HRP20231471T1 - Derivati spiro cikloheksandiona kao herbicidi - Google Patents
Derivati spiro cikloheksandiona kao herbicidi Download PDFInfo
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- HRP20231471T1 HRP20231471T1 HRP20231471TT HRP20231471T HRP20231471T1 HR P20231471 T1 HRP20231471 T1 HR P20231471T1 HR P20231471T T HRP20231471T T HR P20231471TT HR P20231471 T HRP20231471 T HR P20231471T HR P20231471 T1 HRP20231471 T1 HR P20231471T1
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- Prior art keywords
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- alkyl
- hydrogen
- phenyl
- heterocyclyl
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- 239000004009 herbicide Substances 0.000 title claims 4
- OILAIQUEIWYQPH-UHFFFAOYSA-N cyclohexane-1,2-dione Chemical compound O=C1CCCCC1=O OILAIQUEIWYQPH-UHFFFAOYSA-N 0.000 title 1
- 125000003003 spiro group Chemical group 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 15
- 239000001257 hydrogen Substances 0.000 claims 15
- 150000001875 compounds Chemical class 0.000 claims 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 8
- 125000004093 cyano group Chemical group *C#N 0.000 claims 7
- 125000000623 heterocyclic group Chemical group 0.000 claims 7
- 229910052736 halogen Inorganic materials 0.000 claims 6
- 150000002367 halogens Chemical class 0.000 claims 6
- 230000002363 herbicidal effect Effects 0.000 claims 6
- 150000002431 hydrogen Chemical class 0.000 claims 6
- 125000001424 substituent group Chemical group 0.000 claims 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 5
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 4
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 3
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- -1 hydroxyl- Chemical group 0.000 claims 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 claims 2
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims 2
- 241000196324 Embryophyta Species 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 125000000304 alkynyl group Chemical group 0.000 claims 2
- 125000001188 haloalkyl group Chemical group 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000000575 pesticide Substances 0.000 claims 2
- 125000004076 pyridyl group Chemical group 0.000 claims 2
- 229920006395 saturated elastomer Polymers 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 1
- 125000006570 (C5-C6) heteroaryl group Chemical group 0.000 claims 1
- 125000004399 C1-C4 alkenyl group Chemical group 0.000 claims 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims 1
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 125000001072 heteroaryl group Chemical group 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000003223 protective agent Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
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- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/08—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing alicyclic rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
- C07D211/18—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D211/20—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms
