GB992258A - Polymeric stoving lacquers - Google Patents

Polymeric stoving lacquers

Info

Publication number
GB992258A
GB992258A GB531662A GB531662A GB992258A GB 992258 A GB992258 A GB 992258A GB 531662 A GB531662 A GB 531662A GB 531662 A GB531662 A GB 531662A GB 992258 A GB992258 A GB 992258A
Authority
GB
United Kingdom
Prior art keywords
acrylate
hydroxypropyl
maleate
ethylene glycol
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB531662A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beck Koller and Company England Ltd
Original Assignee
Beck Koller and Company England Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beck Koller and Company England Ltd filed Critical Beck Koller and Company England Ltd
Publication of GB992258A publication Critical patent/GB992258A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D135/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D135/02—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)

Abstract

Stoving lacquers free from strongly basic catalysts have as binders, mixtures of polychlorides and of copolymers derived from a ,b -ethylenically unsaturated mono- or di-carboxylic acids, monomers containing the group <FORM:0992258/C3/1> in which R is alkyl or aralkyl and contains one aliphatic hydroxyl group, and other ethylenically unsaturated monomers. The mixtures preferably also contain etherified aminoplasts. Suitable hydroxyesters are 2-hydroxyethyl acrylate, 2 - hydroxypropyl acrylate, 3 - hydroxybutyl acrylate, 6-hydroxyhexyl acrylate, and corresponding methacrylates, ethacrylates or phenylacrylates; 2-hydroxyethyl ethyl maleate, 2 - hydroxypropyl ethyl maleate, 2 - hydroxypropyl butyl maleate, di-(2-hydroxypropyl)maleate or fumarate; 2-hydroxy-3-chloropropyl acrylate, 2-hydroxy-1-phenylethyl acrylate, 2-hydroxy-3-butoxypropyl acrylate, and corresponding ethyl acrylates and a -phenyl acrylates. a ,b -unsaturated acids mentioned are acrylic, methacrylic, maleic, fumaric, and half-esters or similar derivatives thereof. Copolymerizable monomers mentioned are styrene, a -methyl styrene, nuclear substituted styrenes, vinyl chloride, vinyl acetate, esters and nitrogen-containing derivatives of acrylic or methacrylic acid. Suitable polyepoxides are listed. Mono- and di-epoxy compounds may also be added to reduce viscosity. In examples the polyepoxide used is produced from epichlorohydrin and 4,41-dihydroxydiphenyl dimethyl methane. In Example (1). Ethyl acrylate, styrene, methacrylic acid and 2-hydroxypropyl methacrylate are polymerized with cumene hydroperoxide in xylol, butanol, ethylene glycol monoethyl ether and lauryl mercaptan. The epoxy resin and butylated melamine-formaldehyde resin are added. (2). Methacrylic acid, 2-hydroxypropyl methacrylate, 2-ethylhexyl acrylate and methyl methacrylate are copolymerized with cumyl hydroperoxide in xylol, butanol, ethylene glycol monoethyl ether and lauryl mercaptan, and epoxide resin and butylated melamineformaldehyde resin are added. (3). Methacrylic acid, 2-hydroxypropyl butyl maleate, methyl methacrylate and ethyl acrylate are copolymerized with p-tert.-butyl hydroperoxide in xylol, and butanol, ethylene glycol monoethyl ether, butylated melamine-formaldehyde resin, ethylene glycol and epoxy resin are added. (4). Acrylic acid, 2-hydroxypropyl acrylate, methyl methacrylate, and 2-ethylhexyl acrylate are co-polymerized with benzoyl peroxide in xylol, butanol, and ethylene glycol monoethyl ether, and epoxy resin and butylated melamineformaldehyde resin are added. (5) is similar to (4). but the co-polymer is formed from 2-hydroxypropylmethacrylate monobutyl maleate, methyl methacrylate, 2 - ethylhexyl acrylate and methacrylamide.
GB531662A 1961-03-10 1962-02-12 Polymeric stoving lacquers Expired GB992258A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DER29852A DE1162016B (en) 1961-03-10 1961-03-10 Stoving enamels based on combinations made up of resinous epoxy compounds and copolymers of ª ‡, ª ‰ -unsaturated carboxylic acids with other unsaturated polymerizable monomers

Publications (1)

Publication Number Publication Date
GB992258A true GB992258A (en) 1965-05-19

Family

ID=7403131

Family Applications (1)

Application Number Title Priority Date Filing Date
GB531662A Expired GB992258A (en) 1961-03-10 1962-02-12 Polymeric stoving lacquers

Country Status (4)

Country Link
AT (1) AT258436B (en)
CH (1) CH394447A (en)
DE (1) DE1162016B (en)
GB (1) GB992258A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3545893A1 (en) * 1985-12-23 1987-06-25 Synthopol Chemie Dr Koch Binder mixture, process for its preparation, and its use

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2737984A1 (en) * 1977-08-23 1979-03-08 Lentia Gmbh PROCESS FOR THE PRODUCTION OF STORAGE-STABLE AND YELLOW-FREE STOVE-IN LACQUER RESINS

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB730869A (en) * 1952-03-20 1955-06-01 Canadian Ind 1954 Ltd Improvements in and relating to thermoset styrene ªÏ-polymers
GB731946A (en) * 1952-08-21 1955-06-15 Canadian Ind 1954 Ltd Improvements in and relating to thermoset styrene polymers
GB777769A (en) * 1954-11-02 1957-06-26 Canadian Ind Coating compositions
DE1066685B (en) * 1957-05-01 1959-10-08 Canadian Industries Limited, Montreal (Kanada) Burn-in paint for metals

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3545893A1 (en) * 1985-12-23 1987-06-25 Synthopol Chemie Dr Koch Binder mixture, process for its preparation, and its use

Also Published As

Publication number Publication date
CH394447A (en) 1965-06-30
AT258436B (en) 1967-11-27
DE1162016B (en) 1964-01-30

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