GB980980A - Treatment of cellulosic fabrics - Google Patents

Treatment of cellulosic fabrics

Info

Publication number
GB980980A
GB980980A GB44777/62A GB4477762A GB980980A GB 980980 A GB980980 A GB 980980A GB 44777/62 A GB44777/62 A GB 44777/62A GB 4477762 A GB4477762 A GB 4477762A GB 980980 A GB980980 A GB 980980A
Authority
GB
United Kingdom
Prior art keywords
fabric
acid
treatment
aldehyde
gaseous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB44777/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyobo Co Ltd
Original Assignee
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd
Publication of GB980980A publication Critical patent/GB980980A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/54—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur dioxide; with sulfurous acid or its salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D06M13/123—Polyaldehydes; Polyketones

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Cellulosic fabrics are crease proofed by impregnating then with an aqueous liquid containing an aldehyde, or a substance which is capable of liberating an aldehyde, in the absence of an acid catalyst, and then contacting them with gaseous hydrogen choride, sulphur trioxide or sulphur dioxide at a temperature below 50 DEG C. while maintaining the moisture content of the fabric at from 3 to 20% by weight. Suitable aldehydes and aldehyde liberating substances which preferably applied to the fabric in an amount of from 1 to 25% by weight, are formaldehyde, glyoxol, glutaraldehyde, paraformaldehyde, acetal, methylol hydantoin and hexamethylene tetramine. The aqueous liquid may also contain an aldehyde catcher, i.e. a substance capable of holding or retaining the aldehyde during the drying and acid treatment, e.g. polyethyl acrylate, polybutyl acrylate, polyethyl butyl acrylate, polyhydroxy ethyl acrylate, methyl cellulose, ethyl cellulose and hydroxy ethyl cellulose, blueing agents, brightening agents and softeners, e.g. polyethylene, polypropylene and silicon type softeners. After treatment with the aqueous liquid the fabric may be dried at a temperature between room temperature and 120 DEG C. to reduce its moisture content to 3-20% by weight and then treated with an atmosphere containing 1-100% by volume of gaseous hydrogen chloride, sulphur trioxide or sulphur dioxide. The fabric may be contacted with the gaseous acid substance by introduced or by contacting it with a continuously travelling porous belt, e.g. polystyrene sponge sheet, impregnated with hydrochloric acid so that the fabric is contacted with the hydrogen chloride gas developed. The fabric may be contacted with the gaseous acid substance for a few seconds up to 90 minutes and then washed. Alternatively after treatment with the gaseous acid substance the fabric may be left to stand in an acid-free atmosphere at a temperature below 50 DEG C. until the reaction is complete and then washed. The gaseous acid may be mixed with air, nitrogen or moisture. Woven, knitted or non-woven fabrics comprising cotton, linen, hemp, viscose rayon or cuprammonium rayon fibres alone or in admixture with cellulose acetate, polyamide, polyester, polyacrylonitrile, polyolefin, polyvinyl chloride, polyvinylidine chloride or polyvinyl alcohol fibres may be treated. The fabric may be mercerized of alkylated with dimethyl sulphate, diethyl sulphate, butyl chloride, ethyl chloride, butyl bromide, ethyl bromide, ethylene chlorohydrin, ethylenebromohydrin, chloracetic acid, bromoacetic acid or ethylene or propylene oxide in an aqueous medium or in an alcohol or benzene in the presence of an alkali prior, to the treatment. Example 3 refers to the treatment of viscose rayon staple fibres graft copolymerized with ethyl acrylate.
GB44777/62A 1961-11-28 1962-11-27 Treatment of cellulosic fabrics Expired GB980980A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4315861 1961-11-28

Publications (1)

Publication Number Publication Date
GB980980A true GB980980A (en) 1965-01-20

Family

ID=12656039

Family Applications (1)

Application Number Title Priority Date Filing Date
GB44777/62A Expired GB980980A (en) 1961-11-28 1962-11-27 Treatment of cellulosic fabrics

Country Status (4)

