HU212974B - Process for the preparation of a catalyst and for producing olefins - Google Patents
Process for the preparation of a catalyst and for producing olefins Download PDFInfo
- Publication number
- HU212974B HU212974B HU9400312A HU9400312A HU212974B HU 212974 B HU212974 B HU 212974B HU 9400312 A HU9400312 A HU 9400312A HU 9400312 A HU9400312 A HU 9400312A HU 212974 B HU212974 B HU 212974B
- Authority
- HU
- Hungary
- Prior art keywords
- catalyst
- electron donor
- donor compound
- polymerization
- reactor
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 20
- 150000001336 alkenes Chemical class 0.000 title claims description 11
- 238000002360 preparation method Methods 0.000 title description 15
- 239000010936 titanium Substances 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 20
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 229910052719 titanium Inorganic materials 0.000 claims description 19
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 18
- 239000011777 magnesium Substances 0.000 claims description 18
- 229910052749 magnesium Inorganic materials 0.000 claims description 17
- -1 aliphatic ethers Chemical class 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- 150000003624 transition metals Chemical class 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 230000000737 periodic effect Effects 0.000 claims description 8
- 229910052723 transition metal Inorganic materials 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 2
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 150000003334 secondary amides Chemical class 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 9
- 239000004698 Polyethylene Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000012685 gas phase polymerization Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000003426 co-catalyst Substances 0.000 description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
- 239000012495 reaction gas Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical class II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- SQCZQTSHSZLZIQ-UHFFFAOYSA-N 1-chloropentane Chemical compound CCCCCCl SQCZQTSHSZLZIQ-UHFFFAOYSA-N 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical group 0.000 description 1
- 125000002370 organoaluminium group Chemical group 0.000 description 1
- 125000002734 organomagnesium group Chemical group 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003003 phosphines Chemical group 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9207150A FR2691970B1 (fr) | 1992-06-04 | 1992-06-04 | Procede de preparation d'un catalyseur de polymerisation. |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| HU9400312D0 HU9400312D0 (en) | 1994-05-30 |
| HUT68128A HUT68128A (en) | 1995-03-21 |
| HU212974B true HU212974B (en) | 1997-01-28 |
Family
ID=9430695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU9400312A HU212974B (en) | 1992-06-04 | 1993-06-02 | Process for the preparation of a catalyst and for producing olefins |
Country Status (12)
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5968862A (en) * | 1992-06-10 | 1999-10-19 | Chevron Chemical Company | Transition metal-magnesium catalyst precursors for the polymerization of olefins |
| CA2234869A1 (en) * | 1997-06-30 | 1998-12-30 | Chevron Chemical Company | Transition metal-magnesium catalyst precursors, catalysts and polymerization processes |
| DE602004003707T2 (de) * | 2003-07-11 | 2007-04-12 | Innovene Europe Ltd., Staines | Verfahren zur polymerisation und copolymerisation von ethylen in der gasphase |
| PT1644422E (pt) | 2003-07-11 | 2007-02-28 | Ineos Europe Ltd | Processo para a (co-) polimerização de etileno em fase gasosa |
| EP2172490A1 (en) | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Controlled polymerisation process |
| CN101962417B (zh) * | 2009-07-24 | 2012-11-21 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂、制备及应用 |
| EP2357035A1 (en) | 2010-01-13 | 2011-08-17 | Ineos Europe Limited | Polymer powder storage and/or transport and/or degassing vessels |
| EP2383301A1 (en) | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerization process |
| EP2383298A1 (en) | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerization process |
| US9394381B2 (en) | 2010-11-29 | 2016-07-19 | Ineos Sales (Uk) Limited | Polymerisation control process |
| US8383740B1 (en) | 2011-08-12 | 2013-02-26 | Ineos Usa Llc | Horizontal agitator |
