprises a 2θ porous, nonparticulate substrate, having a longitudinal passageway at least partially therethrough.
In a preferred embodiment the aerosol generating means contains a substrate loaded with from about 35 mg to 85 mg of aerosol former. Preferably, at least about 15 weight percent of the aerosol former is delivered as wet total particulate matter under FTC smoking conditions.
A preferred embodiment of the inventive article comprises a charge of tobacco located between the mouth end of the fuel element and the mouth end of the article.
Preferred embodiments of the inventive article are designed such that the fuel element produces substantially no visible sidestream smoke during smolder.
A preferred embodiment of an elongate inventive smoking article comprises a fuel element less than 30 mm in length, a physically separate aerosol generating means including a carrier bearing an aerosol forming material, means for conducting heat from the fuel element to the aerosol generating means, and an insulating member which surrounds at least a portion of the fuel element. Preferably, the heat conducting means comprises a heat conducting member which contacts both the fuel element and the aerosol generating means, and more advantageously the heat conducting member encloses the carrier for the aerosol forming material.
Further advantageous features are subject of enclosed claims to 89. > i 9 j The smoking article of the present invention is described in ; greater detail in the accompanying drawings and in the | 5 detailed description of the invention which follow. l BRIEF DESCRIPTION OF THE DRAWINGS Figures 1 and 2 are longitudinal views of two embodiments of the invention.
The embodiment of the invention illustrated in Fig. 1, which 10 preferably has the diameter of a conventional cigarette, includes a short, combustible carbonaceous fuel element 10, and an abutting aerosol generating means 30. The fuel element 10 may be an element of blowpipe" charcoal, i. e. carbonized wood, a pressed or extruded carbon rod or plug, or an other carbonaceous fuel element, and it is provided with one or several longitudinally extending holes 16.
In this embodiment, the aerosol generating means 30 has a thermally stable conductive carbonaceous substrate, such as a plug of porous carbon, which is impregnated with an aerosol forming substance or substances. This substrate may be provided with an optional axial passageway.
The lighting end 11 of the fuel element 10 may be tapered to improve lightability. 1 The embodiments shown in Figures 1 and 2 include a nonburning insulating jacket 86 around fuel element 10 to insulate and concentrate the heat in the fuel element. These embodiments also help to reduce any fire causing potential of the burning fire cone.
In the embodiment shown in Figure 1, both fuel element 10 and substrate 30 are located within an annular jacket or tube 86 of insulating fibers, such as cetamic (e.g., glass) fibers. Nonburning carbon or graphite fibers may be used in place of ceramic fibers. Fuel element 10 is preferably an extruded carbon plug having a hole 16. In the illustrated embodiment, the lighting end 11 extends, slightly beyond the edge of jacket 86 for ease of lighting.
Substrate 30 is a solid porous carbon material, although other types of substrates may be used. The substrate and the rear portion of the fuel element are surrounded by a piece of aluminum foil 87. As illustrated, this jacketed fuel/substrate unit is coupled to a mouthend piece, such as the elongated cellulose acetate tube 40 shown in the drawing, with an overwrap of conventional cigarette paper 46. The jacket 86 extends to the mouth end of.substrate 30.
The tube 40 also forms an aerosol delivery passage 26 between the aerosol generating means 30 and the mouth end 15 of the article.
The article may include an optional mass or plug of tobacco to contribute flavor to the aerosol. This tobacco charge may be placed at the mouth end of the aerosol generating means 30, or it may be placed in passage 26 at a location spaced from the aerosol generating means 30.
The tube 40 includes an annular section 42 of cellulose acetate tow surrounding an optional plastic, e. g. polypropylene tube 44. As shown in Fig. 1, the jacket 86 extends to the mouth end of substrate 30 but may replace the cellulose acetate rod 42. At the mouth end 15 of tube 44 there is a low efficiency cellulose acetate filter plug 45.
In the embodiment shown in Figure 2, an aluminum macrocapsule 52 is used to enclose a granular substrate 54 and tobacco 56.
This macrocapsule is. preferably positioned entirely within the insulator jacket 86.. In addition, the lighting end 11 of fuel element 10 does not. protrude beyond the forward end of jacket 86. Preferably, the macrocapsule and the rear portion of the fuel element are surrounded by a piece of aluminum foil.
Alternatively, the aluminum foil 52 which surrounds the substrate is only crimped at the mouth end. In such an embodiment, the rear end of the fuel element may be inserted into one end of the foil and a polypropylene tube may be fitted over or placed in abutment with the mouth end of the foil. The entire assembly is overwrapped with fiberglass to a diameter of a conventional cigarette. 3 The granular substrate 54' may be a granular, thermally stable carbon. The capsule 52 is crimped at its ends to enclose the material 54, 56 and to inhibit migration of the aerosol former. The crimped end at the fuel end preferably abuts the rear end of the fuel element to provide for conductive heat transfer. A void spaced formed by the front end of the capsule also helps to inhibit migration of the aerosol former to the fuel. Longitudinal passageways are provided in the crimped ends to permit the passage of air and the aerosol forming substance. Capsule 52 and fuel element 10 may be united by a conventional cigarette paper, a perforated ceramic paper, or a foil strip. If cigarette paper is used, a strip near the rear end of the fuel element should be printed or treated with sodium silicate or other known materials which cause the paper to extinguish.
Upon lighting any of the aforesaid embodiments, the fuel element burns, generating the heat used to volatilize the aerosol forming substance or substances present in the aerosol generating means. These volatile materials are then drawn toward the mouthend, especially during puffing, and into the user’s mouth, akin to the smoke of a conventional cigarette.
Because the fuel element preferably is relatively short, the hot, burning fire cone is always close to the aerosol generating body, which maximizes heat transfer to the aerosol generating means, and production of aerosol, especially when the heat conducting member is used. In the preferred insulating member tends to direct, and concentrate the heat toward the resultant preferred addition, conf ine, central core of the article, thereby increasing the heat transferred to the aerosol forming substance.
Because the aerosol forming substance is physically separate from the fuel element, it is exposed to substantially lower temperatures than are present in the burning fire cone. This minimizes the 4 possibility of former. This during puffing, during preferred separate presence combustion el em.ent of its portion thermal degradation of the aerosol also results in aerosol production but little or no aerosol production smolder. In addition, the use of the carbonaceous fuel elements and a physically aerosol generating means eliminates the of substantial pyrolysis of incomplete products and avoids the production of substantial sidestream smoke.
Because of the small size and burning characteristics of the preferred carbonaceous fuel element employed in the present invention, the fuel usually begins burning over substantially all length within a few puffs. Thus, the fuel element adjacent to the aerosol hot quickly, which transfer to the aerosol during the early and aerosol through exposed of the generating means becomes significantly increases heat generating means, especially middle puffs. Because the preferred fuel element is short, there is never a long section of nonburning fuel to act as a heat sink, as was common in previous thermal aerosol articles. Heat transfer, and therefor delivery, also is enhanced by the use of holes the fuel, which draw hot air to the aerosol generator, especially during puffing.
