GB934969A - Production of metal salts of organic acids - Google Patents
Production of metal salts of organic acidsInfo
- Publication number
- GB934969A GB934969A GB42847/61A GB4284761A GB934969A GB 934969 A GB934969 A GB 934969A GB 42847/61 A GB42847/61 A GB 42847/61A GB 4284761 A GB4284761 A GB 4284761A GB 934969 A GB934969 A GB 934969A
- Authority
- GB
- United Kingdom
- Prior art keywords
- prepared
- acid
- metal
- salts
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Aliphatic carboxylic acid salts of metals, having a normal electrode potential of -0,80 to +0,5 volts, are prepared by reacting a pulverulent metal with the acid diluted with water or an inert organic solvent, at a temperature between room temperature and the boiling point of the acid, in the presence of free oxygen and an activator consisting of the bromide of the metal. Saturated aliphatic monocarboxylic acids, e.g. formic, acetic, propionic and butyric acids, a -ethyl hexanoic acid and unsaturated acids such as oleic are referred to, and the diluents may be g -lactones, nitriles and alkylene carbonates. Chromium, cobalt, nickel, and lead salts are prepared and copper, bismuth and iron salts are mentioned, and pure oxygen or air may be the oxidising agent. The bromides may be prepared in situ by adding metal carbonates with hydrogen bromide or tetrabromoethane, or by adding bromine to the reaction mixture. The process may be batchwise or continuous.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEB60336A DE1196178B (en) | 1960-12-03 | 1960-12-03 | Process for the preparation of carboxylic acid salts or their optionally still carbonic acid-containing solutions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB934969A true GB934969A (en) | 1963-08-21 |
Family
ID=6972784
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB42847/61A Expired GB934969A (en) | 1960-12-03 | 1961-11-30 | Production of metal salts of organic acids |
Country Status (4)
Country | Link |
---|---|
US (1) | US3133942A (en) |
BE (1) | BE611005A (en) |
DE (1) | DE1196178B (en) |
GB (1) | GB934969A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5728854A (en) * | 1996-08-06 | 1998-03-17 | Industrial Technology Research Institute | Method for separating iron from nickel and/or cadmium from a waste containing the same |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5441575B2 (en) * | 1972-07-28 | 1979-12-08 | ||
US4075234A (en) * | 1976-10-12 | 1978-02-21 | The Procter & Gamble Company | Hydrated soap making |
US4175053A (en) * | 1976-10-12 | 1979-11-20 | The Procter & Gamble Company | Base reactant |
FR2464243A1 (en) * | 1979-09-03 | 1981-03-06 | Inst Francais Du Petrole | NOVEL NICKEL COMPOUNDS, THEIR PREPARATION AND THEIR USE AS CATALYSTS FOR OLEFIN OLIGOMERIZATION |
US4404146A (en) * | 1980-12-17 | 1983-09-13 | Biosystems Research Inc. | Metal oxyalkylates and method of making same |
USRE32909E (en) * | 1980-10-07 | 1989-04-18 | Biosystems Research Inc. | Metal oxycarboxylates and method of making same |
US4495105A (en) * | 1983-03-09 | 1985-01-22 | Atlantic Richfield Company | Preparation of higher tin carboxylates in improved yields using an inert gas |
FR2555570B1 (en) * | 1983-11-29 | 1986-10-03 | Inst Francais Du Petrole | NEW COMPOSITION OF BIVALENT NICKEL SOLUBLE IN HYDROCARBONS |
US4546202A (en) * | 1983-11-29 | 1985-10-08 | Amoco Corporation | Process for the recovery of cobalt and manganese from oxidation residue incinerator ash, pyrolysis sand and pyrolysis char |
US4720352A (en) * | 1985-11-01 | 1988-01-19 | Nuodex Inc. | Process for the preparation of vanadium-containing mixed metal soap solutions |
JPH0678271B2 (en) * | 1986-07-12 | 1994-10-05 | 三菱油化株式会社 | Method for producing silver oxalate |
US4921986A (en) * | 1987-12-30 | 1990-05-01 | Hall Chemical Company | Method and apparatus for producing cobalt acetate from cobalt chip |
US5021598A (en) * | 1989-07-24 | 1991-06-04 | Mooney Chemicals, Inc. | Process for making bismuth carboxylates |
US5795615A (en) * | 1994-09-30 | 1998-08-18 | Kemin Industries, Inc. | Process for producing metal carboxylates for use as animal feed supplements |
DE19527284A1 (en) * | 1995-07-26 | 1997-01-30 | Riedel De Haen Ag | Process for the production of a non-ferrous metal carboxylate |
US6303808B1 (en) * | 2000-08-10 | 2001-10-16 | Crompton Corporation | Direct synthesis of tin (II) carboxylates and tin(IV) carboxylates from elemental tin or tin oxides |
US7495117B2 (en) * | 2006-08-04 | 2009-02-24 | Kemin Industries, Inc. | Metal carboxylate salts |
US11753430B2 (en) | 2020-06-03 | 2023-09-12 | Vitalix, Inc. | Method of making cobalt compounds for feed supplements |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2409678A (en) * | 1943-09-18 | 1946-10-22 | Du Pont | Preparation of soaps |
US2416074A (en) * | 1943-09-21 | 1947-02-18 | Du Pont | Preparation of heavy metal soaps |
US2395307A (en) * | 1943-10-06 | 1946-02-19 | Du Pont | Preparation of organic salts |
US2584041A (en) * | 1949-07-06 | 1952-01-29 | Nuodex Products Co Inc | Process of preparing oil-soluble metal soaps |
DE883606C (en) * | 1951-11-23 | 1953-07-20 | Nuodex Products Co | Process for the production of oil-soluble metal soaps |
DE1081445B (en) * | 1954-05-03 | 1960-05-12 | Mid Century Corp | Process for the production of aromatic di- or polycarboxylic acids |
US2890232A (en) * | 1956-05-31 | 1959-06-09 | Swift & Co | Manufacture of metal soaps |
-
1960
- 1960-12-03 DE DEB60336A patent/DE1196178B/en active Pending
-
1961
- 1961-11-30 GB GB42847/61A patent/GB934969A/en not_active Expired
- 1961-11-30 BE BE611005A patent/BE611005A/en unknown
- 1961-12-01 US US156507A patent/US3133942A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5728854A (en) * | 1996-08-06 | 1998-03-17 | Industrial Technology Research Institute | Method for separating iron from nickel and/or cadmium from a waste containing the same |
Also Published As
Publication number | Publication date |
---|---|
BE611005A (en) | 1962-05-30 |
DE1196178B (en) | 1965-07-08 |
US3133942A (en) | 1964-05-19 |
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