HUP0202848A2 - Eljárás poliéter-poliolok előállítására - Google Patents
Eljárás poliéter-poliolok előállításáraInfo
- Publication number
- HUP0202848A2 HUP0202848A2 HU0202848A HUP0202848A HUP0202848A2 HU P0202848 A2 HUP0202848 A2 HU P0202848A2 HU 0202848 A HU0202848 A HU 0202848A HU P0202848 A HUP0202848 A HU P0202848A HU P0202848 A2 HUP0202848 A2 HU P0202848A2
- Authority
- HU
- Hungary
- Prior art keywords
- polyether polyols
- reactor
- hydrogen atoms
- active hydrogen
- starting compounds
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 3
- 229920000570 polyether Polymers 0.000 abstract 3
- 229920005862 polyol Polymers 0.000 abstract 3
- 150000003077 polyols Chemical class 0.000 abstract 3
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 239000007858 starting material Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 230000006698 induction Effects 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyethers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Excavating Of Shafts Or Tunnels (AREA)
Abstract
A találmány a vegyiparban, de különösen a poliuretán kémiában fontospoliéter-poliolok új, hatékonyabb előállítására vonatkozik. Atalálmány szerinti eljárás szerint a poliéter-poliolokat alkilén-oxidoknak aktív hidrogénatomokkal rendelkező kiindulási vegyületekretörténő DMC-katalizált poliaddíciójával úgy állítják elő, hogy azindukciós fázis során a reaktorba folyamatos ütemben alkilén-oxidotvezetnek be. A reakció során a reaktorban uralkodó nyomást konstansértéken tartva 1-8 hidroxilcsoporttal rendelkező és 18-2000 g/molmolekulatömegű aktív hidrogénatomokkal rendelkező kiindulásivegyületek és 0,001-0,1 tömeg% mennyiségű DMC-katalizátoralkalmazásával állíthatók elő a kívánt poliéter-poliolok. Ó
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19937114A DE19937114C2 (de) | 1999-08-06 | 1999-08-06 | Verfahren zur Herstellung von Polyetherpolyolen |
PCT/EP2000/007097 WO2001010933A1 (de) | 1999-08-06 | 2000-07-25 | Verfahren zur herstellung von polyetherpolyolen |
Publications (2)
Publication Number | Publication Date |
---|---|
HUP0202848A2 true HUP0202848A2 (hu) | 2002-12-28 |
HUP0202848A3 HUP0202848A3 (en) | 2003-11-28 |
Family
ID=7917415
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU0202848A HUP0202848A3 (en) | 1999-08-06 | 2000-07-25 | Method for preparing polyetherpolyols |
Country Status (19)
Country | Link |
---|---|
US (1) | US6486361B1 (hu) |
EP (1) | EP1206498B1 (hu) |
JP (1) | JP2003506543A (hu) |
KR (1) | KR20020019605A (hu) |
CN (1) | CN1138810C (hu) |
AT (1) | ATE256158T1 (hu) |
AU (1) | AU6697700A (hu) |
BR (1) | BR0012994A (hu) |
CA (1) | CA2381188A1 (hu) |
CZ (1) | CZ293452B6 (hu) |
DE (2) | DE19937114C2 (hu) |
ES (1) | ES2213034T3 (hu) |
HK (1) | HK1049344B (hu) |
HU (1) | HUP0202848A3 (hu) |
MX (1) | MXPA02001255A (hu) |
PL (1) | PL353099A1 (hu) |
PT (1) | PT1206498E (hu) |
RU (1) | RU2250910C2 (hu) |
WO (1) | WO2001010933A1 (hu) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060183882A1 (en) * | 2001-12-21 | 2006-08-17 | Dexheimer Edward M | Continuous process for preparation of polyether polyols |
WO2003062301A1 (fr) * | 2002-01-22 | 2003-07-31 | Asahi Glass Company, Limited | Procede de production continue de polyether |
DE10205086A1 (de) * | 2002-02-07 | 2003-08-21 | Basf Ag | Verfahren zur Aktivierung von Doppelmetallcyanid-Verbindungen |
US20050107643A1 (en) * | 2003-11-13 | 2005-05-19 | Thomas Ostrowski | Preparation of polyether alcohols |
KR101164264B1 (ko) * | 2003-11-13 | 2012-07-09 | 바스프 에스이 | 폴리에테르 알콜의 제조 방법 |
US7186867B2 (en) * | 2004-04-21 | 2007-03-06 | Basf Aktiengesellschaft | Process for preparing reactive polyether polyols having an ethylene oxide end block |
