GB951308A - Process for the manufacture of wax-like oxidation products from solid low pressure polyolefines - Google Patents
Process for the manufacture of wax-like oxidation products from solid low pressure polyolefinesInfo
- Publication number
- GB951308A GB951308A GB1289560A GB1289560A GB951308A GB 951308 A GB951308 A GB 951308A GB 1289560 A GB1289560 A GB 1289560A GB 1289560 A GB1289560 A GB 1289560A GB 951308 A GB951308 A GB 951308A
- Authority
- GB
- United Kingdom
- Prior art keywords
- wax
- low pressure
- oxidation products
- acid
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/06—Oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A wax-like product is obtained by treating a powdery low pressure olefin polymer (e.g. polyethylene, polypropylene or polybutylene) at a temperature below its softening point with an oxidizing gas (e.g. oxygen or air-preferably ozonized) under conditions which permit intimate mixing. Optionally the reaction is accelerated with an organic peroxide (of those listed, benzoyl peroxide is exemplified) or with acetic or formic acid. The treatment may be in a fluidized bed, or in suspension (in the absence of methanol) in water or an organic medium such as an inert halogenated hydrocarbon or a liquid hydrocarbon which itself becomes oxidized under the conditions of the reaction. The oxidizable hydrocarbons are preferably pre-oxidized and specified are gasoline, microcrystalline wax, Fischer-Tropsch paraffins, high pressure polyolefin waxes and thermally decomposed low pressure polyolefins. The wax-like oxidation products are long-chain dicarboxylic acids also containing alcoholic and ketone groups; they may have an oxygen content of up to 40%, an acid number up to 400, a saponification number up to 500 and a molecular weight up to 5000. The wax-like oxidation products may be esterified with an alcohol or a phenol, optionally in the presence of a mono-, di-, or poly-carboxylic acid (e.g. montan wax acid), to give wax-like materials which find application alone or in conjunction with di- or poly-carboxylic acids, in shoe and floor polishes, polish emulsions, lubricants, and casting and impregnating waxes.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF0028150 | 1959-04-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB951308A true GB951308A (en) | 1964-03-04 |
Family
ID=7092761
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1289560A Expired GB951308A (en) | 1959-04-09 | 1960-04-11 | Process for the manufacture of wax-like oxidation products from solid low pressure polyolefines |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB951308A (en) |
NL (1) | NL250325A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0050524A1 (en) * | 1980-10-21 | 1982-04-28 | Orobis Limited | Method for oxidatively shearing a polyolefin |
EP0296490A2 (en) * | 1987-06-25 | 1988-12-28 | BASF Aktiengesellschaft | Process for the oxidation of polyethylene |
US5064908A (en) * | 1987-06-25 | 1991-11-12 | Basf Aktiengesellschaft | Oxidized polyethylene and use as lubricant for polyvinylchloride |
US7767767B2 (en) * | 2007-10-01 | 2010-08-03 | Equistar Chemicals, Lp | Modification of polyethylene with ozone |
CN114702985A (en) * | 2022-05-07 | 2022-07-05 | 山西潞安煤基清洁能源有限责任公司 | Emulsified wax based on Fischer-Tropsch bottom oil reducing and preparation method thereof |
DE102021133861A1 (en) | 2021-12-20 | 2023-06-22 | Universität Konstanz, Körperschaft des öffentlichen Rechts | Utilization of polyethylene-containing mixtures to form long-chain alkyl dicarboxylic acids by means of oxidative cleavage |
-
0
- NL NL250325D patent/NL250325A/xx unknown
-
1960
- 1960-04-11 GB GB1289560A patent/GB951308A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0050524A1 (en) * | 1980-10-21 | 1982-04-28 | Orobis Limited | Method for oxidatively shearing a polyolefin |
WO1982001372A1 (en) * | 1980-10-21 | 1982-04-29 | Crawford John | Method for oxidatively shearing an olefinic polymer |
EP0296490A2 (en) * | 1987-06-25 | 1988-12-28 | BASF Aktiengesellschaft | Process for the oxidation of polyethylene |
EP0296490A3 (en) * | 1987-06-25 | 1989-03-22 | Basf Aktiengesellschaft | Process for the oxidation of polyethylene |
US4889897A (en) * | 1987-06-25 | 1989-12-26 | Basf Aktiengesellschaft | Oxidation of polyethylene |
US5064908A (en) * | 1987-06-25 | 1991-11-12 | Basf Aktiengesellschaft | Oxidized polyethylene and use as lubricant for polyvinylchloride |
US7767767B2 (en) * | 2007-10-01 | 2010-08-03 | Equistar Chemicals, Lp | Modification of polyethylene with ozone |
DE102021133861A1 (en) | 2021-12-20 | 2023-06-22 | Universität Konstanz, Körperschaft des öffentlichen Rechts | Utilization of polyethylene-containing mixtures to form long-chain alkyl dicarboxylic acids by means of oxidative cleavage |
WO2023118135A1 (en) | 2021-12-20 | 2023-06-29 | Universität Konstanz | Utilization of polyethylene-containing mixtures to form long-chain alkyl dicarboxylic acids by way of oxidative degradation |
CN114702985A (en) * | 2022-05-07 | 2022-07-05 | 山西潞安煤基清洁能源有限责任公司 | Emulsified wax based on Fischer-Tropsch bottom oil reducing and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
NL250325A (en) |
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