HRP20190840T2 - Mješavina gnojiva koja sadrži inhibitor nitrifikacije - Google Patents
Mješavina gnojiva koja sadrži inhibitor nitrifikacije Download PDFInfo
- Publication number
- HRP20190840T2 HRP20190840T2 HRP20190840TT HRP20190840T HRP20190840T2 HR P20190840 T2 HRP20190840 T2 HR P20190840T2 HR P20190840T T HRP20190840T T HR P20190840TT HR P20190840 T HRP20190840 T HR P20190840T HR P20190840 T2 HRP20190840 T2 HR P20190840T2
- Authority
- HR
- Croatia
- Prior art keywords
- calcium
- ammonium nitrate
- fertilizer
- water
- mass
- Prior art date
Links
- 239000003337 fertilizer Substances 0.000 title claims 18
- 239000000203 mixture Substances 0.000 title claims 8
- 239000003112 inhibitor Substances 0.000 title 1
- NGLMYMJASOJOJY-UHFFFAOYSA-O azanium;calcium;nitrate Chemical compound [NH4+].[Ca].[O-][N+]([O-])=O NGLMYMJASOJOJY-UHFFFAOYSA-O 0.000 claims 10
- 239000004615 ingredient Substances 0.000 claims 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 10
- 239000011707 mineral Substances 0.000 claims 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 10
- HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 claims 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 4
- 239000001384 succinic acid Substances 0.000 claims 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims 2
- 239000001095 magnesium carbonate Substances 0.000 claims 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 150000001639 boron compounds Chemical class 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 238000003898 horticulture Methods 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C21/00—Methods of fertilising, sowing or planting
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C1/00—Ammonium nitrate fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C1/00—Ammonium nitrate fertilisers
- C05C1/02—Granulation; Pelletisation; Stabilisation; Colouring
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
- C05C3/005—Post-treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Environmental Sciences (AREA)
- Fertilizers (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Treatment Of Sludge (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Claims (7)
1. Mješavina gnojiva, naznačena time, da sadrži sljedeće sastojke:
A. mineralno gnojivo kalcij-amonijevog nitrata koje, osim amonijevog nitrata i kalcijevog karbonata i/ili magnezijevog karbonata te opcionalno vode, može sadržavati najviše do 15% po masi, na bazi mineralnog gnojiva kalcij-amonijevog nitrata bez vode, još dodatnih sastojaka;
B. 2-(N-3,4-dimetilpirazol)jantarnu kiselinu u količini od 100 do 10 000 ppm po masi, na bazi sastojka A bez vode.
2. Mješavina gnojiva prema patentnom zahtjevu 1, naznačena time, da u sastojku A, na bazi mineralnog gnojiva kalcij-amonijevog nitrata bez vode, sadržaj dušika iznosi najmanje 22% po masi, poželjno od 25 do 29% po masi, još povoljnije od 26 do 28% po masi.
3. Mješavina gnojiva prema patentnom zahtjevu 1 ili 2, naznačena time, da u sastojku A, na bazi mineralnog gnojiva kalcij-amonijevog nitrata bez vode, sadržaj kalcija i/ili magnezija iznosi od 6 do 15% po masi, poželjno od 7 do 13% po masi, još preciznije od 9 do 11% po masi.
4. Mješavina gnojiva prema bilo kojem zahtjevu od 1 do 3, naznačena time, da sastojak A sadrži MgO i/ili Mg sol u iznosu od 0,5 do 7% po masi, poželjno od 1 do 5% po masi, još povoljnije od 3 do 5% po masi, na bazi mineralnog gnojiva kalcij-amonijevog nitrata bez vode.
5. Mješavina gnojiva prema bilo kojem od patentnih zahtjeva 1 do 4, naznačena time, da sastojak A sadrži bor kao element ili u obliku borovih spojeva, u iznosu od 0,01 do 1% po masi, poželjno od 0,1 do 0,5% po masi, još preciznije od 0,15 do 0,3% po masi, na bazi mineralnog gnojiva kalcij-amonijevog nitrata bez vode.
