GB938024A - Fungicides comprising manganese salts of dithiocarbamic acids and their preparation - Google Patents

Fungicides comprising manganese salts of dithiocarbamic acids and their preparation

Info

Publication number
GB938024A
GB938024A GB4507661A GB4507661A GB938024A GB 938024 A GB938024 A GB 938024A GB 4507661 A GB4507661 A GB 4507661A GB 4507661 A GB4507661 A GB 4507661A GB 938024 A GB938024 A GB 938024A
Authority
GB
United Kingdom
Prior art keywords
diamine
manganese
dimethylamine
reaction
ethylene diamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4507661A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG Werk Kalle Albert
Original Assignee
Chemische Werke Albert
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Albert filed Critical Chemische Werke Albert
Publication of GB938024A publication Critical patent/GB938024A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/14—Dithiocarbamic acids; Derivatives thereof
    • C07C333/16—Salts of dithiocarbamic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Fungicidal manganese-containing products are prepared by reacting manganese oxides with a dithiocarbamate formed by reaction between carbon disulphide and an aliphatic, cycloaliphatic or heterocyclic mono- or diamine, other than ethylene diamine, having at least one primary or secondary amino group in the presence of ammonia and/or an excess of the amine. At least 0.5 gm atom of manganese is reacted with each equivalent of the dithiocarbamate, and amines mentioned are dimethylamine, methylamine, ethylamine, diethylamine, propylamine, isopropylamine, butylamine, hexylamine, dodecylamine, cyclohexylamine, methylcyclohexylamine, piperidine, pyrrolidine, morpholine, propylene, butylene, or hexamethylene diamine or substitution derivatives thereof. Mixtures of amines which may include ethylene diamine, may also be used. Mixtures of the product with thiuram disulphides are produced if the amount of monoamine in a mixture with diamine is in excess. Examples describe the reaction of manganese dioxide with the products of the reaction of dimethylamine, ethylamine, and dimethylamine and ethylene diamine, with carbon disulphide. The compounds may be used with a carrier or diluent in fungicidal compositions.ALSO:Fungicidal compositions comprise the manganese containing products prepared by reacting manganese oxides with a dithiocarbamate formed by reaction between carbon disulphide and an aliphatic, cycloaliphatic or heterocyclic mono- or diamine other than ethylene diamine having at least one primary or secondary amino group in the presence of ammonia and/or excess of amine. Amines mentioned are dimethylamine, methylamine, ethylamine, diethylamine, propylamine, isopropylamine, butylamine, hexylamine, dodecylamine, cyclohexylamine, methylcyclohexylamine, piperidine, pyrrolidine, morpholine, propylene, butylene, or hexamethylene diamine or substitution derivatives thereof. Mixtures of amines which may include ethylene diamine may also be used. The compounds are used with a carrier or diluent in the form of solutions, suspensions, emulsions, wettable powders or dusts.
GB4507661A 1959-07-31 1961-12-15 Fungicides comprising manganese salts of dithiocarbamic acids and their preparation Expired GB938024A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DEC19519A DE1186458B (en) 1959-07-31 1959-07-31 Process for the preparation of fungicidally active manganese-ethylene-bis-dithiocarbaminates
DEC20770A DE1195290B (en) 1959-07-31 1960-02-11 Process for the production of fungicidally active manganese-ethylene-bis-dithiocarbaminates
DEC0023379 1961-02-09
CH1070961 1961-09-15

Publications (1)

Publication Number Publication Date
GB938024A true GB938024A (en) 1963-09-25

Family

ID=27429312

Family Applications (2)

Application Number Title Priority Date Filing Date
GB1870260A Expired GB888289A (en) 1959-07-31 1960-05-26 A process for the production of new manganese-containing dithiocarbamate reaction products
GB4507661A Expired GB938024A (en) 1959-07-31 1961-12-15 Fungicides comprising manganese salts of dithiocarbamic acids and their preparation

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB1870260A Expired GB888289A (en) 1959-07-31 1960-05-26 A process for the production of new manganese-containing dithiocarbamate reaction products

Country Status (4)

Country Link
BE (2) BE593153A (en)
DE (2) DE1186458B (en)
FR (2) FR1260525A (en)
GB (2) GB888289A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3412117A (en) * 1963-02-14 1968-11-19 Sipcam Spa Preparation of heavy metal complex salts of ethylenebisdithiocarbamic acid and dimethyldithiocarbamic acid

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE621575A (en) * 1961-08-26
DE3534246A1 (en) * 1985-09-26 1987-03-26 Akzo Gmbh METHOD FOR THE PRODUCTION OF ALKYLENE-BIS-DITHIOCARBAMATES OR THEIR AMMONIA ADDUCTS AND MIXTURES THAT CAN BE PRODUCED THEREOF
DE3739149A1 (en) * 1987-11-19 1989-06-01 Basf Ag METHOD FOR PRODUCING DITHIOCARBAMINE ACIDS OR THEIR SALTS AND THEIR FOLLOW-UP PRODUCTS
CN105949100B (en) * 2016-05-18 2017-12-19 浙江云涛生物技术股份有限公司 The production technology of new dithiocarbamates heavy metal chelant

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2492314A (en) * 1945-01-16 1949-12-27 Sharples Chemicals Inc Process for producing metal salts of substituted dithiocarbamic acids

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3412117A (en) * 1963-02-14 1968-11-19 Sipcam Spa Preparation of heavy metal complex salts of ethylenebisdithiocarbamic acid and dimethyldithiocarbamic acid

Also Published As

Publication number Publication date
GB888289A (en) 1962-01-31
FR81049E (en) 1963-07-19
FR1260525A (en) 1961-05-05
DE1195290B (en) 1965-06-24
DE1186458B (en) 1965-02-04
BE593153A (en)
BE613461A (en)

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