GB914732A - New cyclopentano-naphthalene derivatives and their formation - Google Patents

New cyclopentano-naphthalene derivatives and their formation

Info

Publication number
GB914732A
GB914732A GB2121260A GB2121260A GB914732A GB 914732 A GB914732 A GB 914732A GB 2121260 A GB2121260 A GB 2121260A GB 2121260 A GB2121260 A GB 2121260A GB 914732 A GB914732 A GB 914732A
Authority
GB
United Kingdom
Prior art keywords
cyclopentano
keto
acyloxy
hexahydro
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2121260A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of GB914732A publication Critical patent/GB914732A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J75/00Processes for the preparation of steroids in general

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises 1-acyloxy-6-keto-7-(g - keto - butyl)-9a-methyl-3a,3b,4,5,8,9-hexahydro-cyclopentano-[2,1, c]-naphthalenes of the formula <FORM:0914732/IV (b)/1> where -OAc represents an acyloxy radical derived from an aliphatic, araliphatic or aromatic carboxylic acid and a process for their preparation which comprises condensing a 1-acyloxy - 6 - keto-9a-methyl-3a,4,5,7,8,9-hexahydro-cyclopentano - [2,1,c] - naphthalene with a ,g -dichloro-2-butene to form the corresponding 1-acyloxy-6-keto-7-(g -chloro-2-butenyl)-9a-methyl - 3a,4,5,7,8,9 - hexahydro-cyclopentano-[2,1,c]-naphthalene and hydrolysing the latter compound. In the example, in which the benzoyloxy compound is prepared, the condensation is carried out in toluene in the presence of sodium tert. amylate and the hydrolysis by means of sulphuric acid. Specifications 901,851, 914,733 and 914,739 are referred to.
GB2121260A 1959-06-18 1960-06-16 New cyclopentano-naphthalene derivatives and their formation Expired GB914732A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR797892A FR1237293A (en) 1959-06-18 1959-06-18 Process for the preparation of novel cyclopentanonaphthalene derivatives and products thus obtained

Publications (1)

Publication Number Publication Date
GB914732A true GB914732A (en) 1963-01-02

Family

ID=8716204

Family Applications (2)

Application Number Title Priority Date Filing Date
GB2121260A Expired GB914732A (en) 1959-06-18 1960-06-16 New cyclopentano-naphthalene derivatives and their formation
GB3445861A Expired GB914739A (en) 1959-06-18 1960-06-16 New cyclopentano-naphthalene derivatives and processes for their production

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB3445861A Expired GB914739A (en) 1959-06-18 1960-06-16 New cyclopentano-naphthalene derivatives and processes for their production

Country Status (5)

Country Link
BE (1) BE592003A (en)
CH (1) CH395067A (en)
ES (1) ES259015A1 (en)
FR (1) FR1237293A (en)
GB (2) GB914732A (en)

Also Published As

Publication number Publication date
ES259015A1 (en) 1960-10-16
CH395067A (en) 1965-07-15
FR1237293A (en) 1960-07-29
GB914739A (en) 1963-01-02
BE592003A (en) 1960-12-19

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