GB941271A - New phosphate ester and insecticidal compositions containing it - Google Patents
New phosphate ester and insecticidal compositions containing itInfo
- Publication number
- GB941271A GB941271A GB4197961A GB4197961A GB941271A GB 941271 A GB941271 A GB 941271A GB 4197961 A GB4197961 A GB 4197961A GB 4197961 A GB4197961 A GB 4197961A GB 941271 A GB941271 A GB 941271A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphate
- product
- trichloro
- nitro
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 230000000749 insecticidal effect Effects 0.000 title abstract 3
- 229910019142 PO4 Inorganic materials 0.000 title abstract 2
- 239000010452 phosphate Substances 0.000 title abstract 2
- -1 phosphate ester Chemical class 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 3
- 239000000047 product Substances 0.000 abstract 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- HVZWVEKIQMJYIK-UHFFFAOYSA-N nitryl chloride Chemical compound [O-][N+](Cl)=O HVZWVEKIQMJYIK-UHFFFAOYSA-N 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- XDVNHRVDOGWBHY-UHFFFAOYSA-N 1,2,2-trichloroethenyl dihydrogen phosphate Chemical compound C(=C(Cl)Cl)(OP(=O)(O)O)Cl XDVNHRVDOGWBHY-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 241000209140 Triticum Species 0.000 abstract 1
- 235000021307 Triticum Nutrition 0.000 abstract 1
- 239000000443 aerosol Substances 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 239000012876 carrier material Substances 0.000 abstract 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- XIQMWLRPLVOINP-UHFFFAOYSA-N dimethyl (1,2,2-trichloro-2-nitroethyl) phosphate Chemical compound P(=O)(OC)(OC)OC(C(Cl)(Cl)[N+](=O)[O-])Cl XIQMWLRPLVOINP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 235000012054 meals Nutrition 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000000779 smoke Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises dimethyl-(1, 2, 2,-trichloro-2-nitro-ethyl) phosphate. It may be obtained by passing gaseous nitryl chloride into a cooled solution of dimethyl 2, 2-dichlorovinyl phosphate in an inert anhydrous solvent, e.g. diethyl ether, chloroform or carbon tetrachloride. The product may be recovered by subsequently washing the reaction mixture with water and removing the solvent in vacuo, the product being obtained in the form of an oil. Some 1, 2, 2-trichlorovinyl phosphate is also obtained as by-product. The nitryl chloride used may be obtained by the dropwise addition of chlorosulphonic acid to a cooled mixture of oleum and concentrated nitric acid. The product has insecticidal properties (see Division A5).ALSO:An insecticidal composition comprises dimethyl - (1,2,2 - trichloro - 2 - nitro - ethyl) phosphate (see Division C2) and a liquid or solid diluent or carrier. The composition may be in the form of an emulsion, suspension or dust and may be applied as an aerosol, spray or smoke. Wheat meal is specified as carrier material.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL271371D NL271371A (en) | 1961-11-23 | ||
| BE619127D BE619127A (en) | 1961-11-23 | ||
| GB4197961A GB941271A (en) | 1961-11-23 | 1961-11-23 | New phosphate ester and insecticidal compositions containing it |
| FR880153A FR1320751A (en) | 1961-11-23 | 1961-11-27 | Insecticidal agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4197961A GB941271A (en) | 1961-11-23 | 1961-11-23 | New phosphate ester and insecticidal compositions containing it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB941271A true GB941271A (en) | 1963-11-06 |
Family
ID=10422271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4197961A Expired GB941271A (en) | 1961-11-23 | 1961-11-23 | New phosphate ester and insecticidal compositions containing it |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE619127A (en) |
| GB (1) | GB941271A (en) |
| NL (1) | NL271371A (en) |
-
0
- BE BE619127D patent/BE619127A/xx unknown
- NL NL271371D patent/NL271371A/xx unknown
-
1961
- 1961-11-23 GB GB4197961A patent/GB941271A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE619127A (en) | |
| NL271371A (en) |
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