HRP20200801T1 - Herbicidni pripravci koji sadrže 4-amino-3-klor-5-fluor-6-(4-klor-2-fluor-3-metoksifenil)piridin-2-karboksilnu kiselinu - Google Patents

Herbicidni pripravci koji sadrže 4-amino-3-klor-5-fluor-6-(4-klor-2-fluor-3-metoksifenil)piridin-2-karboksilnu kiselinu Download PDF

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HRP20200801T1
HRP20200801T1 HRP20200801TT HRP20200801T HRP20200801T1 HR P20200801 T1 HRP20200801 T1 HR P20200801T1 HR P20200801T T HRP20200801T T HR P20200801TT HR P20200801 T HRP20200801 T HR P20200801T HR P20200801 T1 HRP20200801 T1 HR P20200801T1
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formula
compound
ester
ranges
weight ratio
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HRP20200801TT
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Carla N. Yerkes
Richard K. Mann
Norbert M. Satchivi
Paul R. Schmitzer
Rory DEGENHARDT
Len JURAS
Monte R. Weimer
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Dow Agrosciences Llc
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Application filed by Dow Agrosciences Llc filed Critical Dow Agrosciences Llc
Publication of HRP20200801T1 publication Critical patent/HRP20200801T1/hr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)
  • Pyridine Compounds (AREA)

Claims (13)

