HRP20130268T1 - Teško zapaljive pigmentne disperzije (masterbatch) za termoplastiäśne polimere i postupak njihove proizvodnje - Google Patents
Teško zapaljive pigmentne disperzije (masterbatch) za termoplastiäśne polimere i postupak njihove proizvodnje Download PDFInfo
- Publication number
- HRP20130268T1 HRP20130268T1 HRP20130268AT HRP20130268T HRP20130268T1 HR P20130268 T1 HRP20130268 T1 HR P20130268T1 HR P20130268A T HRP20130268A T HR P20130268AT HR P20130268 T HRP20130268 T HR P20130268T HR P20130268 T1 HRP20130268 T1 HR P20130268T1
- Authority
- HR
- Croatia
- Prior art keywords
- masterbatch
- mixture
- pigment dispersions
- component
- polymer
- Prior art date
Links
- 239000004594 Masterbatch (MB) Substances 0.000 title claims 13
- 238000000034 method Methods 0.000 title claims 5
- 229920001169 thermoplastic Polymers 0.000 title claims 5
- 238000004519 manufacturing process Methods 0.000 title claims 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title 1
- 239000003063 flame retardant Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims 9
- 239000006185 dispersion Substances 0.000 claims 7
- 239000000049 pigment Substances 0.000 claims 7
- 229920000642 polymer Polymers 0.000 claims 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 239000002041 carbon nanotube Substances 0.000 claims 4
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- 238000001033 granulometry Methods 0.000 claims 3
- 239000000843 powder Substances 0.000 claims 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 2
- 229920001903 high density polyethylene Polymers 0.000 claims 2
- 239000004700 high-density polyethylene Substances 0.000 claims 2
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims 2
- 229910052615 phyllosilicate Inorganic materials 0.000 claims 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims 2
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 238000007872 degassing Methods 0.000 claims 1
- 239000005038 ethylene vinyl acetate Substances 0.000 claims 1
- 230000009970 fire resistant effect Effects 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229920000092 linear low density polyethylene Polymers 0.000 claims 1
- 239000004707 linear low-density polyethylene Substances 0.000 claims 1
- 229920001684 low density polyethylene Polymers 0.000 claims 1
- 239000004702 low-density polyethylene Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims 1
- -1 polypropylene Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920005606 polypropylene copolymer Polymers 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/203—Solid polymers with solid and/or liquid additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Fireproofing Substances (AREA)
Claims (11)
1. Teško zapaljive pigmentne disperzije (masterbatch) za uporabu u termoplastičnom polimeru, obuhvaćaju polimerni nosač i smjesu ugljikovih nanocijevi te drugu komponentu, gdje su ugljikove nanocijevi prisutne između 0.1 % i 5% po težini i druga je komponenta prisutna između 5% i 65% po težini, naznačeno time što se druga komponenta izabire između filosilikata, silikata s trodimenzionalnom kristalnom strukturom, kalcijevog karbonata, cink borata, cink stanata ili melamin cijanurata ili mješavine dva ili više od ovih spojeva, i prisutna je u obliku praška s maksimalnim dimenzijama do oko , prosječnim dimenzijama (D50) do oko i minimalnim dimenzijama većim od 1 mm.
2. Teško zapaljive pigmentne disperzije (masterbatch) prema zahtjevu 1, gdje je druga komponenta aluminosilikat.
3. Teško zapaljive pigmentne disperzije (masterbatch) prema bilo kojem od zahtjeva 1 ili 2, gdje aluminosilikat ima prosječnu granulometriju između oko 2 i 7 mm.
4. Teško zapaljive pigmentne disperzije (masterbatch) prema bilo kojem od zahtjeva 1 do 3, gdje polimerni nosač ima veći MFI indeks od termoplastičnog polimera u koji se masterbatch mora dodati.
5. Teško zapaljive pigmentne disperzije (masterbatch) prema zahtjevu 4, gdje se polimerni nosač izabire između linearnih polietilena niske gustoće, polietilena niske gustoće ili polietilena visoke gustoće, polipropilena, kopolimera polipropilena i etilen vinil acetata.
6. Teško zapaljive pigmentne disperzije (masterbatch) prema bilo kojem od zahtjeva 1 do 5, gdje je termoplastični polimer polietilen visoke gustoće.