In the preferred embodiments of the invention, the carbonaceous fuel element, heat conducting insulating means, and passages in the fuel cooperate with the aerosol generator to provide a system which is capable of producing substantial quantities of aerosol, on virtually every puff. The close proximity of the fire cone to the aerosol generator after a few puffs, together with the insulating means, results in high heat delivery both short membe r, during puffing and during the relatively long period of smolder between puffs.
While not wishing to be bound by theory, it is believed that the aerosol generating means is maintained at a relatively high temperature between puffs, and that the additional heat delivered during puffs, which is significantly increased by the hole or holes in the fuel element, is primarily utilized to vaporize the aerosol forming substance. This increased heat transfer makes more efficient use of the available fuel energy, reduces the amount of fuel needed, and helps deliver early aerosol. Further, the conductive heat transfer utilized in the present invention is. believed to reduce the carbon fuel combustion temperature which, it is further believed, reduces the CO/CO2 ratio in the combustion products produced by the fuel. See, e.g., G. Hagg, General Chemistry. at p. 592 (John Wiley & Sons, Iiior genic 1969) .
Furthermore, fuel element, overwrap, and possible source. to by the appropriate selection of the the. insulating jacket, the paper the heat conducting means, it is control the burn properties of the fuel This provides opportunities for control of heat transfer to the aerosol generator, which in turn, alters the number of puffs and/or the amount of aerosol delivered to the user.
In general, the combustible fuel elements which may be employed in practicing the invention are less than about 30 mm long. Advantageously the fuel element is about 20 mm or less, preferably about 15 mm or less in length. Advantageously, the diameter of the fuel element is between about 3 and 8 mm, preferably about 4 to 5 mm. The density of the fuel elements employed' herein has ranged from about 0.5 g/ce to about 1.5 g/cc. Preferably, the density is -greater than 0.7 g/cc., more preferably greater than 0.8 g/cc. Preferably, the fuel is provided with one or more longitudinally extending holes, such as holes 16 in Figures Γ and 2. These holes provide porosity and increase early heat transfer to the substrate by increasing the amount of hot gases which reach the substrate.
The preferred fuel elements employed herein are primarily formed of a- carbonaceous material. Carbonaceous fuel elements are preferably from about 5 to 15 mm, more preferably, from about 8 to 12 mm in length. Carbonaceous fuel elements having these characteristics are sufficient to provide fuel for at least about 7 to 10 puffs, the normal number of puffs generally obtained by smoking a conventional cigarette under FTC conditions.
Preferably, the carbon content of such a fuel element is at least 60 - 70%, most preferably at least about 80% or more by weight. Excellent results have been achieved with fuel elements having a carbon content of above above about 85% by weight. High carbon content fuels are preferred because they produce minimal pyrolysis and incomplete combustion products, little or no visible sidestream smoke, and minimal ash and have high heat capacity. However, lower carbon content fuel elements, e.g., about 50 65 weight percent, are within the scope of this invention, especially where a nonburning inert filler is used.
Also, while not preferred, other fuel materials may be employed, such as tobacco, tobacco substitutes and the like, provided that they they generate and 7 conduct sufficient heat to the aerosol generating means to produce the desired level of aerosol from the aerosol forming material, as discussed above. The of the fuel used should be above about preferably above about 0.7 g/cc., which is density 0.5g/cc. higher than the densities normally used in conventional smoking articles. Where such other materials are used, it is much preferred to include carbon in the fuel, preferably in amounts of at least about 20 - 40% by weight, more preferably at least about 50% by weight, and most preferably at least about 65 -70% by weight, the balance being being the other fuel components, including any binder, burn modifiers, moisture, etc.
The carbonaceous materials used in or as the preferred fuel may be derived from virtually any of the numerous carbon sources known to those skilled in the art. Preferably, the carbonaceous material is obtained by the pyrolysis or carbonization of cellulosic materials, such as wood, cotton, rayon, tobacco, coconut, paper, and the like, although carbonaceous materials from other sources may be used.
In most instances, the carbonaceous fuel element should be capable of being ignited by a conventional cigarette lighter without the use of an oxidizing agent. Burning characteristics of this type may generally be obtained from a cellulosic material which has been pyrolyzed at temperatures between about 400°C to about 1000°C, preferably 500°C to about 950°C, in an inert under a vacuum. The pyrolysis time is not believed to be critical, as long as the temperature at the center of the pyrolyzed mass has reached the aforesaid temperature range for at least a few minutes.
However, a slow pyrolysis, employing gradually between about atmosphere or 8 increasing temperatures over several hours is believed to produce a more uniform material with a higher carbon yield.
While undesirable in most cases, carbonaceous fuel 5 elements which require the addition of an oxidizing agent to render them ignitable by a cigarette lighter are within the 'scope of this invention, as are carbonaceous materials which require the use of a glow retardant or other type of combustion modifying agent.
Such combustion modifying agents are disclosed in many patents and publications' and are known to those of ordinary skill in the art.
The most preferred carbonaceous-fuel elements used in practicing the invention are substantially free of volatile organic material. By that, it is meant that the fuel element is not purposely impregnated or mixed with substantial amounts of volatile organic materials, such as volatile aerosol forming or flavoring agents, which could degrade in the burning fuel. However, small amounts of water, which are naturally adsorbed by the fuel, may be present therein. Similarly, small amounts of aerosol forming substances may migrate from the aerosol generating means and thus may also be present in the fuel element. a preferred carbonaceous fuel element is a pressed or extruded carbon mass prepared from carbon and a binder, by conventional pressure forming or extrusion techniques. A preferred activated carbon for such a fuel element is PCB-G, and a preferred non-activated carbon is PXC, both available from Calgon Carbon Corporation, Pittsburgh, PA. Other preferred carbons for pressure forming and/or extrusion are prepared from pyrolyzed cotton or pyrolyzed papers.
The binders which may be used in preparing such a fuel element are well known in the art. A preferred 9 binder is sodium carboxymethylcellul ose (SCMC), which may be used alone, which is preferred, or in conjunction with materials such as sodium chloride, vermiculite, bentonite, calcium carbonate, and the like. Other useful binders include gums, such as guar gum, and other cellulose derivatives, such as methylcellulose and carboxy me thyl cel lulose (CMC) .
A wide range of binder concentrations can be utilized. Preferably, the amount of binder is limited to minimize contribution of the binder to undesirable combustion products. On the other hand, sufficient binder must be included to hold the fuel element together during manufacture and use. The amount used will thus depend on the cohesiveness of the carbon in the fuel element.
If desired, the aforesaid fuel elements may be pyrolyzed after formation, for example, to about 650°C for two hours, to convert the binder to carbon ^hereby forming a virtually 100% carbon fuel element.
The fuel elements employed in the present invention also may contain one or more additives to improve burning, such as up to about 5 weight percent sodium chloride to improve smoldering characteristics and as a glow retardant. Also, up to about 5, preferably 1 to 2, weight percent of potassium carbonate may be included to improve lightability. Additives to improve physical characteristics, such as clays like kaolins, serpentines, attapulgites, and the like also may be used.
