AR114374A1 - Compuestos herbicidas - Google Patents

Compuestos herbicidas

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Publication number
AR114374A1
AR114374A1 ARP190100560A ARP190100560A AR114374A1 AR 114374 A1 AR114374 A1 AR 114374A1 AR P190100560 A ARP190100560 A AR P190100560A AR P190100560 A ARP190100560 A AR P190100560A AR 114374 A1 AR114374 A1 AR 114374A1
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AR
Argentina
Prior art keywords
alkyl
alkoxy
group
hydrogen
haloalkyl
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ARP190100560A
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English (en)
Inventor
Julia Comas-Barcelo
Yunas Bhonoah
Ian Thomas Tinmouth Houlsby
Alexander William Gregory
Suzanna Jane Dale
Nigel James Willetts
Shuji Hachisu
Elizabeth Pearl Jones
Alan Joseph Hennessy
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Syngenta Participations Ag
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Publication of AR114374A1 publication Critical patent/AR114374A1/es

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
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    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/18Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D211/20Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms
    • C07D211/22Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms by oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D221/00Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00
    • C07D221/02Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00 condensed with carbocyclic rings or ring systems
    • C07D221/20Spiro-condensed ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/08Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing alicyclic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/10Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
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    • C07D405/02Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/06Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Reivindicación 1: Un compuesto de fórmula (1), en donde R¹ es metilo; R² es metilo o metoxi; R³ es metilo o metoxi; R⁴ se selecciona, entre el grupo que consiste en -S(O)ₙ-alquilo C₁₋₆, -S(O)ₙ-haloalquilo C₁₋₆, -S(O)ₙ-(CH₂)ₙ-cicloalquilo C₃₋₆, -S(O)ₙC(R¹¹)R¹²R¹³, -C(O)H, -C(O)-(CH₂)ₙ-cicloalquilo C₃₋₆, -C(O)C(R¹¹)R¹²R¹³, -C(O)alquenilo C₂₋₄, -C(O)(CR⁹R¹⁰)CN, -C(O)(CR⁹R¹⁰)(CR⁹R¹⁰)CN, -C(O)CH₂C(O)-alquilo C₁₋₆, -C(O)CH₂OC(O)-alquilo C₁₋₆, -C(O)O-alquilo C₁₋₆, -C(O)O-haloalquilo C₁₋₆, -C(O)(CR⁹R¹⁰)ₙS(O)ₙ-alquilo C₁₋₆, -C(O)alcoxi C₁₋₃-alquilo C₁₋₆, -C(O)alcoxi C₁₋₃-alquenilo C₂₋₆, -C(O)alcoxi C₁₋₃-alquinilo C₂₋₆, -C(O)alcoxi C₁₋₃-haloalquilo C₁₋₆, -C(O)alcoxi C₁₋₃-cicloalquilo C₃₋₆, -C(O)O-alcoxi C₁₋₃-alquilo C₁₋₆, -C(O)alcoxi C₁₋₃-alcoxi C₁₋₃-alquilo C₁₋₆, -C(O)(CH₂)ₙNR⁵R⁶, -C(O)-(CH₂)ₙ-NR⁷C(O)R⁸, -C(O)-(CH₂)ₙ-O-N=CR⁵R⁵, -CN, -(CH₂)ₙ-fenilo, -C(O)-(CH₂)ₙ-fenilo, -S(O)ₙ-(CH₂)-fenilo, -heterociclilo, -C(O)-(CH₂)ₙ-heterociclilo, -C(O)(CH₂)ₙO-(CH₂)ₙ-heterociclilo, -S(O)ₙ-(CH₂)ₙ-heterociclilo, en donde cada heterociclilo es un heterociclilo de 5 ó 6 miembros que puede ser aromático, saturado o parcialmente saturado y puede contener de 1 a 4 heteroátomos seleccionados cada uno independientemente entre el grupo que consiste en oxígeno, nitrógeno y azufre y en donde dichos grupos heterociclilo o fenilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente entre el grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; R⁵ se selecciona entre el grupo que consiste en hidrógeno y alquilo C₁₋₆; R⁶ se selecciona entre el grupo que consiste en hidrógeno, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, hidroxilo-, alcoxi C₁₋₆, cicloalquilo C₃₋₆, -alcoxi C₁₋₄-alquilo C₁₋₆, -alcoxi C₁₋₃-haloalquilo C₁₋₆, -(CR⁹R¹⁰)haloalquilo C₁₋₆, -(CR⁹R¹⁰)C(O)NR⁵R⁵, fenilo, piridilo, en donde el fenilo y el piridilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente entre el grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; o R⁵ y R⁶ juntos forman -CH₂CH₂OCH₂CH₂-; y R⁷ se selecciona entre el grupo que consiste en hidrógeno y alquilo C₁₋₆; R⁸ se selecciona entre el grupo que consiste en hidrógeno, alquilo C₁₋₆, alcoxi C₁₋₆, cicloalquilo C₃₋₆, fenilo, piridilo, en donde el fenilo y el piridilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente entre el grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; R⁹ es hidrógeno o metilo; R¹⁰ es hidrógeno o metilo; o R⁹ y R¹⁰ juntos forman -CH₂CH₂-; y R¹¹ es hidrógeno o metilo; R¹² se selecciona entre el grupo que consiste en hidrógeno, alquilo C₁₋₆, hidroxilo y alcoxi C₁₋₆-; R¹³ se selecciona entre el grupo que consiste en hidrógeno, alquilo C₁₋₆, hidroxilo y alcoxi C₁₋₆; o R¹² y R¹³ juntos forman -CH₂-X-CH₂-; y X se selecciona entre el grupo que consiste en O, S y N-R¹⁴; R¹⁴ se selecciona entre el grupo que consiste en hidrógeno, alquilo C₁₋₃ y alcoxi C₁₋₃-; n es 0, 1 ó 2; G se selecciona entre el grupo que consiste en hidrógeno, -(CH₂)ₙ-Rᵃ, -C(O)-Rᵃ, -C(O)-(CRᶜRᵈ)ₙ-O-Rᵇ, -C(O)-(CRᶜRᵈ)ₙ-S-Rᵇ, -C(O)NRᵃRᵃ, -S(O)₂-Rᵃ y alcoxi C₁₋₈-alquilo-C₁₋₃-; Rᵃ se selecciona independientemente entre el grupo que consiste en hidrógeno, alquilo C₁₋₈, haloalquilo C₁₋₃, alquenilo C₂₋₈, alquinilo C₂₋₈, cicloalquilo C₃₋₆, heterociclilo y fenilo, en donde dichos grupos heterociclilo y fenilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente entre el grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; Rᵇ se selecciona entre el grupo que consiste en alquilo C₁₋₈, haloalquilo C₁₋₃, alquenilo C₂₋₈, alquinilo C₂₋₈, cicloalquilo C₃₋₆, heterociclilo y fenilo, en donde dichos grupos heterociclilo y fenilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente entre el grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; Rᶜ es hidrógeno o alquilo C₁₋₃; y Rᵈ es hidrógeno o alquilo C₁₋₃; o una sal aceptable en agricultura del mismo.
ARP190100560A 2018-03-13 2019-03-07 Compuestos herbicidas AR114374A1 (es)

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KR (1) KR20200131842A (es)
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AU (1) AU2019236406B2 (es)
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