| ES2665545T3 (es) | 2011-10-17 | 2018-04-26 | Ineos Europe Ag | Control del proceso de desgasificación del polímero |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57108109A (en) * | 1980-12-24 | 1982-07-06 | Mitsubishi Chem Ind Ltd | Producton of olefin polymer |
| JPS57151601A (en) * | 1981-03-16 | 1982-09-18 | Idemitsu Kosan Co Ltd | Polymerization of olefins |
| IT1137631B (it) * | 1981-07-29 | 1986-09-10 | Anic Spa | Procedimento per la polimerizzazione e copolimerizzazione in alta resa di composti olefinicamente insaturi e mezzi adatti allo socpo |
| EP0452156B1 (en) * | 1990-04-13 | 1997-08-13 | Mitsui Petrochemical Industries, Ltd. | Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization |
-
1992
- 1992-06-04 FR FR9207150A patent/FR2691970B1/fr not_active Expired - Fee Related
-
1993
- 1993-06-02 BR BR9305539A patent/BR9305539A/pt not_active Application Discontinuation
- 1993-06-02 CZ CZ94189A patent/CZ18994A3/cs unknown
- 1993-06-02 HU HU9400312A patent/HU212974B/hu not_active IP Right Cessation
- 1993-06-02 EP EP93913271A patent/EP0598094A1/en not_active Withdrawn
- 1993-06-02 SK SK113-94A patent/SK11394A3/sk unknown
- 1993-06-02 PL PL30231593A patent/PL302315A1/xx unknown
- 1993-06-02 WO PCT/GB1993/001166 patent/WO1993024542A1/en not_active Application Discontinuation
- 1993-06-02 JP JP6501842A patent/JPH07502300A/ja active Pending
- 1993-06-03 TW TW82104428A patent/TW226383B/zh active
- 1993-06-04 MX MX9303367A patent/MX9303367A/es not_active Application Discontinuation
- 1993-06-04 CN CN 93108275 patent/CN1083820A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| HUT68128A (en) | 1995-03-21 |
| FR2691970B1 (fr) | 1995-08-25 |
| FR2691970A1 (fr) | 1993-12-10 |
| WO1993024542A1 (en) | 1993-12-09 |
| TW226383B (enrdf_load_stackoverflow) | 1994-07-11 |
| SK11394A3 (en) | 1994-09-07 |
| PL302315A1 (en) | 1994-08-08 |
| MX9303367A (es) | 1994-07-29 |
| CN1083820A (zh) | 1994-03-16 |
| JPH07502300A (ja) | 1995-03-09 |
| CZ18994A3 (en) | 1994-06-15 |
| HU9400312D0 (en) | 1994-05-30 |
| EP0598094A1 (en) | 1994-05-25 |
| BR9305539A (pt) | 1994-12-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0322798B1 (en) | A solid catalyst component for the polymerization of olefins and an olefin polymerization catalyst | |
| EP1125950B1 (en) | Polymerization catalyst comprising a reaction product of aluminum alkyl and cyclodextrin. | |
| US4829038A (en) | Alpha-olefin polymerization catalyst system including an advantageous modifier component | |
| EP0250229B1 (en) | Alpha-olefin polymerization catalyst system including an advantageous modifier component | |
| CA1163617A (en) | Catalyst for polymerization of olefins and polymerization process employing such catalyst | |
| US5798424A (en) | Olefin polymerization catalyst and process for the polymerization of olefins using the same | |
| US20030064882A1 (en) | Olefin polymerization catalyst compositions and method of preparation | |
| EP0474249B1 (en) | Solid component of a catalyst for the (co)polymerization of ethylene | |
| JP2000516987A (ja) | オレフィンの重合用成分および触媒 | |
| US4159963A (en) | Catalyst for producing polyolefins | |
| EP0198151A2 (en) | Catalyst components, a catalyst and a process for the polymerization of olefins | |
| JPH03502207A (ja) | オレフィンの重合用担持バナジウム触媒及びその製造及び使用方法 | |
| US4820672A (en) | Hydrocarbon soluble and insoluble organo magnesium chloride complexes, processes and uses | |
| HU212974B (en) | Process for the preparation of a catalyst and for producing olefins | |
| JP2010537028A (ja) | オレフィンの重合用の触媒 | |
| JP2010209362A (ja) | マグネシウムジクロライド−アルコール付加物の製造方法 | |
| US4295992A (en) | Support prepared from organomagnesium compounds and silicon halides; and catalysts for polymerizing olefins | |
| US4283515A (en) | Support, catalyst and process for polymerizing olefins | |
| JP3306119B2 (ja) | オレフィン重合体の製造方法 | |
| KR20060126929A (ko) | 폴리올레핀용 지글러-나타 촉매 | |
| EP0020808B1 (en) | Support, catalyst and process for polymerizing olefins | |
| EP0111902B1 (en) | Catalyst and process using same for producing olefin polymer | |
| JP2717723B2 (ja) | ポリオレフィンの製造方法 | |
| EP0111903B1 (en) | Olefin polymerization catalysts and process for producing olefin polymers by using such catalysts | |
| US4297462A (en) | Polymerization of monoolefins using an aluminum-titanium catalyst system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HMM4 | Cancellation of final prot. due to non-payment of fee |