Another carbonaceous fuel element is a carbon fiber fuel, which may be prepared by carbonizing a fibrous precursor, such as cotton, rayon, paper, polyacrylonitile, and the like. Generally, pyrolysis at from about 650°C to 10j00°, preferably at about 0 element. substrate. 950°, for about ‘30 minutes, in an inert atmosphere or vacuum, is sufficient to produce a suitable carbon fiber with good burning characteristics. Combustion modifying additives also may be added to these fibrous fuels.
The aerosol generating means used in practicing the invention is physically separate from- the fuel By physically separate it is meant that the container or chamber which contains the aerosol forming materials is not mixed with, or a part of, the burning ,. fuel element; As noted previously, this arrangement helps reduce or eliminate thermal degradation of the aerosol forming substance and the presence of sidestream smoke. While not a part of the fuel, the aerosol generating means is in a conductive heat exchange relationship with the fuel element, and preferably abuts or is adjacent to the fuel element.
Preferably, the aerosol generating means includes .one or more thermally stable materials which carry one or more aerosol forming substances. As used herein, a thermally stable material is one capable of withstanding the high temperatures, e.g., 400°C 600°C, which exist near the fuel without decomposition or burning. The use of such material is believed to help maintain the simple smoke chemistry of the aerosol, as evidenced by the lack of Ames activity in the preferred embodiments. While not preferred, other aerosol generating means, such as heat rupturable microcapsules, or solid aerosol forming substances, are within the scope of the invention, provided they are capable of releasing sufficient aerosol forming vapors to satisfactorily resemble tobacco smoke.
Thermally stable materials which may be used as a 1 substrate or carrier for the aerosol forming substance are well known to those skilled in the art. Useful substrates should be porous and must be capable of retaining an aerosol forming compound when not in use and capable of releasing a potential aerosol forming vapor upon heating by the fuel element.
Useful thermally stable materials include thermally stable adsorbent carbons, such as porous grade carbons, graphite, activated, or nonactivated carbons, and the like. Other suitable materials include inorganic solids such as ceramics, glass, alumina, vermiculite, clays such as bentonite, and the like. The currently preferred substrate materials are carbon felts, fibers, and mats, activated carbons, and porous carbons such as PC-25 and PG-60 available from Union Carbide, as well as SGL carbon available from Calgon.
Depending upon the particular aerosol generating means employed herein, the composition and configuration thereof may generally be selected from particulate, fibrous, porous blocks, solid blocks with one or more axially extending passageways therethrough, and the like. Substrates, especially particulates, may be placed within a container, preferably formed from a metallic foil.
The aerosol generating means used in the invention is usually located no more than about 60 mm, preferably no more than 30 mm, most preferably no more than 15 mm from the lighting end of the fuel element. The aerosol generator may vary in length from about 2 nun to about 60 mm, preferably frpm about 5 mm to 40 nun, and most preferably from about 20 mm to 35 mm. if a non-particulate substrate is used, it may be provided with one or more holes, to increase the surface area of the substrate, and to increase air flow and heat transfer.
The aerosol forming substance or substances used in the invention must be capable of forming an aerosol at the temperatures present in the aerosol generating means when heated by the burning fuel element. Such substances preferably will be composed of carbon, hydrogen and oxygen, but they may include other materials. The aerosol forming substances can be in solid, semisolid, or liquid form. The boiling point of the substance and/or the mixture of substances can range up to about 500°C. - Substances having these characteristics include polyhydric alcohols, such as glycerin and propylene glycol, as well as aliphatic esters of mono-, di-, or poly-carboxylic acids, such as methyl stearate, dodecandioate, dimethyl tetradodecandioate, and others.
Preferably, the aerosol forming substances will include a mixture of a high boiling, low vapor pressure 'substance and a low boiling, high vapor pressure substance. Thus, on early puffs, substance will provide most while, when the temperature increases, the high boiling substance will provide most of the aerosol.
The preferred aerosol forming substances are polyhydric alcohols, or mixtures of polyhydric alcohols. Especially preferred aerosol formers are selected from glycerin, propylene glycol, triethylene glycol, or mixtures thereof.
The aerosol forming substance may be dispersed on or within the aerosol generating means in a concentration sufficient to permeate or coat the substrate, carrier, or container. For example, the aerosol forming substance may be applied full strength the low boiling of the initial aerosol, in the aerosol generator or in a dilute solution by dipping, spraying, vapor deposition, or similar techniques. Solid aerosol forming components may be admixed with the substrate and distributed evenly throughout prior to formation. while the loading of the aerosol forming substance will vary from carrier to carrier and from aerosol forming substance to aerosol forming substance, the amount of liquid aerosol forming substances may generally vary from about 20 mg to about 120 mg, preferably from about 35 mg to about 85 mg, and most preferably from about 45 mg to about 65 mg. As much as possible of the aerosol former carried on the aerosol generating means should be delivered to the user as WTPH. Preferably, above about 2 weight percent, more preferably above about 15 weight percent, and most preferably above about 20 weight percent of the aerosol former carried on the aerosol generating means is delivered to the user as WTPM.
The aerosol generating means also may include one or more volatile flavoring agents, such as menthol, vanillin, artificial coffee, tobacco extracts, nicotine, caffeine, liquors, and other agents which impart flavor to the aerosol. It also may include any other desirable volatile solid or liquid materials.
As previously pointed out, the smoking article of the present invention also may include a charge or plug of tobacco which may be used to add a tobacco flavor to the aerosol. Preferably, the tobacco is placed at the mouth end of the aerosol generating means, or it may be mixed with the carrier for the aerosol forming substance. Flavoring agents also may be incorporated into the article to flavor the aerosol delivered to the user.
If a charge of tobacco is employed, hot vapors are swept through the bed of tobacco to extract and vaporize the volatile components in the tobacco, without the need for tobacco combustion. Thus the user of this smoking article receives an aerosol which contains the qualities and flavors of natural tobacco without the combustion . products produced by a conventional cigarette.
Alternatively, these optional agents may be placed between the aerosol generating means and the mouthend, such as in a separate substrate or chamber in the passage which leads from the aerosol generating means to the mouthend, or in the optional tobacco charge. If desired, these volatile agents may be used in lieu of part, or all, of the aerosol forming substance, so that the article delivers a nonaerosol flavor or other material to the user.
Articles of the type disclosed herein may be used or may be modified for use as drug delivery articles, for delivery of volatile pharmacologically or physiologically active materials such as ephedrine, metaproterenol, terbutaline or the like.
The heat conducting member preferably employed in practicing this invention is typically a metallic foil, such as aluminum foil, varying in thickness from less than about 0.01 mm to about 0.1 mm, or more. The thickness and/or the' type of conducting material may be varied to achieve virtually any desired degree of heat transfer. As shown in the illustrated embodiments, the heat conducting member preferably contacts or overlaps a portion of the fuel element and the aerosol generating means, and may form the container which encloses the aerosol forming substance.
Insulating members which may be used in accordance with the present invention generally comprise inorganic or organic fibers such as those made out of glass, alumina, silica, vitreous materials, mineral wool, carbons, silicons, boron, organic polymers, cellulosics, and the like, including mixtures of these materials. Nonfibrous insulating materials, such as silica aerogel, pearlite, glass, and the like, formed in mats, strips or other shapes, may also be used. Preferred insulating members are resilient, to help simulate the feel of a conventional cigarette. These materials act primarily as an insulating jacket, retaining and directing a significant portion of the heat formed by the burning fuel element to the aerosol generating means. Because the insulating jacket becomes hot adjacent to the burning fuel element, to a limited extent, it also may conduct heat toward the aerosol generating means.
