IE35451B1 - A process for reducing the total sulphur content of claus off-gases - Google Patents
A process for reducing the total sulphur content of claus off-gasesInfo
- Publication number
- IE35451B1 IE35451B1 IE899/71A IE89971A IE35451B1 IE 35451 B1 IE35451 B1 IE 35451B1 IE 899/71 A IE899/71 A IE 899/71A IE 89971 A IE89971 A IE 89971A IE 35451 B1 IE35451 B1 IE 35451B1
- Authority
- IE
- Ireland
- Prior art keywords
- gases
- claus
- hydrogen
- absorbent
- sulphide
- Prior art date
Links
- 239000007789 gas Substances 0.000 title abstract 13
- 238000000034 method Methods 0.000 title abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title 1
- 239000005864 Sulphur Substances 0.000 title 1
- 230000002745 absorbent Effects 0.000 abstract 5
- 239000002250 absorbent Substances 0.000 abstract 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 abstract 2
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal salts Chemical class 0.000 abstract 1
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910052810 boron oxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 abstract 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 abstract 1
- 229940043276 diisopropanolamine Drugs 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- WHXRLGMKAWGISQ-UHFFFAOYSA-M potassium;2-(dimethylamino)acetate Chemical compound [K+].CN(C)CC([O-])=O WHXRLGMKAWGISQ-UHFFFAOYSA-M 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 1
- 239000004291 sulphur dioxide Substances 0.000 abstract 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 abstract 1
- 229960004418 trolamine Drugs 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/12—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
- C10K1/14—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors organic
- C10K1/143—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors organic containing amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Treating Waste Gases (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLAANVRAGE7010604,A NL171144B (nl) | 1970-07-17 | 1970-07-17 | Werkwijze voor het verlagen van het totale zwavelgehalte van clausafgassen. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE35451L IE35451L (en) | 1972-01-17 |
| IE35451B1 true IE35451B1 (en) | 1976-02-18 |
Family
ID=19810608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE899/71A IE35451B1 (en) | 1970-07-17 | 1971-07-15 | A process for reducing the total sulphur content of claus off-gases |
Country Status (18)
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7310929A (enrdf_load_stackoverflow) * | 1973-08-08 | 1974-01-25 | ||
| FR2295784A1 (fr) * | 1974-12-27 | 1976-07-23 | Inst Francais Du Petrole | Procede d'epuration d'un gaz contenant des composes du soufre |
| GB1470950A (en) * | 1976-03-08 | 1977-04-21 | Shell Int Research | Process for working-up hydrogen sulphide-containing gases |
| DE2648190C3 (de) * | 1976-10-25 | 1980-02-21 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von Schwefel nach dem Claus-Verfahren |
| GB1563251A (en) * | 1976-12-07 | 1980-03-26 | Shell Int Research | Process for working hydrogen suphidecontaining gases |
| NL7701174A (nl) * | 1977-02-04 | 1978-08-08 | Shell Int Research | Werkwijze voor het bereiden van een gasmengsel met gewenste h2s/co2 verhouding. |
| FR2425886A1 (fr) * | 1978-05-16 | 1979-12-14 | Elf Aquitaine | Procede de purification de gaz residuaires industriels renfermant en faibles concentrations des composes soufres |
| NL186377C (nl) | 1978-05-23 | 1990-11-16 | Shell Int Research | Werkwijze voor het opwerken van zwavelwaterstof bevattende gassen. |
| GB2116531B (en) * | 1982-03-11 | 1985-11-20 | Shell Int Research | Process and apparatus for the combustion of ammonia-containing waste gases |
| FR2631561B1 (fr) * | 1988-05-20 | 1990-07-20 | Elf Aquitaine | Procede et dispositif pour l'elimination de l'h2s present a faible concentration dans un gaz renfermant egalement une quantite importante de vapeur d'eau |
| GB8830199D0 (en) * | 1988-12-23 | 1989-02-22 | Shell Int Research | Removing hydrogen sulphide from a gas mixture |
| DE3901600C2 (de) * | 1989-01-20 | 1998-12-24 | Krupp Koppers Gmbh | Verfahren zur Behandlung der Vakuumabluft von Teerdestillationsanlagen |
