GB958856A - Copolymers - Google Patents
CopolymersInfo
- Publication number
- GB958856A GB958856A GB2151462A GB2151462A GB958856A GB 958856 A GB958856 A GB 958856A GB 2151462 A GB2151462 A GB 2151462A GB 2151462 A GB2151462 A GB 2151462A GB 958856 A GB958856 A GB 958856A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acrylic
- acid
- methacrylic acid
- vinyl acetate
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Copolymers suitable for use as coating compositions are prepared by polymerizing a mixture comprising (1) one or more esters of acrylic and/or methacrylic acid having 1 to 20 carbon atoms in the alcohol moiety, (2) 1 to 30% by weight, based on the total monomer mixture, of a methylol compound and/or an alkyl ether thereof of acrylic and/or methacrylic acid amide, the alkyl residue of the said ether containing not more than 10 carbon atoms, (3) 0.1 to 10% by weight, based on the total monomer mixture, of a mixed ester of a diol or a monothiodiol esterified with acrylic or methacrylic acid and a di- or polybasic organic or inorganic acid having a pk value of less than 4, and (4) if desired, up to 20% by weight of the total monomer mixture, of one or more monomers copolymerizable with said monomers (1) to (3). Preferably emulsion polymerization in an aqueous phase or solution polymerization in a suitable medium e.g. a ketone, an ester or an aromatic or aliphatic hydrocarbon solvent, is used, and a catalyst such as azodiisobutyric acid nitrile may be used. Lists of glycols and thioglycols from which the mixed esters may be prepared are given and the di- or poly-basic organic and inorganic acids mentioned are orthophosphoric, phosphorous, sulphuric oxalic and phosphinic acids. The polybasic acids may be further esterified e.g. with alkyl or aryl groups. Examples of monomers (4) are acrylic and methacrylic acid, acrylo- and methacrylonitrile, styrene, dibutyl maleate, vinyl acetate and unsaturated polyesters. In the examples copolymers are formed from (1) ethyl acrylate, N-methylolmethacrylamide isobutyl ether, 2-methacryloxy -2- methyl-ethyl-phosphorous acid and vinyl acetate; (2) methylmethacrylate, vinyl acetate, ethyl acrylate, N-methylolmethacrylamide-isobutyl ether and 2-methacryloxy -2-chloromethyl-ethyl phosphorous acid; (3) ethyl acrylate, N-methylol methacrylamide-isobutyl ether, 2-methacryloxyethyl-phosphoric acid monomethyl ester and vinyl acetate; and (4) ethyl acrylate, N-methylolmethacrylamide-isobutyl ether, methacryloxyethyl-phenyl-phosphinic acid and vinyl acetate.ALSO:Coating compositions which may be applied for example to textiles, wood, paper, leather or metals are prepared by polymerizing a mixture comprising (1) one or more esters of acrylic and/or methacrylic acid having 1-20 carbon atoms in the alcohol moiety, (2) 1-30% by weight, based on the total monomer mixture, of a methylol compound and/or an alkyl ether thereof of acrylic and/or methacrylic acid amide, the alkyl residue of the said ether containing not more than 10 carbon atoms, (3) 0,1-10% by weight, based on the total monomer mixture, of a mixed ester of a diol or a monothiodiol esterified with acrylic or methacrylic acid and a di- or polybasic organic or inorganic acid having a pK value of less than 4, and (4) if desired, up to 20% by weight of the total monomer mixture, of one or more monomers copolymerizable with said monomers (1) to (3). Lists of glycols and thioglycols from which the mixed esters may be prepared are given and the di- or polybasic organic and inorganic acids mentioned are orthophosphoric, phosphorous, sulphuric, oxalic and phosphinic acids; the polybasic acids may be further esterified. Lists of monomers (4) are given. In one example nylon fabrics are coated with a copolymer derived from ethyl acrylate, a 45% solution of N-methylol methacrylamide isobutyl ether is iso-butanol, 2-methacryloxy-2-methyl-ethyl-phosphorous acid and vinyl acetate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DER30460A DE1229219B (en) | 1961-06-03 | 1961-06-03 | Firmly adhering, water, detergent and solvent-resistant coating agents that harden at low temperatures through crosslinking |
