GB963902A - Mono- or polyoxyethylated esters and their manufacture - Google Patents
Mono- or polyoxyethylated esters and their manufactureInfo
- Publication number
- GB963902A GB963902A GB2679660A GB2679660A GB963902A GB 963902 A GB963902 A GB 963902A GB 2679660 A GB2679660 A GB 2679660A GB 2679660 A GB2679660 A GB 2679660A GB 963902 A GB963902 A GB 963902A
- Authority
- GB
- United Kingdom
- Prior art keywords
- symbol
- semi
- ester
- formula
- oxyethylation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6136—Condensation products of esters, acids, oils, oxyacids with oxiranes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
- C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises esters of the general formula: <FORM:0963902/C1/1> where the symbol R represents a hydrocarbon radical and n represents a number from 1 to 40 and the preparation thereof by heating a semi-ester of the general formula: <FORM:0963902/C1/2> where the symbol R has the meaning defined above, with ethylene oxide in the presence of an oxyethylation catalyst and in the absence of oxygen. The oxyethylation catalyst may be an alkaline substance e.g. a lithium, sodium or potassium, hydroxide carbonate or alcoholate containing an alkyl group having 1 to 6 carbon atoms preferably a lithium, sodium or potassium salt of the semi-ester starting materials, when the reaction is carried out in the temperature range of 100 DEG to 200 DEG C. to give a product of the formula I when the symbol n has the value 1. About 0.1% to 7%, preferably 0.1% to 2% of the semi-ester, calculated as the weight of alkali metal on the weight of semi-ester, may be used. The oxyethylation catalyst may also be a Lewis Acid, e.g. an aluminium halide, phosphorus pentafluoride or a complex compound thereof, titanium tetrachloride, tin tetrachloride, ferric chloride or zinc chloride, when the reaction is carried out at 30 DEG to 100 DEG C. to give a compound of the formula I where the symbol n has the values 2 to 40, 0.1% to 7% by weight, calculated on the semi-ester of the formula II, of the Lewis Acid may be used.ALSO:The invention comprises mixed esters of the general formula: <FORM:0963902/C3/1> where the symbol R represents a hydrocarbon radical and the symbol n is 1 to 40 and the preparation thereof by heating a semi-ester of the general formula: <FORM:0963902/C3/2> when the symbol R has the meaning defined above with ethylene oxide in the presence of an oxyethylation catalyst. The oxyethylation-catalyst may be a Lewis acid e.g. an aluminium halide, phosphorus pentachloride or a complex compound thereof, titanium tetrachloride, tin tetrachloride, ferric chloride or zinc chloride, when the reaction is carried out at 30 DEG to 100 DEG C to give a compound of the formula I where the symbol n has the values 2 to 40. 0.1% to 7% by weight calculated on the weight of semi-ester of the formula II, of the Lewis acid may be used.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF29077A DE1128147B (en) | 1959-08-01 | 1959-08-01 | Process for the oxaethylation of compounds containing carboxyl groups |
Publications (1)
Publication Number | Publication Date |
---|---|
GB963902A true GB963902A (en) | 1964-07-15 |
Family
ID=7093149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2679660A Expired GB963902A (en) | 1959-08-01 | 1960-08-02 | Mono- or polyoxyethylated esters and their manufacture |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE593654A (en) |
CH (1) | CH390896A (en) |
DE (1) | DE1128147B (en) |
GB (1) | GB963902A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3689532A (en) * | 1969-10-14 | 1972-09-05 | Rohm & Haas | Process for polyoxyalkylation |
WO2016061756A1 (en) * | 2014-10-22 | 2016-04-28 | Dow Global Technologies Llc | Preparation of a sorbate ester |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE694078C (en) * | 1937-08-20 | 1940-07-25 | Kalle & Co Akt Ges | Photosensitive layers |
DE855111C (en) * | 1948-01-31 | 1952-11-10 | Monsanto Chemicals | Process for the preparation of condensation products from alkylene oxides and organic compounds |
US2674619A (en) * | 1953-10-19 | 1954-04-06 | Wyandotte Chemicals Corp | Polyoxyalkylene compounds |
-
1959
- 1959-08-01 DE DEF29077A patent/DE1128147B/en active Pending
-
1960
- 1960-07-29 CH CH866160A patent/CH390896A/en unknown
- 1960-08-01 BE BE593654A patent/BE593654A/en unknown
- 1960-08-02 GB GB2679660A patent/GB963902A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3689532A (en) * | 1969-10-14 | 1972-09-05 | Rohm & Haas | Process for polyoxyalkylation |
WO2016061756A1 (en) * | 2014-10-22 | 2016-04-28 | Dow Global Technologies Llc | Preparation of a sorbate ester |
Also Published As
Publication number | Publication date |
---|---|
BE593654A (en) | 1961-02-01 |
CH390896A (en) | 1965-04-30 |
DE1128147B (en) | 1962-04-19 |
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