GB934969A - Production of metal salts of organic acids - Google Patents

Production of metal salts of organic acids

Info

Publication number
GB934969A
GB934969A GB42847/61A GB4284761A GB934969A GB 934969 A GB934969 A GB 934969A GB 42847/61 A GB42847/61 A GB 42847/61A GB 4284761 A GB4284761 A GB 4284761A GB 934969 A GB934969 A GB 934969A
Authority
GB
United Kingdom
Prior art keywords
prepared
acid
metal
salts
acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB42847/61A
Inventor
Edgar Hahl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB934969A publication Critical patent/GB934969A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41Preparation of salts of carboxylic acids
    • C07C51/412Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Aliphatic carboxylic acid salts of metals, having a normal electrode potential of -0,80 to +0,5 volts, are prepared by reacting a pulverulent metal with the acid diluted with water or an inert organic solvent, at a temperature between room temperature and the boiling point of the acid, in the presence of free oxygen and an activator consisting of the bromide of the metal. Saturated aliphatic monocarboxylic acids, e.g. formic, acetic, propionic and butyric acids, a -ethyl hexanoic acid and unsaturated acids such as oleic are referred to, and the diluents may be g -lactones, nitriles and alkylene carbonates. Chromium, cobalt, nickel, and lead salts are prepared and copper, bismuth and iron salts are mentioned, and pure oxygen or air may be the oxidising agent. The bromides may be prepared in situ by adding metal carbonates with hydrogen bromide or tetrabromoethane, or by adding bromine to the reaction mixture. The process may be batchwise or continuous.
GB42847/61A 1960-12-03 1961-11-30 Production of metal salts of organic acids Expired GB934969A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB60336A DE1196178B (en) 1960-12-03 1960-12-03 Process for the preparation of carboxylic acid salts or their optionally still carbonic acid-containing solutions

Publications (1)

Publication Number Publication Date
GB934969A true GB934969A (en) 1963-08-21

Family

ID=6972784

Family Applications (1)

Application Number Title Priority Date Filing Date
GB42847/61A Expired GB934969A (en) 1960-12-03 1961-11-30 Production of metal salts of organic acids

Country Status (4)

Country Link
US (1) US3133942A (en)
BE (1) BE611005A (en)
DE (1) DE1196178B (en)
GB (1) GB934969A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5728854A (en) * 1996-08-06 1998-03-17 Industrial Technology Research Institute Method for separating iron from nickel and/or cadmium from a waste containing the same

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5441575B2 (en) * 1972-07-28 1979-12-08
US4075234A (en) * 1976-10-12 1978-02-21 The Procter & Gamble Company Hydrated soap making
US4175053A (en) * 1976-10-12 1979-11-20 The Procter & Gamble Company Base reactant
FR2464243A1 (en) * 1979-09-03 1981-03-06 Inst Francais Du Petrole NOVEL NICKEL COMPOUNDS, THEIR PREPARATION AND THEIR USE AS CATALYSTS FOR OLEFIN OLIGOMERIZATION
US4404146A (en) * 1980-12-17 1983-09-13 Biosystems Research Inc. Metal oxyalkylates and method of making same
USRE32909E (en) * 1980-10-07 1989-04-18 Biosystems Research Inc. Metal oxycarboxylates and method of making same
US4495105A (en) * 1983-03-09 1985-01-22 Atlantic Richfield Company Preparation of higher tin carboxylates in improved yields using an inert gas
FR2555570B1 (en) * 1983-11-29 1986-10-03 Inst Francais Du Petrole NEW COMPOSITION OF BIVALENT NICKEL SOLUBLE IN HYDROCARBONS
US4546202A (en) * 1983-11-29 1985-10-08 Amoco Corporation Process for the recovery of cobalt and manganese from oxidation residue incinerator ash, pyrolysis sand and pyrolysis char
US4720352A (en) * 1985-11-01 1988-01-19 Nuodex Inc. Process for the preparation of vanadium-containing mixed metal soap solutions
JPH0678271B2 (en) * 1986-07-12 1994-10-05 三菱油化株式会社 Method for producing silver oxalate
US4921986A (en) * 1987-12-30 1990-05-01 Hall Chemical Company Method and apparatus for producing cobalt acetate from cobalt chip
US5021598A (en) * 1989-07-24 1991-06-04 Mooney Chemicals, Inc. Process for making bismuth carboxylates
US5795615A (en) * 1994-09-30 1998-08-18 Kemin Industries, Inc. Process for producing metal carboxylates for use as animal feed supplements
DE19527284A1 (en) * 1995-07-26 1997-01-30 Riedel De Haen Ag Process for the production of a non-ferrous metal carboxylate
US6303808B1 (en) * 2000-08-10 2001-10-16 Crompton Corporation Direct synthesis of tin (II) carboxylates and tin(IV) carboxylates from elemental tin or tin oxides
US7495117B2 (en) * 2006-08-04 2009-02-24 Kemin Industries, Inc. Metal carboxylate salts
US11753430B2 (en) 2020-06-03 2023-09-12 Vitalix, Inc. Method of making cobalt compounds for feed supplements

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2409678A (en) * 1943-09-18 1946-10-22 Du Pont Preparation of soaps
US2416074A (en) * 1943-09-21 1947-02-18 Du Pont Preparation of heavy metal soaps
US2395307A (en) * 1943-10-06 1946-02-19 Du Pont Preparation of organic salts
US2584041A (en) * 1949-07-06 1952-01-29 Nuodex Products Co Inc Process of preparing oil-soluble metal soaps
DE883606C (en) * 1951-11-23 1953-07-20 Nuodex Products Co Process for the production of oil-soluble metal soaps
DE1081445B (en) * 1954-05-03 1960-05-12 Mid Century Corp Process for the production of aromatic di- or polycarboxylic acids
US2890232A (en) * 1956-05-31 1959-06-09 Swift & Co Manufacture of metal soaps

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5728854A (en) * 1996-08-06 1998-03-17 Industrial Technology Research Institute Method for separating iron from nickel and/or cadmium from a waste containing the same

Also Published As

Publication number Publication date
BE611005A (en) 1962-05-30
DE1196178B (en) 1965-07-08
US3133942A (en) 1964-05-19

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