6. Postupak proizvodnje mješavine gnojiva prema bilo kojem od patentnih zahtjeva 1 do 5, naznačen time, da se provodi putem uvođenja 2-(N-3,4-dimetilpirazol)jantarne kiseline u mineralno gnojivo kalcij-amonijevog nitrata i/ili nanošenjem 2-(N-3,4-dimetilpirazol)jantarne kiseline na mineralno gnojivo kalcij-amonijevog nitrata.
7. Postupak za gnojenje obradivih zemljišta koja se iskorištavaju u agrokulturi ili hortikulturi, naznačen time, da mješavina gnojiva koja se nanosi na obradivo tlo, sadrži:
A. mineralno gnojivo kalcij-amonijevog nitrata koje, osim amonijevog nitrata i kalcijevog karbonata i/ili magnezijevog karbonata te opcionalno vode, može sadržavati najviše do 15% po masi, na bazi mineralnog gnojiva kalcij-amonijevog nitrata bez vode, još dodatnih sastojaka;
B. 2-(N-3,4-dimetilpirazol)jantarnu kiselinu u količini od 100 do 10 000 ppm po masi, na bazi sastojka A bez vode,
ili se sastojci A i B nanose odvojeno, ali unutar vremenskog perioda od 0 do 5 sati.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102013020588 | 2013-12-13 | ||
| PCT/EP2014/077570 WO2015086823A2 (de) | 2013-12-13 | 2014-12-12 | Nitrifikationsinhibitor enthaltende düngemittelmischung |
| EP14821540.3A EP3080057B1 (de) | 2013-12-13 | 2014-12-12 | Nitrifikationsinhibitor enthaltende düngemittelmischung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HRP20190840T1 HRP20190840T1 (hr) | 2019-08-23 |
| HRP20190840T2 true HRP20190840T2 (hr) | 2023-03-17 |
Family
ID=52278575
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20230121TT HRP20230121T1 (hr) | 2013-12-13 | 2014-12-12 | Mješavina gnojiva koja sadrži inhibitor nitrifikacije |
| HRP20190840TT HRP20190840T2 (hr) | 2013-12-13 | 2014-12-12 | Mješavina gnojiva koja sadrži inhibitor nitrifikacije |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20230121TT HRP20230121T1 (hr) | 2013-12-13 | 2014-12-12 | Mješavina gnojiva koja sadrži inhibitor nitrifikacije |
Country Status (22)
| Country | Link |
|---|---|
| US (2) | US10640431B2 (hr) |
| EP (3) | EP3080057B1 (hr) |
| CN (2) | CN115385741A (hr) |
| AU (2) | AU2014363415B2 (hr) |
| BR (2) | BR122020005031B1 (hr) |
| CA (2) | CA3193214A1 (hr) |
| CY (1) | CY1121642T1 (hr) |
| DK (2) | DK3623362T3 (hr) |
| ES (3) | ES2765817T3 (hr) |
| HR (2) | HRP20230121T1 (hr) |
| HU (2) | HUE061412T2 (hr) |
| LT (2) | LT3623362T (hr) |
| ME (1) | ME03439B (hr) |
| MX (2) | MX2016007734A (hr) |
| PL (2) | PL3623362T3 (hr) |
| PT (2) | PT3623362T (hr) |
| RS (2) | RS63921B1 (hr) |
| RU (1) | RU2665587C1 (hr) |
| SI (2) | SI3623362T1 (hr) |
| TR (1) | TR201908135T4 (hr) |
| UA (2) | UA119759C2 (hr) |
| WO (1) | WO2015086823A2 (hr) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115385741A (zh) | 2013-12-13 | 2022-11-25 | 欧洲化学农业有限公司 | 含硝化抑制剂的肥料混合物 |
