HRP20131080T1 - Metoda za pripremanje vodenih suspenzija mineralnih tvari korištenjem amina kombiniranih sa vinil-karboksilnim polimerima - Google Patents
Metoda za pripremanje vodenih suspenzija mineralnih tvari korištenjem amina kombiniranih sa vinil-karboksilnim polimerima Download PDFInfo
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- HRP20131080T1 HRP20131080T1 HRP20131080AT HRP20131080T HRP20131080T1 HR P20131080 T1 HRP20131080 T1 HR P20131080T1 HR P20131080A T HRP20131080A T HR P20131080AT HR P20131080 T HRP20131080 T HR P20131080T HR P20131080 T1 HRP20131080 T1 HR P20131080T1
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- 229910052500 inorganic mineral Inorganic materials 0.000 title claims 24
- 239000011707 mineral Substances 0.000 title claims 24
- 239000007900 aqueous suspension Substances 0.000 title claims 23
- 238000000034 method Methods 0.000 title claims 17
- 150000001412 amines Chemical class 0.000 title claims 7
- 229920000642 polymer Polymers 0.000 title claims 6
- 239000000463 material Substances 0.000 title 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title 1
- 229920002554 vinyl polymer Polymers 0.000 title 1
- 239000000126 substance Substances 0.000 claims 24
- 235000010755 mineral Nutrition 0.000 claims 23
- 125000004432 carbon atom Chemical group C* 0.000 claims 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 5
- -1 vinyl carboxyl Chemical group 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims 3
- 239000012141 concentrate Substances 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 230000003472 neutralizing effect Effects 0.000 claims 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- 229910021532 Calcite Inorganic materials 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 235000019738 Limestone Nutrition 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims 1
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 239000012973 diazabicyclooctane Substances 0.000 claims 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
- 239000010459 dolomite Substances 0.000 claims 1
- 229910000514 dolomite Inorganic materials 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- 239000006028 limestone Substances 0.000 claims 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims 1
- 239000000347 magnesium hydroxide Substances 0.000 claims 1
- 235000012254 magnesium hydroxide Nutrition 0.000 claims 1
- 229960000816 magnesium hydroxide Drugs 0.000 claims 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims 1
- 239000000395 magnesium oxide Substances 0.000 claims 1
- 235000012245 magnesium oxide Nutrition 0.000 claims 1
- 229960000869 magnesium oxide Drugs 0.000 claims 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- 239000004579 marble Substances 0.000 claims 1
- 229910052754 neon Inorganic materials 0.000 claims 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims 1
- 239000003973 paint Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Claims (17)
1. Metoda za pripremanje vodene suspenzije mineralne tvari, naznačena time, što sadrži korake:
a) najmanje jednu mineralnu tvar učiniti dostupnom,
b) pripremiti vodenu suspenziju koja sadrži najmanje mineralnu tvar iz koraka a),
c) samljeti mineral u vodenoj suspenziji iz koraka b),
d) i, opciono, selekcionirati i/ili koncentrirati vodenu suspenziju iz koraka c) prije dispeziranja dobijenog koncentrata,
koji se karakterizira time što se najmanje jedan amin i jedan vinil-karboksilni polimer potpuno neutraliziran neutralizujućim sredstvom različitim od amina, dodaju između koraka a) i/ili b) i/ili c) ili tokom koraka c) ili poslije koraka c) tokom ili poslije disperziranja dobijenog koncentrata.
2. Metoda za pripremanje vodene suspenzije mineralne tvari prema zahtjevu 1, naznačena time, što odnos masa amin:vinil-karboksilni polimer iznosi između 0.05:1 i 0.35:1, poželjno između 0.10:1 i 0.25:1.
3. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 ili 2, naznačena time, što se amin bira između dimetilamina, monoetanolamina, dietanolamina, trietanolamina, N-metiletanolamina, 2-amino-2-metil-1-propanola, triizopropanolamina, 2,3,4,6,7,8,9,10-oktahidropirimido[1,2- a]azepina (DBU; CAS No. = 6674-22-2), 2,2-diazabiciklo[2.2 .2]oktana (DABCO; CAS No. = 280-57-9).
4. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 ili 2, naznačena time, što amin ima formulu (I):
NR1R2R3(I)
gdje su R1,R2 , R3 isti ili različiti, odabrani između:
- linearnog ili razgranatog alkil- ili oksialkil-radikala sa 1 do 12 ugljikovih atoma,
- cikloalkil-radikala sa 3 do 12 ugljikovih atoma,
- linearnog hidroksialkil-radikala sa 1 do 6 ugljikovih atoma,
uz uvjet da:
- najviše jedna od grupa R2 ili R3 bude vodik,
- najmanje jedna od grupa R1, R2, R3 sadrži OH grupu,
- najmanje jedna od grupa R1, R2, R3 uključuje najmanje jednu granu na poziciji α u odnosu na atom dušika.
