HRP20211122T1 - Postupak za proizvodnju solarne ćelije - Google Patents

Postupak za proizvodnju solarne ćelije Download PDF

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Publication number
HRP20211122T1
HRP20211122T1 HRP20211122TT HRP20211122T HRP20211122T1 HR P20211122 T1 HRP20211122 T1 HR P20211122T1 HR P20211122T T HRP20211122T T HR P20211122TT HR P20211122 T HRP20211122 T HR P20211122T HR P20211122 T1 HRP20211122 T1 HR P20211122T1
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HR
Croatia
Prior art keywords
silicon
passivation layer
layer
plasma
deposition
Prior art date
Application number
HRP20211122TT
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English (en)
Inventor
Benjamin Strahm
Damien LACHENAL
Chloé Guerin
Antoine DESCOEUDRES
Stefaan DE WOLF
Loris BARRAUD
Original Assignee
Meyer Burger (Germany) Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Meyer Burger (Germany) Gmbh filed Critical Meyer Burger (Germany) Gmbh
Publication of HRP20211122T1 publication Critical patent/HRP20211122T1/hr

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier
    • H01L31/072Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PN heterojunction type
    • H01L31/0745Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PN heterojunction type comprising a AIVBIV heterojunction, e.g. Si/Ge, SiGe/Si or Si/SiC solar cells
    • H01L31/0747Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PN heterojunction type comprising a AIVBIV heterojunction, e.g. Si/Ge, SiGe/Si or Si/SiC solar cells comprising a heterojunction of crystalline and amorphous materials, e.g. heterojunction with intrinsic thin layer or HIT® solar cells; solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic System
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/186Particular post-treatment for the devices, e.g. annealing, impurity gettering, short-circuit elimination, recrystallisation
    • H01L31/1868Passivation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Claims (7)

1. Postupak za proizvodnju solarne ćelije (1) koja sadrži - kristalnu silicijsku jezgru (2), - najmanje jedan n- ili p-dopiran sloj silicija ili sloj silicijeve slitine (3, 3') i - najmanje jedan pasivacijski sloj (4, 4') koji se sastoji od silicija ili silicijeve slitine između najmanje jedne površine (21, 22) silicijeve jezgre (2) i najmanje jednog n- ili p-dopiranog sloja silicija ili sloja silicijeve slitine (3, 3'), pri čemu je pasivacijski sloj (4, 4') istaložen se na takav način da proizvedeni pasivacijski sloj (4, 4') sadrži molekulske skupine silicijevog monohidrida (Si-H) i molekulske skupine silicijevog dihidrida (Si-H2) i da je omjer (Q) broja molekulskih skupina silicijevog dihidrida (nSi-H2) prema ukupnom broju molekulskih skupina silicijevog dihidrida (nSi-H2) i molekulskih skupina silicijevog monohidrida (nSi-H) veći od 0,4 u usporedbenom volumenu pasivacijskog sloja (4, 4') [image] pri čemu se pasivacijski sloj (4, 4') taloži u mnoštvu podkoraka postupka plazma pražnjenja, naznačen time što, se u prvoj varijanti postupka, tijekom taloženja pasivacijskog sloja (4, 4'), koristi naizmjenični niz koraka taloženja silana u plazmi i koraka obrade H2 plazme, ili, u drugoj varijanti postupka, tijekom taloženja pasivacijskog sloja (4, 4'), kontinuirano izgaranje plazme koja djeluje na pasivacijski sloj (4, 4') koristi se tijekom svih podkoraka postupka plazma pražnjenja, te u sljedećem podkoraku postupka plazma pražnjenja za taloženje pasivacijskog sloja (4, 4'), koji slijedi prethodni podkorak ovog postupka plazma pražnjenja, najmanje jedan promjenjivi parametar taloženja, odabran od parametara taloženja tlaka procesa, električne snage i struje prekursorskog plina, se svaki puta mijenja u usporedbi s odgovarajućim parametrom taloženja prethodnog podkoraka.
2. Postupak prema patentnom zahtjevu 1, naznačen time što se prekursor ugljika koristi najmanje privremeno tijekom taloženja n- ili p-dopiranog sloja silicija ili sloja silicijeve slitine (3, 3') i/ili pasivacijskog sloja (4, 4'), pri čemu, korištenjem prekursora ugljika, proizvedeni n- ili p-dopirani sloj silicija ili sloj silicijeve slitine (3, 3') i/ili pasivacijski sloj (4, 4') sadrži ugljikove atome u Si-C vezama.
3. Postupak prema patentnom zahtjevu 1 ili 2, naznačen time što se prekursor kisika koristi najmanje privremeno tijekom taloženja n- ili p-dopiranog sloja silicija ili sloja silicijeve slitine (3, 3') i/ili pasivacijskog sloja (4, 4'), pri čemu, korištenjem prekursora kisika, proizvedeni n- ili p-dopirani sloj silicija ili sloj silicijeve slitine (3, 3') i/ili pasivacijski sloj (4, 4') sadrži ugljikove atome u Si-O vezama.
4. Postupak prema najmanje jednom od prethodnih patentnih zahtjeva, naznačen time što, se u drugoj varijanti postupka, najmanje jedan promjenjivi parametar taloženja kontinuirano povećava ili smanjuje u najmanje jednom podkoraku postupka plazma pražnjenja.
5. Postupak prema najmanje jednom od prethodnih patentnih zahtjeva, naznačen time što se, u drugoj varijanti postupka, struja plinovitog silicijevog prekursora i struja plinovitog vodika provode u procesnu komoru u prvom koraku postupka plazma pražnjenja radi taloženja pasivacijskog sloja (4, 4') i plazma se pali u drugom podkoraku ovog postupka plazma pražnjenja, pri čemu se plazma pali s početnim impulsom snage koji je dovoljno velik da spriječi epitaksijalni rast pasivacijskog sloja (4, 4') na kristalnoj silicijskoj jezgri (2).
6. Postupak prema patentnom zahtjevu 4 ili 5, naznačen time što, se u podkoraku postupka plazma pražnjenja radi taloženja pasivacijskog sloja (4, 4') koji uključuje strujanje plinovitog silicijevog prekursora, strujanje plinovitog vodika i plazmu, taloži sloj pasivacijskog sloja (4, 4'), a u daljnjem podkoraku postupka plazma pražnjenja, strujanje plinovitog vodika i plazma se održavaju, dok se strujanje plinovitog silicijevog prekursora smanjuje ili prekida.
7. Postupak prema patentnom zahtjevu 6, naznačen time što se postupak plazma pražnjenja za taloženje pasivacijskog sloja (4, 4') provodi kao postupak proizvodnje sloj na sloju, s nizom od dva podkoraka koji se ponavljaju najmanje jednom.
HRP20211122TT 2011-08-08 2021-07-14 Postupak za proizvodnju solarne ćelije HRP20211122T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102011052480A DE102011052480A1 (de) 2011-08-08 2011-08-08 Solarzelle und Verfahren zur Herstellung einer Solarzelle
PCT/IB2012/053626 WO2013021298A2 (de) 2011-08-08 2012-07-16 Solarzelle und verfahren zur herstellung einer solarzelle
EP12772428.4A EP2742538B1 (de) 2011-08-08 2012-07-16 Verfahren zur herstellung einer solarzelle