| ES2691371T3 (es) * | 2015-06-22 | 2018-11-27 | Eurochem Agro Gmbh | Mezcla para el tratamiento de fertilizantes con contenido en urea |
| DE102017201608A1 (de) * | 2017-02-01 | 2018-08-02 | Eurochem Agro Gmbh | 3,4-Dimethylpyrazol enthaltende Mischung und ihre Verwendung |
| WO2018158675A1 (en) * | 2017-03-03 | 2018-09-07 | Basf Se | Mixture comprising 2-(3,4-dimethyl-1h-pyrazol-1-yl) succinic acid and/or its 4,5-isomer and a compound comprising an ether group, an alkynyl group and a benzyl group as well as the use thereof as nitrification inhibitor |
| WO2018197433A1 (en) | 2017-04-24 | 2018-11-01 | Eurochem Agro Gmbh | Method and composition for improving nutrient acquisition of plants |
| CN111010874A (zh) * | 2017-07-10 | 2020-04-14 | 巴斯夫欧洲公司 | 包含至少两种选自2-(3,4-二甲基-1h-吡唑-1-基)琥珀酸(dmpsa)、3,4-二甲基吡唑鎓乙醇酸盐(dmpg)和其他化合物的不同硝化抑制剂的混合物，尤其是包含dmpsa和dmp/dmpp的混合物或包含dmpsa和dcd的混合物 |
| WO2019012377A1 (en) * | 2017-07-10 | 2019-01-17 | Basf Se | MIXTURES COMPRISING AN INSECTICIDE AND A NITRIFICATION INHIBITOR SUCH AS 2- (3,4-DIMETHYL-1H-PYRAZOL-1-YL) SUCCINIC ACID (DMPSA) OR 3,4-DIMETHYL PYRAZOLIUM GLYCOLATE (DMPG) |
| WO2019012381A1 (en) * | 2017-07-10 | 2019-01-17 | Basf Se | MIXTURES COMPRISING A PLANT GROWTH REGULATOR (PGR) AND A NITRIFICATION INHIBITOR SUCH AS 2- (3,4-DIMETHYL-1H-PYRAZOL-1-YL) SUCCINIC ACID (DMPSA) OR 3,4-GLYCOLATE DIMETHYLPYRAZOLIUM (DMPG) |
| US20210145003A1 (en) * | 2017-07-10 | 2021-05-20 | Basf Se | Mixtures comprising a herbicide and a nitrification inhibitor such as 2-(3,4-dimethyl-1h-pyrazol-1-yl)succinic acid (dmpsa) or 3,4-dimethyl pyrazolium glocolate (dmpg) |
| CA3066991A1 (en) | 2017-07-10 | 2019-01-17 | Basf Se | Mixtures comprising an urease inhibitor (ui) and a nitrification inhibitor such as 2-(3,4-dimethyl-1h-pyrazol-1-yl)succinic acid (dmpsa) or 3,4-dimethyl pyrazolium glycolate (dmpg) |
| DE102017212104A1 (de) | 2017-07-14 | 2019-01-17 | Eurochem Agro Gmbh | Beschichtete harnstoffhaltige Düngemittelteilchen und Verfahren zu ihrer Herstellung |
| US11505511B2 (en) * | 2017-08-18 | 2022-11-22 | Basf Se | Process for preparing improved 3,4-dimethyl-1H-pyrazole phosphate formulations |
| WO2019121228A1 (en) | 2017-12-22 | 2019-06-27 | Basf Se | Aqueous composition comprising 2-(dimethyl-1h-pyrazole-1-yl) succinic acid and at least one metal hydroxide |
| BR112020010840A2 (pt) | 2017-12-22 | 2020-11-10 | Basf Se | composição aquosa e uso da composição aquosa |
| WO2019121226A1 (en) | 2017-12-22 | 2019-06-27 | Basf Se | Aqueous composition comprising 2-(dimethyl-1h-pyrazole-1-yl) succinic acid and at least one further acid |
