HUE034360T2 - Polipropilén kompozíció, amely kombinálja a puhaságot, szívósságot, kis homályosságot és nagy hõellenállást - Google Patents
Polipropilén kompozíció, amely kombinálja a puhaságot, szívósságot, kis homályosságot és nagy hõellenállást Download PDFInfo
- Publication number
- HUE034360T2 HUE034360T2 HUE13706011A HUE13706011A HUE034360T2 HU E034360 T2 HUE034360 T2 HU E034360T2 HU E13706011 A HUE13706011 A HU E13706011A HU E13706011 A HUE13706011 A HU E13706011A HU E034360 T2 HUE034360 T2 HU E034360T2
- Authority
- HU
- Hungary
- Prior art keywords
- propylene
- propylene polymer
- mol
- comonomer
- polypropylene composition
- Prior art date
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- 229920001155 polypropylene Polymers 0.000 title claims description 150
- 239000000203 mixture Substances 0.000 title claims description 143
- -1 Polypropylene Polymers 0.000 title claims description 87
- 239000004743 Polypropylene Substances 0.000 title claims description 67
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 51
- 238000006116 polymerization reaction Methods 0.000 claims description 31
- 229920000642 polymer Polymers 0.000 claims description 16
- 229920001577 copolymer Polymers 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 229920001384 propylene homopolymer Polymers 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 235000002566 Capsicum Nutrition 0.000 claims 1
- 239000006002 Pepper Substances 0.000 claims 1
- 235000016761 Piper aduncum Nutrition 0.000 claims 1
- 235000017804 Piper guineense Nutrition 0.000 claims 1
- 244000203593 Piper nigrum Species 0.000 claims 1
- 235000008184 Piper nigrum Nutrition 0.000 claims 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims 1
- 210000001367 artery Anatomy 0.000 claims 1
- 210000004556 brain Anatomy 0.000 claims 1
- 238000012512 characterization method Methods 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 238000005260 corrosion Methods 0.000 claims 1
- 230000007797 corrosion Effects 0.000 claims 1
- 230000006837 decompression Effects 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 230000003381 solubilizing effect Effects 0.000 claims 1
- 239000002195 soluble material Substances 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 description 46
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 42
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 36
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 36
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 35
- 239000005977 Ethylene Substances 0.000 description 32
- 239000008096 xylene Substances 0.000 description 30
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 17
- 229920006395 saturated elastomer Polymers 0.000 description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 239000011949 solid catalyst Substances 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 230000007547 defect Effects 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 238000010348 incorporation Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 125000005842 heteroatom Chemical group 0.000 description 7
- 239000003446 ligand Substances 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 239000000155 melt Substances 0.000 description 6
- 230000000737 periodic effect Effects 0.000 description 6
- 230000002087 whitening effect Effects 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 5