Country Link
US (1) US3663974A (en)
DE (1) DE1444129C3 (en)
GB (1) GB980980A (en)
NL (1) NL286002A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3423167A (en) * 1964-12-15 1969-01-21 Fmc Corp Wet state cross-linking of carboxyalkyl cellulose ether modified regenerated cellulose fibers
US3642428A (en) * 1970-04-27 1972-02-15 Cotton Inc Vapor phase resin fixation process for cellulosic material permitting subsequent cure
US3647353A (en) * 1966-08-26 1972-03-07 Triatex International Method and apparatus for processing cellulose-containing textiles with the vapors from an azeotropic liquid comprising an acidic catalyst
US3653805A (en) * 1968-09-24 1972-04-04 Cotton Inc Delayed cure process using formaldehyde vapor to cause creaseproofing
US3660013A (en) * 1969-08-01 1972-05-02 Mc Graw Edison Co Method and apparatus for producing a durable press in garments containing cellulose or cellulosic derivatives
US3703773A (en) * 1970-04-09 1972-11-28 Burlington Industries Inc Gas phase reactor
US4108598A (en) 1976-12-02 1978-08-22 The Strike Corporation Durable press process
FR2384867A1 (en) * 1977-03-21 1978-10-20 Chemiefaser Lenzing Ag CELLULOSE-BASED FIBER, CROSS-LINKED IN A WET ENVIRONMENT, AND ITS MANUFACTURING PROCESS
WO1999010589A1 (en) * 1997-08-22 1999-03-04 Hiroharu Okamoto Moisture-controlled curing durable press process

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH1438269D (en) * 1968-09-24
US3706526A (en) * 1971-12-06 1972-12-19 Cotton Inc Process for treating cellulosic material with formaldehyde and sulfur dioxide
USRE30860E (en) * 1971-12-06 1982-02-02 Cotton, Incorporated Process for treating cellulosic material with formaldehyde in liquid phase and sulfur dioxide
US3884632A (en) * 1973-03-14 1975-05-20 Mc Graw Edison Co Continuous durable-press processing of fabric and garments
US3951595A (en) * 1974-07-10 1976-04-20 Mcgraw-Edison Company Vapor phase process for cellulose fabrics
US4269603A (en) * 1979-05-04 1981-05-26 Riegel Textile Corporation Non-formaldehyde durable press textile treatment
US4269602A (en) * 1979-05-07 1981-05-26 Riegel Textile Corporation Buffered non-formaldehyde durable press textile treatment
US4396390A (en) * 1981-09-04 1983-08-02 Springs Mills, Inc. Aqueous formaldehyde textile finishing process
IL82915A (en) * 1986-06-27 1991-05-12 Buckeye Cellulose Corp Individualized,crosslinked fibers and their production
CA1340299C (en) * 1986-06-27 1999-01-05 Jeffrey Tood Cook Process for marking individualized crosslinked fibers and fibers thereof
US5885303A (en) * 1997-05-13 1999-03-23 American Laundry Machinery Incorporated Durable press/wrinkle-free process
US6511928B2 (en) * 1998-09-30 2003-01-28 The Procter & Gamble Company Rayon fabric with substantial shrink-resistant properties
US6375685B2 (en) 1997-05-13 2002-04-23 The Procter & Gamble Company Textile finishing process
AU7373398A (en) * 1998-05-11 1999-11-29 Procter & Gamble Company, The Durable press/wrinkle-free process
US6565612B2 (en) * 1998-09-30 2003-05-20 The Procter & Gamble Company Shrink resistant rayon fabrics
US7169293B2 (en) * 1999-08-20 2007-01-30 Uop Llc Controllable space velocity reactor and process
AU2001251127A1 (en) * 2000-03-29 2001-10-08 The Procter And Gamble Company Methods for improving fibrillation or pill resistance of fabrics and fabrics with improved properties
AU4963301A (en) * 2000-03-29 2001-10-08 Procter & Gamble Methods for reducing fabric drying time and fabrics with improved properties
WO2001073185A2 (en) * 2000-03-29 2001-10-04 The Procter & Gamble Company Methods for improving brightness of fabrics and fabrics of improved brightness
US20020031970A1 (en) * 2000-03-29 2002-03-14 The Procter & Gamble Company Methods for improving water absorbency of fabrics and fabrics with improved properties
US7169742B2 (en) * 2001-10-18 2007-01-30 The Procter & Gamble Company Process for the manufacture of polycarboxylic acids using phosphorous containing reducing agents
US7008457B2 (en) * 2001-10-18 2006-03-07 Mark Robert Sivik Textile finishing composition and methods for using same
US7018422B2 (en) * 2001-10-18 2006-03-28 Robb Richard Gardner Shrink resistant and wrinkle free textiles
US6989035B2 (en) 2001-10-18 2006-01-24 The Procter & Gamble Company Textile finishing composition and methods for using same
US6841198B2 (en) * 2001-10-18 2005-01-11 Strike Investments, Llc Durable press treatment of fabric
US7144431B2 (en) * 2001-10-18 2006-12-05 The Procter & Gamble Company Textile finishing composition and methods for using same
US20080147026A1 (en) * 2006-12-15 2008-06-19 Jian Qin Absorbent fiber with a low absorbent capacity and slow absorption rate