Currently preferred insulating materials include ceramic fibers, such as glass fibers. Two especially preferred glass fibers are available from the Manning Paper Company of Troy, New York, under the designations, Manniglas 1000 and Manniglas 1200. Generally the insulating fiber is wrapped over at least a portion of the fuel element and any other desired portion of the article, to a final diameter of from about 7 to 8 mm. Thus, the preferred thickness of the insulating layer is from about 0.5 mm to 2.5 mm, preferably, from about 1 mm to 2 mm. When possible, glass fiber materials having a low softening point, e.g., below about 650°C, are preferred.
When the insulating means is fibrous, there is preferably employed a barrier. means at the mouth end of the article. One such barrier means comprises an annular member of high density cellulose acetate tow which abuts the fibrous insulating means and which is for example. the combination will be such as a foil lined sealed, preferably at the mouth end, with glue, to block air flow through the tow.
In most embodiments of the invention, fuel/aerosol generating means attached to a. mouthend piece, paper or cellulose acetate/plastic tubes illustrated in the figures, although a mouthend piece may be provided separately, e.g., in the form of a cigarette holder. This element of the article provides the passageway which channels the-vaporized aerosol forming substance into the mouth of the user.· Due to i£s length, preferably about 50 to 60 mm or more, it also keeps the hot fire cone away from the mouth and fingers of the user.
Suitable mouthend pieces should be inert with respect to the aerosol forming substances, should have a water or liquid proof inner layer, should offer minimum aerosol loss by condensation or filtration, and should be capable of withstanding the temperature at the interface with the other elements of the article.
Preferred mouthend pieces include the cellulose-acetate tube employed in the embodiments of Figures 1 and 2. Other suitable mouthend pieces will be apparent to those of ordinary skill in the art.
The mouthend pieces of the invention may include an optional filter tip, which is used to give the article the appearance of the conventional filtered cigarette. Such filters include low density cellulose acetate filters and hollow or baffled plastic filters, such as those made of polypropylene. In addition, the entire length of article Or any portion thereof may be overwrapped with cigarette paper.
The aerosol produced by the preferred articles of the present invention is chemically simple, consisting essentially of air, oxides of carbon, the aerosol which carries any desired flavorants or other desired volatile materials, water, and trace amounts of other materials. The wet total particulate matter (WTPM) produced by the preferred articles of this invention has no mutagenic activity as measured by the Ames test, i.e., there is no significant dose response relationship between the WTPM of the present invention and the number of revertants occurring in standard test microorganisms exposed to such products. According to the proponents of the Ames test, a significant dose dependent response indicates the presence of mutagenic materials in the products tested. See Ames £t al. , Hut. Res.. 31:347-364 (1975); Nagas £t al · , Mut. Res.. 42:335 (1977).
A further benefit from the preferred embodiments of the present invention is the relative lack of ash 'produced during use in comparison to ash from a conventional cigarette. As the preferred carbon fuel source is burned, it is essentially converted to oxides of carbon, with relatively, little ash generation, and thus there is no need to dispose of ashes while using the article.
.The smoking article of. the present invention will be further illustrated with reference to the following ^example which aids in the understanding of the present invention, but which are not to be construed as limitations thereof. All percentages reported herein, unless otherwise specified, are percent by weight. All temperatures are expressed in degrees Celsius and are uncorrected. In all instances, the smoking articles have a diameter of about 7 to 8 mm, the diameter of a conventional cigarette.
Exampl e A modified version of the smoking article of Figure 2 was made as follows: A 9.5 mm long carbon fuel source with a 4.5 mm diameter and a 1 mm diameter longitudinal passageway was extruded from a mixture of 10% SCMC, 5% potassium carbonate, and 85% carbonized paper mixed with 10% water. The ' mixture had a dough-like consistency and was fed into an extruder. The extruded material was cut to length after drying at 80°C overnight. The macrocapsule was made from a 22 mm long piece of 0.0089 nun thick aluminum formed into a cylinder of 4.5 mm i.D. The macrocapsule was filled with (a) 70 mg of vermiculite containing 50 mg of a 1:1 mixture of propylene glycol and glycerin, and (b) 30 mg of burley tobacco to which 6% glycerin and 6% propylene glycol had been added. The fuel source and macrocapsule were joined by inserting the fuel source about 2 mm ‘into the end of the macrocapsule. A 35 mm long polypropylene tube of 4.5 mm I.D. was inserted in the other end of the macrocapsule. The fuel source, macrocapsule and polypropylene tube were thus joined to form a 65 mm long, 4.5 mm diameter segment. This segment was wrapped with several layers of Manniglas 1000 from Manning Paper Company until a circumference of 24.7 mm was reached. The unit was then combined with a 5 mm long cellulose acetate filter and wrapped with cigarette paper. When smoked under FTC conditions, the' article delivered 8 mg of WTPM over the initial three puffs; 7 mg WTPM over puffs 4-6; and 5 mg WTPM over puffs 7-9. Total aerosol delivery over the 9 puffs was 20 mg. When placed horizontally on a piece of tissue paper, the article did not ignite or even scorch the tissue paper. 9

Claims (90)

CLAIMS :
1. A smoking article having a front end and a rear end and comprising: (a) a fuel element having a lighting end; (b) a physically separate aerosol generating means comprising at least one aerosol forming material and being disposed between the lighting end of the fuel element and said rear end; characterized by: (c) a resilient insulating member, surrounding at least a portion of the fuel element and comprising inorganic fibers and being at least 0.5 mm thick; and (d) an overwrap for the insulating member.
2. Article as claimed in claim 1, said smoking article being designed as a cigarette type article wherein the fuel element, the aerosol generating means and the insulating member are structured and arranged to transfer heat from the fuel element to said aerosol forming material both during puffing and during smolder.
3. Article according to claim 1 or 2, wherein the fuel element is located at the lighting end of the article.
4. Article according to one of the preceding claims, wherein the fuel element includes at least one longitudinally extending passageway.
5. Article according to claim 4, wherein the fuel element has a plurality of such passageways.
6. Article according to claim 4 or 5, wherein at least one passageway is in the form of a hole.
7. Article according to one of the preceding claims, wherein the fuel element is about 30 mm or less in length prior to smoking.
8. Article according to claim 7, wherein the fuel element is about 20 mm or less in length prior to smoking.
9. Article according to claim 8, wherein the fuel element is about 15 mm or less in length before smoking.
10. Article according to one of claims 7 to 9, wherein the fuel element has a length of at least about 5 mm prior to smoking.
11. Article according to one of the preceding claims, wherein the fuel element has a diameter between about 3 mm and 8 mm.
12. Article according to claim 11, wherein the fuel element has a diameter of from about 4 mm to about 5 mm.
13. Article according to one of the preceding claims, wherein the fuel element has a density of at least 0.5 g/cm 3 .
14. Article according to claim 13, wherein the fuel element has a density range from about 0.5 g/cm 3 to about 1.5 g/cm 3 .
