HRP20131121T4 - Postupak za poboljšanje neprozirnosti - Google Patents
Postupak za poboljšanje neprozirnosti Download PDFInfo
- Publication number
- HRP20131121T4 HRP20131121T4 HRP20131121TT HRP20131121T HRP20131121T4 HR P20131121 T4 HRP20131121 T4 HR P20131121T4 HR P20131121T T HRP20131121T T HR P20131121TT HR P20131121 T HRP20131121 T HR P20131121T HR P20131121 T4 HRP20131121 T4 HR P20131121T4
- Authority
- HR
- Croatia
- Prior art keywords
- carbonate
- aqueous suspension
- weight
- calcium carbonate
- dispersed calcium
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 18
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 34
- 239000007900 aqueous suspension Substances 0.000 claims 17
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 17
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 11
- 239000002270 dispersing agent Substances 0.000 claims 7
- 239000003513 alkali Substances 0.000 claims 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 239000006185 dispersion Substances 0.000 claims 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 229910000027 potassium carbonate Inorganic materials 0.000 claims 2
- 235000011181 potassium carbonates Nutrition 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 239000000725 suspension Substances 0.000 claims 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 229920006243 acrylic copolymer Polymers 0.000 claims 1
- 238000007865 diluting Methods 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 229960003975 potassium Drugs 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims 1
- 235000015497 potassium bicarbonate Nutrition 0.000 claims 1
- 239000011736 potassium bicarbonate Substances 0.000 claims 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
- 235000017557 sodium bicarbonate Nutrition 0.000 claims 1
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- 235000019830 sodium polyphosphate Nutrition 0.000 claims 1
- 235000019832 sodium triphosphate Nutrition 0.000 claims 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 1
- 229920006163 vinyl copolymer Polymers 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
- C09C1/022—Treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
- Disintegrating Or Milling (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Claims (16)
1. Postupak pripreme vodene suspenzije disperziranog kalcijevog karbonata koji daje poboljšana optička svojstva ovojnicama koje se od njega pripremaju, postupak obuhvaća korake:
a) pribavljanje vodene suspenzije disperziranog kalcijevog karbonata koja sadrži barem jedno sredstvo za disperziju, gdje vodena suspenzija ima sadržaj krutina između 65 i 80%tež, u odnosu na ukupnu težinu vodene suspenzije;
b) pribavljanje barem jednog alkalijskog karbonata i/ili alkalijskog hidrogenkarbonata, gdje se alkalijski ion odabire između kalija i/ili natrija;
c) razrjeđivanje te vodene suspenzije disperziranog kalcijevog karbonata vodom; i
d) prije i/ili tijekom i/ili nakon koraka c), dovođenje te vodene suspenzije disperziranog kalcijevog karbonata u doticaj s tim barem jednim alkalijskim karbonatom i/ili alkalijskim hidrogenkarbonatom, gdje se taj barem jedan alkalijski karbonat i/ili alkalijski hidrogenkarbonat dodaje u količini između 0.025%tež i 2tež%, u odnosu na suhu težinu kalcijevog karbonata u suspenziji iz koraka a),
gdje vodena suspenzija disperziranog kalcijevog karbonata nakon koraka d) ima pH vrijednost u rasponu 7.5 do 12.
2. Postupak prema zahtjevu 1, naznačen time što vodena suspenzija disperziranog kalcijevog karbonata iz koraka a) ima sadržaj krutina između 68%tež i 78%tež i najpoželjnije između 70%tež i 78%tež, u odnosu na ukupnu težinu vodene suspenzije disperziranog kalcijevog karbonata iz koraka a).
3. Postupak prema zahtjevu 1 ili 2, naznačen time što se barem jedan alkalijski karbonat i/ili hidrogenkarbonat odabire iz skupine koju čine natrijev karbonat, kalijev karbonat, natrijev hidrogenkarbonat, kalijev hidrogenkarbonat njihove mješavine.
4. Postupak prema zahtjevu 3, naznačen time što barem jedan alkalijski karbonat i/ili hidrogenkarbonat jest natrijev karbonat i/ili kalijev karbonat.
5. Postupak prema bilo kojem od zahtjeva 1 do 4, naznačen time što se barem jedan alkalijski karbonat i/ili hidrogenkarbonat dodaje u količini između 0.05%tež i 1%tež i najpoželjnije između 0.1%tež i 0.5%tež, u odnosu na suhu težinu kalcijevog karbonata u suspenziji iz koraka a).