7. Postupak proizvodnje teško zapaljivog masterbatch-a prema bilo kojem od zahtjeva 1 do 6, koji obuhvaća sljedeće faze:
- prethodno miješanje ugljikovih nanocijevi i polimernog nosača u obliku praška u mješalici, s brzinom rotacije lopatica ne većom od 500 rpm;
- dodavanje, toj prethodnoj smjesi, barem druge komponente koja se sastoji od spoja izabranog između filosilikata, silikata s trodimenzionalnom kristalnom strukturom, kalcijevog karbonata, cink borata, cink stanata ili melamin cijanurata ili mješavine dva ili više od ovih spojeva, i miješanje, u početku s brzinom rotacije lopatica ne većom od 500 rpm i zatim s brzinom rotacije lopatica između 1000 i 1250 rpm, uz istovremeno zagrijavanje smjese do temperature između 40 i ;
- punjenje tako dobivene još uvijek vruće smjese u ko-rotirajući dvovijčani ekstruder ili gnječilicu s rotirajućom i oscilirajućom osi i zonom degaziranja, termalni profil se povećava iz zone punjenja smjese prema izlazu, tako da je izlazna temperatura ekstrudata ili protusnutog materijala između oko 190 i , kao funkcija tališta polimernog nosača;
- rezanje smjese na vrhu ekstrudera ili gnječilice, čime se dobivaju pigmentne disperzije (masterbatch) u obliku cilindričnih, disku sličnih ili okruglih granula željenih dimenzija.
8. Postupak prema zahtjevu 7, gdje polimerni nosač koji se koristi u fazi prethodnoh miješanja ima granulometriju između 200 i .
9. Postupak prema bilo kojem od zahtjeva 7 ili 8, gdje se druga komponenta koristi u obliku praška granulometrije između 1 i .
10. Postupak prema bilo kojem od zahtjeva 7 do 9, gdje se ugljikove nanocijevi i druga komponenta koriste naizmjence u obliku masterbatch-a.
11. Uporaba masterbatch-a prema bilo kojem od zahtjeva 1 do 6 za proizvodnju serije termoplastičnog polimera, gdje se tijekom proizvodnje taj masterbatch dodaje polimeru u takvoj količini da čini između oko 10% i oko 40% težine ukupne smjese.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IT2010/000147 WO2011125078A1 (en) | 2010-04-08 | 2010-04-08 | Flame retardant masterbatch for thermoplastic polymers and process for its production |
| PCT/IT2010/000175 WO2011132208A1 (en) | 2010-04-23 | 2010-04-23 | Flame retardant masterbatch for thermoplastic polymers and process for its production |
| PCT/IT2010/000390 WO2012032550A1 (en) | 2010-09-10 | 2010-09-10 | Flame retardant masterbatch for thermoplastic polymers and process for its production |
| PCT/EP2011/055345 WO2011124606A1 (en) | 2010-04-08 | 2011-04-06 | Flame retardant masterbatch for thermoplastic polymers and process for its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20130268T1 true HRP20130268T1 (hr) | 2013-05-31 |
Family
ID=44323042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20130268AT HRP20130268T1 (hr) | 2010-04-08 | 2013-03-25 | Teško zapaljive pigmentne disperzije (masterbatch) za termoplastiäśne polimere i postupak njihove proizvodnje |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2417187B1 (hr) |
| ES (1) | ES2402984T3 (hr) |
| HR (1) | HRP20130268T1 (hr) |
| PT (1) | PT2417187E (hr) |
| WO (1) | WO2011124606A1 (hr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103724786A (zh) * | 2013-12-12 | 2014-04-16 | 扬州大学 | 无卤膨胀阻燃eva专用料及其制备方法 |
| CN110669259B (zh) * | 2019-10-18 | 2021-08-03 | 广东联塑科技实业有限公司 | 一种高效阻燃抑烟环保双功能助剂及由其制备的pvc-u材料 |
| CN112175300A (zh) * | 2020-09-14 | 2021-01-05 | 金发科技股份有限公司 | 一种碳纳米管母粒及其制备方法与应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003064536A1 (fr) | 2002-01-30 | 2003-08-07 | Idemitsu Petrochemical Co., Ltd. | Composition de resine thermoplastique, composition de resine de polycarbonate, et article moule les comprenant |
| US7223811B2 (en) | 2002-03-20 | 2007-05-29 | Facultes Universitaires Notre-Dame De La Paix | Nanocomposite: products, process for obtaining them and uses thereof |
| US20070096083A1 (en) | 2005-10-27 | 2007-05-03 | Intel Corporation | Substrate core polymer nanocomposite with nanoparticles and randomly oriented nanotubes and method |
| ES2394219T3 (es) | 2005-10-28 | 2013-01-23 | Nanocyl S.A. | Composición resistente al fuego |
-
2011
- 2011-04-06 ES ES11717516T patent/ES2402984T3/es active Active
- 2011-04-06 WO PCT/EP2011/055345 patent/WO2011124606A1/en active Application Filing
- 2011-04-06 EP EP11717516A patent/EP2417187B1/en not_active Not-in-force
- 2011-04-06 PT PT117175166T patent/PT2417187E/pt unknown
-
2013
- 2013-03-25 HR HRP20130268AT patent/HRP20130268T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PT2417187E (pt) | 2013-04-30 |
| WO2011124606A1 (en) | 2011-10-13 |
| EP2417187A1 (en) | 2012-02-15 |
| EP2417187B1 (en) | 2013-01-16 |
| ES2402984T3 (es) | 2013-05-13 |
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