GB957237A - New thiophosphoric acid esters - Google Patents

New thiophosphoric acid esters

Info

Publication number
GB957237A
GB957237A GB1197662A GB1197662A GB957237A GB 957237 A GB957237 A GB 957237A GB 1197662 A GB1197662 A GB 1197662A GB 1197662 A GB1197662 A GB 1197662A GB 957237 A GB957237 A GB 957237A
Authority
GB
United Kingdom
Prior art keywords
sulphur
alkyl
oxygen
prepared
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1197662A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB957237A publication Critical patent/GB957237A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/16Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165Esters of thiophosphoric acids
    • C07F9/18Esters of thiophosphoric acids with hydroxyaryl compounds

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Molecular Biology (AREA)
  • Agronomy & Crop Science (AREA)
  • Biochemistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention comprises compounds of formula: <FORM:0957237/C2/1> where R, R1 and R2 are C1-4 alkyl and X is oxygen or sulphur. They may be prepared by reacting appropriate O,O-dialkyl phosphites or thiophosphites with appropriate nitrophenylsulphenic acid chlorides, e.g. in an organic solvent at 20-40 DEG C. The hydrogen chloride formed may be removed by washing or by means of an acid-binding agent. The products are pesticides. 2- and 3-methyl-4-nitrophenyl sulphenic acid chlorides used as starting materials are prepared by the action of chlorine on 2,21- and 3,31-dimethyl-4 41-dinitro-diphenyl disulphides respectively. Specification 819,672 is referred to.ALSO:Pesticidal compositions comprise thiophosphoric esters of formula <FORM:0957237/A5-A6/1> where R, R1 and R2 are C1-4 alkyl and X is oxygen or sulphur (for preparation see Division C2) together with a solid or liquid carrier (e.g. in solution). Specification 819,672 is referred to.
GB1197662A 1961-03-28 1962-03-28 New thiophosphoric acid esters Expired GB957237A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF33528A DE1154486B (en) 1961-03-28 1961-03-28 Process for the preparation of insecticidally active dialkylthiophosphoric acid esters

Publications (1)

Publication Number Publication Date
GB957237A true GB957237A (en) 1964-05-06

Family

ID=7095131

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1197662A Expired GB957237A (en) 1961-03-28 1962-03-28 New thiophosphoric acid esters

Country Status (6)

Country Link
BE (1) BE615670A (en)
BR (1) BR6237473D0 (en)
CH (1) CH422823A (en)
DE (1) DE1154486B (en)
GB (1) GB957237A (en)
NL (1) NL276517A (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR994479A (en) * 1949-07-10 1951-11-16 S-nitrophenyl-0, 0-dialkylthiolphosphates and process for obtaining them
DE921870C (en) * 1952-05-02 1954-12-30 Bayer Ag Process for the preparation of 0, 0-dimethyl-0-4-nitro-3-chlorophenyl thiophosphate
DE1026323B (en) * 1955-10-04 1958-03-20 Bayer Ag Process for the preparation of insecticidally active O, O-dialkyl-S-phenyl-thionothiolphosphoric acid esters

Also Published As

Publication number Publication date
BR6237473D0 (en) 1973-05-10
BE615670A (en)
NL276517A (en)
DE1154486B (en) 1963-09-19
CH422823A (en) 1966-10-31

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