IE39407L - Vinyl chloride polymerisation in micro-suspension - Google Patents

Vinyl chloride polymerisation in micro-suspension

Info

Publication number
IE39407L
IE39407L IE741192A IE119274A IE39407L IE 39407 L IE39407 L IE 39407L IE 741192 A IE741192 A IE 741192A IE 119274 A IE119274 A IE 119274A IE 39407 L IE39407 L IE 39407L
Authority
IE
Ireland
Prior art keywords
acid
polymerization
soluble
vinyl chloride
micro
Prior art date
Application number
IE741192A
Other versions
IE39407B1 (en
Original Assignee
Rhone Progil
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Progil filed Critical Rhone Progil
Publication of IE39407L publication Critical patent/IE39407L/en
Publication of IE39407B1 publication Critical patent/IE39407B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
    • C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

1435425 Micro-suspension polymerization of vinyl chloride RHONE-PROGIL SA 5 June 1974 [8 June 1973] 24940/74 Heading C3P A method of homo- or co-polymerizing vinyl chloride in microsuspension which comprises polymerization of the monomer or monomers in micro-suspension in the presence of a seeding product in the form of particles of the vinyl chloride homopolymer or copolymer prepared by micro-suspension polymerization, which particles contain all of the organo-soluble initiator necessary for the polymerization, and in which the initiator is activated by the presence of an organo-soluble metallic complex produced in situ throughout the polymerization reaction system by reacting a water soluble metallic salt present in the polymerization system with a complexing agent that is capable of causing the metal to change from its water-soluble form to a form soluble in vinyl chloride, that has no inhibiting action on the polymerization or on the activation of the initiator, and that is progressively introduced throughout the course of the reaction. In a modification of the process the complex per se may be progressively introduced throughout the course of the reaction. The metal of the organo-soluble complex may be Fe, Cu, Co, Ni, Sn, Zn, Ti, V, Mn, Cr, or Ag and the complexing agent may be a monocarboxylic acid, a polycarboxylic acid, an alkyl phosphoric acid, lactone, ketone, or carbazone capable of causing the metal to change from its watersoluble form to a form soluble in vinyl chloride and having no inhibiting action on the polymerization and on the activation of the initiator, e.g. sulphosalicylic acid, naphthenic acid, octanoic acid, succinic acid, tartaric acid, maleic anhydride, di(2-ethyl)hexylphosphoric acid, ascorbic acid, γ-butyrolactone, benzoin, ascorbic acid, acetylacetone, or diphenylthiocarbazone. [GB1435425A]
IE1192/74A 1973-06-08 1974-06-06 Vinyl chloride polymerisation IE39407B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7320882A FR2234321B1 (en) 1973-06-08 1973-06-08

Publications (2)

Publication Number Publication Date
IE39407L true IE39407L (en) 1974-12-08
IE39407B1 IE39407B1 (en) 1978-09-27

Family

ID=9120689

Family Applications (1)

Application Number Title Priority Date Filing Date
IE1192/74A IE39407B1 (en) 1973-06-08 1974-06-06 Vinyl chloride polymerisation

Country Status (17)

Country Link
JP (1) JPS5137232B2 (en)
AT (1) AT328735B (en)
BE (1) BE815984A (en)
CA (1) CA1025149A (en)
CH (1) CH585769A5 (en)
DE (1) DE2427385C3 (en)
DK (1) DK145183C (en)
ES (1) ES427000A1 (en)
FI (1) FI57959C (en)
FR (1) FR2234321B1 (en)
GB (1) GB1435425A (en)
IE (1) IE39407B1 (en)
IT (1) IT1013397B (en)
LU (1) LU70259A1 (en)
NL (1) NL162933C (en)
NO (1) NO145661C (en)
SE (1) SE415356B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3882195A (en) * 1973-05-16 1975-05-06 Air Prod & Chem Pre-emulsification-delayed initiation suspension pearl polymerization process
FR2309569A1 (en) * 1975-04-30 1976-11-26 Rhone Poulenc Ind Microsuspension polymerisation of PVC - in presence of previously prepd. latex as mucleating agent
DE2702053A1 (en) * 1977-01-19 1978-07-20 Bayer Ag PRODUCTION OF COPOLYMERISATES FROM ACRYLIC NITRILE AND VINYL CHLORIDE
JPS5595074A (en) * 1979-01-13 1980-07-18 Kyoei Zoki Kk Crushed ice storage vessel
DE3165931D1 (en) * 1980-04-21 1984-10-18 Ici Plc VINYL CHLORIDE MICROSUSPENSION POLYMERISATION PROCESS
EP0094160B1 (en) * 1982-05-06 1986-07-16 Imperial Chemical Industries Plc Vinyl chloride polymerisation process
SE8503507L (en) * 1985-07-17 1987-01-18 Kenobel Ab SET FOR POLYMERIZATION OF VINYL CHLORIDE
FR2607138B1 (en) * 1986-11-24 1990-05-04 Atochem PROCESS FOR THE PREPARATION OF VINYL CHLORIDE IN SOMETHING MICROSUSPENSION AND COPOLYMERS
JPS63120064U (en) * 1987-01-28 1988-08-03
EP0556053B2 (en) 1992-02-13 2001-08-29 European Vinyls Corporation Technology Ag Polymerisation process
DE19841510A1 (en) * 1998-09-11 2000-03-16 Bayer Ag Polymerization process for the production of cross-linked copolymers