- C07D211/22—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms by oxygen atoms
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- C07D221/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00
- C07D221/02—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00 condensed with carbocyclic rings or ring systems
- C07D221/20—Spiro-condensed ring systems
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- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
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- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
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Claims (15)
1. Spoj s formulom (I)
[image]
naznačen time što
R1 je odabran od metila, fenila i 5- ili 6-eročlanog heteroarila koji sadrži jedan ili dva dušikova heteroatoma, navedeni fenil i heteroaril su izborno supstituirani s jednim ili dva R15 supstituenta;
R2 je metil ili metoksi;
R3 je metil ili metoksi;
R4 je odabran iz skupine koja sadrži C1-C4alkil, C1-C4alkoksi-, C1-C4haloalkil, -C(=O)C1-C4alkil, -C(=O)C1-C4haloalkil, -S(O)nC1-C6alkil, - S(O)nC1-C6haloalkil, -S(O)n-(CH2)n-C3-C6cikloalkil, -S(O)nC(R11)R12R13, - C(O)H, -C(O)-(CH2)n-C3-C6cikloalkil, -C(O)C(R11)R12R13, -C(O)C2-C4alkenil, - C(O)(CR9R10)CN, -C(O)(CR9R10)(CR9R10)CN, -C(O)CH2C(O)-C1-C6alkil, - C(O)CH2OC(O)-C1-C6alkil, -C(O)OC1-C6alkil, -C(O)OC1-C6haloalkil, - C(O)(CH2)nS(O)nCl-C6alkil, -C(O)C1-C3alkoksiC1-C6alkil, -C(O)C1-C3alkoksiC2-C6alkenil, -C(O)C1-C3alkoksiC2-C6alkinil, -C(O)C1-C3alkoksiC1-C6haloalkil, -C(O)C1-C3alkoksiC3-C6cikloalkil, -C(O)OC1-C3alkoksiC1-C6alkil, -C(O)C1-C3alkoksiC1-C3alkoksiC1-C6alkil, -C(O)(CH2)nNR5R6, -C(O)-(CH2)n-NR7C(O)R8, -C(O)-(CH2)n-O-N=CR5R5, -CN, -(CH2)n-fenil, -C(O)-(CH2)n-fenil, -S(O)n-(CH2)n-fenil, -heterociklil, -C(O)-(CH2)n-heterociklil, - C(O)(CH2)nO-(CH2)n-heterociklil, -S(O)n-(CH2)n-heterociklil, pri čemu je svaki heterociklil 5- ili 6-eročlani heterociklil koji može biti aromatski, zasićen ili djelomično zasićen i može sadržavati od 1 do 4 heteroatoma od kojih je svaki neovisno odabran iz skupine koju čine kisik, dušik i sumpor, te pri čemu su navedene heterociklilne ili fenilne skupine izborno supstituirane s jednim, dva ili tri supstituenta neovisno odabrana iz skupine koju čine C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C2-C3alkenil, C2-C3alkinil, halogen, cijano i nitro;
R5 je odabran iz skupine koja sadrži vodik i C1-C6 alkil;
R6 je odabran iz skupine koja sadrži vodik, C1-C6alkil, C2-C6alkenil, C2-C6alkinil, C1-C6haloalkil, hidroksil-, C1-C6alkoksi, C3-C6 cikloalkil, , -C1-C4alkoksiC1-C6alkil, -C1-C3alkoksiC1-C6haloalkil, -(CR9R10)C1-C6haloalkil, - (CR9R10)C(O)NR5R5, fenil, -piridil, pri čemu su fenil i piridil izborno supstituirani s jednim, dva ili tri supstituenta neovisno odabrana iz skupine koja sadrži C1-C3 alkil, C1-C3 haloalkil, C1-C3 alkoksi, C2-C3 alkenil, C2-C3 alkinil, halogen, cijano i nitro; ili
R5 i R6 zajedno tvore -CH2CH2OCH2CH2-; i
R7je odabran iz skupine koja sadrži vodik i C1-C6 alkil;