15. Article according to claim 13 or 14, wherein the fuel element has a density of more than about 0.7 g/cm 3 .
16. Article according to one of claims 13 to 15, wherein the fuel element has a density of at least about 0.8 g/cm^.
17. Article according to one of the preceding claims, wherein the fuel element is carbonaceous.
18. Article according to claim 17, wherein the fuel element comprises at least about 50 % by weight carbon, as such.
19. Article according to claim 18, wherein the fuel element comprises at least 60 % to 80 % by weight carbon
20. Article according to claim 19, wherein the fuel element comprises at least about 80 % by weight carbon.
21. Article according to claim 20, wherein the fuel element comprises at least about 85 % by weight carbon.
22. Article according to one of the preceding claims, wherein the fuel element has a tapered lighting end.
23. Article according to one of the preceding claims, wherein the fuel element is a pressed or extruded carbonaceous mass.
24. Article according to one of the preceding claims, wherein the fuel element is substantially free of volatile organic material.
25. Article according to one of the preceding claims, wherein the constituents of the mass forming the fuel element are selected to avoid any substantial visible sidestream smoke during smolder. 3 2
26. Article according to one of the preceding claims, further comprising an insulating member which is designed and arranged to increase heat transfer from the fuel element to the aerosol generating means.
27. Article according to one of the preceding claims, wherein the insulating member surrounds at least a portion of the aerosol generating means.
28. Article according to one of the preceding claims, wherein the aerosol generating means is arranged in a container.
29. Article according to one of the preceding claims, wherein a heat transferring member is provided for transferring heat generated by the fuel element to the aerosol generating means substantially throughout the time of burning of the fuel element.
30. Article according to one of the preceding claims, wherein a heat transfer member is provided which contacts or overlaps at least a portion of the fuel element and of the aerosol generating means.
31. Article according to claim 29 or 30, wherein the heat transferring member encompasses at least a portion of the aerosol generating means.
32. Article according to one of claims 29 to 31, wherein the heat transferring member is at least partially within the fuel element.
33. Article according to one of claims 29 to 32, wherein the heat transferring member circumscribes a portion of the external longitudinal periphery of the fuel element and at least a portion of the external longitudinal periphery of the aerosol generating means.
34. Article according to one of claims 29 to 33, wherein the heat transferring member is a heat conducting container for the aerosol generating means.
35. Article according to claim 34, wherein the fuel end of the conductive container contacts the rear portion of the fuel element.
36. Article according to one of the claims 29 to 35, wherein the heat transferring member is spaced behind the lighting end of the fuel element.
37. Article according to one of the claims 29 to 36, wherein the heat transferring member is a metallic member, preferably of aluminum.
38. Article according to one of claims 28 to 37, wherein the container is a heat conductive metallic tube.
39. Article according to one of claims 28 to 38, wherein the container overlaps the rear portion of the fuel element, encloses the aerosol generating means and permits the passage of air and the aerosol forming material.
40. Article according to one of claims 29 to 39, wherein the heat transferring member comprises a conductive rod embedded within at least a portion of both the fuel element and the aerosol generating means.
41. Article according to one of claims 34 to 40, comprising an insulating member which circumscribes at least a portion of the conductive container.
42. Article according to one of the preceding claims, wherein the insulating member is non-combustible.
43. Article according to one of the preceding claims, wherein the insulating member is about 1 mm to 2.5 mm thick.
44. Article according to claim 43, wherein the insulating member is about 1 mm to 2 mm thick.
45. Article according to one of the preceding claims, wherein the insulating member comprises an air permeable mass of inorganic fibers.
46. Article according to one of the preceding claims, wherein the insulating member comprises an air permeable resilient jacket of fibers.
47. Article according to one of the preceding claims, wherein the insulating member has a thermal conductivity of less than about 0.005 g-cal/(sec)(cm^) (°C/cm).
48. Article according to one of the preceding claims, wherein said insulating member comprises a material which fuses during use.
49. Article according to claim 48, wherein the insulating member comprises inorganic fibers which fuse during use.
50. Article according to one of the preceding claims, wherein said insulating member comprises a low temperature grade of glass fibers.
51. Article according to claim 50, wherein said insulating member comprises glass fibers having a softening point below about 650°C.
52. Article according to one of the preceding claims, wherein a charge of tobacco is provided. 3 S
53. Article according to claim 52, wherein the charge of tobacco is located between the rear end of the fuel element and the mouth end of the article. 5
54. Article according to one of the preceding claims, wherein tobacco is placed between the aerosol generating means and the mouth end of the article.
55. Article according to claim 54, wherein the tobacco 10 is placed at the rear end of the aerosol generating means.
56. Article according to one of the preceding claims, comprising a charge of tobacco extract being located 15 between the rear end of the fuel element and the mouth end of the article.
57. Article according to one of the preceding claims, wherein in the longitudinal direction of the article the 20 aerosol generating means is disposed adjacent to the fuel element.
58. Article according to one of the preceding claims, wherein the aerosol generating means is in close 25 proximity to the fuel element.
59. Article according to one of the preceding claims, wherein the aerosol generating means abuts the fuel element.
60. Article according to one of the preceding claims, wherein the fuel element and aerosol generating means are arranged in a conductive heat exchange relationship such that the aerosol generating means receives conductive 35 heat transfer substantially throughout the time of burning of the fuel element.
61. Article according to claim 60, wherein the fuel element and the aerosol generating means are arranged in a conductive heat exchange relationship by contact between the aerosol generating means and a part of the 5 fuel element.
62. Article according to one of the preceding claims, wherein the aerosol generating means is located no more than about 30 mm from the lighting end of the fuel 10 element.
63. Article according to claim 62, wherein the aerosol generating means is located no more than about 15 mm from the lighting end of the fuel element.
64. Article according to one of the preceding claims, wherein the aerosol generating means is loaded with from about 20 mg to 120 mg of aerosol forming material. 20
65. Article according to claim 64, wherein the aerosol generating means is loaded with 35 mg to 85 mg of aerosol forming material.
66. Article according to one of the preceding claims, 25 wherein above about 15 weight percent of an aerosol forming material carried by the aerosol generating means is delivered as wet total particulate matter under smoking conditions of 35 ml puffs of 2 seconds duration separated by 58 seconds of smolder.
67. Article according to one of the preceding claims, wherein the article delivers at least about 0.6 mg of wet total particulate matter in the first 3 puffs under smoking conditions of 35 ml puffs of 2 seconds duration 35 separated by 58 seconds of smolder.
68. Article according to one of the preceding claims, wherein the aerosol generating means is loaded with 3 7 sufficient aerosol forming substance such that the article delivers at least about 1.5 mg of wet total particulate matter in the first 3 puffs under smoking conditions of 35 ml puffs of 2 seconds duration separated by 58 seconds of smolder.
69. Article according to one of the preceding claims, wherein the aerosol generating means is loaded with sufficient aerosol forming substance such that the article delivers an average of at least about 0.8 mg per puff of wet total particulate matter under smoking conditions of 35 ml puffs of 2 seconds duration separated by 58 seconds of smolder for at least 6 puffs.