- 238000004364 calculation method Methods 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 150000003623 transition metal compounds Chemical class 0.000 description 5
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 150000002431 hydrogen Chemical group 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- ULGZDMOVFRHVEP-RWJQBGPGSA-N Erythromycin Chemical compound O([C@@H]1[C@@H](C)C(=O)O[C@@H]([C@@]([C@H](O)[C@@H](C)C(=O)[C@H](C)C[C@@](C)(O)[C@H](O[C@H]2[C@@H]([C@H](C[C@@H](C)O2)N(C)C)O)[C@H]1C)(C)O)CC)[C@H]1C[C@@](C)(OC)[C@@H](O)[C@H](C)O1 ULGZDMOVFRHVEP-RWJQBGPGSA-N 0.000 description 3
- 238000005004 MAS NMR spectroscopy Methods 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 3
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 238000004009 13C{1H}-NMR spectroscopy Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- ALSOCDGAZNNNME-UHFFFAOYSA-N ethene;hex-1-ene Chemical compound C=C.CCCCC=C ALSOCDGAZNNNME-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000011002 quantification Methods 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 2
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- MXHQDFMXJIMLEN-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC=C(C=C1)C(C)(C)C)C)C1C(=CC2=C(C=CC=C12)C1=CC=C(C=C1)C(C)(C)C)C)C1CCCCC1 Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=C(C=CC=C12)C1=CC=C(C=C1)C(C)(C)C)C)C1C(=CC2=C(C=CC=C12)C1=CC=C(C=C1)C(C)(C)C)C)C1CCCCC1 MXHQDFMXJIMLEN-UHFFFAOYSA-L 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000003918 fraction a Anatomy 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Claims (3)
- PÛUPROPiUÈN KOMPOZÍCIÓ. AMELY KOMBINÁLJA A PUHASÁGOT, SZÍVÓSSÁGOT, KIS HOMÁLYOSSÁGOT ÉS HAGY HôateÂLÀsr SZABADALMI IGÉNYPONTOK 1 PollpropJéo kompozíció amely Oi> « v xorer , s o km V ?a ?* - », a*'vonat Ύ^?Αο 1 ív)> * ' eí> <,> tömeg % kiölti nmimylsogbén, ás íogaiápb egy Cvv sils-olef-nboi, 1.0 mól % és 3.0 möi % kálóit; fnsooyi#gi)o?L mâ * polipropilén kompod tsndoi» iegaGbb 40 tömeg % meftnylségber* xüoibso oldható anyagokkal t*ylé® :SÄ« (Ä amelyek 2SUC liőméísákiétén árinak meghatározva stz s SO 1G152 szabvány («iso k«âdàs. 2005-0 í -th) szerint, es a xí!0:bsn ölUhoip anpgöksazioiSní-emdötSikömonoínsf egységekből olyan mennyiséggel bírnak, amely 4,0 tömeg % es rö tömeg 1¾ közölt van, Äi :.a- Következő összefüggés van Kielégítve; píKSi : y :ÁSí1SSjY Cllslal 1: 'Q:M öböl: a Képletben :óE|KS|i2iÁtíién-gíöctelÖ kcvaokarn®T:®§yöépk tneonyiságo !ümeg:Ák'-te axiiöibsn oki sate anysgskbain MM iPÉipöpílén: kpmgozioio kiioljsan oiéáa*Á spyagninAk aisanylsöp töbieg AGosn, amely Ä·#:: boméssákiafón van iöi^Éieáa" SC s\,'«ab\a,,v «-kok &» \C>> öt;e «r.'* Clptöl.....mlsklppn C2pps), m komonomér agysipk mennyisége tömeg %m. m pilist» Ácmpsaistöbam. G, ::Áz %>: fglnypsPiiaKenó II pokgmplén kompoksisi, Aboi á léggllfeö ö|y fezkS:í8#§«n a: Imvoteozök Ä vsiasztasto kï, i-paÄ,. í-okSon, 0$ ezek Lát milyen kovereke. 3 Az L vagy 2, igénypont satina poilpropsén kompozíció, onoí a xiloiöarrotöbafö aliyagok tartalmazoak adöi írtóonyissgú olyan komonomer egyseget, amely legelőbb egy Cm:· aíia-oMfinOöi asiímaziSö ahol ez a mennyiség 8,81 rnä H eo %8-Teái· % kozott, elónyóson 0,05 mó? % és 1,0 mól % kozok von. 4. A? 1*3. igénypontok bármelyike szerinti polipropilén kompezii^á, oho? a komonömer egységek, előnyösen ez eiáritíos os fegavtlbb egy íjgfá# r?ieb8:^ii^rA· 3,0 rnol % és limai.¾ előnyösen 5,0 mól % és 1? mél % között van. I. Az 1-4 igénypontok Dámielyikö §20ΐΙηΙ| |Sölit3T0pMrt Kéím^öSílclÖ, amelynek olyan rugalmasság; (bózásá modulusa (tensile eiOJoioa} van, abet ez keveseDb, mm! 450 kíPa (az ISO §27-2 szabvány szóén? mérve)