US20060223979A1 (en) * | 2005-04-04 | 2006-10-05 | Thomas Ostrowski | Process for preparing polyether polyols |
US8692030B1 (en) * | 2006-04-20 | 2014-04-08 | Pittsburg State University | Biobased-petrochemical hybrid polyols |
DE102006024025A1 (de) * | 2006-05-23 | 2007-11-29 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyetherpolyolen |
US20080132729A1 (en) * | 2006-12-01 | 2008-06-05 | Mcdaniel Kenneth G | Continuous process for the production of ethoxylates |
DE102008009407A1 (de) | 2008-02-15 | 2009-08-20 | Bayer Materialscience Ag | Klebstoff |
DE102008000903A1 (de) * | 2008-04-01 | 2009-10-08 | Evonik Goldschmidt Gmbh | Neue Organosiloxangruppen tragende Polyetheralkohole durch Alkoxylierung epoxidfunktioneller (Poly)Organosiloxane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung |
DE102009008867A1 (de) | 2009-02-13 | 2010-08-19 | Bayer Materialscience Ag | Klebstoff |
WO2011047780A1 (en) * | 2009-10-19 | 2011-04-28 | Basf Se | Conditioning of double metal cyanide catalysts |
US20130143909A1 (en) * | 2009-11-18 | 2013-06-06 | Nektar Therapeutics | Acid Salt Forms of Polymer-Drug Conjugates and Alkoxylation Methods |
KR101404702B1 (ko) | 2011-03-08 | 2014-06-17 | 에스케이이노베이션 주식회사 | 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법 |
CA2859566A1 (en) | 2011-12-20 | 2013-06-27 | Bayer Intellectual Property Gmbh | Hydroxy-aminopolymers and method for producing same |
DE102011089783A1 (de) | 2011-12-23 | 2013-06-27 | Bayer Materialscience Aktiengesellschaft | Niedrigviskose reaktive Polyurethan-Zusammensetzungen |
CN103360595B (zh) * | 2013-06-26 | 2015-09-09 | 淮安巴德聚氨酯科技有限公司 | 间歇法中催化环氧化物开环聚合时缩短诱导时间的方法 |
EP3106221A1 (en) | 2015-06-15 | 2016-12-21 | Universität Hamburg | Process for preparing double metal cyanide catalysts and their use in polymerization reactions |
GB201515350D0 (en) | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
EP3515965B1 (en) * | 2016-09-20 | 2020-07-15 | Dow Global Technologies, LLC | Alkoxylation process using tubular reactor |
GB201703324D0 (en) | 2017-03-01 | 2017-04-12 | Econic Tech Ltd | Method for preparing polyether carbonates |
WO2018158318A1 (de) | 2017-03-02 | 2018-09-07 | Covestro Deutschland Ag | Reaktionsgemische von isocyanaten und polyolen mit verlängerter topfzeit |
GB201717441D0 (en) | 2017-10-24 | 2017-12-06 | Econic Tech Ltd | A polymerisation process |
GB201814526D0 (en) | 2018-09-06 | 2018-10-24 | Econic Tech Ltd | Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates |
GB201906214D0 (en) | 2019-05-02 | 2019-06-19 | Econic Tech Ltd | A polyol block copolymer, compositions and processes therefor |
GB201906210D0 (en) | 2019-05-02 | 2019-06-19 | Econic Tech Limited | A polyol block copolymer, compositions and processes therefor |
GB202003003D0 (en) | 2020-03-02 | 2020-04-15 | Econic Tech Ltd | A polyol block copolymer |
GB202003002D0 (en) | 2020-03-02 | 2020-04-15 | Crane Ltd | Method of preparation of a polyol block copolymer |
CN111518268B (zh) * | 2020-05-28 | 2022-09-16 | 万华化学集团股份有限公司 | 一种聚醚多元醇的制备方法 |
GB202017531D0 (en) | 2020-11-05 | 2020-12-23 | Econic Tech Limited | (poly)ol block copolymer |
WO2023017276A1 (en) | 2021-08-11 | 2023-02-16 | Econic Technologies Ltd | Method for preparing surfactants by copolymerisation of epoxides and co2 using a mixture of a macrocyclic bimetal catalyst and a double metal cyanide catalyst |
GB202115335D0 (en) | 2021-10-25 | 2021-12-08 | Econic Tech Ltd | Surface-active agent |
CN115181259B (zh) * | 2022-08-11 | 2024-04-09 | 万华化学集团股份有限公司 | 一种连续化制备聚醚的方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
US3829505A (en) | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
US3941849A (en) | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
AU552988B2 (en) * | 1982-03-31 | 1986-06-26 | Shell Internationale Research Maatschappij B.V. | Polymerizing epoxides and catalyst suspensions for this |