| EP3898555B1 (en) | 2018-12-21 | 2024-02-28 | Basf Se | Process for obtaining a fertilizer composition comprising a dmpsa nitrification inhibitor via adding dmpsa salts into the fertilizer melt |
| WO2020126645A1 (en) * | 2018-12-21 | 2020-06-25 | Basf Se | Process for preparing 2-(3, 4-dimethyl- 1 h-pyrazole-1 -yl) succinic acid and 2-(4, 5-dim ethyl- 1 h-pyrazole-1 -yl) succinic acid in a two phase solvent system |
| EP3680223A1 (en) | 2019-01-10 | 2020-07-15 | Basf Se | Mixture comprising an urease inhibitor (ui) and a nitrification inhibitor (ni) such as an ni mixture comprising 2-(3,4-dimethyl-1h-pyrazol-1-yl)succinic acid (dmpsa) and dicyandiamide (dcd) |
| CN109665927B (zh) * | 2019-02-15 | 2021-11-19 | 金正大生态工程集团股份有限公司 | 一种稳定的硝化抑制剂及其制备方法与应用 |
| CN111116259B (zh) * | 2019-12-13 | 2022-04-05 | 沈阳农业大学 | 一种稳定性肥料及其制备方法 |
| CA3164114A1 (en) | 2020-01-16 | 2021-07-22 | Gregor Pasda | Mixtures comprising a solid carrier comprising an urease inhibitor and a further solid carrier comprising a nitrification inhibitor |
| EP4090158A1 (en) | 2020-01-16 | 2022-11-23 | Basf Se | Mixtures comprising nitrification inhibitors and carriers |
| WO2022053660A2 (en) | 2020-09-14 | 2022-03-17 | Eurochem Antwerpen | N-heterocyclic compounds used as nitrification inhibitor |
| WO2022053659A2 (en) | 2020-09-14 | 2022-03-17 | Eurochem Antwerpen | Heterocyclic compounds used as nitrification inhibitor |
| WO2022053661A2 (en) | 2020-09-14 | 2022-03-17 | Eurochem Antwerpen | Pyrazolo[3,4-b]pyridine-4-carboxamide nitrification inhibitor |
| CN112321508A (zh) * | 2020-11-06 | 2021-02-05 | 浙江今晖新材料股份有限公司 | 一种硝化抑制剂的制备方法 |
| CN112358369A (zh) * | 2020-11-06 | 2021-02-12 | 浙江今晖新材料股份有限公司 | 一种硝化抑制剂的合成方法 |
| WO2022106596A1 (en) | 2020-11-23 | 2022-05-27 | Wocklab Gmbh & Co. Kg | Composition comprising dmpp and phosphonate |
| EP4015489A1 (en) * | 2020-12-21 | 2022-06-22 | Yara International ASA | Improved ammonium-based composition and method for the manufacture thereof |
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| EP4111863A1 (en) | 2021-07-02 | 2023-01-04 | EuroChem Antwerpen | Phosphorus use efficiency enhancers as plant growth promotors |
| EP4111861A1 (en) | 2021-07-02 | 2023-01-04 | EuroChem Antwerpen | P-booster |
| EP4242195A1 (en) | 2022-03-09 | 2023-09-13 | EuroChem Antwerpen | Use of pyrazolo[3,4-b]pyridine compounds as nitrification inhibitor |
| WO2023169964A1 (en) | 2022-03-09 | 2023-09-14 | Eurochem Antwerpen | Use of pyrazolo[3,4-b]pyridine compounds as nitrification inhibitor |
| CN115490565B (zh) * | 2022-06-30 | 2023-09-08 | 金正大生态工程集团股份有限公司 | 一种慢肥及其制备方法 |
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| WO2024099948A1 (en) | 2022-11-07 | 2024-05-16 | Basf Se | Use of dimethylpyrazole phosphate in can type fertilizers |
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