6. Postupak prema bilo kojem od zahtjeva 1 do 5, naznačen time što se vodena suspenzija disperziranog kalcijevog karbonata prvo razrjeđuje (korak c)) i zatim dovodi u doticaj s barem jednim alkalijskim karbonatom i/ili hidrogenkarbonatom (korak d)).
7. Postupak prema bilo kojem od zahtjeva 1 do 5, naznačen time što se vodena suspenzija disperziranog kalcijevog karbonata istodobno razrjeđuje (korak c)) i dovodi u doticaj s barem jednim alkalijskim karbonatom i/ili hidrogenkarbonatom (korak d)).
8. Postupak prema bilo kojem od zahtjeva 1 do 5, naznačen time što se vodena suspenzija disperziranog kalcijevog karbonata razrjeđuje (korak c)) odmah nakon dovođenja u doticaj s barem jednim alkalijskim karbonatom i/ili hidrogenkarbonatom (korak d)), poželjno za manje od 45 min nakon potpunog dodavanja barem jednog alkalijskog karbonata i/ili hidrogenkarbonata.
9. Postupak prema bilo kojem od zahtjeva 1 do 5, naznačen time što se vodena suspenzija disperziranog kalcijevog karbonata razrjeđuje u jednom ili više dijelova i barem jedan alkalijski karbonat i/ili hidrogenkarbonat se dodaje u jednom ili više dijelova.
10. Postupak prema bilo kojem od zahtjeva 1 do 9, naznačen time što vodena suspenzija disperziranog kalcijevog karbonata obuhvaća barem jedno sredstvo za disperziju, to barem jedno sredstvo za disperziju odabire se iz skupine koju čine organsko sredstvo za disperziju, anorgansko sredstvo za disperziju i njihove mješavine.
11. Postupak prema zahtjevu 10, naznačen time što organsko sredstvo za disperziju obuhvaća akrilni polimer, vinil polimer, akrilni i/ili vinil kopolimer i anorgansko sredstvo za disperziju obuhvaća mono-, di i/ili trinatrijev ortofosfat, natrijev tripolifosfat i/ili natrijev polifosfat.
12. Postupak prema zahtjevu 10 ili 11, naznačen time što su kisela mjesta barem jednog organskog sredstva za disperziju djelomično ili potpuno neutralizirana natrijem.
13. Postupak prema bilo kojem od zahtjeva 1 do 12, naznačen time što se vodena suspenzija disperziranog kalcijevog karbonata iz koraka a) dobiva koncentriranjem vodene suspenzije kalcijevog karbonata.
14. Postupak prema zahtjevu 13, naznačen time što se sredstvo za disperziju dodaje prije koraka koncentriranja.
15. Postupak prema zahtjevu 13, naznačen time što se sredstvo za disperziju dodaje nakon koraka koncentriranja.
16. Postupak prema bilo kojem od zahtjeva 13 do 15, naznačen time što se kalcijev karbonat u vodenoj suspenziji melje prije koraka koncentriranja.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09164353.6A EP2292701B2 (en) | 2009-07-01 | 2009-07-01 | Method for improving opacity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HRP20131121T1 HRP20131121T1 (hr) | 2014-01-31 |
| HRP20131121T4 true HRP20131121T4 (hr) | 2017-04-21 |
Family
ID=40910833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20131121TT HRP20131121T4 (hr) | 2009-07-01 | 2013-11-25 | Postupak za poboljšanje neprozirnosti |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US8821628B2 (hr) |
| EP (2) | EP2292701B2 (hr) |
| JP (1) | JP5710607B2 (hr) |
| CN (1) | CN102471607B (hr) |
| BR (1) | BRPI1011910A2 (hr) |
| CA (1) | CA2766787C (hr) |
| DK (1) | DK2292701T4 (hr) |
| ES (1) | ES2438278T5 (hr) |
| HR (1) | HRP20131121T4 (hr) |
| PL (1) | PL2292701T5 (hr) |