Publications (1)

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HRP20211122T1 true HRP20211122T1 (hr) 2021-10-15

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Country Status (10)

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EP (1) EP2742538B1 (hr)
CN (1) CN103748692B (hr)
DE (1) DE102011052480A1 (hr)
ES (1) ES2880836T3 (hr)
HR (1) HRP20211122T1 (hr)
HU (1) HUE054929T2 (hr)
PL (1) PL2742538T3 (hr)
PT (1) PT2742538T (hr)
TW (1) TWI492396B (hr)
WO (1) WO2013021298A2 (hr)

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EP3021366A1 (en) 2014-11-17 2016-05-18 Total Marketing Services Solar cell and method of manufacturing thereof
EP3396722A4 (en) 2015-12-24 2019-08-28 Kaneka Corporation METHOD FOR PRODUCING A DEVICE FOR PHOTOELECTRIC CONVERSION
KR101879363B1 (ko) 2017-01-17 2018-08-16 엘지전자 주식회사 태양 전지 제조 방법
TWI647327B (zh) * 2017-12-01 2019-01-11 財團法人金屬工業研究發展中心 矽基疊層的形成方法及矽基異質接面太陽能電池的製造方法
CN108922937B (zh) * 2018-07-29 2024-04-05 江苏润阳悦达光伏科技有限公司 Hit太阳电池的硼掺杂发射极结构与制备方法

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FR2472842A1 (fr) * 1979-07-06 1981-07-03 Sorapec Structure d'electrode pour generateur electrochimique
JPS6150378A (ja) * 1984-08-20 1986-03-12 Mitsui Toatsu Chem Inc 非晶質太陽電池の製法
FR2711276B1 (fr) * 1993-10-11 1995-12-01 Neuchatel Universite Cellule photovoltaïque et procédé de fabrication d'une telle cellule.
JP3490964B2 (ja) 2000-09-05 2004-01-26 三洋電機株式会社 光起電力装置
JP4171428B2 (ja) 2003-03-20 2008-10-22 三洋電機株式会社 光起電力装置
TWI419341B (zh) * 2009-05-18 2013-12-11 Ind Tech Res Inst 量子點薄膜太陽能電池
WO2011032879A2 (en) * 2009-09-18 2011-03-24 Oerlikon Solar Ag, Truebbach Method for manufacturing a thin-film, silicon-based solar cell
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Publication number Publication date
CN103748692A (zh) 2014-04-23
DE102011052480A1 (de) 2013-02-14
EP2742538B1 (de) 2021-05-05
PL2742538T3 (pl) 2021-11-02
EP2742538A2 (de) 2014-06-18
TWI492396B (zh) 2015-07-11
WO2013021298A2 (de) 2013-02-14
PT2742538T (pt) 2021-07-07
HUE054929T2 (hu) 2021-10-28
CN103748692B (zh) 2016-03-02
TW201312778A (zh) 2013-03-16
WO2013021298A3 (de) 2013-11-07
ES2880836T3 (es) 2021-11-25

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