70. Article according to claim 69, wherein the article delivers an average of at least about 0.8 mg per puff of wet total particulate matter under smoking conditions of 35 ml puffs of 2 seconds duration separated by 58 seconds of smolder for at least 10 puffs.
71. Article according to one of claims 28 to 70 wherein the container is crimped at its mouth end.
72. Article according to one of the preceding claims, wherein the aerosol generating means includes a tobacco extract.
73. Article according to one of the preceding claims, wherein volatile flavoring agents are placed between the aerosol generating means and the mouth end.
74. Article according to one of the preceding claims, wherein the smoke produced consists essentially of the oxides of carbon, air, water, volatile substance comprised in the aerosol generating means, other desired volatiles and trace amounts of other materials.
75. Article according to one of claims 17 to 74, wherein the article has no mutagenic activity in the wet total particulate matter as measured by the Ames Test. 5
76. Article according to one of the preceding claims, wherein the article has a diameter of about 8 mm or less.
77. Article according to one of the preceding claims, wherein the article has the size and shape of a 10 cigarette.
78. Article according to one of the preceding claims, wherein the smoking article includes a mouthend piece. 15
79. Article according to claim 78, wherein the smoking article includes means for delivering the aerosol forming material to the user, said mouthend piece and aerosol delivering means extend over more than half the length of the article.
80. Article according to one of the preceding claims, wherein the article delivers a visible smoke-like aerosol. 25
81. Article according to one of the preceding claims, wherein the article is adapted to be used together with a separate mouthpiece.
82. Article according to one of the preceding claims, 30 wherein the smoking article additionally comprises means for directing gases of the fuel element through the aerosol generating means and to the mouthpiece.
83. Article according to one of the preceding claims, 35 wherein the aerosol generating means comprises a thermally stable substrate bearing an aerosol forming material. 3 9
84. Article according to claim 83, wherein the thermally stable substrate includes ceramics.
85. Article according to one of the preceding claims, wherein the aerosol generating means comprises a particulate substrate.
86. Article according to one of the preceding claims, comprising in addition a filter.
87. Article according to one of the preceding claims, wherein the fuel element and the aerosol generating means are designed and arranged to transfer heat from the fuel element to the aerosol generating means to volatilize the aerosol forming material during puffing throughout smoking.
88. Article according to one of claims 1 to 60 and 62 to 87, wherein the aerosol generating means is in contact with the fuel element to receive heat from the fuel element substantially throughout the burning period of the fuel element.
89. Article according to one of the preceding claims, wherein the burning of the fuel element produces no disposable ash during use.
90. A smoking article substantially as hereinbefore described with particular reference to the accompanying drawings. F. R. KELLY & CO., AGENTS FOR THE APPLICANTS.
IE205085A 1984-09-14 1985-08-20 Smoking article IE65637B1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
IE940573A IE65679B1 (en) 1984-09-14 1985-08-20 Cigarette type smoking article
IE940574A IE65680B1 (en) 1984-09-14 1985-08-20 Smoking article
IE950598A IE80788B1 (en) 1984-09-14 1985-08-20 Smoking article
IE950597A IE79075B1 (en) 1984-09-14 1985-08-20 A carbonaceous fuel element for a smoking article

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/650,604 US4793365A (en) 1984-09-14 1984-09-14 Smoking article
US68453784A 1984-12-21 1984-12-21

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IE852050L IE852050L (en) 1986-03-14
IE65637B1 true IE65637B1 (en) 1995-11-01

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IE950598A IE80788B1 (en) 1984-09-14 1985-08-20 Smoking article
IE205085A IE65637B1 (en) 1984-09-14 1985-08-20 Smoking article
IE940573A IE65679B1 (en) 1984-09-14 1985-08-20 Cigarette type smoking article
IE940574A IE65680B1 (en) 1984-09-14 1985-08-20 Smoking article
IE950597A IE79075B1 (en) 1984-09-14 1985-08-20 A carbonaceous fuel element for a smoking article

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IE940574A IE65680B1 (en) 1984-09-14 1985-08-20 Smoking article
IE950597A IE79075B1 (en) 1984-09-14 1985-08-20 A carbonaceous fuel element for a smoking article

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Families Citing this family (112)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1183599B (en) * 1985-05-10 1987-10-22 Inphardial Spa DEVICE TO DETERMINE THE QUANTITY OF PLASMATIC WATER REMOVED DURING AN EXTRA-BODY DIALYSIS SESSION
US4800903A (en) * 1985-05-24 1989-01-31 Ray Jon P Nicotine dispenser with polymeric reservoir of nicotine
US4938238A (en) * 1985-08-26 1990-07-03 R. J. Reynolds Tobacco Company Smoking article with improved wrapper
IN166122B (en) * 1985-08-26 1990-03-17 Reynolds Tobacco Co R
US4989619A (en) * 1985-08-26 1991-02-05 R. J. Reynolds Tobacco Company Smoking article with improved fuel element
US4708151A (en) * 1986-03-14 1987-11-24 R. J. Reynolds Tobacco Company Pipe with replaceable cartridge
US5076297A (en) * 1986-03-14 1991-12-31 R. J. Reynolds Tobacco Company Method for preparing carbon fuel for smoking articles and product produced thereby
US4732168A (en) * 1986-05-15 1988-03-22 R. J. Reynolds Tobacco Company Smoking article employing heat conductive fingers
US4771795A (en) * 1986-05-15 1988-09-20 R. J. Reynolds Tobacco Company Smoking article with dual burn rate fuel element
US4827950A (en) * 1986-07-28 1989-05-09 R. J. Reynolds Tobacco Company Method for modifying a substrate material for use with smoking articles and product produced thereby
GB8622606D0 (en) * 1986-09-19 1986-10-22 Imp Tobacco Ltd Smoking article
US4858630A (en) * 1986-12-08 1989-08-22 R. J. Reynolds Tobacco Company Smoking article with improved aerosol forming substrate
US4765348A (en) * 1986-12-12 1988-08-23 Brown & Williamson Tobacco Corporation Non-combustible simulated cigarette device
IE873108L (en) * 1986-12-12 1988-06-12 Huels Chemische Werke Ag Impact modifying agent for use with smoking articles
US4819665A (en) * 1987-01-23 1989-04-11 R. J. Reynolds Tobacco Company Aerosol delivery article
US5052413A (en) * 1987-02-27 1991-10-01 R. J. Reynolds Tobacco Company Method for making a smoking article and components for use therein
US4779631A (en) * 1987-03-06 1988-10-25 Kimberly-Clark Corporation Wrappers for specialty smoking devices
US4924883A (en) * 1987-03-06 1990-05-15 R. J. Reynolds Tobacco Company Smoking article
DE3709749A1 (en) * 1987-03-25 1988-10-13 Wab Kosmetik Kuhs Ohg REPLACEMENT CIGARETTE
GB8713645D0 (en) 1987-06-11 1987-07-15 Imp Tobacco Ltd Smoking device
US4870748A (en) * 1987-07-17 1989-10-03 R. J. Reynolds Tobacco Co. Apparatus for assembling elements of a smoking article
US5088507A (en) * 1987-07-17 1992-02-18 R. J. Reynolds Tobacco Company Apparatus for assembling components of a smoking article
US5019122A (en) * 1987-08-21 1991-05-28 R. J. Reynolds Tobacco Company Smoking article with an enclosed heat conductive capsule containing an aerosol forming substance
