GB998107A - Improvements in or relating to liquid liquid chromatography - Google Patents

Improvements in or relating to liquid liquid chromatography

Info

Publication number
GB998107A
GB998107A GB3124662A GB3124662A GB998107A GB 998107 A GB998107 A GB 998107A GB 3124662 A GB3124662 A GB 3124662A GB 3124662 A GB3124662 A GB 3124662A GB 998107 A GB998107 A GB 998107A
Authority
GB
United Kingdom
Prior art keywords
wire
solvent
detector
argon
eluate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3124662A
Inventor
Raymond Peter William Scott
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pye Electronic Products Ltd
Original Assignee
Pye Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US98230A priority Critical patent/US3128619A/en
Application filed by Pye Ltd filed Critical Pye Ltd
Priority to GB3124662A priority patent/GB998107A/en
Priority to US302272A priority patent/US3292420A/en
Priority to DE19631498946 priority patent/DE1498946A1/en
Priority to CH248664A priority patent/CH429237A/en
Priority to FR967489A priority patent/FR1386791A/en
Priority to CH441864A priority patent/CH411397A/en
Priority to FR969878A priority patent/FR1399650A/en
Priority to DE19641498952 priority patent/DE1498952A1/en
Priority to GB1481364A priority patent/GB1058167A/en
Publication of GB998107A publication Critical patent/GB998107A/en
Expired legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
    • G01N35/00009—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor provided with a sample supporting tape, e.g. with absorbent zones
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/62—Detectors specially adapted therefor
    • G01N30/64—Electrical detectors
    • G01N30/66—Thermal conductivity detectors
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/62—Detectors specially adapted therefor
    • G01N30/64—Electrical detectors
    • G01N30/68—Flame ionisation detectors
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/80—Fraction collectors
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/84—Preparation of the fraction to be distributed
    • G01N2030/8411—Intermediate storage of effluent, including condensation on surface
    • G01N2030/8417—Intermediate storage of effluent, including condensation on surface the store moving as a whole, e.g. moving wire

Abstract

998,107. Partition chromatography detection systems. PYE Ltd. Aug. 7, 1963 [Aug. 15, 1962], No. 31246/62. Heading B1X. A liquid-liquid chromatographic apparatus comprises a solid body adapted to carry away as a surface film, a sample of the effluent from the chromatographic column first past means to vaporize the solvent, and then past a heater to pyrolize the soulte, and means to pass the pyrolysis products to a detector. In a specific embodiment, Fig. 1, glass tube 1 has inlet 2 for argon, and outlets 3 and 4, the outlet 4 being to a flame ionization or argon detector. A portion of the eluate from column 5 is deposited on wire 7, e.g. an iron wire coated with glass fibres, the wire being passed from feed spool 8 to take-up spool 9. H.F. heater coils 10 and 11 remove the solvent and pyrolyse the solute, respectively. The solvent vapour is carried away through 3 while the pyrolysis products pass through 4 to the detector. In a modification, Fig. 2 (not shown), a wire, e.g. of Pt on the end of a dipper, is dipped into the eluate and then raised through two heating zones in a vertical tube. The first heating zone volatilizes the solvent while the second pyrolyses the solute. A flow of argon entering the tube between the two heating zones causes the solvent vapour to be swept downwards whilst the pyrolysis products are swept upwards to an argon detector. The Provisional Specification describes the use of a band in place of the wire and a flame to clean the wire before receiving the portion of eluate. The pyrolysis of the solute takes place in the ionization chamber. Specification 921,215 is referred to.
GB3124662A 1961-03-24 1962-08-15 Improvements in or relating to liquid liquid chromatography Expired GB998107A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US98230A US3128619A (en) 1961-03-24 1961-03-24 Method of and apparatus for monitoring for flowing stream content
GB3124662A GB998107A (en) 1962-08-15 1962-08-15 Improvements in or relating to liquid liquid chromatography
US302272A US3292420A (en) 1962-08-15 1963-08-15 Liquid chromatography
DE19631498946 DE1498946A1 (en) 1962-08-15 1963-08-16 Device for liquid-liquid chromatography
CH248664A CH429237A (en) 1962-08-15 1964-02-28 Method and apparatus for analyzing the eluate supplied by a column for liquid-liquid chromatography
FR967489A FR1386791A (en) 1962-08-15 1964-03-16 Improvements to liquid / liquid chromatography
CH441864A CH411397A (en) 1962-08-15 1964-04-03 Method for the continuous monitoring of the content of a stream of carrier liquid in foreign substances and device for carrying out this method
FR969878A FR1399650A (en) 1962-08-15 1964-04-06 Improvements in devices for monitoring the content of a carrier liquid stream
DE19641498952 DE1498952A1 (en) 1962-08-15 1964-04-08 Method for checking a fluid flow and device for carrying out the method
GB1481364A GB1058167A (en) 1962-08-15 1964-04-09 Method of and apparatus for monitoring for flowing stream content

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3124662A GB998107A (en) 1962-08-15 1962-08-15 Improvements in or relating to liquid liquid chromatography

Publications (1)

Publication Number Publication Date
GB998107A true GB998107A (en) 1965-07-14

Family

ID=10320238

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3124662A Expired GB998107A (en) 1961-03-24 1962-08-15 Improvements in or relating to liquid liquid chromatography

Country Status (1)

Country Link
GB (1) GB998107A (en)

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