GB991028A - Coating compositions - Google Patents
Coating compositionsInfo
- Publication number
- GB991028A GB991028A GB5861/62A GB586162A GB991028A GB 991028 A GB991028 A GB 991028A GB 5861/62 A GB5861/62 A GB 5861/62A GB 586162 A GB586162 A GB 586162A GB 991028 A GB991028 A GB 991028A
- Authority
- GB
- United Kingdom
- Prior art keywords
- styrene
- copolymer
- methyl methacrylate
- interpolymer
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
- C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/28—Condensation with aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Heat hardenable resin compositions comprise a copolymer of the ester reaction product of a resinous polyhydric alcohol and a drying oil or drying oil fatty acids and 5 to 45% by weight of the copolymer of copolymerizable ethylenically unsaturated monomer comprising a major proportion of methyl methacrylate, and an interpolymer of a carboxylic acid amide containing a CH2=C< group with at least one other ethylenically unsaturated monomer, the interpolymer having amido hydrogen atoms replaced by -ROR1, where R is a saturated C1-8 aliphatic hydrocarbon group having its free valencies on a single carbon atom and R1 is H or C1-8 alkyl. The copolymer may be derived from ester reaction products of linseed, coconut, cottonseed, dehydrated castor, tall, fish or soyabean oils or the acids therefrom and alkyds derived from dicarboxylic acids and alcohols containing at least three hydroxyl groups, e.g. glycerol or pentaerythritol, or copolymers of allyl or methallyl alcohol with styrene, halo or alkyl substituted styrenes or methyl methacrylate. Specified comonomers which may be used in minor proportions are styrene and substituted styrenes, and acrylic and methacrylic esters. The interpolymer may be derived from acrylamide, methacrylamide or itaconic acid diamide and styrene or substituted styrenes, acrylic or methacrylic esters, maleic anhydride, monoesters or diesters or olefins. The interpolymer is modified with an aldehyde, preferably formaldehyde and optionally etherified, e.g. with butanol. In examples, acrylamide is interpolymerized with (1 and 4) styrene and ethyl acrylate, (3) styrene, ethyl acrylate and methyl methacrylate, (5) ethyl acrylate, methyl methacrylate and 2-ethylhexyl acrylate, (6) vinyl toluene and ethyl acrylate and (7) styrene, methyl acrylate and 2-ethylhexyl acrylate, and the interpolymers reacted with formaldehyde in the presence of butanol; glycerol and phthalic acid are reacted with (12) dehydrated castor oil and (18) cottonseed oil, coconut oil and dehydrated castor oil fatty acids, and the products copolymerized with (13) methyl methacrylate and styrene and (16) methyl methacrylate; a styrene-allyl alcohol copolymer is reacted with (19) dehydrated castor oil and the product copolymerized with methyl methacrylate and styrene. The interpolymers and copolymers are admixed with conventional ingredients, e.g. titanium dioxide, talc, silica, solvents such as xylene and butanol and butylated melamine-formaldehyde resins to form enamels.ALSO:Metal substrates, e.g. steel and aluminium, may be coated with heat hardenable resin compositions comprising a copolymer of the ester reaction product of a resinous polyhydric alcohol and a drying oil or fatty acids therefrom and 5-45% by weight of the copolymer of ethylenically unsaturated monomer comprising a major proportion of methyl methacrylate, and an interpolymer of a carboxylic acid amide containing a CH2=C ? group with at least one copolymerizable monomer, said interpolymer having amido hydrogen atoms replaced by -ROR1 where R is a saturated aliphatic hydrocarbon group having its free valencies on a single carbon atom and R1 is H or C1-8 alkyl. The ester reaction product may be derived from a hydroxy polyester or allyl alcohol copolymer and linseed, coconut, cotton-seed, dehydrated castor, tall, fish or soya bean oil or acids therefrom. In examples aluminium strips are coated with high gloss enamels comprising (14) the copolymer of methyl methacrylate and styrene with an ester reaction product of glycerol, phthalic anhydride and dehydrated castor oil, a butylated formaldehyde modified interpolymer of acrylamide, styrene and ethyl acrylate, titanium dioxide and xylene, optionally together with (20) a butanol/xylene solution of a butylated melamine/formaldehyde resin; and a low gloss enamel comprising (15) the above copolymer and interpolymer, a styrene/allyl alcohol copolymer, xylene, talc, titanium dioxide and silica.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8966761A | 1961-02-16 | 1961-02-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB991028A true GB991028A (en) | 1965-05-05 |
Family
ID=22218933
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5861/62A Expired GB991028A (en) | 1961-02-16 | 1962-02-15 | Coating compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB991028A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112759748A (en) * | 2020-12-30 | 2021-05-07 | 长兴化学(天津)有限公司 | Nano titanium dioxide modified alkyd resin and preparation method and application thereof |
-
1962
- 1962-02-15 GB GB5861/62A patent/GB991028A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112759748A (en) * | 2020-12-30 | 2021-05-07 | 长兴化学(天津)有限公司 | Nano titanium dioxide modified alkyd resin and preparation method and application thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1009217A (en) | Vinyl addition polymers and their preparation | |
GB1084203A (en) | ||
DE3060063D1 (en) | Paper coating compositions | |
DE59405136D1 (en) | Aqueous dispersions of acrylic copolymers | |
GB1249390A (en) | Copolymers of vinylesters | |
ES466866A1 (en) | Air-drying acrylate lacquer binders | |
GB793776A (en) | Esters of drying oil acids with certain vinyl polymers | |
GB1264232A (en) | ||
GB991028A (en) | Coating compositions | |
GB1145564A (en) | A process for the production of thermoplastic copolymers | |
GB958856A (en) | Copolymers | |
GB1173081A (en) | Composition Capable of Forming a Floor Polish and Floor Polish Formed therefrom | |
GB838656A (en) | Production of resinous compositions | |
GB556113A (en) | Interpolymers of vinyl esters | |
GB916282A (en) | Terpolymers and production thereof | |
GB1048060A (en) | Addition copolymers and water dilutable salts thereof | |
GB1257919A (en) | ||
JPS5566940A (en) | Aqueous coating composition | |
GB597218A (en) | Improvements in or relating to resinous electrically insulating compositions and to electrical apparatus impregnated therewith | |
GB1117126A (en) | Preparation of resins for use in water-thinnable compositions | |
GB869145A (en) | Modified resins | |
GB944629A (en) | Improvements in or relating to unsaturated polyesters | |
GB1199620A (en) | Copolymers and the production of Coatings therefrom | |
GB1041425A (en) | Polymeric vehicles for coating compositions | |
GB1161819A (en) | Electrodeposition of Polymers. |