R8 je odabran iz skupine koja sadrži vodik, C1-C6 alkil, C1-C6 alkoksi, C3-C6 cikloalkil, fenil, -piridil, pri čemu su fenil i piridil izborno supstituirani s jednim, dva ili tri supstituenta neovisno odabrana iz skupine koja sadrži C1-C3 alkil, C1-C3 haloalkil, C1-C3 alkoksi, C2-C3 alkenil, C2-C3 alkinil, halogen, cijano i nitro;
R9 je vodik ili metil;
R10 je vodik ili metil; ili
R9 i R10 zajedno tvore -CH2CH2-; i
R11 je vodik ili metil;
R12 je odabran iz skupine koja sadrži vodik, C1-C6 alkil, hidroksil i C1-C6 alkoksi-;
R13 je odabran iz skupine koja sadrži vodik, C1-C6 alkil, hidroksil i C1-C6 alkoksi; ili
R12 i R13 zajedno tvore -CH2-X-CH2-; i
X je odabran iz skupine koja sadrži O, S i N-R14;
R14 je odabran iz skupine koja sadrži vodik, C1-C3 alkil i C1-C3 alkoksi-;
R15 je neovisno odabran iz skupine koja sadrži C1-C4 alkil, C1-C4 haloalkil, cijano i halogen;
G je odabran iz skupine koja sadrži vodik, -(CH2)n-Ra, -C(O)-Ra, - C(O)-(CRcRd)n-O-Rb, -C(O)-(CRcRd)n-S-Rb, -C(O)NRaRa, -S(O)2-Ra i C1-C8alkoksi-C1-C3alkil-;
R8 je neovisno odabran iz skupine koja sadrži vodik, C1-Csalkil, C1-C3haloalkil, C2-Csalkenil, C2-C8alkinil, C3-C6cikloalkil, heterociklil i fenil pri čemu su navedene heterociklilne i fenilne skupine izborno supstituirane s jednim, dva ili tri supstituenta neovisno odabrana iz skupine koja sadrži C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C2-C3alkenil, C2-C3alkinil, halogen, cijano i nitro;
Rb je odabran iz skupine koja sadrži C1-C8alkil, C1-C3haloalkil, C2-Csalkenil, C2-Csalkinil, C3-C6 cikloalkil, heterociklil i fenil pri čemu su navedene heterociklilne i fenilne skupine izborno supstituirane s jednim, dva ili tri supstituenta neovisno odabrana iz skupine koja sadrži C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C2-C3alkenil, C2-C3alkinil, halogen, cijano i nitro;
Rc je vodik ili C1-C3 alkil;
Rd je vodik ili C1-C3 alkil; i
n je neovisno 0, 1 ili 2;
ili njegova poljoprivredno prihvatljiva sol.
2. Spoj prema zahtjevu 1, naznačen time što R2 je metil.
3. Spoj prema bilo kojem od prethodnih zahtjeva, naznačen time što R3 je metil.
4. Spoj prema bilo kojem od prethodnih zahtjeva 1 do 2, naznačen time što R3 je metoksi.
5. Spoj prema bilo kojem od prethodnih zahtjeva, naznačen time što R4 je C1-C4alkoksi-.
6. Spoj prema bilo kojem od zahtjeva 1 do 4, naznačen time što R4 je - C(=O)C1-C4alkil.
7. Spoj prema bilo kojem od zahtjeva 1 do 4, naznačen time što R4 je - C(O)OC1-C6alkil.
8. Spoj prema bilo kojem od prethodnih zahtjeva, naznačen time što G je vodik.
9. Spoj prema bilo kojem od zahtjeva 1 do 7, naznačen time što G je -C(O)C1-C6alkil.
10. Spoj prema bilo kojem od zahtjeva 1 do 7, naznačen time što G je -C(O)-O-C1-C6alkil.
11. Herbicidni pripravak, naznačen time što sadrži spoj Formule (I) prema bilo kojem od prethodnih zahtjeva i poljoprivredno prihvatljiv formulacijski adjuvant.
12. Herbicidni pripravak prema zahtjevu 11, naznačen time što nadalje sadrži najmanje jedan dodatni pesticid.
13. Herbicidni pripravak prema zahtjevu 12, naznačen time što je dodatni pesticid herbicid ili herbicidno zaštitno sredstvo.
14. Postupak suzbijanja korova na mjestu rasta, naznačena time što se sastoji od primjene na mjesto rasta količine pripravka za suzbijanje korova prema bilo kojem od zahtjeva 11 do 13.