- 8, Az VS. igénypontok báneeiy;ke»níi polipmplin korpái #Sí é &tälpropiin.:ta^#- «· fcWÄfc rector keverék, amely a kővetkező propilén polvne? frakciókat iartaírnazza. Pl. P2 es P?: a (Pl) propilén homopolimer vagy proplién kopolimer, amely olyan komoftome? egységeket tartalmaz amelyek iegaiÄefy G& v? aiia-oíeilnböl származnak,: pipa mennyiségfeea, .p^íyÁáPPiiLtáiblíítl.iél % a (P2) propilén koçmtmi amely piyap kontsinomir sgysépke? elei: szék: $pg|$: ;4p: Óem ifamiaiibot származnak, olyan mennyiségben, amely 2,0 mól % és 7,0 mól % kézéi? van. a (P3) propilén kopoiímer, Mti£ iárlÉrnaz olyan mémiyisepen, amely 4 0 tömeg % és 70 tömeg % kézét? var; 7amelyek tsrtslmazzák az 1 -6. igényporéok oármoiyike szerin?: polipropilén kompeziaóí. I, iÉijárés az 1;4l,. l|É?ipéÉok -álárinS poaproplén: ikontpézlöió síélGilste üielf :e^|ítÁk· M il*étkS^: íégáéáikát' •artalmazza: (i) etkészliünk egy PR1 első pöllmerizáció? mnktooom eső propilén polimer frakciókén! egy ptoplién homopoiimért vagy ^Y oiysn propilén kopognod, amely Isgaiâbb egy C* íxaiAMeitnoél szármas® komenomer egységeket tártaimat (ii'? àtvissaâk a PR" eto poiimenzáciés reaktöroatí Kspoïî eisá propra polimer ?r?,îkftî6î 8 PR2 második gdimentatos reaktora ès «lkés?.!Kmk egy rr»asodïk proven boiimer rrakciôi oromén ás lepíább agy pétirseréâtsa réven ag plip prépiiÉîî polimer iffegigéir Φ&Μ a második prepáén pohníer rmkcio^ rendőr keverékéi (blend), P! at* w.' a > Vidar '*s s 'R,< \r , mx ft\"" >eWo«ir x i-kávftmk *g\ *> »má?\ k'v'P' .·$ il) iépis rálkior kekekének jelenlétében, ez&tai megkapjuk a? eisö, második és natreadik pmpifôn polimer irskolók reaktor keveréké* 9 A 8 :géoypcat szerinti eljárás. ahol a felosztás (sold a PRi alsó propHér« polimer Pakoló ás a PR2 második. propilén polimer frakció koséit 70/30 és W0 ®í! van. előnyösen §0/40 és 40/60 kozm. és/vagy ahol a feiosttős a H lépés mm keveréke és a PR3 harmadik propilén polimer irakcio közön OOMO és 40/60 kosod vas. előnyösen 55/40 és 45/55 későd: 10, A 8. vagy B. igénypont szerinti eljárás, ahoi a RR1 elad poümsrizáotés reaktor zagy (slurry) reaktor reaktor, ás a második és harmadik polimsrizáolós reaktorok mindketten gázfázisú reaktorok. 11. A 3Ί0, igénypontok hárrmeyske szerinti eljárás, ahol egy egyedi helyű (simple site) katalizátort eisaimpapk. á RB1 - RRá psiimetlzáctös reaktorok legalább egyikében,
- 42. Alkalmazása az *-6. igénypontok bármelyike ezerie! kempáldőhak fidpeeóhtpA |ine<k|ek: :ρΐ5&ρί?#3%
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| HUE13706011A HUE034360T2 (hu) | 2012-02-27 | 2013-02-26 | Polipropilén kompozíció, amely kombinálja a puhaságot, szívósságot, kis homályosságot és nagy hõellenállást |
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| Country | Link |
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| US (1) | US9416207B2 (hu) |
| EP (1) | EP2820082B1 (hu) |
| CN (1) | CN104169355B (hu) |
| ES (1) | ES2626851T3 (hu) |
| HU (1) | HUE034360T2 (hu) |
| IN (1) | IN2014KN01645A (hu) |
| PL (1) | PL2820082T3 (hu) |
| PT (1) | PT2820082T (hu) |
| WO (1) | WO2013127760A1 (hu) |
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| US9115279B2 (en) | 2013-03-15 | 2015-08-25 | Asahi Kasei Plastics North America, Inc. | Polypropylene compounds with high impact performance and improved stress whitening resistance |