1. Sinergistički herbicidni pripravak, naznačen time što sadrži herbicidno djelotvornu količinu (a) spoja formule (I): [image] ili C1-4 alkilnog ili benzilnog estera formule (I), ili natrijeve, kalijeve, magnezijeve ili amonijeve soli formule (I), i (b) sintetski auksin herbicid, gdje je (b) najmanje jedan spoj, ili njegova poljoprivredno prihvatljiva sol, karboksilna kiselina, karboksilatna sol ili ester, kojeg se bira iz skupine koju čine: 2,4-D, 2,4-D EHE, 2,4-D DMA, 2,4-D kolin, 2,4-DB, aminociklopiraklor, aminopiralid, aminopiralid TIPA, klopiralid, klopiralid MEA, dikamba, dikamba DMA, diklorprop-P, fluroksipir, fluroksipir MHE, MCPA, MCPA EHE, mekoprop-P, pikloram, K+ sol piklorama, kvinklorak, triklopir, triklopir TEA, triklopir kolin, triklopir BEE, halauksifen-metil, te kalijeva sol halauksifena.
2. Pripravak u skladu s patentnim zahtjevom 1, naznačen time što ja (a) spoj formule (I), C1-4 alkilni ester spoja formule (I), ili benzilni ester spoja formule (I).
3. Pripravak u skladu s bilo kojim od patentnih zahtjeva 1-2, naznačen time što dodatno sadrži poljoprivredno prihvatljivi adjuvans ili nosač.
4. Pripravak u skladu s bilo kojim od patentnih zahtjeva 1-3, naznačen time što dodatno sadrži fitoprotektiv od herbicida.
5. Postupak kontroliranja neželjeno raslinje, naznačen time što se sastoji u stavljanju u kontakt raslinja ili mjesta na kojoj se nalazi s, ili u primjeni na tlo ili u vodu radi sprječavanja pojave ili rasta raslinja herbicidno djelotvorne količine (a) spoja formule (I): [image] ili C1-4 alkilnog ili benzilnog estera formule (I), ili natrijeve, kalijeve, magnezijeve ili amonijeve soli formule (I), i (b) sintetskog auksinskog herbicida na površinu, gdje je (b) najmanje jedan spoj, ili njegova poljoprivredno prihvatljiva sol, karboksilna kiselina, karboksilatna sol ili ester, kojeg se bira iz skupine koju čine: 2,4-D, 2,4-D EHE, 2,4-D DMA, 2,4-D kolin, 2,4-DB, aminociklopiraklor, aminopiralid, aminopiralid TIPA, klopiralid, klopiralid MEA, dikamba, dikamba DMA, diklorprop-P, fluroksipir, fluroksipir MHE, MCPA, MCPA EHE, mekoprop-P, pikloram, K+ sol piklorama, kvinklorak, triklopir, triklopir TEA, triklopir kolin, triklopir BEE, halauksifen-metil, te kalijeva sol halauksifena, gdje kombinacija (a) i (b) pokazuje sinergizam.
6. Postupak u skladu s patentnim zahtjevom 5, naznačen time što ja (a) spoj formule (I), C1-4 alkilni ester spoja formule (I), ili benzilni ester spoja formule (I).
7. Postupak u skladu s bilo kojim od patentnih zahtjeva 5-6, naznačen time što se neželjeno raslinje kontrolira kod izravno sijane, riže sijane u vodi i presađene riže, žitarica, pšenice, ječma, zobi, raži, prosa, kukuruza, šećerne trske, suncokreta, uljane repice, kanole, šećerne repe, soje, pamuka, ananasa, pašnjaka, travnjaka, ledina, zemljišta na ugaru, tratina, voćnjaka i vinograda, vodenih površina, industrijskog raslinja (IVM) ili terena s pravom prolaza (ROW).
8. Postupak u skladu s bilo kojim od patentnih zahtjeva 5-7, naznačen time što se (a) i (b) primjenjuje prije pojave korova ili usjeva.
9. Postupak u skladu s bilo kojim od patentnih zahtjeva 5-8, naznačen time što se neželjeno raslinje kontrolira kod usjeva koji podnose glifosat, inhibitor 5-enolpiruvilšikimat-3-fosfat (EPSP)-sintaze, glufosinat, inhibitor glutamin-sintetaze, dikambu, fenoksi auksin, piridiloksi auksin, sintetski auksin, inhibitor auksinskog transporta, ariloksifenoksipropionat, cikloheksandion, fenilpirazolin, inhibitor acetil-CoA-karboksilaze (ACCaze), imidazolinon, sulfonilureu, pirimidiniltiobenzoat, triazolopirimidin, sulfonilaminokarboniltriazolinon, inhibitore acetolaktat-sintaze (ALS) ili acetohidroksi-kiselinske sintaze (AHAS), inhibitor 4-hidroksifenilpiruvat-dioksigenaze (HPPD), inhibitor fitoen-desaturaze, inhibitor biosinteze karotenoida, inhibitor protoporfirinogen-oksidaze (PPO), inhibitor biosinteze celuloze, inhibitor mitoze, inhibitor mikrotubula, inhibitor masnih kiselina vrlo dugog lanca, inhibitor biosinteze masnih kiselina i lipida, inhibitor fotosustava I, inhibitor fotosustava II, triazin ili bromoksinil.
10. Postupak u skladu s patentnim zahtjevom 9, naznačen time što podnosi usjev posjeduje višestruka ili kumulativna svojstva koja omogućuju podnošenje višestrukih herbicida ili višestrukih načina djelovanja.
11. Postupak u skladu s bilo kojim od patentnih zahtjeva 5-10, naznačen time što neželjeno raslinje uključuje biljku koja je otporna ili podnosi herbicide.
12. Pripravak u skladu s bilo kojim od patentnih zahtjeva 1-4, naznačen time što su (a) i (b) prisutni u pripravku u takvom omjeru da pripravak pokazuje herbicidnu sinergiju, te što kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je 2,4-D, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:2 do 1:96; kada je (a) spoj formule (I), ili njegov benzilni ester, a (b) je 2,4-D EHE, težinski omjer između (a) i (b) se kreće od 1:4 do 1:56; kada je (a) spoj formule (I), a (b) je 2,4-D DMA, težinski omjer između (a) i (b) se kreće od 1:4 do 1:56; kada je (a) benzilni ester spoja formule (I), a (b) je 2,4-D DMA, težinski omjer između (a) i (b) se kreće od 1:2 do 1:56; kada je (a) spoj formule (I), a (b) je 2,4-D kolin, težinski omjer između (a) i (b) se kreće od 1:6,9 do 1:84; kada je (a) benzilni ester spoja formule (I), a (b) je 2,4-D kolin, težinski omjer između (a) i (b) se kreće od 1:6 do 1:96; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je aminociklopiraklor, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 2:1 do 1:4; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je aminopiralid, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 3:1 do 1:8; kada je (a) benzilni ester spoja formule (I), a (b) je aminopiralid TIPA, težinski omjer između (a) i (b) se kreće od 1:1 do 1:8; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je klopiralid, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:4 do 1:16; kada je (a) benzilni ester spoja formule (I), a (b) je klopiralid MEA, težinski omjer između (a) i (b) se kreće od 1:4 do 1:16; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je dikamba, ili njezina karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:3.3 to 1:56; kada je (a) benzilni ester spoja formule (I), a (b) je dikamba DMA, težinski omjer između (a) i (b) se kreće od 1: 11.4 do 1: 45.5; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je