GB981275A - Method of, and apparatus for, obtaining pure hydrogen from gas mixtures - Google Patents
Method of, and apparatus for, obtaining pure hydrogen from gas mixturesInfo
- Publication number
- GB981275A GB981275A GB36152/61A GB3615261A GB981275A GB 981275 A GB981275 A GB 981275A GB 36152/61 A GB36152/61 A GB 36152/61A GB 3615261 A GB3615261 A GB 3615261A GB 981275 A GB981275 A GB 981275A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen
- mixture
- gas
- pressure
- produced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
- C01B2203/041—In-situ membrane purification during hydrogen production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Pure hydrogen is separated from hydrogen-containing gas mixtures, which are produced at high temperatures from hydrogen-containing compounds in a process characterized in that at least a considerable part of the heat contained in the gas mixture is utilized to pass the mixture at an elevated temperature through a foil of a metal of the platinum group. If the dissociated gas is produced for example by the catalytic decomposition of ammonia at temperatures of 600-900 DEG C. the dissociated gas is passed directly in a hot condition to the hydrogen-pervious separating wall which seals off the space for receiving the diffused pure gas. Hydrocarbons and alcohols can be decomposed by heating with coated vapour and the carbon monoxide thus produced further reacted with water vapour to produce carbon dioxide and additional hydrogen. The mixture of carbon dioxide, water vapour and hydrogen then produced is subjected to preliminary purification at low temperatures characterized in that, a heat exchanger is connected in line ahead of the equipment for absorbing or precipitating the readily removable constituents of the gas, i.e. carbon dioxide and water vapour respectively, in which the mixture flowing from the decomposition chamber transfers a considerable part of its heat content to the mixture passing in the cooled condition from the purification equipment, which latter mixture is heated to an elevated temperature and thereby passed to the diffusion cill. The diffusion of hydrogen is accelerated by a difference in pressure between the inlet and receiving compartments. If the hydrogen compound which is split up to produce hydrogen is delivered in pressure chambers, the pressure stored therein can be utilized to provide the pressure in the dissociation chamber and the inlet chamber of the diffusion cill. If liquid hydrocarbons are converted into hydrogen-containing mixtures, the evaporation process to which the initial material is subjected can be utilized to generate pressure in the plant.ALSO:Pure hydrogen is separated from hydrogen-containing gas mixtures, which are produced at high temperature from hydrogen containing components, in a process characterized in that at least a considerable part of the heat contained in the gas mixture is utilized to pass the mixture at an elevated temperature through a foil of a metal of the platinum group. If the dissociated gas is produced for example by the catalytic decomposition of ammonia at temperatures of 600-900 DEG C. the dissociated gas is passed directly in a hot condition to the hydrogen-pervious separating wall which seals off the space for receiving the diffused pure gas. Hydrocarbons and alcohols can be decomposed by heating with water vapour and the carbon monoxide thus produced further reacted with water vapour to produce carbon dioxide and additional hydrogen. The mixture of carbon dioxide, water vapour and hydrogen thus produced is subjected to preliminary purification at low temperatures characterized in that a heat exchanger is connected in line ahead of the equipment for absorbing or precipitating the readily removable constituents of the gas, i.e. carbon dioxide and water vapour respectively, in which the mixture flowing from the decomposition chamber transfers a considerable part of the heat content to the mixture passing, in the cooled condition, from the purification equipment, which latter mixture is heated to an elevated temperature and thereby passed to the diffusion cell. The diffusion of hydrogen is accelerated by a difference in pressure between the inlet and receiving compartments. If the hydrogen compound which is split up to produce hydrogen is delivered in pressure chambers, the pressure stored therein can be utilized to provide the pressure in the dissociation chamber and the inlet chamber of the diffusion cell. If liquid hydrocarbons are converted into hydrogen-containing mixtures, the evaporation process to which the initial material is thereby subjected can be utilized to generate pressure in the plant.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEL0037312 | 1960-10-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB981275A true GB981275A (en) | 1965-01-20 |
Family
ID=7267841
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB36152/61A Expired GB981275A (en) | 1960-10-20 | 1961-10-09 | Method of, and apparatus for, obtaining pure hydrogen from gas mixtures |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1417806A1 (en) |
GB (1) | GB981275A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3450500A (en) * | 1965-08-03 | 1969-06-17 | United Aircraft Corp | Method for catalytically reforming hydrogen-containing carbonaceous feed-stocks by simultaneous abstractions through a membrane selectively permeable to hydrogen |
-
1960
- 1960-10-20 DE DE19601417806 patent/DE1417806A1/en active Pending
-
1961
- 1961-10-09 GB GB36152/61A patent/GB981275A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3450500A (en) * | 1965-08-03 | 1969-06-17 | United Aircraft Corp | Method for catalytically reforming hydrogen-containing carbonaceous feed-stocks by simultaneous abstractions through a membrane selectively permeable to hydrogen |
Also Published As
Publication number | Publication date |
---|---|
DE1417806A1 (en) | 1969-03-13 |
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