HRP20200224T1 - Elektrolitički postupak proizvodnje amonijaka - Google Patents

Elektrolitički postupak proizvodnje amonijaka Download PDF

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Publication number
HRP20200224T1
HRP20200224T1 HRP20200224TT HRP20200224T HRP20200224T1 HR P20200224 T1 HRP20200224 T1 HR P20200224T1 HR P20200224T T HRP20200224T T HR P20200224TT HR P20200224 T HRP20200224 T HR P20200224T HR P20200224 T1 HRP20200224 T1 HR P20200224T1
Authority
HR
Croatia
Prior art keywords
crystal surface
nitride
ammonia
catalyst
crystal
Prior art date
Application number
HRP20200224TT
Other languages
English (en)
Croatian (hr)
Inventor
Egill SKULASON
Original Assignee
Haskoli Islands
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haskoli Islands filed Critical Haskoli Islands
Publication of HRP20200224T1 publication Critical patent/HRP20200224T1/hr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • F01N3/2073Selective catalytic reduction [SCR] with means for generating a reducing substance from the exhaust gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/60Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/02Preparation, purification or separation of ammonia
    • C01C1/04Preparation of ammonia by synthesis in the gas phase
    • C01C1/0494Preparation of ammonia by synthesis in the gas phase using plasma or electric discharge
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/012Diesel engines and lean burn gasoline engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/02Adding substances to exhaust gases the substance being ammonia or urea

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Plasma & Fusion (AREA)
  • Physics & Mathematics (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
HRP20200224TT 2014-06-13 2020-02-11 Elektrolitički postupak proizvodnje amonijaka HRP20200224T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IS050086A IS2972B (is) 2014-06-13 2014-06-13 Aðferð og kerfi til að framleiða ammóníak með rafgreiningu
PCT/IS2015/050012 WO2015189865A1 (en) 2014-06-13 2015-06-12 Electrolytic production of ammonia
EP15732963.2A EP3155144B1 (en) 2014-06-13 2015-06-12 Electrolytic production of ammonia

Publications (1)

Publication Number Publication Date
HRP20200224T1 true HRP20200224T1 (hr) 2020-05-29

Family

ID=53496910

Family Applications (1)

Application Number Title Priority Date Filing Date
HRP20200224TT HRP20200224T1 (hr) 2014-06-13 2020-02-11 Elektrolitički postupak proizvodnje amonijaka

Country Status (14)

Country Link
US (1) US10344650B2 (pt)
EP (1) EP3155144B1 (pt)
CN (1) CN106661740B (pt)
CA (1) CA2951377C (pt)
DK (1) DK3155144T3 (pt)
ES (1) ES2774375T3 (pt)
HR (1) HRP20200224T1 (pt)
HU (1) HUE048908T2 (pt)
IL (1) IL249415B (pt)
IS (1) IS2972B (pt)
PL (1) PL3155144T3 (pt)
PT (1) PT3155144T (pt)
RU (1) RU2686465C2 (pt)
WO (1) WO2015189865A1 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3074963A1 (en) * 2017-09-08 2019-03-21 Haskoli Islands Electrolytic ammonia production using transition metal oxide catalysts
CN108355699B (zh) * 2018-03-01 2020-12-11 中国科学院理化技术研究所 一种碳负载镍铜二元氮化物催化剂及其制备方法和应用
WO2020075202A1 (en) 2018-10-09 2020-04-16 Atmonia Ehf. Electrochemical reactions with cyclic varied potential
US20220033978A1 (en) 2018-11-29 2022-02-03 Atmonia Ehf. Process for electrolytic production of ammonia from nitrogen using metal sulfide catalytic surface
TWI659780B (zh) * 2018-11-30 2019-05-21 財團法人工業技術研究院 氮化物觸媒與其形成方法
US11885029B2 (en) 2019-02-12 2024-01-30 Georgia Tech Research Corporation Systems and methods for forming nitrogen-based compounds
CN110055558B (zh) * 2019-06-04 2021-03-16 宁夏回族自治区环境监测中心站 常温固氮电催化剂及电催化电极的制备方法和固氮方法
CN111298813B (zh) * 2020-03-04 2023-01-10 青岛科技大学 一种电催化氮还原催化剂的方法
CN111450867A (zh) * 2020-05-09 2020-07-28 青岛科技大学 用于电催化二氧化碳还原的Cu3N纳米催化剂的制备方法
WO2022035961A1 (en) * 2020-08-13 2022-02-17 Massachusetts Institute Of Technology Transition metal nitrides as solid carriers for ammonia storage
FR3119553B1 (fr) * 2021-02-10 2023-07-14 Electricite De France Dispositif électrochimique pour la conversion d’oxydes d’azotes NOx en ammoniac et/ou hydrogène
WO2023286090A1 (en) 2021-07-16 2023-01-19 Atmonia Ehf. Bioreactor system and process for nitrate production
CN114950527B (zh) * 2022-05-31 2023-09-08 安徽大学 一种用于偶氮苯类化合物合成的催化剂
CN116666669B (zh) * 2023-07-25 2023-10-03 四川大学 VN负载的Ir团簇及其制备方法与其在催化剂中的用途