fluroksipir, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) je 1:2 do 1:35; kada je (a) benzilni ester spoja formule (I), a (b) je fluroksipir MHE, težinski omjer između (a) i (b) se kreće od 1:2 do 1:35; kada je (a) spoj formule (I), a (b) je fluroksipir MHE, težinski omjer između (a) i (b) se kreće od 1:7 do 1:28; kada je (a) n-butilni ester spoja formule (I), a (b) je fluroksipir MHE, težinski omjer između (a) i (b) se kreće od 1:8.2 do 1:17.5; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je MCPA, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:1 do 1:60; kada je (a) spoj formule (I), ili njegov benzilni ili n-butilni ester, a (b) je MCPA EHE, težinski omjer između (a) i (b) se kreće od 1:2 do 1:28; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je mekoprop-P, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:15 do otprilike 1:30; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je pikloram, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:1,1 do 1:16; kada je (a) benzilni ester spoja formule (I), a (b) je pikloram, težinski omjer između (a) i (b) se kreće od 1:2 do 1:16; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je kvinklorak, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:6,6 do 1:64; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je triklopir, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:1,7 do 1:44; kada je (a) spoj formule (I), a (b) je triklopir TEA, težinski omjer između (a) i (b) se kreće od 1:2 do 1:44; kada je (a) spoj formule (I), a (b) je triklopir kolin, težinski omjer između (a) i (b) se kreće od 1:1,7 do 1:28; kada je (a) benzilni ester spoja formule (I), a (b) je triklopir BEE, težinski omjer između (a) i (b) se kreće od 1:2 do 1:16; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je halauksifen-metil, ili njegova karboksilna kiselina ili karboksilatna sol, težinski omjer između (a) i (b) se kreće od 9,6:1 do 1:2; ili kada je (a) benzilni ester spoja formule (I), a (b) je kalijeva sol halauksifena, težinski omjer između (a) i (b) se kreće od 2:1 do 1:2.
13. Postupak u skladu s bilo kojim od patentnih zahtjeva 5-11, naznačen time što su (a) i (b) prisutni u pripravku u takvom omjeru da pripravak pokazuje herbicidnu sinergiju, te što kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je 2,4-D, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:2 do 1:96; kada je (a) spoj formule (I), ili njegov benzilni ester, a (b) je 2,4-D EHE, težinski omjer između (a) i (b) se kreće od 1:4 do 1:56; kada je (a) spoj formule (I), a (b) je 2,4-D DMA, težinski omjer između (a) i (b) se kreće od 1:4 do 1:56; kada je (a) benzilni ester spoja formule (I), a (b) je 2,4-D DMA, težinski omjer između (a) i (b) se kreće od 1:2 do 1:56; kada je (a) spoj formule (I), a (b) je 2,4-D kolin, težinski omjer između (a) i (b) se kreće od 1:6,9 do 1:84; kada je (a) benzilni ester spoja formule (I), a (b) je 2,4-D kolin, težinski omjer između (a) i (b) se kreće od 1:6 do 1:96; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je aminociklopiraklor, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 2:1 do 1:4; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je aminopiralid, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 3:1 do 1:8; kada je (a) benzilni ester spoja formule (I), a (b) je aminopiralid TIPA, težinski omjer između (a) i (b) se kreće od 1:1 do 1:8; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je klopiralid, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:4 do 1:16; kada je (a) benzilni ester spoja formule (I), a (b) je klopiralid MEA, težinski omjer između (a) i (b) se kreće od 1:4 do 1:16; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je dikamba, ili njezina karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:3.3 to 1:56; kada je (a) benzilni ester spoja formule (I), a (b) je dikamba DMA, težinski omjer između (a) i (b) se kreće od 1: 11.4 do 1: 45.5; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je fluroksipir, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) je 1:2 do 1:35; kada je (a) benzilni ester spoja formule (I), a (b) je fluroksipir MHE, težinski omjer između (a) i (b) se kreće od 1:2 do 1:35; kada je (a) spoj formule (I), a (b) je fluroksipir MHE, težinski omjer između (a) i (b) se kreće od 1:7 do 1:28; kada je (a) n-butilni ester spoja formule (I), a (b) je fluroksipir MHE, težinski omjer između (a) i (b) se kreće od 1:8.2 do 1:17.5; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je MCPA, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:1 do 1:60; kada je (a) spoj formule (I), ili njegov benzilni ili n-butilni ester, a (b) je MCPA EHE, težinski omjer između (a) i (b) se kreće od 1:2 do 1:28; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je mekoprop-P, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:15 do otprilike 1:30; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je pikloram, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:1,1 do 1:16; kada je (a) benzilni ester spoja formule (I), a (b) je pikloram, težinski omjer između (a) i (b) se kreće od 1:2 do 1:16; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je kvinklorak, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:6,6 do 1:64; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je triklopir, ili njegova karboksilatna sol ili ester, težinski omjer između (a) i (b) se kreće od 1:1,7 do 1:44; kada je (a) spoj formule (I), a (b) je triklopir TEA, težinski omjer između (a) i (b) se kreće od 1:2 do 1:44; kada je (a) spoj formule (I), a (b) je triklopir kolin, težinski omjer između (a) i (b) se kreće od 1:1,7 do 1:28; kada je (a) benzilni ester spoja formule (I), a (b) je triklopir BEE, težinski omjer između (a) i (b) se kreće od 1:2 do 1:16; kada je (a) spoj formule (I), ili njegova sol ili ester, a (b) je halauksifen-metil, ili njegova karboksilna kiselina ili karboksilatna sol, težinski omjer između (a) i (b) se kreće od 9,6:1 do 1:2; ili kada je (a) benzilni ester spoja formule (I), a (b) je kalijeva sol halauksifena, težinski omjer između (a) i (b) se kreće od 2:1 do 1:2.
HRP20200801TT 2012-07-24 2020-05-18 Herbicidni pripravci koji sadrže 4-amino-3-klor-5-fluor-6-(4-klor-2-fluor-3-metoksifenil)piridin-2-karboksilnu kiselinu HRP20200801T1 (hr)

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