5. Metoda za pripremanje vodene suspenzije mineralne tvari prema zahtjevu 4, naznačena time, što je u formuli (I) R1 vodik, R2 i R3 su isti ili različiti, odabrani između:
- linearnog ili razgranatog alkil- ili oksialkil-radikala sa 1 do 12 ugljikovih atoma,
- cikloalkil radikala sa 3 do 12 ugljikovih atoma,
- linearnog hidroksialkil-radikala sa 1 do 6 ugljikovih atoma,
uz uvjet da:
- najviše jedna od grupa R2 ili R3 sadrži OH grupu,
- najmanje jedna od grupa R2 ili R3 uključuje najmanje jednu granu na poziciji α u odnosu na atom dušika.
6. Metoda za pripremanje vodene suspenzije mineralne tvari prema zahtjevu 4, naznačena time, što u formuli (I) svaki alkil- ili cikloalkil- ili oskialkil-radikal sadrži od 3 do 10, poželjno od 3 do 8 ugljikovih atoma.
7. Metoda za pripremanje vodene suspenzije mineralne tvari prema zahtjevu 4, naznačena time, što u formuli (I), jedan ili više radikala koji nose OH grupu imaju 2 ili 3, poželjno 2 ugljikova atoma.
8. Metoda za pripremanje vodene suspenzije mineralne tvari prema zahtjevu 4, naznačena time, što je u formuli (I), R1 vodik, R2 i R3 su identični ili različiti, odabrani između:
- linearnog ili razgranatog alkil- ili oksialkil-radikala sa 3 do 8 ugljikovih atoma,
- cikloalkil-radikala sa 6 do 10 ugljikovih atoma,
- linearnog hidroksialkil-radikala sa 2 do 3, poželjno 2 ugljikova atoma,
uz uvjet da:
- najmanje jedna od grupa R2 ili R3 sadrži OH grupu,
- najmanje jedna od grupa R2 ili R3 uključuje najmanje jednu granu na poziciji α u odnosu na atom dušika.
9. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 4 do 8, naznačena time, što se amin bira između:
- N-(1-metilpropil)-N-(2-hidroksietilamina),
- N-(1,3-dimetilbutil)-N-(2-hidroksietilamina),
- N-(1-etil-3-metilpentil)-N-(2-hidroksietilamina),
- N-(3,3 ',5-trimetilcikloheksil)-N-(2-hidroksietilamina),
- N-(4-hidroksicikloheksil)-N-(2-hidroksietilamina).
10. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 do 9, naznačena time, što je vinil karboksilni polimer potpuno neutraliziran najmanje jednim neutralizirajućim sredstvom koje se bira između kalcijeva-, magnezijeva-hidroksida i/ili oksida, ili između natrijeva-, kalijeva-, litijeva- hidroksida i njihovih mješavina.
11. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 do 10, naznačena time, što je spomenuti vinil-karboksilni polimer homopolimer akrilne kiseline ili kopolimer akrilne kiseline i drugog monomera.
12. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 do 11, naznačena time, što se za kopolimer akrilne kiseline i drugog monomera, ovaj drugi monomer bira između metakrilne kiseline, maleinskog anhidrida, 2-akrilamido-2-metil-propansulfonske kiseline, fosfornih estera (met) akrilata alkilen-glikola i neonskih monomera formule (II):
[image]
gdje su m, n, p i q cijeli brojevi i m, n, p su manji od 150, q je veći od 0 i najmanje jedan cijeli broj m, n i p nije 0, R je radikal sa polimerizabilnom nesaturiranom funkcionalnom grupom, R1 i R2 su identični ili različiti i predstavljaju vodikove atome ili alkil-grupe, R' predstavlja vodik ili ugljikovodični radikal sa 1 do 40 ugljikovih atoma ili ionsku ili ionizabilnu grupu.
13. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 do 12, naznačena time, što spomenuta vodena suspenzija poslije disperziranja i/ili mljevenja ima sadržaj čvrste supstance izražen kao postotak suhe težine mineralne tvari prema ukupnoj težini, između 10% i 82%, poželjno između 50% i 81%, najpoželjnije između 65% i 78%.
14. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 do 13, naznačena time, što spomenuta vodena suspenzija ima sadržaj suhe težine vinil-karboksilnog polimera, prema ukupnoj suhoj težini mineralne tvari, između 0.01% i 5.00%, poželjno između 0.01% i 2.00%, i najpoželjnije između 0.05% i 1.00%.
15. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 do 14, naznačena time, što se mineralna materija bira između prirodnog kalcijeva-karbonata, sintetskog ili precipitiranog kalcijeva-karbonata, talka, kaolina, i njihovih mješavina, poželjno između prirodnog, sintetskog ili precipitiranog kalcijeva-karbonata i njihovih mješavina, i poželjno je prirodni kalcijev-karbonat.
16. Metoda za pripremanje vodene suspenzije mineralne tvari prema jednom od zahtjeva 1 do 15, naznačena time, što se prirodni kalcijev-karbonat bira između krečnjaka, mramora, kalcita, krede, dolomita i njihovih mješavina.
17. Uporaba vodene suspenzije mineralne tvari dobijene u jednom od zahtjeva 1 do 16, naznačena time, što se koristi u području papira, kao potporna supstanca i papirna obloga, i u području boja i plastike.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10014783.4A EP2455429B1 (fr) | 2010-11-19 | 2010-11-19 | Procédé de préparation de suspensions aqueuses de matiéres minérales au moyen d'amines en combinaison avec des polymères vinyl-carboxyliques. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20131080T1 true HRP20131080T1 (hr) | 2013-12-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| HRP20131080AT HRP20131080T1 (hr) | 2010-11-19 | 2013-11-12 | Metoda za pripremanje vodenih suspenzija mineralnih tvari korištenjem amina kombiniranih sa vinil-karboksilnim polimerima |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US9029448B2 (hr) |
| EP (2) | EP2455429B1 (hr) |
| JP (2) | JP6208013B2 (hr) |
| KR (1) | KR101881615B1 (hr) |
| CN (1) | CN103328585B (hr) |
| AR (1) | AR083892A1 (hr) |
| AU (1) | AU2011330888B2 (hr) |
| BR (1) | BR112013012092B1 (hr) |
| CA (1) | CA2816733C (hr) |
| CL (1) | CL2013001346A1 (hr) |
| DK (1) | DK2455429T3 (hr) |
| ES (1) | ES2435649T3 (hr) |
| HR (1) | HRP20131080T1 (hr) |
| IL (1) | IL226365B (hr) |
| JO (1) | JO3104B1 (hr) |
| MX (1) | MX2013005153A (hr) |
| PT (1) | PT2455429E (hr) |
| RS (1) | RS53031B (hr) |
| RU (1) | RU2643548C2 (hr) |
| SI (1) | SI2455429T1 (hr) |
| TW (1) | TWI496843B (hr) |
| UY (1) | UY33737A (hr) |
| WO (1) | WO2012066410A1 (hr) |
| ZA (1) | ZA201303415B (hr) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| FR2992982B1 (fr) | 2012-07-06 | 2015-04-24 | Roquette Freres | Suspensions aqueuses de dioxyde de titane et de matiere amylacee cationique destinees a la fabrication de papier et de carton |
| US10774399B2 (en) | 2013-07-02 | 2020-09-15 | Solenis Technologies, L.P. | Hydrolyzed starches as grinding aids for mineral ore processing |
| JP2015150530A (ja) * | 2014-02-18 | 2015-08-24 | 株式会社日本触媒 | 無機微粒子分散剤 |
| US10004838B2 (en) * | 2014-06-24 | 2018-06-26 | Medtronic, Inc. | Reserve zirconium phosphate module for use in sorbent dialysis |
| EP3530805A1 (en) * | 2018-02-21 | 2019-08-28 | Imertech Sas | Bimodal precipitated calcium carbonate slurries suitable for paper and board applications, methods for making the same and their uses |
| SI3561002T1 (sl) * | 2018-04-23 | 2021-01-29 | Omya International Ag | Uporaba aditivov, ki vsebujejo primarne alkanolamine v vodnih mineralnih suspenzijah |
| FR3093012B1 (fr) * | 2019-02-26 | 2021-01-22 | Coatex Sas | Réduction de l’hygroscopicité d’un matériau minéral |
| EP4149887A1 (en) | 2020-05-13 | 2023-03-22 | Basf Se | Biocide free pigment dispersions and methods of preparing them |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2370171A (en) | 1943-08-20 | 1945-02-27 | Jepson Percy | Locking pin |