US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
US5545601A (en) | 1995-08-22 | 1996-08-13 | Arco Chemical Technology, L.P. | Polyether-containing double metal cyanide catalysts |
US5767323A (en) | 1995-12-22 | 1998-06-16 | Arco Chemical Technology, L.P. | Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation |
US5777177A (en) | 1996-02-07 | 1998-07-07 | Arco Chemical Technology, L.P. | Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter |
US5627120A (en) | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
US5689012A (en) | 1996-07-18 | 1997-11-18 | Arco Chemical Technology, L.P. | Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter |
US5714428A (en) | 1996-10-16 | 1998-02-03 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing functionalized polymers |
DE19730467A1 (de) | 1997-07-16 | 1999-01-21 | Bayer Ag | Neue Zink/Metall-Hexacyanocobaltat-Katalysatoren für die Herstellung von Polyetherpolyolen |
CN1273217C (zh) | 1997-10-13 | 2006-09-06 | 拜尔公司 | 用于生产聚醚多元醇的晶态双金属氰化物催化剂 |
US6358877B1 (en) * | 1999-09-10 | 2002-03-19 | The Dow Chemical Company | Metal catalysts complexed with sulfone or sulfoxide compounds |
-
1999
- 1999-08-06 DE DE19937114A patent/DE19937114C2/de not_active Expired - Fee Related
-
2000
- 2000-07-25 RU RU2002106401/04A patent/RU2250910C2/ru not_active IP Right Cessation
- 2000-07-25 ES ES00954562T patent/ES2213034T3/es not_active Expired - Lifetime
- 2000-07-25 CA CA002381188A patent/CA2381188A1/en not_active Abandoned
- 2000-07-25 MX MXPA02001255A patent/MXPA02001255A/es active IP Right Grant
- 2000-07-25 CZ CZ2002459A patent/CZ293452B6/cs not_active IP Right Cessation
- 2000-07-25 DE DE50004742T patent/DE50004742D1/de not_active Expired - Fee Related
- 2000-07-25 HU HU0202848A patent/HUP0202848A3/hu unknown
- 2000-07-25 EP EP00954562A patent/EP1206498B1/de not_active Expired - Lifetime
- 2000-07-25 AT AT00954562T patent/ATE256158T1/de not_active IP Right Cessation
- 2000-07-25 CN CNB008113432A patent/CN1138810C/zh not_active Expired - Fee Related
- 2000-07-25 JP JP2001515737A patent/JP2003506543A/ja active Pending
- 2000-07-25 KR KR1020027001578A patent/KR20020019605A/ko not_active Application Discontinuation
- 2000-07-25 WO PCT/EP2000/007097 patent/WO2001010933A1/de active IP Right Grant
- 2000-07-25 PL PL00353099A patent/PL353099A1/xx not_active Application Discontinuation
- 2000-07-25 BR BR0012994-1A patent/BR0012994A/pt not_active IP Right Cessation
- 2000-07-25 AU AU66977/00A patent/AU6697700A/en not_active Abandoned
- 2000-07-25 US US10/048,684 patent/US6486361B1/en not_active Expired - Fee Related
- 2000-07-25 PT PT00954562T patent/PT1206498E/pt unknown
-
2003
- 2003-02-28 HK HK03101527.7A patent/HK1049344B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1138810C (zh) | 2004-02-18 |
ATE256158T1 (de) | 2003-12-15 |
AU6697700A (en) | 2001-03-05 |
BR0012994A (pt) | 2002-05-07 |
JP2003506543A (ja) | 2003-02-18 |
DE50004742D1 (de) | 2004-01-22 |
CN1368989A (zh) | 2002-09-11 |
DE19937114A1 (de) | 2001-02-15 |
CA2381188A1 (en) | 2001-02-15 |
CZ2002459A3 (cs) | 2002-05-15 |
HK1049344B (zh) | 2004-12-17 |
PL353099A1 (en) | 2003-10-20 |
EP1206498B1 (de) | 2003-12-10 |
CZ293452B6 (cs) | 2004-04-14 |
EP1206498A1 (de) | 2002-05-22 |
PT1206498E (pt) | 2004-04-30 |
MXPA02001255A (es) | 2002-08-12 |
RU2250910C2 (ru) | 2005-04-27 |
HK1049344A1 (en) | 2003-05-09 |
DE19937114C2 (de) | 2003-06-18 |
ES2213034T3 (es) | 2004-08-16 |
WO2001010933A1 (de) | 2001-02-15 |
HUP0202848A3 (en) | 2003-11-28 |
KR20020019605A (ko) | 2002-03-12 |
US6486361B1 (en) | 2002-11-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD9A | Lapse of provisional protection due to non-payment of fees |