US4903714A (en) * 1987-08-25 1990-02-27 R. J. Reynolds Tobacco Company Smoking article with improved mouthend piece
US5137034A (en) * 1988-05-16 1992-08-11 R. J. Reynolds Tobacco Company Smoking article with improved means for delivering flavorants
US4881556A (en) * 1988-06-06 1989-11-21 R. J. Reynolds Tobacco Company Low CO smoking article
US4991606A (en) * 1988-07-22 1991-02-12 Philip Morris Incorporated Smoking article
US4966171A (en) 1988-07-22 1990-10-30 Philip Morris Incorporated Smoking article
US5159940A (en) * 1988-07-22 1992-11-03 Philip Morris Incorporated Smoking article
US5345951A (en) 1988-07-22 1994-09-13 Philip Morris Incorporated Smoking article
US5076296A (en) * 1988-07-22 1991-12-31 Philip Morris Incorporated Carbon heat source
US4981522A (en) * 1988-07-22 1991-01-01 Philip Morris Incorporated Thermally releasable flavor source for smoking articles
GB8819291D0 (en) * 1988-08-12 1988-09-14 British American Tobacco Co Improvements relating to smoking articles
US4947874A (en) * 1988-09-08 1990-08-14 R. J. Reynolds Tobacco Company Smoking articles utilizing electrical energy
US5040551A (en) * 1988-11-01 1991-08-20 Catalytica, Inc. Optimizing the oxidation of carbon monoxide
US4955399A (en) * 1988-11-30 1990-09-11 R. J. Reynolds Tobacco Company Smoking article
US5211684A (en) * 1989-01-10 1993-05-18 R. J. Reynolds Tobacco Company Catalyst containing smoking articles for reducing carbon monoxide
WO1990010394A1 (en) * 1989-03-16 1990-09-20 R.J. Reynolds Tobacco Company Catalyst containing smoking articles for reducing carbon monoxide
US4913169A (en) * 1989-03-17 1990-04-03 Brown & Williamson Tobacco Corporation Smoking article
US4961438A (en) * 1989-04-03 1990-10-09 Brown & Williamson Tobacco Corporation Smoking device
GR890100237A (en) * 1989-04-12 1991-09-27 Reynolds Tobacco Co R Catalyst containing smoking articles for reducing carbon monoxide
EP0399252A3 (en) * 1989-05-22 1992-04-15 R.J. Reynolds Tobacco Company Smoking article with improved insulating material
US5188130A (en) 1989-11-29 1993-02-23 Philip Morris, Incorporated Chemical heat source comprising metal nitride, metal oxide and carbon
US5348027A (en) * 1991-02-14 1994-09-20 R. J. Reynolds Tobacco Company Cigarette with improved substrate
US5185088A (en) * 1991-04-22 1993-02-09 The Procter & Gamble Company Granular fabric softener compositions which form aqueous emulsion concentrates
CA2079495A1 (en) * 1991-10-03 1993-04-04 John H. Kolts Smoking article with co oxidation catalyst
TR25593A (en) * 1992-01-14 1993-07-01 Inter Muehendislik Danismanlik INFRARED ELECTROOPTIC COMMUNICATION DEVICE
CA2090918C (en) * 1992-03-25 2006-01-17 Robert Leonard Meiring Components for smoking articles and process for making same
US5345955A (en) * 1992-09-17 1994-09-13 R. J. Reynolds Tobacco Company Composite fuel element for smoking articles
US5469871A (en) * 1992-09-17 1995-11-28 R. J. Reynolds Tobacco Company Cigarette and method of making same
PH30299A (en) * 1993-04-07 1997-02-20 Reynolds Tobacco Co R Fuel element composition
US5944025A (en) * 1996-12-30 1999-08-31 Brown & Williamson Tobacco Company Smokeless method and article utilizing catalytic heat source for controlling products of combustion
US5996589A (en) 1998-03-03 1999-12-07 Brown & Williamson Tobacco Corporation Aerosol-delivery smoking article
US20070215167A1 (en) 2006-03-16 2007-09-20 Evon Llewellyn Crooks Smoking article
US10188140B2 (en) 2005-08-01 2019-01-29 R.J. Reynolds Tobacco Company Smoking article
US7647932B2 (en) * 2005-08-01 2010-01-19 R.J. Reynolds Tobacco Company Smoking article
CA2682432C (en) * 2007-03-30 2017-06-06 Duke University Device and method for delivery of a medicament
US8991402B2 (en) 2007-12-18 2015-03-31 Pax Labs, Inc. Aerosol devices and methods for inhaling a substance and uses thereof
WO2011081558A1 (en) * 2009-08-21 2011-07-07 Komissarov Jury Vladimirovich Smoking device for giving up tobacco smoking
EP2542285B8 (en) * 2010-03-04 2023-11-15 C/O CLK Consult v Carsten Leonhard Knudsen An inhalator
CN102821625B (en) 2010-03-26 2016-11-23 菲利普莫里斯生产公司 There is the smoking article of heat-resisting sheet material
ES2741139T5 (en) 2010-03-26 2022-11-14 Japan Tobacco Inc smoking article
EP3831220B1 (en) 2010-07-30 2022-09-07 Japan Tobacco Inc. Smokeless flavor inhalator
UA112440C2 (en) 2011-06-02 2016-09-12 Філіп Морріс Продактс С.А. SMOKING SOURCE OF HEAT FOR SMOKING PRODUCTS
PL2779848T3 (en) 2011-11-15 2019-11-29 Philip Morris Products Sa Smoking article comprising a combustible heat source with a rear barrier coating
ES2672879T3 (en) 2011-12-29 2018-06-18 Philip Morris Products S.A. Composite heat source for a smoking article
TWI639391B (en) 2012-02-13 2018-11-01 菲利浦莫里斯製品股份有限公司 Smoking article comprising an isolated combustible heat source
TWI590769B (en) * 2012-02-13 2017-07-11 菲利浦莫里斯製品股份有限公司 Smoking article including dual heat-conducting elements and method of adjusting the puff-by-puff aerosol delivery of a smoking article
KR101633578B1 (en) * 2012-04-02 2016-06-24 필립모리스 프로덕츠 에스.에이. Method of manufacturing a combustible heat source
SG11201406968VA (en) * 2012-04-30 2014-11-27 Philip Morris Products Sa Smoking article mouthpiece including aerogel
EP2676559A1 (en) 2012-06-21 2013-12-25 Philip Morris Products S.A. Method of manufacturing a combustible heat source with a barrier
EP2869721B1 (en) * 2012-07-04 2019-12-04 Philip Morris Products S.a.s. Combustible heat source with improved binding agent
US20140261487A1 (en) * 2013-03-14 2014-09-18 R. J. Reynolds Tobacco Company Electronic smoking article with improved storage and transport of aerosol precursor compositions
WO2014155378A1 (en) * 2013-03-27 2014-10-02 Ian Michael Solomon Modified risk tobacco product
LT2975955T (en) * 2013-08-13 2017-11-10 Philip Morris Products S.A. Smoking article with dual heat-conducting elements and improved airflow
KR20170037680A (en) * 2013-08-13 2017-04-04 필립모리스 프로덕츠 에스.에이. Smoking article comprising a blind combustible heat source
CN103610230A (en) * 2013-09-12 2014-03-05 湖北中烟工业有限责任公司 Preparation method for cigarette generating smoke based on combination of combustion and distillation and processing device
TWI657755B (en) * 2013-12-30 2019-05-01 Philip Morris Products S. A. Smoking article comprising an insulated combustible heat source
CN103750535B (en) * 2014-01-22 2015-12-02 红云红河烟草(集团)有限责任公司 Preparation method of heating non-combustion type cigarette block
GB201407642D0 (en) 2014-04-30 2014-06-11 British American Tobacco Co Aerosol-cooling element and arrangements for apparatus for heating a smokable material
GB201418817D0 (en) 2014-10-22 2014-12-03 British American Tobacco Co Apparatus and method for generating an inhalable medium, and a cartridge for use therewith
JP6725524B2 (en) 2015-02-27 2020-07-22 ブリティッシュ アメリカン タバコ (インヴェストメンツ) リミテッドBritish American Tobacco (Investments) Limited Cartridge, component and method for generating aspirable media
GB201503411D0 (en) 2015-02-27 2015-04-15 British American Tobacco Co Apparatus and method for generating an inhalable medium, and a cartridge for use therewith
DE102015205768A1 (en) 2015-03-31 2016-10-06 Hauni Maschinenbau Gmbh A method of making a first subunit of a HNB smoking article having a rod body and a cavity disposed thereon
ITUB20153803A1 (en) * 2015-09-22 2017-03-22 Gd Spa Machine for the production of cartridges for electronic cigarettes.