| JPS5765317A (en) * | 1980-10-06 | 1982-04-20 | Sanyo Chem Ind Ltd | Dispersant of alumina |
| US4370171A (en) | 1981-02-02 | 1983-01-25 | Angus Chemical Co. | Method for dispersing comminuted solids |
| FR2539137A1 (fr) | 1982-08-06 | 1984-07-13 | Coatex Sa | Agent de broyage a base de polymeres et/ou copolymeres acryliques neutralises pour suspension aqueuse de materiaux mineraux grossiers en vue d'applications pigmentaires |
| US4752340A (en) * | 1987-01-27 | 1988-06-21 | Kerr-Mcgee Chemical Corporation | Titanium dioxide pigments |
| JPS63248839A (ja) * | 1987-04-03 | 1988-10-17 | Kansai Paint Co Ltd | 水性顔料分散液 |
| FR2642415B1 (fr) * | 1989-01-27 | 1991-04-05 | Coatex Sa | Procede de broyage de carbonate de calcium en milieu aqueux |
| DE4104573A1 (de) | 1991-02-14 | 1992-08-20 | Pluss Stauffer Ag | Verfahren und vorrichtung zur technischen fraktionierung von polymeren |
| FR2683539B1 (fr) | 1991-11-12 | 1993-12-31 | Coatex Sa | Procede de broyage en suspension aqueuse en presence d'un agent de broyage neutralise en partie par du magnesium. |
| FR2683538B1 (fr) | 1991-11-12 | 1993-12-31 | Coatex Sa | Procede de broyage en suspension aqueuse en presence d'un agent de broyage neutralise en partie par du magnesium. |
| FR2683537B1 (fr) | 1991-11-12 | 1993-12-31 | Coatex Sa | Agent de broyage et/ou de dispersion a base de polymeres et/ou copolymeres neutralises en partie par du magnesium pour suspensions aqueuses de materiaux mineraux en vue d'applications pigmentaires. |
| FR2683536B1 (fr) | 1991-11-12 | 1993-12-31 | Coatex Sa | Agent de broyage et/ou de dispersion a base de polymeres et/ou copolymeres neutralises en partie par du magnesium pour suspensions aqueuses de materiaux mineraux en vue d'applications pigmentaires. |
| JPH10110015A (ja) * | 1996-10-07 | 1998-04-28 | Sanyo Chem Ind Ltd | 顔料分散剤 |
| GB9627002D0 (en) | 1996-12-27 | 1997-02-12 | Ecc Int Ltd | Dispersed aqueous suspensions |
| JP2984926B2 (ja) * | 1997-10-30 | 1999-11-29 | 三洋化成工業株式会社 | 顔料分散剤 |
| WO1999023185A1 (fr) * | 1997-10-30 | 1999-05-14 | Sanyo Chemical Industries, Ltd. | Agent dispersant pigmentaire et composition de dispersion de pigments |
| FR2802830B1 (fr) | 1999-12-27 | 2002-06-07 | Coatex Sa | Utilisation de polymeres hydrosolubles comme agent de dispersion de suspension aqueuse de carbonate de calcium suspensions aqueuses obtenues et leurs utilisations |
| FR2818166B1 (fr) * | 2000-12-20 | 2003-10-31 | Coatex Sas | Agent d'aide au broyage et/ou de dispersion de materiaux mineraux en suspension aqueuse. suspensions aqueuses obtenues et leurs utilisations |
| FR2818165B1 (fr) | 2000-12-20 | 2003-10-31 | Coatex Sas | Agent d'aide au broyage de materiaux mineraux en suspension aqueuse. suspensions aqueuses obtenues et leurs utilisations |
| FR2821620B1 (fr) | 2001-03-02 | 2003-06-27 | Coatex Sas | Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres de faible polydispersite obtenus, et leurs applications |
| FR2842814B1 (fr) | 2002-07-26 | 2004-10-22 | Coatex Sas | Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications. |
| FR2846972B1 (fr) | 2002-11-08 | 2005-02-18 | Omya Ag | Suspensions aqueuses de matieres minerales broyees, faiblement chargees ioniquement et leurs utilisations |
| JP4492046B2 (ja) * | 2002-11-28 | 2010-06-30 | セイコーエプソン株式会社 | インクセット、記録方法、及び記録物 |
| FR2871474B1 (fr) * | 2004-06-11 | 2006-09-15 | Omya Development Ag | Nouveau pigment mineral sec contenant du carbonate de calcium, suspension aqueuse le contenant et ses usages |
| JP2006282760A (ja) * | 2005-03-31 | 2006-10-19 | Seiko Epson Corp | インク組成物、これを用いたインクジェット記録方法及び記録物 |
| FR2894846B1 (fr) | 2005-12-20 | 2008-02-01 | Coatex Sas | Utilisation de dispersants pour concentrer des matieres minerales dans l'eau, dispersions obtenues et leurs utilisations. |