| AU638543B2 (en) * | 1990-02-09 | 1993-07-01 | Mitsubishi Jukogyo Kabushiki Kaisha | Process for purifying high-temperature reducing gases and integrated coal gasification combined cycle power generation plant |
| US5266274A (en) * | 1992-10-13 | 1993-11-30 | Tpa, Inc. | Oxygen control system for a sulfur recovery unit |
| MY117311A (en) * | 1996-08-22 | 2004-06-30 | Shell Int Research | Process for reducing total sulphur content in gases containing hydrogen sulphide and other sulphur components |
| EP1902769A1 (en) * | 2006-09-22 | 2008-03-26 | Jacobs Nederland B.V. | Process for the recovery of sulfur from sulfur containing gases |
| EP3067109B1 (en) * | 2015-03-12 | 2018-12-05 | Prosernat | Process for removing sulfur compounds from a gas with hydrogenation and direct oxidation steps |
| WO2019022603A1 (en) | 2017-07-26 | 2019-01-31 | Wte-Tech B.V. | PROCESS FOR TREATING A SOFT COMPOUND COMPRISING A GAS CHARGE |
| CN116477580B (zh) * | 2023-04-26 | 2025-01-03 | 福州大学 | 一种可循环使用的硫化氢吸附剂解析气制硫磺的工艺及系统 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2361825A (en) * | 1941-08-25 | 1944-10-31 | Union Oil Co | Reduction of sulphur dioxide to hydrogen sulphide and free sulphur |
| FR1105475A (fr) * | 1954-01-24 | 1955-12-05 | Azote Office Nat Ind | Procédé pour la désulfuration des gaz et vapeurs industriels |
| US2860030A (en) * | 1954-12-17 | 1958-11-11 | Phillips Petroleum Co | Recovery of hydrogen sulfide and/or carbon dioxide substantially free from hydrocarbons and substantially pure hydrocarbons by chemical treatment of an impure hydrocarbon stream |
| US2887363A (en) * | 1956-09-28 | 1959-05-19 | Exxon Research Engineering Co | Conversion of methane to produce hydrogen sulfide |
| US3476513A (en) * | 1966-08-25 | 1969-11-04 | Exxon Research Engineering Co | Process and apparatus for the conversion of so2 in flue gas to sulfur |
| GB1116129A (en) * | 1967-03-02 | 1968-06-06 | Shell Int Research | Catalytic reduction of sulphur dioxide to hydrogen sulphide |
-
1970
- 1970-07-17 NL NLAANVRAGE7010604,A patent/NL171144B/xx not_active IP Right Cessation
-
1971
- 1971-07-15 ES ES393290A patent/ES393290A1/es not_active Expired
- 1971-07-15 CH CH1044271A patent/CH580982A5/xx not_active IP Right Cessation
- 1971-07-15 SU SU711683575A patent/SU751318A3/ru active
- 1971-07-15 BE BE770058A patent/BE770058A/xx not_active IP Right Cessation
- 1971-07-15 AT AT617071A patent/AT308768B/de not_active IP Right Cessation
- 1971-07-15 AU AU31283/71A patent/AU459768B2/en not_active Expired
- 1971-07-15 FI FI2009/71A patent/FI56320C/fi active
- 1971-07-15 IT IT7344/71A patent/IT941574B/it active
- 1971-07-15 FR FR7125898A patent/FR2101724A5/fr not_active Expired
- 1971-07-15 JP JP5215671A patent/JPS5716846B1/ja active Pending
- 1971-07-15 NO NO2707/71A patent/NO132088C/no unknown
- 1971-07-15 CS CS7100005221A patent/CS179372B2/cs unknown
- 1971-07-15 ZA ZA714698A patent/ZA714698B/xx unknown
- 1971-07-15 DE DE2135522A patent/DE2135522C2/de not_active Expired
- 1971-07-15 GB GB3321771A patent/GB1356289A/en not_active Expired
- 1971-07-15 IE IE899/71A patent/IE35451B1/xx unknown
- 1971-07-15 DK DK349871A patent/DK149328C/da not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE2135522C2 (de) | 1983-01-13 |
| JPS5716846B1 (enrdf_load_stackoverflow) | 1982-04-07 |
| DE2135522A1 (de) | 1972-01-20 |
| AU3128371A (en) | 1973-01-18 |
| CH580982A5 (enrdf_load_stackoverflow) | 1976-10-29 |
| DK149328B (da) | 1986-05-05 |
| FI56320B (fi) | 1979-09-28 |
| GB1356289A (en) | 1974-06-12 |
| FI56320C (fi) | 1980-01-10 |
| NL171144B (nl) | 1982-09-16 |
| NL7010604A (enrdf_load_stackoverflow) | 1972-01-19 |
| BE770058A (fr) | 1972-01-17 |
| DK149328C (da) | 1986-10-06 |
| ES393290A1 (es) | 1973-08-16 |
| NO132088B (enrdf_load_stackoverflow) | 1975-06-09 |
| CS179372B2 (en) | 1977-10-31 |
| AT308768B (de) | 1973-07-25 |
| NO132088C (enrdf_load_stackoverflow) | 1975-09-17 |
| SU751318A3 (ru) | 1980-07-23 |
| ZA714698B (en) | 1972-04-26 |
| IE35451L (en) | 1972-01-17 |
| IT941574B (it) | 1973-03-10 |
| AU459768B2 (en) | 1975-04-10 |
| FR2101724A5 (enrdf_load_stackoverflow) | 1972-03-31 |
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