GB201517471D0 (en) 2015-10-02 2015-11-18 British American Tobacco Co Apparatus for generating an inhalable medium
US20170265517A1 (en) * 2016-03-15 2017-09-21 Rai Strategic Holdings, Inc. Multi-Layered Micro-Beads for Electronic Cigarettes
TW201801618A (en) 2016-05-31 2018-01-16 菲利浦莫里斯製品股份有限公司 Aerosol-generating article with an insulated heat source
GB201610220D0 (en) 2016-06-13 2016-07-27 Nicoventures Holdings Ltd Aerosol delivery device
US10212964B2 (en) 2016-07-07 2019-02-26 Altria Client Services Additive assembly for electronic vaping device
US11191911B2 (en) 2016-08-09 2021-12-07 British American Tobacco (Investments) Limited Receptacle, cartridge, apparatus and methods for generating an inhalable medium
GB201618481D0 (en) 2016-11-02 2016-12-14 British American Tobacco Investments Ltd Aerosol provision article
GB201700136D0 (en) 2017-01-05 2017-02-22 British American Tobacco Investments Ltd Aerosol generating device and article
GB201700620D0 (en) 2017-01-13 2017-03-01 British American Tobacco Investments Ltd Aerosol generating device and article
GB201720338D0 (en) 2017-12-06 2018-01-17 British American Tobacco Investments Ltd Component for an aerosol-generating apparatus
KR20200101447A (en) * 2017-12-29 2020-08-27 필립모리스 프로덕츠 에스.에이. Aerosol-generating device and aerosol-generating system comprising bimetallic elements
GB201801257D0 (en) 2018-01-25 2018-03-14 British American Tobacco Investments Ltd Apparatus for heating aerosol-generating material
JP7029553B2 (en) * 2018-05-21 2022-03-03 チャイナ タバコ フーナン インダストリアル カンパニー リミテッド Low temperature smoker and its manufacturing method
CN114269169A (en) 2019-02-11 2022-04-01 斯瓦蒙卢森堡公司 Cocoa wrapper for a smoking article
CA3129135A1 (en) 2019-02-11 2020-08-20 Swm Luxembourg Filler containing blends of aerosol generating materials
CA3129119A1 (en) 2019-02-11 2020-08-20 Swm Luxembourg Reconstituted cannabis material for generating aerosols
US11388925B2 (en) 2019-02-11 2022-07-19 Schweitzer-Mauduit International, Inc. Cannabis wrapper for smoking articles
CN114269168B (en) 2019-02-11 2023-06-23 斯瓦蒙卢森堡公司 Reconstituted cocoa material for aerosol generation
EP3937681A4 (en) * 2019-03-11 2023-03-22 Selby, Ryan Daniel Improved smoking article
US12075819B2 (en) * 2019-07-18 2024-09-03 R.J. Reynolds Tobacco Company Aerosol delivery device with consumable cartridge
KR102433808B1 (en) * 2019-08-08 2022-08-18 주식회사 케이티앤지 Aerosol generating system
WO2021074127A1 (en) 2019-10-14 2021-04-22 Philip Morris Products S.A. Aerosol generating article with non-combustible coating
GB202013121D0 (en) * 2020-08-21 2020-10-07 Nicoventures Trading Ltd A combustion retarding materials and uses thereof
CN113662242B (en) * 2021-07-27 2023-10-20 常德市雄鹰科技有限责任公司 Device and system for preparing and forming explosion beads in cigarette filter tip
CN113412970B (en) * 2021-08-02 2023-10-20 云南喜科科技有限公司 Detachable and reusable electromagnetic heating component and electromagnetic heating smoking set comprising same
KR20230096602A (en) * 2021-12-23 2023-06-30 주식회사 케이티앤지 Combustible heat source for a smoking article and a smoking article comprising the same
WO2023161690A1 (en) 2022-02-24 2023-08-31 Compañía Industrial De Tabacos Monte Paz S.A. Refill tablet for hnb devices

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2907686A (en) * 1954-12-23 1959-10-06 Henry I Siegel Cigarette substitute and method
US3258015A (en) * 1964-02-04 1966-06-28 Battelle Memorial Institute Smoking device
US3356094A (en) * 1965-09-22 1967-12-05 Battelle Memorial Institute Smoking devices
GB1113979A (en) * 1966-05-19 1968-05-15 Ici Ltd Modified carbohydrate material for smoking mixtures
GB1431045A (en) * 1972-04-20 1976-04-07 Gallaher Ltd Synthetic smoking product
GB1421045A (en) * 1973-10-05 1976-01-14 Kurpanek W H Magnetomotive bista be switching devices
US4340072A (en) * 1979-11-16 1982-07-20 Imperial Group Limited Smokeable device
US4481958A (en) * 1981-08-25 1984-11-13 Philip Morris Incorporated Combustible carbon filter and smoking product
US4474191A (en) * 1982-09-30 1984-10-02 Steiner Pierre G Tar-free smoking devices
EP0117355B1 (en) * 1982-12-16 1991-03-20 Philip Morris Products Inc. Process for making a carbon heat source and smoking article including the heat source and a flavor generator

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