GB1145564A - A process for the production of thermoplastic copolymers - Google Patents
A process for the production of thermoplastic copolymersInfo
- Publication number
- GB1145564A GB1145564A GB1212266A GB1212266A GB1145564A GB 1145564 A GB1145564 A GB 1145564A GB 1212266 A GB1212266 A GB 1212266A GB 1212266 A GB1212266 A GB 1212266A GB 1145564 A GB1145564 A GB 1145564A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- ester
- weight
- copolymers
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
Abstract
1,145,564. Preparation of thermoplastic copolymers. BECK KOLLER & CO., (ENGLAND), Ltd. 18 March, 1966 [3 July, 1965], No. 12122/66. Heading C3P. Thermoplastic copolymers are prepared by polymerizing in an organic solvent in the presence of a polymerization initiator a monomer mixture comprising (a) 10-50% by weight of a vinyl ester of the formula where R 3 and R 4 each represents H, methyl, ethyl, propyl, butyl or phenyl and n is an integer from 1 to 17 (with the provision that the viynl ester does not contain more than 91 carbon atoms), (b) 0-6% by weight of an α,#-ethylenically unsaturated mono-, di- and/or polycarboxylic acid or a partial ester of such a di- or poly-basic acid with a C 1 -C 8 alkanol, (c) 20-50% by weight of methyl methacrylate, (d) 20-50% by weight of a C 4 -C 18 -alkyl acrylate and (e) 5-20% by weight of a hydroxyalkyl or hydroxyaralkyl ester of an α,#-ethylenically unsaturated carboxylic acid. Component (b) may be acrylic, methacrylic, ethacrylic, α-phenylacrylic, maleic, fumaric, itaconic, citraconio or crotonic acid or an appropriate mono-ester of an aforementioned dicarboxylic acid. Component (e) may also be derived from an aforementioned acid. The vinyl ester (a) is preferably an ester of Versatic acid-911 (the word "Versatic" is a registered Trade Mark). Polymerization solvents specified are xylene, toluene, butanol, ketones, glycol esters and glycol ethers. Polymerization initiators specified are benzoyl peroxide, di-t-butyl peroxide, tbutyl hydroperoxide, cumene hydroperoxide and azodiisobutyronitrile. A chain transfer agent may also be present, e.g. butyl or lauryl mercaptan or thioglycolic acid. The copolymers can be used to form coatings on various substrates, particularly when in combination with a condensation resin; the coatings can be stored by heating to 100-200‹ C. (Compositions containing such copolymers in combination with aminoplast resins form the invention of Specification 1,087,623).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1965R0041010 DE1289936B (en) | 1965-07-03 | 1965-07-03 | Heat-curable coating agents based on organic solvents, thermoplastic copolymers containing hydroxyl groups and amino resins |
DER0041011 | 1965-07-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1145564A true GB1145564A (en) | 1969-03-19 |
Family
ID=25991906
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1212266A Expired GB1145564A (en) | 1965-07-03 | 1966-03-18 | A process for the production of thermoplastic copolymers |
GB1494166A Expired GB1087623A (en) | 1965-07-03 | 1966-04-04 | Thermosetting coating compositions |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1494166A Expired GB1087623A (en) | 1965-07-03 | 1966-04-04 | Thermosetting coating compositions |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH493611A (en) |
DE (2) | DE1595243C3 (en) |
GB (2) | GB1145564A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0462677A2 (en) * | 1990-06-20 | 1991-12-27 | Shell Internationale Researchmaatschappij B.V. | Interpolymer dispersions from vinyl esters of branched chain carboxylic acids and ethylenically unsaturated acids and/or their esters |
EP0546640A1 (en) * | 1991-12-13 | 1993-06-16 | Shell Internationale Researchmaatschappij B.V. | Interpolymer-based binders |
EP0573037A1 (en) * | 1992-06-05 | 1993-12-08 | Wacker-Chemie GmbH | Coating agent for coating aluminium |
US5288828A (en) * | 1993-03-08 | 1994-02-22 | The Sherwin-Williams Company | Dispersant polymers |