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2473549A (en) * 1947-10-11 1949-06-21 Goodrich Co B F Method of polymerizing vinylidene compounds in aqueous medium in the presence of silver ion and oxalate ion
GB895153A (en) * 1957-09-26 1962-05-02 Kureha Kasei Co Ltd Process for the production of vinyl polymers
US3255164A (en) * 1961-05-25 1966-06-07 Dow Chemical Co Redox polymerization incorporating step of dissolving reducing agent in monomer
US3281497A (en) * 1962-12-05 1966-10-25 Union Oil Co Transition metal salts of complex carboxylic acids as promoters of polymerization
GB978875A (en) * 1963-03-29 Ici Ltd
DE1213119B (en) * 1963-08-01 1966-03-24 Dynamit Nobel Ag Process for the polymerization or copolymerization of vinyl chloride
FR1485547A (en) * 1966-01-19 1967-06-23 Pechiney Saint Gobain Continuous process of polymerization of vinyl chloride
FR1512417A (en) * 1966-12-22 1968-02-09 Pechiney Saint Gobain Process for the preparation in suspension of polymers and copolymers based on vinyl chloride in the presence of a titanium-based catalytic system and resulting products
US3523111A (en) * 1967-08-18 1970-08-04 Monsanto Co Emulsion polymerization of vinyl chloride with redox initiator system components and emulsifier prepared before monomer addition
FR2044364A5 (en) * 1969-05-19 1971-02-19 Pechiney Saint Gobain
DE2006966C3 (en) * 1970-02-16 1982-08-26 Wacker-Chemie GmbH, 8000 München Process for the polymerization of vinyl chloride in an aqueous emulsion
FR2086634A5 (en) * 1970-04-03 1971-12-31 Pechiney Saint Gobain Vinyl chloride polymers - by low temp polymerisation in aqs emulsion with redox catalyst system one component which is added
FR2086635A5 (en) * 1970-04-03 1971-12-31 Pechiney Saint Gobain Vinyl chloride polymers - by aqs emulsion polymerisation in reaction medium contg an emulsifier, org peroxide and reducing age
DE2335930C2 (en) * 1972-07-18 1986-05-28 Fabio Lucca Perini Winding machine for winding a paper web, e.g. toilet paper web or the like.
GB1458367A (en) * 1973-06-08 1976-12-15 Ici Ltd Vinyl chloride polymerisation process
HU173513B (en) * 1975-04-30 1979-05-28 Rhone Poulenc Ind Process for the polymerization of vinylchloride in grafted microsuspension

Also Published As

Publication number Publication date
NO742045L (en) 1975-01-06
FR2234321B1 (en) 1976-06-11
JPS5033275A (en) 1975-03-31
FI172674A (en) 1974-12-09
DK145183B (en) 1982-09-27
DE2427385C3 (en) 1987-04-16
ES427000A1 (en) 1976-07-16
BE815984A (en) 1974-12-06
DE2427385A1 (en) 1974-12-19
DK145183C (en) 1983-02-21
FR2234321A1 (en) 1975-01-17
GB1435425A (en) 1976-05-12
IT1013397B (en) 1977-03-30
FI57959C (en) 1980-11-10
NL162933C (en) 1980-07-15
AT328735B (en) 1976-04-12
NL7407592A (en) 1974-12-10
SE7407483L (en) 1974-12-09
DK302574A (en) 1975-02-03
NO145661B (en) 1982-01-25
DE2427385B2 (en) 1979-06-07
SE415356B (en) 1980-09-29
JPS5137232B2 (en) 1976-10-14
CH585769A5 (en) 1977-03-15
FI57959B (en) 1980-07-31
ATA470474A (en) 1975-06-15
LU70259A1 (en) 1975-03-06
NO145661C (en) 1982-05-05
CA1025149A (en) 1978-01-24
IE39407B1 (en) 1978-09-27

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