GB930992A - Oxidation of aryloxy-substituted phenols - Google Patents
Oxidation of aryloxy-substituted phenolsInfo
- Publication number
- GB930992A GB930992A GB19526/59A GB1952659A GB930992A GB 930992 A GB930992 A GB 930992A GB 19526/59 A GB19526/59 A GB 19526/59A GB 1952659 A GB1952659 A GB 1952659A GB 930992 A GB930992 A GB 930992A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dimethyl
- phenol
- dimethylphenoxy
- mono
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- 150000002989 phenols Chemical class 0.000 title 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- 150000003512 tertiary amines Chemical class 0.000 abstract 3
- MMARFGDTMJBIBK-UHFFFAOYSA-N 5-bromo-2-methoxy-1,3-dimethylbenzene Chemical compound COC1=C(C)C=C(Br)C=C1C MMARFGDTMJBIBK-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- -1 aryloxy phenols Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 abstract 2
- 229920001955 polyphenylene ether Polymers 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000005909 Kieselgur Substances 0.000 abstract 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003463 adsorbent Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003957 anion exchange resin Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 235000013312 flour Nutrition 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000391 magnesium silicate Substances 0.000 abstract 1
- 229910052919 magnesium silicate Inorganic materials 0.000 abstract 1
- 235000019792 magnesium silicate Nutrition 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000004053 quinones Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 239000011669 selenium Substances 0.000 abstract 1
- 239000000741 silica gel Substances 0.000 abstract 1
- 229910002027 silica gel Inorganic materials 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 150000005186 trinitrobenzenes Chemical class 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/24—Quinones containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
- C07C43/275—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings having all ether-oxygen atoms bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/08—Quinones with polycyclic non-condensed quinoid structure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/26—Quinones containing groups having oxygen atoms singly bound to carbon atoms
- C07C50/30—Quinones containing groups having oxygen atoms singly bound to carbon atoms with polycyclic non-condensed quinoid structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/44—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols by oxidation of phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyethers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US744087A US3134753A (en) | 1958-06-24 | 1958-06-24 | Oxidation of aryloxy-substituted phenols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB930992A true GB930992A (en) | 1963-07-10 |
Family
ID=24991380
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19526/59A Expired GB930992A (en) | 1958-06-24 | 1959-06-24 | Oxidation of aryloxy-substituted phenols |
Country Status (5)
Country | Link |
---|---|
US (1) | US3134753A (en, 2012) |
JP (1) | JPS3714645B1 (en, 2012) |
DE (1) | DE1145360B (en, 2012) |
FR (1) | FR1234336A (en, 2012) |
GB (1) | GB930992A (en, 2012) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4868283A (en) * | 1986-08-29 | 1989-09-19 | Huls Aktiengesellschaft | Process for the production of polyphenylene ethers with reduced inherent color |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3382212A (en) * | 1959-06-17 | 1968-05-07 | Gen Tire & Rubber Co | Process for preparing polyphenylene ethers |
US3228910A (en) * | 1960-09-22 | 1966-01-11 | Du Pont | Process for preparing solid poly-1, 4-phenylene ethers |
US3236807A (en) * | 1961-05-02 | 1966-02-22 | Du Pont | Process for preparing poly(unsymmetri-cally-2, 6-disubstituted phenylene) ether |
CH401019A (de) * | 1961-06-19 | 1965-10-31 | Gen Electric | Verfahren zur Herstellung von tetrasubstituierten Diphenchinonen |
US3262911A (en) * | 1961-11-29 | 1966-07-26 | Gen Electric | Substituted polyphenylene ethers |
US3226361A (en) * | 1961-11-29 | 1965-12-28 | Gen Electric | Functional aromatic substituents in polyphenylene oxides |
US3378505A (en) * | 1961-11-29 | 1968-04-16 | Gen Electric | Substituted polyphenylene ethers |
NL287348A (en, 2012) * | 1962-01-02 | |||
US3260701A (en) * | 1962-12-12 | 1966-07-12 | Sun Oil Co | Preparation of aromatic polyethers with lead dioxide catalyst |
US3281393A (en) * | 1962-12-28 | 1966-10-25 | Borden Co | Phenylene oxide polymers substituted with epoxidized alkenyl groups |
US3256243A (en) * | 1962-12-31 | 1966-06-14 | Gen Electric | Process for preparing poly |