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR968142A (fr) * 1947-06-28 1950-11-20 Pennsylvania Salt Mfg Co Perfectionnements apportés aux procédés et appareils pour l'obtention de fluor par électrolyse
CH395036A (de) * 1958-04-25 1965-07-15 Amalgamated Curacao Patents Co Elektrode, geeignet als Anode für Elektrolysen, und Verfahren zu ihrer Herstellung
FR1429307A (fr) 1964-11-27 1966-02-25 Centre Nat Rech Scient Procédé de préparation des solutions solides de nitrures et d'oxynitrures de certains métaux de transition et nouvelles solutions solides desdits nitrures et oxynitrures
GB1191846A (en) 1966-08-31 1970-05-13 Ici Ltd Catalyst Composition and Treatment Method
DE1948183A1 (de) * 1969-09-24 1971-04-08 Huels Chemische Werke Ag Widerstandsfaehige Elektrode
JPH06220675A (ja) * 1993-01-21 1994-08-09 Tosoh Corp 電解槽
JP4038311B2 (ja) 1999-09-30 2008-01-23 Jfeエンジニアリング株式会社 アンモニア合成触媒及びその製造方法並びにアンモニア合成方法
JP4554752B2 (ja) 2000-02-29 2010-09-29 Jfeエンジニアリング株式会社 アンモニア合成触媒
US6881308B2 (en) 2002-03-04 2005-04-19 Lynntech, Inc. Electrochemical synthesis of ammonia
JP2005272856A (ja) * 2004-03-22 2005-10-06 Kenichi Machida アンモニア合成装置、アンモニア合成方法および燃焼装置を含むシステム
WO2008154613A1 (en) * 2007-06-12 2008-12-18 Hsm Systems, Inc. Improved procedures for ammonia production
JP4676472B2 (ja) 2007-10-01 2011-04-27 Jfeエンジニアリング株式会社 アンモニア合成方法
AU2011235087B2 (en) * 2010-04-02 2014-04-24 Ohio University Selective catalytic reduction via electrolysis of urea
US8927453B2 (en) * 2012-04-20 2015-01-06 Brookhaven Science Associates, Llc Molybdenum and tungsten nanostructures and methods for making and using same

Also Published As

Publication number Publication date
IS2972B (is) 2017-07-15
HUE048908T2 (hu) 2020-08-28
RU2686465C2 (ru) 2019-04-26
US10344650B2 (en) 2019-07-09
CA2951377C (en) 2022-07-19
EP3155144B1 (en) 2019-12-04
RU2016151299A (ru) 2018-07-16
CN106661740A (zh) 2017-05-10
CN106661740B (zh) 2019-03-22
IL249415B (en) 2019-12-31
ES2774375T3 (es) 2020-07-20
CA2951377A1 (en) 2015-12-17
DK3155144T3 (da) 2020-02-24
IL249415A0 (en) 2017-02-28
WO2015189865A1 (en) 2015-12-17
PT3155144T (pt) 2020-02-24
US20170122173A1 (en) 2017-05-04
PL3155144T3 (pl) 2020-06-01
RU2016151299A3 (pt) 2018-11-09
EP3155144A1 (en) 2017-04-19

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