15. Upotreba spoja formule (I) kako je definirano u zahtjevu 1 kao herbicida.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1804002.2A GB201804002D0 (en) | 2018-03-13 | 2018-03-13 | Improvements in or relating to organic compounds |
| PCT/EP2019/056049 WO2019175117A1 (en) | 2018-03-13 | 2019-03-11 | Spiro cyclohexanedione derivates as herbicides |
| EP19711543.9A EP3765445B1 (en) | 2018-03-13 | 2019-03-11 | Spiro cyclohexanedione derivates as herbicides |
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| GB201901961D0 (en) * | 2019-02-13 | 2019-04-03 | Syngenta Crop Protection Ag | Improvements in or relating to organic compounds |
| GB201910040D0 (en) * | 2019-07-12 | 2019-08-28 | Syngenta Crop Protection Ag | Improvements in or relating to organic compounds |
| GB201910168D0 (en) * | 2019-07-16 | 2019-08-28 | Syngenta Crop Protection Ag | Improvements in or relating to organic compounds |
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| US4659372A (en) | 1977-03-28 | 1987-04-21 | Union Carbide Corporation | Biocidal 2-aryl-1,3-cyclohexanedione enol ester compounds |
| EP0241490A1 (en) * | 1985-10-14 | 1987-10-21 | Dunlena Pty. Limited | Herbicidal cyclohexene derivatives |
| DE4236880A1 (de) * | 1992-10-31 | 1994-05-05 | Basf Ag | N-Phenyl substituierte Glutarimide und N-Phenylglutarsäureamide, deren Herstellung und Verwendung |
| ES2167371T3 (es) * | 1993-07-02 | 2002-05-16 | Bayer Ag | Derivados de 1h-3-aril-pirrolidin-2,4-diona espirociclicos substituidos. |
| DE19935963A1 (de) | 1999-07-30 | 2001-02-01 | Bayer Ag | Biphenylsubstituierte cyclische Ketoenole |
| US20090005249A1 (en) * | 2004-04-22 | 2009-01-01 | Bayer Cropscience Lp | Method and composition for controlling weeds |
| GB0704652D0 (en) * | 2007-03-09 | 2007-04-18 | Syngenta Participations Ag | Novel herbicides |
| GB0820344D0 (en) | 2008-11-06 | 2008-12-17 | Syngenta Ltd | Herbicidal compositions |
| EP2387309A2 (en) | 2009-01-19 | 2011-11-23 | Bayer CropScience AG | Cyclic diones and their use as insecticides, acaricides and/or fungicides |
| CN102898354A (zh) * | 2011-07-28 | 2013-01-30 | 华南农业大学 | 一类螺环季酮酸肟醚衍生物及其制备和杀虫,杀螨,杀菌和除草用途 |
| AU2013366561B2 (en) * | 2012-12-21 | 2017-12-21 | Syngenta Limited | Herbicidally active cyclic dione compounds, or derivatives thereof, substituted by a phenyl which has an alkynyl-containing substituent |
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| Publication number | Publication date |
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| KR20200131842A (ko) | 2020-11-24 |
| IL277034A (en) | 2020-10-29 |
| EP3765445A1 (en) | 2021-01-20 |
| US11980188B2 (en) | 2024-05-14 |
| CA3093171A1 (en) | 2019-09-19 |
| AR114374A1 (es) | 2020-08-26 |
| CN111868034B (zh) | 2023-12-01 |
| CN111868034A (zh) | 2020-10-30 |
| MX2020009342A (es) | 2021-01-08 |
| RS64844B1 (sr) | 2023-12-29 |
| PL3765445T3 (pl) | 2024-02-19 |
| US20210000113A1 (en) | 2021-01-07 |
| JP2021518349A (ja) | 2021-08-02 |
| UA127114C2 (uk) | 2023-05-03 |
| WO2019175117A1 (en) | 2019-09-19 |
| BR112020018473A2 (pt) | 2020-12-22 |
| GB201804002D0 (en) | 2018-04-25 |
| CL2020002324A1 (es) | 2021-01-15 |
| ES2967109T3 (es) | 2024-04-25 |
| UY38143A (es) | 2019-10-31 |
| JP7317035B2 (ja) | 2023-07-28 |
| EP3765445B1 (en) | 2023-08-30 |
| ZA202005480B (en) | 2022-09-28 |
| AU2019236406A1 (en) | 2020-09-24 |
| IL277034B2 (en) | 2024-04-01 |
| PH12020551477A1 (en) | 2021-09-06 |
| IL277034B1 (en) | 2023-12-01 |
| AU2019236406B2 (en) | 2022-12-01 |
| HUE064202T2 (hu) | 2024-02-28 |
| EA202092130A1 (ru) | 2021-02-11 |
| EP3765445C0 (en) | 2023-08-30 |
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