NL302583A (en, 2012) * | 1962-12-31 | 1900-01-01 | ||
US3257357A (en) * | 1963-04-01 | 1966-06-21 | Du Pont | Copolymers of polyphenylene ethers |
US3257358A (en) * | 1963-07-02 | 1966-06-21 | Du Pont | 2, 6-dichloro-1, 4-polyphenylene ether |
US3292061A (en) * | 1963-08-13 | 1966-12-13 | Gen Electric | Electrical capacitor with a polyphenylene ether dielectric |
US3259520A (en) * | 1963-10-09 | 1966-07-05 | Gen Electric | Antistatic compositions derived from polyphenylene oxides |
US3262892A (en) * | 1963-11-29 | 1966-07-26 | Gen Electric | Substituted polyphenylene ethers |
US3422062A (en) * | 1963-11-29 | 1969-01-14 | North American Rockwell | Copolymers of alkenyl phenol |
US3220979A (en) * | 1964-03-27 | 1965-11-30 | Sun Oil Co | Preparation of aromatic phenols |
US3342892A (en) * | 1964-08-07 | 1967-09-19 | Eastman Kodak Co | Preparation of linear polyaryl ethers |
US3350844A (en) * | 1964-09-21 | 1967-11-07 | Gen Electric | Process for the separation or enrichment of gases |
US3379672A (en) * | 1965-05-17 | 1968-04-23 | Northrop Corp | Substituted polyphenyl ether |
US3373226A (en) * | 1965-08-02 | 1968-03-12 | Gen Electric | Polymeric films comprising a polyphenylene oxide and blends thereof with polystyrene |
US3373942A (en) * | 1965-10-05 | 1968-03-19 | Speakman Co | Plastic shower head plungers |
US3367978A (en) * | 1966-05-03 | 1968-02-06 | Gen Electric | 4-(phenoxy)phenols |
NL135413C (en, 2012) * | 1966-07-21 | |||
US3503818A (en) * | 1966-12-01 | 1970-03-31 | Union Carbide Corp | Polyarylene polyether insulated conductors and process for making same |
US3429850A (en) * | 1967-01-18 | 1969-02-25 | Gen Electric | Stabilized polyphenylene ether compositions |
US3420792A (en) * | 1967-01-18 | 1969-01-07 | Gen Electric | Stabilized polyphenylene ether |
US3527665A (en) * | 1967-01-23 | 1970-09-08 | Fmc Corp | Copper-clad laminates of unsaturated thermosetting resins with copper layer coated with polyphenylene oxide resin |
US3450670A (en) * | 1967-01-27 | 1969-06-17 | Gen Electric | Stabilized polyphenylene ether composition |
US3465062A (en) * | 1967-02-02 | 1969-09-02 | Gen Electric | Stable polyphenylene ether composition |
US3925307A (en) * | 1973-04-23 | 1975-12-09 | Raychem Corp | Antioxidants for polyarylether ketones |
JPS5217559B2 (en, 2012) * | 1973-06-26 | 1977-05-16 | ||
DE3047366A1 (de) * | 1980-12-16 | 1982-07-22 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von polyphenylenaethern |
US4478752A (en) * | 1981-07-20 | 1984-10-23 | Sun Tech, Inc. | Process for oxidizing phenol to p-benzoquinone |
US4491649A (en) * | 1983-12-01 | 1985-01-01 | Borg-Warner Chemicals, Inc. | High impact polyphenylene ether compositions having improved processability |
US4485219A (en) * | 1983-12-01 | 1984-11-27 | Borg-Warner Chemicals, Inc. | Phenylene ether copolymer aromatic polycarbonate blends |
JPS61130340A (ja) * | 1984-11-30 | 1986-06-18 | Mitsubishi Petrochem Co Ltd | ポリフェニレンエーテルの製造方法 |
US4654405A (en) * | 1985-12-05 | 1987-03-31 | Borg-Warner Chemicals, Inc. | Carboxylated phenylene ether resins |
CN102807673A (zh) * | 2011-06-03 | 2012-12-05 | 第一毛织株式会社 | 聚亚芳基醚及其制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE11764C (de) * | Dr. O. BRAUN in Berlin, Wichmannstrafse 18 | Verbesserungen an der durch Patent Nr. 2325 von nagel & kämp geschützten Maschine, um bei Luftabschlufs durch Schlagstiftscheiben Mahlgut zu zerkleinern | ||
DE357756C (de) * | 1920-02-08 | 1922-08-31 | Chemische Werke Grenzach Aktie | Verfahren zur Darstellung von harzartigen Kondensationsprodukten aus Kresolen und Xylenolen |
FR537335A (en, 2012) * | 1920-06-25 | 1922-05-20 | ||
US2911380A (en) * | 1955-08-26 | 1959-11-03 | Dow Chemical Co | Poly-(aromatic ether) compositions and method of making same |
US2961384A (en) * | 1956-12-27 | 1960-11-22 | American Marietta Co | Electrolytic polymerization of phenol |
-
1958
- 1958-06-24 US US744087A patent/US3134753A/en not_active Expired - Lifetime
-
1959
- 1959-06-23 JP JP2073959A patent/JPS3714645B1/ja active Pending
- 1959-06-23 DE DEG27341A patent/DE1145360B/de active Pending
- 1959-06-24 GB GB19526/59A patent/GB930992A/en not_active Expired
- 1959-06-24 FR FR798380A patent/FR1234336A/fr not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4868283A (en) * | 1986-08-29 | 1989-09-19 | Huls Aktiengesellschaft | Process for the production of polyphenylene ethers with reduced inherent color |
Also Published As
Publication number | Publication date |
---|---|
US3134753A (en) | 1964-05-26 |
DE1145360B (de) | 1963-03-14 |
FR1234336A (fr) | 1960-10-17 |
JPS3714645B1 (en, 2012) | 1962-09-20 |
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