US5342878A (en) * | 1991-12-30 | 1994-08-30 | Ppg Industries, Inc. | Base neutralized, stable, aqueous dispersion of a hydroxyl functional acrylic polymer and coating compositions prepared therefrom |
US5464897A (en) * | 1991-12-30 | 1995-11-07 | Ppg Industries, Inc. | Aqueous fluoropolymer dispersions |
EP0432811B1 (en) * | 1989-11-06 | 1996-03-13 | Shell Internationale Researchmaatschappij B.V. | Interpolymer latices from esters of (meth)acrylic acid and vinyl esters of branched chain carboxylic acids |
US5641829A (en) * | 1991-12-30 | 1997-06-24 | Ppg Industries, Inc. | Coating compositions prepared from base neutralized, stable aqueous dispersion of hydroxyl functional acrylic polymers |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1249390A (en) * | 1969-07-03 | 1971-10-13 | Shell Int Research | Copolymers of vinylesters |
US4164488A (en) | 1974-03-29 | 1979-08-14 | E. I. Du Pont De Nemours And Company | Aqueous thermosetting acrylic enamel |
CN1283205A (en) * | 1997-12-24 | 2001-02-07 | 国际壳牌研究有限公司 | Copolymers of ethylenically unsaturated monomers to be used in powder coatings |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2681897A (en) * | 1950-10-06 | 1954-06-22 | American Cyanamid Co | Surface coating compositions comprising aminoplast resins and a thermoplastic copolymer containing a polymerized hydroxy alkyl ester of an alpha, beta ethylenically unsaturated carboxylic acid |
-
1965
- 1965-07-03 DE DE19651595243 patent/DE1595243C3/en not_active Expired
- 1965-07-03 DE DE1965R0041010 patent/DE1289936B/en active Pending
- 1965-12-31 CH CH1814565A patent/CH493611A/en not_active IP Right Cessation
-
1966
- 1966-03-18 GB GB1212266A patent/GB1145564A/en not_active Expired
- 1966-04-04 GB GB1494166A patent/GB1087623A/en not_active Expired
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0432811B1 (en) * | 1989-11-06 | 1996-03-13 | Shell Internationale Researchmaatschappij B.V. | Interpolymer latices from esters of (meth)acrylic acid and vinyl esters of branched chain carboxylic acids |
EP0462677A3 (en) * | 1990-06-20 | 1992-10-21 | Shell Internationale Research Maatschappij B.V. | Interpolymer dispersions from vinyl esters of branched chain carboxylic acids and ethylenically unsaturated acids and/or their esters |
EP0462677A2 (en) * | 1990-06-20 | 1991-12-27 | Shell Internationale Researchmaatschappij B.V. | Interpolymer dispersions from vinyl esters of branched chain carboxylic acids and ethylenically unsaturated acids and/or their esters |
EP0546640A1 (en) * | 1991-12-13 | 1993-06-16 | Shell Internationale Researchmaatschappij B.V. | Interpolymer-based binders |
US5464897A (en) * | 1991-12-30 | 1995-11-07 | Ppg Industries, Inc. | Aqueous fluoropolymer dispersions |
US5641829A (en) * | 1991-12-30 | 1997-06-24 | Ppg Industries, Inc. | Coating compositions prepared from base neutralized, stable aqueous dispersion of hydroxyl functional acrylic polymers |
US5342878A (en) * | 1991-12-30 | 1994-08-30 | Ppg Industries, Inc. | Base neutralized, stable, aqueous dispersion of a hydroxyl functional acrylic polymer and coating compositions prepared therefrom |
EP0573037A1 (en) * | 1992-06-05 | 1993-12-08 | Wacker-Chemie GmbH | Coating agent for coating aluminium |
US5525656A (en) * | 1992-06-05 | 1996-06-11 | Wacker Chemie Gmbh | Coating agents for coating aluminum |
US5430089A (en) * | 1993-03-08 | 1995-07-04 | The Sherwin-Williams Company | Dispersant polymers |
US5360856A (en) * | 1993-03-08 | 1994-11-01 | The Sherwin-Williams Company | Dispersant polymers |
US5554682A (en) * | 1993-03-08 | 1996-09-10 | The Sherwin-Williams Company | Dispersant polymers |
US5288828A (en) * | 1993-03-08 | 1994-02-22 | The Sherwin-Williams Company | Dispersant polymers |
Also Published As
Publication number | Publication date |
---|---|
DE1595243C3 (en) | 1974-01-31 |
CH493611A (en) | 1970-07-15 |
DE1595243A1 (en) | 1970-01-02 |
GB1087623A (en) | 1967-10-18 |
DE1289936B (en) | 1969-02-27 |
DE1595243B2 (en) | 1973-06-28 |
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