GB943941A - Dehydrogenation of paraffinic hydrocarbons - Google Patents
Dehydrogenation of paraffinic hydrocarbonsInfo
- Publication number
- GB943941A GB943941A GB11024/62A GB1102462A GB943941A GB 943941 A GB943941 A GB 943941A GB 11024/62 A GB11024/62 A GB 11024/62A GB 1102462 A GB1102462 A GB 1102462A GB 943941 A GB943941 A GB 943941A
- Authority
- GB
- United Kingdom
- Prior art keywords
- forms
- dehydrogenation
- hydrocarbon
- catalyst
- paraffins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polymerization Catalysts (AREA)
Abstract
943,941. Dehydrating paraffins. POLYMER CORPORATION Ltd. March 22, 1962 [April 6, 1961], No. 11024/62. Heading C5E. In the dehydrogenation of paraffins having at least 3 carbon atoms in the molecule in a cyclic process comprising alternately passing the hydrocarbon and steam over a calcium nickel phosphate catalyst at dehydrogenation temperature and regenerating the catalyst, there is added 5-40% by volume of oxygen based on the hydrocarbon during the dehydrogenation phase. Suitable conditions are 550- 700‹ C. with a volume ratio of steam to hydrocarbon of 2-20: 1 and contact times of 0.25-6 seconds generally using atmospheric pressure. Oxygen should be present as O, O2 or O3 and may be mixed with diluents, e.g. carbon dioxide, nitrogen, natural gas, or as air or may be formed in situ from hydrogen peroxide, nitrogen dioxide or organic peroxides or hydroperoxides. The catalyst may also contain chromium oxide. Butane forms butenes and butadiene, pentane forms pentene and pentadiene, isopentane forms isopentene and isoprene, hexane forms benzene.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA820606 | 1961-04-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB943941A true GB943941A (en) | 1963-12-11 |
Family
ID=31501546
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11024/62A Expired GB943941A (en) | 1961-04-06 | 1962-03-22 | Dehydrogenation of paraffinic hydrocarbons |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB943941A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3268611A (en) * | 1965-06-11 | 1966-08-23 | Petro Tex Chem Corp | Process for dehydrogenating hydrocarbons |
-
1962
- 1962-03-22 GB GB11024/62A patent/GB943941A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3268611A (en) * | 1965-06-11 | 1966-08-23 | Petro Tex Chem Corp | Process for dehydrogenating hydrocarbons |
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