Publications (1)
Publication Number | Publication Date |
---|---|
GB958856A true GB958856A (en) | 1964-05-27 |
Family
ID=7403304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2151462A Expired GB958856A (en) | 1961-06-03 | 1962-06-04 | Copolymers |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE617606A (en) |
DE (1) | DE1229219B (en) |
GB (1) | GB958856A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4487859A (en) * | 1983-11-21 | 1984-12-11 | Scm Corporation | Self-curing water dispersed polymers |
US5191029A (en) * | 1988-12-29 | 1993-03-02 | Deldonno Theodore A | Phosphorus-containing polymer compositions containing water-soluble polyvalent metal compounds |
US5663224A (en) * | 1991-12-03 | 1997-09-02 | Rohm And Haas Company | Process for preparing an aqueous dispersion |
US6080802A (en) * | 1991-12-03 | 2000-06-27 | Rohm And Haas Company | Process for preparing an aqueous dispersion of composite particles including polymeric latex adsorbed to titanium dioxide |
US6485786B2 (en) | 2000-04-26 | 2002-11-26 | Rohm And Haas Company | Aqueous stain-blocking coating composition |
US6756459B2 (en) | 2000-09-28 | 2004-06-29 | Rohm And Haas Company | Binder compositions for direct-to-metal coatings |
US6818697B2 (en) | 2001-10-01 | 2004-11-16 | Rohm And Haas Company | Coating composition |
WO2010074806A1 (en) * | 2008-12-23 | 2010-07-01 | E. I. Du Pont De Nemours And Company | (meth)acrylic esters of poly(trimethylene ether) glycol and uses thereof |
US9006365B2 (en) | 2010-12-31 | 2015-04-14 | Rohm And Haas Company | Method of making polymeric bead from phosphorous acid containing monomers |
US9493585B2 (en) | 2010-12-31 | 2016-11-15 | Rohm Ad Haas Company | Polymeric bead composition comprising polymerized phosphorous-containing acid monomer |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT342737B (en) * | 1975-10-24 | 1978-04-25 | Vianova Kunstharz Ag | IMPROVING THE LIABILITY OF COATING AGENTS ON METAL SUBSTRATES |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE539963A (en) * | 1954-07-23 | |||
BE590585A (en) * | 1959-05-08 | 1960-11-07 | Canadian Ind | Coating compositions |
-
0
- BE BE617606D patent/BE617606A/xx unknown
-
1961
- 1961-06-03 DE DER30460A patent/DE1229219B/en active Pending
-
1962
- 1962-06-04 GB GB2151462A patent/GB958856A/en not_active Expired
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4487859A (en) * | 1983-11-21 | 1984-12-11 | Scm Corporation | Self-curing water dispersed polymers |
US5191029A (en) * | 1988-12-29 | 1993-03-02 | Deldonno Theodore A | Phosphorus-containing polymer compositions containing water-soluble polyvalent metal compounds |
US5663224A (en) * | 1991-12-03 | 1997-09-02 | Rohm And Haas Company | Process for preparing an aqueous dispersion |
US6080802A (en) * | 1991-12-03 | 2000-06-27 | Rohm And Haas Company | Process for preparing an aqueous dispersion of composite particles including polymeric latex adsorbed to titanium dioxide |
US6485786B2 (en) | 2000-04-26 | 2002-11-26 | Rohm And Haas Company | Aqueous stain-blocking coating composition |
US6756459B2 (en) | 2000-09-28 | 2004-06-29 | Rohm And Haas Company | Binder compositions for direct-to-metal coatings |
US6818697B2 (en) | 2001-10-01 | 2004-11-16 | Rohm And Haas Company | Coating composition |
WO2010074806A1 (en) * | 2008-12-23 | 2010-07-01 | E. I. Du Pont De Nemours And Company | (meth)acrylic esters of poly(trimethylene ether) glycol and uses thereof |
US8198360B2 (en) | 2008-12-23 | 2012-06-12 | E I Du Pont De Nemours And Company | (Meth)acrylic esters of poly(trimethylene ether) glycol and uses thereof |
US9006365B2 (en) | 2010-12-31 | 2015-04-14 | Rohm And Haas Company | Method of making polymeric bead from phosphorous acid containing monomers |
US9493585B2 (en) | 2010-12-31 | 2016-11-15 | Rohm Ad Haas Company | Polymeric bead composition comprising polymerized phosphorous-containing acid monomer |
Also Published As
Publication number | Publication date |
---|---|
BE617606A (en) | |
DE1229219B (en) | 1966-11-24 |
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