AR119369A1 - Compuestos herbicidas - Google Patents

Compuestos herbicidas

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Publication number
AR119369A1
AR119369A1 ARP200101919A ARP200101919A AR119369A1 AR 119369 A1 AR119369 A1 AR 119369A1 AR P200101919 A ARP200101919 A AR P200101919A AR P200101919 A ARP200101919 A AR P200101919A AR 119369 A1 AR119369 A1 AR 119369A1
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AR
Argentina
Prior art keywords
alkyl
alkoxy
group
hydrogen
haloalkyl
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ARP200101919A
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English (en)
Inventor
Alan Joseph Hennessy
Elizabeth Pearl Jones
Suzanna Jane Dale
Alexander William Gregory
Ian Thomas Tinmouth Houlsby
Yunas Bhonoah
Julia Comas-Barcelo
Philip Michael Elves
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Syngenta Crop Protection Ag
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Publication of AR119369A1 publication Critical patent/AR119369A1/es

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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D221/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00
    • C07D221/02—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00 condensed with carbocyclic rings or ring systems
    • C07D221/20—Spiro-condensed ring systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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    • C07—ORGANIC CHEMISTRY
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    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07D417/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)

Abstract

La presente se refiere a compuestos de fórmula (1), donde R¹, R², R³, R⁴ y G son como se definen en el presente documento. La presente también se refiere a composiciones herbicidas que comprenden un compuesto de fórmula (1) y a su uso para controlar malezas, en particular en cultivos de plantas útiles. Reivindicación 1: Un compuesto de fórmula (1) en donde R¹ se selecciona de metilo, etinilo, 1-propinilo, fenilo y un heteroarilo de 5 ó 6 miembros que comprende uno o dos heteroátomos de nitrógeno, estando dicho fenilo y heteroarilo opcionalmente sustituidos con uno o dos sustituyentes R¹⁵; R² es etilo o cloro; R³ se selecciona del grupo que consiste en metilo, etilo, metoxilo y cloro; R⁴ se selecciona del grupo que consiste en alquilo C₁₋₄, alcoxilo C₁₋₄, haloalquilo C₁₋₄, -C(=O)alquilo C₁₋₄, -C(=O)haloalquilo C₁₋₄, -S(O)ₙ-alquilo C₁₋₆, -S(O)ₙ-haloalquilo C₁₋₆, -S(O)ₙ-(CH₂)ₙ-cicloalquilo C₃₋₆, -S(O)ₙC(R¹¹)R¹²R¹³, -C(O)H, -C(O)-(CH₂)ₙ-cicloalquilo C₃₋₆, -C(O)C(R¹¹)R¹²R¹³, -C(O)alquenilo C₂₋₄, -C(O)(CR⁹R¹⁰)CN, -C(O)(CR⁹R¹⁰)(CR⁹R¹⁰)CN, -C(O)CH₂C(O)-alquilo C₁₋₆, -C(O)CH₂OC(O)-alquilo C₁₋₆, -C(O)O-alquilo C₁₋₆, -C(O)O-haloalquilo C₁₋₆, -C(O)(CH₂)ₙS(O)ₙ-alquilo C₁₋₆, -C(O)alcoxi C₁₋₃-alquilo C₁₋₆, -C(O)alcoxi C₁₋₃-alquenilo C₂₋₆, -C(O)alcoxi C₁₋₃-alquinilo C₂₋₆, -C(O)alcoxi C₁₋₃-haloalquilo C₁₋₆, -C(O)alcoxi C₁₋₃-cicloalquilo C₃₋₆, -C(O)O-alcoxi C₁₋₃-alquilo C₁₋₆, -C(O)alcoxi C₁₋₃-alcoxi C₁₋₃-alquilo C₁₋₆, -C(O)(CH₂)ₙNR⁵R⁶, -C(O)-(CH₂)ₙ-NR⁷C(O)R⁸, -C(O)-(CH₂)ₙ-O-N=CR⁵R⁵, -CN, -S(O)₂NR¹⁶R¹⁷, -S(O)(=NR¹⁸)R¹⁹, -C(O)C(O)R²⁰, -C(O)C(R²³)=N-O-R²⁴ o -C(O)C(R²³)=N-NR²⁵R²⁶, -(CH₂)ₙ-fenilo, -C(O)-(CH₂)ₙ-fenilo, -S(O)ₙ-(CH₂)ₙ-fenilo, -heterociclilo, -C(O)-(CH₂)ₙ-heterociclilo, -C(O)(CH₂)ₙO-(CH₂)ₙ-heterociclilo, -S(O)ₙ-(CH₂)ₙ-heterociclilo, donde cada heterociclilo es un heterociclilo de 5 ó 6 miembros que puede ser aromático, saturado o parcialmente saturado y puede contener de 1 a 4 heteroátomos seleccionados cada uno independientemente entre el grupo que consiste en oxígeno, nitrógeno y azufre y en donde dichos grupos heterociclilo o fenilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente entre el grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; R⁵ se selecciona independientemente del grupo constituido por hidrógeno y alquilo C₁₋₆; R⁶ se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, hidroxilo, alcoxi C₁₋₆, cicloalquilo C₃₋₆, -alcoxi C₁₋₄-alquilo C₁₋₆, -alcoxi C₁₋₃-haloalquilo C₁₋₆, -(CR⁹R¹⁰)haloalquilo C₁₋₆, -(CR⁹R¹⁰)C(O)NR⁵R⁵, fenilo, -piridilo, donde el fenilo y el piridilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente del grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; o R⁵ y R⁶ juntos forman -CH₂CH₂OCH₂CH₂-; y R⁷ se selecciona del grupo que consiste en hidrógeno y alquilo C₁₋₆; R⁸ se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₆, alcoxi C₁₋₆, cicloalquilo C₃₋₆, fenilo, -piridilo, donde el fenilo y el piridilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente del grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; R⁹ es hidrógeno o metilo; R¹⁰ es hidrógeno o metilo; o R⁹ y R¹⁰ juntos forman -CH₂CH₂-; y R¹¹ es hidrógeno o metilo; R¹² se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₆, hidroxilo y alcoxi C₁₋₆-; R¹³ se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₆, hidroxilo y alcoxi C₁₋₆; o R¹² y R¹³ juntos forman -CH₂-X-CH₂-; y X se selecciona del grupo que consiste en O, S y N-R¹⁴; R¹⁴ se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₃ y alcoxilo C₁₋₃; R¹⁵ se selecciona independientemente del grupo que consiste en alquilo C₁₋₄, haloalquilo C₁₋₄, ciano y halógeno; R¹⁶ es hidrógeno o alquilo C₁₋₆; y R¹⁷ se selecciona del grupo constituido por hidrógeno, alquilo C₁₋₆, cicloalquilo C₃₋₆, (alcoxi C₁₋₆)-(alquil C₁₋₃)-, -C(O)(alquilo C₁₋₆), -C(O)O(alquilo C₁₋₆) y CH₂CN; o R¹⁶ y R¹⁷ juntos forman -CH₂CH₂OCH₂CH₂-, -CH₂CH₂S(O)₂CH₂CH₂-; R¹⁸ es hidrógeno o alquilo C₁₋₆; R¹⁹ se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₆, alcoxi C₁₋₆, cicloalquilo C₃₋₆, fenilo, -piridilo, donde el fenilo y el piridilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente del grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; R²⁰ se selecciona del grupo que consiste en alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆-, haloalcoxi C₁₋₆, -NR²¹R²², fenilo y -piridilo, donde el fenilo y el piridilo están opcionalmente sustituidos por uno, dos o tres sustituyentes seleccionados independientemente del grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; R²¹ se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₆, alcoxi C₁₋₆, alcoxi C₁₋₆-alquil C₁₋₃-, cicloalquilo C₃₋₆, haloalquil C₁₋₆- y haloalcoxi C₁₋₆-, -C(O)alquilo C₁₋₆, fenilo, -piridilo, donde el fenilo y el piridilo están opcionalmente sustituidos por uno, dos o tres sustituyentes seleccionados independientemente del grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxi C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; R²² es hidrógeno o alquilo C₁₋₆; o R²¹ y R²² juntos forman -CH₂CH₂OCH₂CH₂-; R²³ se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxilo C₁₋₆- y haloalcoxilo C₁₋₆-; R²⁴ se selecciona del grupo que consiste en hidrógeno, C₁₋₆alquilo, alcoxilo C₁₋₆ alquilo C₁₋₃, cicloalquilo C₃₋₆, -CH₂CN, tetrahidropiranilo, fenilo y piridilo, donde el fenilo y el piridilo están opcionalmente sustituidos por uno, dos o tres sustituyentes seleccionados independientemente del grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxilo C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; R²⁵ es hidrógeno o alquilo C₁₋₆; R²⁶ es hidrógeno o alquilo C₁₋₆; y G se selecciona del grupo que consiste en hidrógeno, -(CH₂)ₙ-Rᵃ, -C(O)-Rᵃ, -C(O)-(CRᶜRᵈ)ₙ-O-Rᵇ, -C(O)-(CRᶜRᵈ)ₙS-Rᵇ, -C(O)NRᵃRᵃ, -S(O)₂-Rᵃ y (alcoxilo C₁₋₈)-(alquilo C₁₋₃)-; Rᵃ se selecciona independientemente del grupo que consiste en hidrógeno, alquilo C₁₋₈, haloalquilo C₁₋₃, alquenilo C₂₋₈, alquinilo C₂₋₈, cicloalquilo C₃₋₆, heterociclilo y fenilo, donde dichos grupos heterociclilo y fenilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente del grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxilo C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; Rᵇ se selecciona del grupo que consiste en alquilo C₁₋₈, haloalquilo C₁₋₃, alquenilo C₂₋₈, alquinilo C₂₋₈, cicloalquilo C₃₋₆, heterociclilo y fenilo, donde dichos grupos heterociclilo y fenilo están opcionalmente sustituidos con uno, dos o tres sustituyentes seleccionados independientemente del grupo que consiste en alquilo C₁₋₃, haloalquilo C₁₋₃, alcoxilo C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, halógeno, ciano y nitro; Rᶜ es hidrógeno o alquilo C₁₋₃; Rᵈ es hidrógeno o alquilo C₁₋₃; y n es independientemente 0, 1 ó 2; o una sal aceptable en agricultura de este.
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