| PT (1) | PT2292701E (hr) |
| RS (1) | RS53093B2 (hr) |
| RU (1) | RU2527219C2 (hr) |
| SI (2) | SI2292701T2 (hr) |
| TW (1) | TWI519607B (hr) |
| WO (1) | WO2011001374A1 (hr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103958616B (zh) | 2011-10-05 | 2016-09-28 | 索尔维公司 | 沉淀碳酸钙颗粒及其用途 |
| EP2781557A1 (en) | 2013-03-18 | 2014-09-24 | Solvay Sa | Precipitated calcium carbonate, a method for its manufacture and uses thereof |
| SI3042878T1 (sl) * | 2015-01-07 | 2019-07-31 | Omya International Ag | Postopek za pridobivanje ultrafinih GCC z visoko zmožnostjo razprševanja svetlobe in visoko vsebnostjo trdih delcev |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3006779A (en) † | 1959-01-09 | 1961-10-31 | Wyandotte Chemicals Corp | Continuous calcium carbonate slurry process |
| DE1188423B (de) * | 1960-11-12 | 1965-03-04 | Degussa | Verfahren zur Herstellung von Weisspigmenten auf der Grundlage von Calciumcarbonat fuer Papier-Streichfarben |
| US3245819A (en) † | 1962-07-30 | 1966-04-12 | Wyandotte Chemicals Corp | Stabilization of calcium carbonate slurries |
| US3157533A (en) | 1963-07-17 | 1964-11-17 | Little Inc A | Starch stabilized casein coating emulsions |
| US3992314A (en) * | 1974-09-27 | 1976-11-16 | The Procter & Gamble Company | Process for the preparation of spray-dried calcium carbonate-containing granules |
| GB1472701A (en) | 1975-01-03 | 1977-05-04 | English Clays Lovering Pochin | Production of aqueous calcium carbonate suspensions |
| LU77723A1 (fr) * | 1977-07-11 | 1979-03-26 | Solvay | Procede pour la preparation de suspensions aqueuses concentrees de carbonate de calcium |
| US5269818A (en) † | 1990-03-13 | 1993-12-14 | Pfizer Inc | Rhombohedral calcium carbonate and accelerated heat-aging process for the production thereof |
| US5558850A (en) | 1990-07-27 | 1996-09-24 | Ecc International Limited | Precipitated calcium carbonate |
| US5080717A (en) * | 1991-01-24 | 1992-01-14 | Aqualon Company | Fluid suspensions of polysaccharide mixtures |
| US5449402A (en) | 1994-02-17 | 1995-09-12 | Whalen-Shaw; Michael | Modified inorganic pigments, methods of preparation, and compositions containing the same |
| FI100729B (fi) * | 1995-06-29 | 1998-02-13 | Metsae Serla Oy | Paperinvalmistuksessa käytettävä täyteaine ja menetelmä täyteaineen va lmistamiseksi |
| US5647902A (en) * | 1995-10-20 | 1997-07-15 | Ecc International Inc. | Stabilized calcium carbonate composition using sodium carbonate and mixtures of acids and uses therefor |
| US5972088A (en) † | 1996-03-13 | 1999-10-26 | Sun Chemical Corporation | Water-based gravure printing ink |
| DE19820122A1 (de) | 1998-05-06 | 1999-11-11 | Solvay Alkali Gmbh | Verfahren zur Herstellung sedimentationsstabiler Calciumcarbonatsuspension |
| JP2002003219A (ja) * | 2000-06-20 | 2002-01-09 | Toyo Denka Kogyo Co Ltd | 高濃度炭酸カルシウムスラリー及びその製造方法 |
| FR2818165B1 (fr) | 2000-12-20 | 2003-10-31 | Coatex Sas | Agent d'aide au broyage de materiaux mineraux en suspension aqueuse. suspensions aqueuses obtenues et leurs utilisations |
| RU2280115C2 (ru) * | 2001-12-20 | 2006-07-20 | Спешиалти Минералз (Мичиган) Инк. | Составы покрытий из карбоната кальция для придания высокого лоска и бумага и картон с покрытием, образованным из вышеуказанных составов |