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB503859A (en) * 1937-10-15 1939-04-17 Henry Dreyfus Improvements relating to the treatment of artificial textile materials
IT381105A (en) * 1939-03-04
US2311080A (en) * 1940-11-08 1943-02-16 Du Pont Textile treatment
US2441859A (en) * 1945-06-12 1948-05-18 Alrose Chemical Company Treatment of textile materials with aldehydes
NL113784C (en) * 1959-01-29
US3046079A (en) * 1960-05-24 1962-07-24 Wilson A Reeves Process of reacting partially swollen cotton textiles with aqueous solutions of specific aldehydes containing acid catalysts to produce wet and dry crease resistance
US3189404A (en) * 1960-10-13 1965-06-15 Toyo Boseki Treatment of cellulosic fibre fabrics
US3154373A (en) * 1962-04-02 1964-10-27 John D Guthrie Process for treating cellulosic textiles with formaldehyde in vapor form

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3423167A (en) * 1964-12-15 1969-01-21 Fmc Corp Wet state cross-linking of carboxyalkyl cellulose ether modified regenerated cellulose fibers
US3647353A (en) * 1966-08-26 1972-03-07 Triatex International Method and apparatus for processing cellulose-containing textiles with the vapors from an azeotropic liquid comprising an acidic catalyst
US3653805A (en) * 1968-09-24 1972-04-04 Cotton Inc Delayed cure process using formaldehyde vapor to cause creaseproofing
US3660013A (en) * 1969-08-01 1972-05-02 Mc Graw Edison Co Method and apparatus for producing a durable press in garments containing cellulose or cellulosic derivatives
US3703773A (en) * 1970-04-09 1972-11-28 Burlington Industries Inc Gas phase reactor
US3642428A (en) * 1970-04-27 1972-02-15 Cotton Inc Vapor phase resin fixation process for cellulosic material permitting subsequent cure
US4108598A (en) 1976-12-02 1978-08-22 The Strike Corporation Durable press process
FR2384867A1 (en) * 1977-03-21 1978-10-20 Chemiefaser Lenzing Ag CELLULOSE-BASED FIBER, CROSS-LINKED IN A WET ENVIRONMENT, AND ITS MANUFACTURING PROCESS
WO1999010589A1 (en) * 1997-08-22 1999-03-04 Hiroharu Okamoto Moisture-controlled curing durable press process
US6121167A (en) * 1997-08-22 2000-09-19 Okamoto; Hiroharu Moisture-controlled curing durable press process

Also Published As

Publication number Publication date
DE1444129C3 (en) 1975-04-17
NL286002A (en)
US3663974A (en) 1972-05-23
DE1444129A1 (en) 1968-11-07

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