| FR2896171B1 (fr) * | 2006-01-19 | 2010-12-17 | Omya Development Ag | Procede de fabrication de particules a base de carbonate de calcium naturel et de sels d'acide ethylene acrylique, suspensions et pigments secs obtenus, leurs utilisations. |
| FR2903618B1 (fr) | 2006-07-12 | 2008-10-31 | Coatex Sas | Agent de dispersion et/ou d'aide au broyage pour dispersion et suspension aqueuse de matieres minerales, dispersion et suspension obtenues et leurs utilisations. |
| FR2913428B1 (fr) * | 2007-03-05 | 2009-06-05 | Coatex Soc Par Actions Simplif | Utilisation dans une peinture,d'un carbonate de calcium broye a sec avec un copolymere de l'acide (meth) acrylique avec une fonction alcoxy ou hydroxy polyalkyleneglycol. |
| FR2926083B1 (fr) * | 2008-01-04 | 2010-04-09 | Arkema France | Agent de neutralisation et de co-dispersion a fort pouvoir de developpement de la force colorante, et les peintures et concentres pigmentaires le contenant. |
| EP2194103A1 (en) | 2008-12-04 | 2010-06-09 | Omya Development Ag | Process for manufacturing calcium carbonate materials having a particle surface with improved adsorption properties |
| FR2940141B1 (fr) | 2008-12-19 | 2010-12-17 | Coatex Sas | Utilisation de polymeres acryliques neutralises par le lithium comme agents dispersants ou d'aide au broyage en milieu aqueux de matieres minerales |
| EP2208761B1 (en) * | 2009-01-16 | 2012-10-10 | Omya Development AG | Process to prepare self-binding pigment particles implementing acrylic comb copolymers with hydrophobic groups as coupling agents, self binding pigment particles and uses thereof |
| WO2010122994A1 (ja) * | 2009-04-23 | 2010-10-28 | コニカミノルタＩｊ株式会社 | 水性インクジェットインクとそれを用いたインクジェットプリント物の製造方法、及び水性インクジェットインクの製造方法 |
-
2010
- 2010-11-19 PT PT100147834T patent/PT2455429E/pt unknown
- 2010-11-19 RS RS20130491A patent/RS53031B/en unknown
- 2010-11-19 EP EP10014783.4A patent/EP2455429B1/fr active Active
- 2010-11-19 SI SI201030421T patent/SI2455429T1/sl unknown
- 2010-11-19 ES ES10014783T patent/ES2435649T3/es active Active
- 2010-11-19 DK DK10014783.4T patent/DK2455429T3/da active
-
2011
- 2011-11-15 JO JOP/2011/0341A patent/JO3104B1/ar active
- 2011-11-16 AR ARP110104277A patent/AR083892A1/es not_active Application Discontinuation
- 2011-11-17 AU AU2011330888A patent/AU2011330888B2/en not_active Ceased
- 2011-11-17 KR KR1020137014323A patent/KR101881615B1/ko active IP Right Grant
- 2011-11-17 RU RU2013127662A patent/RU2643548C2/ru active
- 2011-11-17 WO PCT/IB2011/002724 patent/WO2012066410A1/fr active Application Filing
- 2011-11-17 CN CN201180055688.8A patent/CN103328585B/zh active Active
- 2011-11-17 UY UY0001033737A patent/UY33737A/es not_active Application Discontinuation
- 2011-11-17 JP JP2013539355A patent/JP6208013B2/ja not_active Expired - Fee Related
- 2011-11-17 BR BR112013012092-4A patent/BR112013012092B1/pt not_active IP Right Cessation
- 2011-11-17 EP EP11801824.1A patent/EP2640786A1/fr not_active Withdrawn
- 2011-11-17 CA CA2816733A patent/CA2816733C/fr active Active
- 2011-11-17 US US13/883,627 patent/US9029448B2/en active Active
- 2011-11-17 MX MX2013005153A patent/MX2013005153A/es active IP Right Grant
- 2011-11-18 TW TW100142214A patent/TWI496843B/zh not_active IP Right Cessation
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2013
- 2013-05-10 ZA ZA2013/03415A patent/ZA201303415B/en unknown
- 2013-05-15 CL CL2013001346A patent/CL2013001346A1/es unknown
- 2013-05-16 IL IL226365A patent/IL226365B/en not_active IP Right Cessation
- 2013-11-12 HR HRP20131080AT patent/HRP20131080T1/hr unknown
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2017
- 2017-05-30 JP JP2017106910A patent/JP2017214574A/ja active Pending
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