| PL3064548T3 (pl) * | 2015-03-02 | 2017-09-29 | Borealis Ag | Kompozycja polipropylenowa łącząca niską temperaturę inicjowania zgrzewania, niskie zmętnienie, niską zawartość substancji rozpuszczalnych w heksanie oraz polepszoną odporność na rozdarcie i temperaturę topnienia |
| KR101943224B1 (ko) | 2017-12-12 | 2019-01-28 | 한화토탈 주식회사 | 이종 고무 성분을 포함하는 전선용 폴리올레핀 수지 조성물 |
| ES2966041T3 (es) * | 2018-01-05 | 2024-04-18 | Borealis Ag | Copolímeros impactados a base de catalizadores de sitio único con excelentes propiedades mecánicas y ópticas |
| KR101985611B1 (ko) | 2018-01-16 | 2019-06-03 | 한화토탈 주식회사 | 전선 절연용 폴리올레핀 수지 조성물 |
| EP4136129A1 (en) * | 2020-04-17 | 2023-02-22 | Borealis AG | Blown film |
| WO2023036716A1 (en) | 2021-09-09 | 2023-03-16 | Totalenergies Onetech | Polypropylene-based compositions with transparency and elongational properties |
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| DE69518094T2 (de) | 1994-04-11 | 2001-03-22 | Mitsui Chemicals, Inc. | Verfahren zur Herstellung von einer Propylen-Polymer-Zusammensetzung und Propylen-Polymer-Zusammensetzung |
| WO1998059002A1 (en) | 1997-06-24 | 1998-12-30 | Borealis A/S | Heterophasic propylene copolymer and process for its preparation |
| SG119146A1 (en) | 2001-03-07 | 2006-02-28 | Sumitomo Chemical Co | Polypropylene-based resin composition process for producing the same and injection molded article |
| EP1279699A1 (en) * | 2001-07-27 | 2003-01-29 | Baselltech USA Inc. | Soft polyolefin compositions |
| EP1323747A1 (en) | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| KR100944929B1 (ko) * | 2002-03-12 | 2010-03-03 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 내충격성 폴리올레핀 물품 제조용 폴리올레핀 마스터배치 |
| BRPI0620531B1 (pt) | 2005-11-22 | 2018-01-30 | Basell Poliolefine Italia S.R.L. | Composições poliolefínicas resistentes a impacto |
| KR101422554B1 (ko) * | 2006-08-04 | 2014-07-24 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 헤테로상 프로필렌 공중합체의 기체 상 제조 방법 |
| ES2619729T3 (es) | 2008-11-07 | 2017-06-26 | Borealis Ag | Composición de catalizador sólida |
| SG171320A1 (en) | 2008-12-17 | 2011-07-28 | Basell Poliolefine Srl | Foamed polyolefin composition |
| BR112012032548B1 (pt) | 2010-06-23 | 2020-10-27 | Basell Poliolefine Italia S.R.L. | composição de poliolefina, e folhas e sistemas de tubulação compreendendo tal composição de poliolefina |
-
2013
- 2013-02-26 ES ES13706011.7T patent/ES2626851T3/es active Active
- 2013-02-26 PL PL13706011T patent/PL2820082T3/pl unknown
- 2013-02-26 CN CN201380010163.1A patent/CN104169355B/zh active Active
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- 2013-02-26 WO PCT/EP2013/053767 patent/WO2013127760A1/en not_active Ceased
- 2013-02-26 PT PT137060117T patent/PT2820082T/pt unknown
- 2013-02-26 IN IN1645KON2014 patent/IN2014KN01645A/en unknown
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| Publication number | Publication date |
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| IN2014KN01645A (hu) | 2015-10-23 |
| CN104169355A (zh) | 2014-11-26 |
| PL2820082T3 (pl) | 2017-08-31 |
| WO2013127760A1 (en) | 2013-09-06 |
| EP2820082A1 (en) | 2015-01-07 |
| US9416207B2 (en) | 2016-08-16 |
| ES2626851T3 (es) | 2017-07-26 |
| EP2820082B1 (en) | 2017-03-29 |
| PT2820082T (pt) | 2017-05-19 |
| CN104169355B (zh) | 2016-04-13 |
| US20150045522A1 (en) | 2015-02-12 |
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