GB934815A - Process for the manufacture of hard waxes rich in esters - Google Patents
Process for the manufacture of hard waxes rich in estersInfo
- Publication number
- GB934815A GB934815A GB14498/60A GB1449860A GB934815A GB 934815 A GB934815 A GB 934815A GB 14498/60 A GB14498/60 A GB 14498/60A GB 1449860 A GB1449860 A GB 1449860A GB 934815 A GB934815 A GB 934815A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- air
- weight
- wax
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/035—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with saturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
- C10G73/38—Chemical modification of petroleum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A hard wax rich in esters is produced by oxidizing in the molten state at not above 200 DEG C., preferably 130 DEG -170 DEG C., with oxygen or a gas containing oxygen such as air or oxygenenriched air a mixture of (a) montan wax acids and (b) natural or synthetic paraffin hydrocarbons, including microcrystalline waxes, having solidification point above 70 DEG C., preferably above 90 DEG C., which may contain not more than 40% by weight of (b) of (c) wax-like high or low pressure polyolefins, suitably polyethylene and/or polypropylene, having molecular weights of 1,000-20,000, preferably 5,000-10,000. The oxidation is generally carried out in the presence of up to 1% by weight of a catalyst such as a metal salt or oxide, an organic peroxide or an acid, but most usually cobalt or manganese stearate or naphthenate, the ratio of montan wax acids to hydrocarbons in the reaction mixture being 4:1 to 1:4, and air being passed into the mixture at 200-1,000 l./hr./kg. of mixture. Any free acid groups present in the hard wax product may be subsequently converted into salt form, or into amide or ester groups. The product may be used in floor polishes or leatherdressing compositions, and may be mixed with lime soap or with other ester, amide, or hydrocarbon waxes.ALSO:A hard wax rich in esters is produced by oxidizing in the molten state at not above 200 DEG C., preferably 130 DEG -170 DEG C., with oxygen or gas containing oxygen such as air or oxygen-enriched air a mixture of (a) montan wax acids, (b) natural or synthetic paraffin hydrocarbons having a solidification point above 70 DEG C. and preferably above 90 DEG C., and (c) wax-like high or low pressure olefins, suitably polyethylene and/or polypropylene having a molecular weight of 1,000-20,000, preferably 5,000-10,000, the amount of (c) comprising up to 40% by weight of (b) and the ratio of (a) to hydrocarbons in the reaction mixture being 4:1 to 1:4. The oxidation is generally carried out in the presence of up to 1% by weight of a catalyst such as a metal salt or oxide, an organic peroxide or an acid, most usually cobalt or manganese stearate or naphthenate, air being passed into the mixture at 200-1,000 l./hr./kg. of mixture.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF28312A DE1160840B (en) | 1959-04-25 | 1959-04-25 | Process for the production of hard waxes with a high ester content |
Publications (1)
Publication Number | Publication Date |
---|---|
GB934815A true GB934815A (en) | 1963-08-21 |
Family
ID=7092824
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14498/60A Expired GB934815A (en) | 1959-04-25 | 1960-04-25 | Process for the manufacture of hard waxes rich in esters |
Country Status (3)
Country | Link |
---|---|
US (1) | US3060046A (en) |
DE (1) | DE1160840B (en) |
GB (1) | GB934815A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112852486A (en) * | 2021-01-12 | 2021-05-28 | 国家能源集团宁夏煤业有限责任公司 | Oxidized wax and preparation method thereof |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1255836B (en) * | 1962-03-30 | 1967-12-07 | Hoechst Ag | Wax mixtures in ionogenic self-gloss wax emulsions |
US3437496A (en) * | 1963-05-16 | 1969-04-08 | Hoechst Ag | Process for preparing strewable waxes for bright drying polish emulsions |
DE2546791C2 (en) * | 1975-10-18 | 1977-09-15 | Hoechst Ag, 6000 Frankfurt | Process for the production of carbon paper waxes |
US4732612A (en) * | 1983-09-02 | 1988-03-22 | The Drackett Company | Polish emulsion compositions |
CN112125990A (en) * | 2019-06-24 | 2020-12-25 | 内蒙古伊泰煤基新材料研究院有限公司 | Esterification modification method of wax |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE523518C (en) * | 1928-02-08 | 1931-04-30 | Riebeck Sche Montanwerke Akt G | Process for obtaining oxidation products from hydrocarbons |
US1985871A (en) * | 1930-03-05 | 1934-12-25 | Firm Of A Riebeck Sche Montanw | Method of treating montan wax |
GB386715A (en) * | 1931-09-16 | 1933-01-26 | Ig Farbenindustrie Ag | Improvements in the oxidation of organic compounds |
-
1959
- 1959-04-25 DE DEF28312A patent/DE1160840B/en active Pending
-
1960
- 1960-04-21 US US23638A patent/US3060046A/en not_active Expired - Lifetime
- 1960-04-25 GB GB14498/60A patent/GB934815A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112852486A (en) * | 2021-01-12 | 2021-05-28 | 国家能源集团宁夏煤业有限责任公司 | Oxidized wax and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
DE1160840B (en) | 1964-01-09 |
US3060046A (en) | 1962-10-23 |
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