| EP1752499A1 (en) * | 2005-07-25 | 2007-02-14 | Omya Development AG | Process to disperse and/or grind and/or concentrate calcium carbonate in aqueous media using an aqueous solution containing zirconium compounds |
| JP5067967B2 (ja) * | 2005-08-17 | 2012-11-07 | 日本製紙株式会社 | 電子写真用転写紙 |
| JP2007161537A (ja) * | 2005-12-14 | 2007-06-28 | Oji Paper Co Ltd | 軽質炭酸カルシウムスラリー |
| JP5305602B2 (ja) * | 2007-03-13 | 2013-10-02 | 丸尾カルシウム株式会社 | 表面処理炭酸カルシウム及びそれを配合してなる樹脂組成物 |
| RU2350637C2 (ru) * | 2007-03-29 | 2009-03-27 | Открытое Акционерное Общество "Каустик" | Многофункциональный наполнитель на основе химически осажденного карбоната кальция и способ его получения |
| FR2968219B1 (fr) * | 2010-12-02 | 2012-12-14 | Coatex Sas | Utilisation de sels alcalins de carbonate pour reduire la dose de polymere acrylique dans un procede de broyage de carbonate de calcium dans l'eau. |
-
2009
- 2009-07-01 RS RS20130534A patent/RS53093B2/sr unknown
- 2009-07-01 PT PT09164353T patent/PT2292701E/pt unknown
- 2009-07-01 DK DK09164353.6T patent/DK2292701T4/en active
- 2009-07-01 SI SI200930787A patent/SI2292701T2/sl unknown
- 2009-07-01 EP EP09164353.6A patent/EP2292701B2/en active Active
- 2009-07-01 PL PL09164353T patent/PL2292701T5/pl unknown
- 2009-07-01 SI SI200930787T patent/SI2292701T1/sl unknown
- 2009-07-01 ES ES09164353.6T patent/ES2438278T5/es active Active
-
2010
- 2010-06-29 CA CA2766787A patent/CA2766787C/en not_active Expired - Fee Related
- 2010-06-29 BR BRPI1011910A patent/BRPI1011910A2/pt not_active Application Discontinuation
- 2010-06-29 RU RU2012103320/05A patent/RU2527219C2/ru not_active IP Right Cessation
- 2010-06-29 JP JP2012518143A patent/JP5710607B2/ja not_active Expired - Fee Related
- 2010-06-29 EP EP10734560A patent/EP2449035A1/en not_active Withdrawn
- 2010-06-29 US US13/380,683 patent/US8821628B2/en not_active Expired - Fee Related
- 2010-06-29 CN CN201080036140.4A patent/CN102471607B/zh not_active Expired - Fee Related
- 2010-06-29 WO PCT/IB2010/052963 patent/WO2011001374A1/en active Application Filing
- 2010-06-30 TW TW099121407A patent/TWI519607B/zh not_active IP Right Cessation
-
2013
- 2013-11-25 HR HRP20131121TT patent/HRP20131121T4/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PT2292701E (pt) | 2013-12-10 |
| PL2292701T3 (pl) | 2014-04-30 |
| EP2292701B1 (en) | 2013-09-04 |
| TW201111449A (en) | 2011-04-01 |
| RS53093B (en) | 2014-06-30 |
| JP2012532084A (ja) | 2012-12-13 |
| SI2292701T1 (sl) | 2014-01-31 |
| SI2292701T2 (sl) | 2017-04-26 |
| ES2438278T3 (es) | 2014-01-16 |
| JP5710607B2 (ja) | 2015-04-30 |
| CN102471607A (zh) | 2012-05-23 |
| RS53093B2 (sr) | 2018-05-31 |
| US20120097069A1 (en) | 2012-04-26 |
| TWI519607B (zh) | 2016-02-01 |
| WO2011001374A1 (en) | 2011-01-06 |
| CA2766787C (en) | 2018-01-16 |
| RU2012103320A (ru) | 2013-08-10 |
| CN102471607B (zh) | 2014-04-23 |
| EP2292701A1 (en) | 2011-03-09 |
| DK2292701T4 (en) | 2017-03-27 |
| BRPI1011910A2 (pt) | 2016-04-19 |
| EP2292701B2 (en) | 2017-01-25 |
| HRP20131121T1 (hr) | 2014-01-31 |
| PL2292701T5 (pl) | 2017-12-29 |
| RU2527219C2 (ru) | 2014-08-27 |
| US8821628B2 (en) | 2014-09-02 |
| ES2438278T5 (es) | 2017-07-11 |
| CA2766787A1 (en) | 2011-01-06 |
| DK2292701T3 (da) | 2013-12-16 |
| EP2449035A1 (en) | 2012-05-09 |
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